An analysis of a 68-year monthly hindcast output from an eddy-resolving ocean general circulation model reveals the relationship between the interannual variability of the Kerama Gap transport(KGT)and the Kuroshio/Ryu...An analysis of a 68-year monthly hindcast output from an eddy-resolving ocean general circulation model reveals the relationship between the interannual variability of the Kerama Gap transport(KGT)and the Kuroshio/Ryukyu Current system.The study found a significant difference in the interannual variability of the upstream and downstream transports of the East China Sea-(ECS-)Kuroshio and the Ryukyu Current.The interannual variability of the KGT was found to be of paramount importance in causing the differences between the upstream and downstream ECS-Kuroshio.Additionally,it contributed approximately 37%to the variability of the Ryukyu Current.The interannual variability of the KGT was well described by a two-layer rotating hydraulic theory.It was dominated by its subsurface-intensified flow core,and the upper layer transport made a weaker negative contribution to the total KGT.The subsurface flow core was found to be mainly driven by the subsurface pressure head across the Kerama Gap,and the pressure head was further dominated by the subsurface density anomalies on the Pacific side.These density anomalies could be traced back to the eastern open ocean,and their propagation speed was estimated to be about 7.4 km/d,which is consistent with the speed of the local first-order baroclinic Rossby wave.When the negative(positive)density anomaly signal reached the southern region of the Kerama Gap,it triggered the increase(decrease)of the KGT towards the Pacific side and the formation of an anticyclonic(cyclonic)vortex by baroclinic adjustment.Meanwhile,there is an increase(decrease)in the upstream transport of the entire Kuroshio/Ryukyu Current system and an offshore flow that decreases(increases)the downstream Ryukyu Current.展开更多
With the introduction of Poisson's ratio in the expression of Young's modulus,nearly all the theoretical values of the various elastic moduli for the alkaline earth metals and rare earth elements can be greatl...With the introduction of Poisson's ratio in the expression of Young's modulus,nearly all the theoretical values of the various elastic moduli for the alkaline earth metals and rare earth elements can be greatly refined, with the single exception of the theoreticalvalue of Young's modulus for Pr which is slightly increased This points to the validityof the new theory, that the bulk modulus is independent of the Poisson's ratio, and further that the valency electron structures of solids as determined by Yu's theory are correct.展开更多
A modern view of the properties of chemical elements has confirmed the theory of the hot origin of the Earth. The next step in developing this theory was the hypothesis of the initial hydride Earth. In this work, we a...A modern view of the properties of chemical elements has confirmed the theory of the hot origin of the Earth. The next step in developing this theory was the hypothesis of the initial hydride Earth. In this work, we attempted to find additional evidence for this hypothesis and show additional effects that flow from it. The effect of the physical properties of atoms and ions on their behavior during the formation of the Earth was studied. The maximum contribution to the distribution of elements was made by those elements whose content in the original protoplanets of the disk was the maximum. Correlation dependence is obtained, which allows one to calculate the distribution of elements in the protoplanetary disk. It was shown that hydrogen was the main element in the proto substance located in the zone of the Earth’s formation. In this case, various chemical compounds formed, most represented by hydrogen compounds—hydrides. Since the pressure inside the Earth is 375 GPa, this factor forces the chemical compounds to adopt stoichiometry and structure that would not be available in atmospheric conditions. It is shown that many chemical elements at high pressure in a hydrogen medium form simple hydrides and super hydrides—polyhydrides with high hydrogen content. Pressure leads to a higher density of matter inside the planet. Given the possibility of forming polyhydrides, there is the possibility of binding the initially available hydrogen in an amount that can reach 49.3 mole%. Young Earth could contain about 10.7 mass% of hydrogen in hydrides, polyhydrides, and adsorbed form is almost twice higher than previous estimates. This fact additionally confirms the theory of the original hydride Earth. In hydrides, the occurrence of the phenomenon of superconductivity was discovered. Polyhydrides were shown as potential superconductors with a high critical temperature above 200 K. We, based on these data, hypothesized the presence of superconducting properties in the Earth’s core, which explains the presence of a magnetic field in the Earth, as well as the unevenness and instability of this field and the possibility of migration of the Earth’s poles. The fact that the Earth has a hydroid core causes its change in time due to the instability of hydrides. Arranged several possible models of the destruction of the Earth’s core. The calculations showed that both models give close results. These results give predictions that can be measured. The proposed models also made it possible to estimate the initial size of the Earth. Possible ways of further testing the hypothesis of the initial hydride Earth is shown.展开更多
Recently, effects of Earth's curvature and radial heterogeneity on coseismic deformations are often investi- gated based on the 2004 Sumatra earthquake. However, such effects are strongly related to earthquake types....Recently, effects of Earth's curvature and radial heterogeneity on coseismic deformations are often investi- gated based on the 2004 Sumatra earthquake. However, such effects are strongly related to earthquake types. As a low dip angle event, the 2004 Sumatra earthquake is not a good seismic case for such a topic since the effects for moderate dip angle events are much bigger. In this study, the half-space and spherical dislocation theories are used, respectively, to calculate co- seismic displacements caused by the 2008 Wenchuan earthquake and the 2004 Sumatra earthquake. Effects of Earth's curva- ture and stratification are investigated through the discrepancies of results calculated using the two dislocation theories. Re- sults show that the effects of Earth's curvature and stratification for the 2008 Wenchuan earthquake are much larger than those for the 2004 Sumatra earthquake. Ignoring the effects will cause errors up to 100%-200% in far field displacements for a moderate dip angle event like the 2008 Wenchuan earthquake. Such great effects are much bigger than those conclusions of previous studies. Besides, comparison with observations verifies that spherical dislocation theories yield better results than half-space ones in far fields.展开更多
Er^(3+)-doped heavy metal oxyfluoride silicate glass was fabricated and characterized, and the absorption spectrum and fluorescence spectrum of the glass were studied. The Judd-Ofelt intensity parameters Ω_t (t =2, ...Er^(3+)-doped heavy metal oxyfluoride silicate glass was fabricated and characterized, and the absorption spectrum and fluorescence spectrum of the glass were studied. The Judd-Ofelt intensity parameters Ω_t (t =2, 4, 6), spontaneous transition probability, fluorescence branching ratio and radiative lifetime of each energy levels for Er^(3+) were calculated by Judd-Ofelt theory, and stimulated emission cross-section of (()~4I_(13/2))→(()~4I_(15/2)) transition was calculated by McCumber theory. The results show that fluorescence full width at half maximum and stimulated emission cross-section of Er^(3+)-doped heavy metal oxyfluoride silicate glass are broad and large, respectively. Compared with other host glasses, the gain bandwidth property of Er^(3+)-doped heavy metal oxyfluoride silicate glass is close to those of tellurite and bismuth glasses, and has advantage over those of silicate, phosphate and germante glasses.展开更多
The structural,electronic,and magnetic properties of the Nd-doped Rare earth aluminate,La1-xNdxAlO3(x = 0%to 100%) alloys are studied using the full potential linearized augmented plane wave(FP-LAPW) method within...The structural,electronic,and magnetic properties of the Nd-doped Rare earth aluminate,La1-xNdxAlO3(x = 0%to 100%) alloys are studied using the full potential linearized augmented plane wave(FP-LAPW) method within the density functional theory.The effects of the Nd substitution in La AlO3 are studied using the supercell calculations.The computed electronic structure with the modified Becke–Johnson(m BJ) potential based approximation indicates that the La1-xNdxAlO3 alloys may possess half-metallic(HM) behaviors when doped with Nd of a finite density of states at the Fermi level(EF).The direct and indirect band gaps are studied each as a function of x which is the concentration of Nddoped La AlO3.The calculated magnetic moments in the La1-xNdxAlO3 alloys are found to arise mainly from the Nd-4f state.A probable half-metallic nature is suggested for each of these systems with supportive integral magnetic moments and highly spin-polarized electronic structures in these doped systems at EF.The observed decrease of the band gap with the increase in the concentration of Nd doping in La AlO3 is a suitable technique for harnessing useful spintronic and magnetic devices.展开更多
We put forward a first-principles density-functional theory about the impact of pressure on the structural and elastic properties of bulk CaN2,SrN2 and BaN2.The ground state properties of three alkaline earth diazenid...We put forward a first-principles density-functional theory about the impact of pressure on the structural and elastic properties of bulk CaN2,SrN2 and BaN2.The ground state properties of three alkaline earth diazenides were obtained,and these were in good agreement with previous experimental and theoretical data.By using the quasi-harmonic Debye model,the thermodynamic properties including the debye temperature ΘD,thermal expansion coefficient α,and gruneisen parameter y are successfully obtained in the temperature range from 0 to 100 K and pressure range from 0 to 100 GPa,respectively.The optical properties including dielectric function ε(ω),absorption coefficient α(ω),reflectivity coefficient R(ω),and refractive index n(ω) are also calculated and analyzed.展开更多
The authors have proposed a new of magnetic isotope theory of life on Earth. According to this theory the initial impetus for the beginning of the synthesis of organic compounds is the impact of electromagnetic radiat...The authors have proposed a new of magnetic isotope theory of life on Earth. According to this theory the initial impetus for the beginning of the synthesis of organic compounds is the impact of electromagnetic radiation from the sun and energy radioactive isotopes.展开更多
Kuo,Yeh-Tzu founded Taiwan’s Sung Shan Tsu Huei Temple in 1970.She organized more than 200 worshipers as a group named“Taiwan Tsu Huei Temple Queen Mother of the West Delegation to China to Worship at the Ancestral ...Kuo,Yeh-Tzu founded Taiwan’s Sung Shan Tsu Huei Temple in 1970.She organized more than 200 worshipers as a group named“Taiwan Tsu Huei Temple Queen Mother of the West Delegation to China to Worship at the Ancestral Temples”in 1990.At that time,the temple building of the Queen Mother Palace in Huishan of Gansu Province was in disrepair,and Temple Master Kuo,Yeh-Tzu made a vow to rebuild it.Rebuilding the ancestral temple began in 1992 and was completed in 1994.It was the first case of a Taiwan temple financing the rebuilding of a far-away Queen Mother Palace with its own donations.In addition,Sung Shan Tsu Huei Temple celebrated its 45th anniversary and hosted Yiwei Yuanheng Lizhen Daluo Tiandi Qingjiao(Momentous and Fortuitous Heaven and Earth Prayer Ceremony)in 2015.This is the most important and the grandest blessing ceremony of Taoism,a rare event for Taoism locally and abroad during this century.Those sacred rituals were replete with unprecedented grand wishes to propagate the belief in Queen Mother of the West.Stopping at nothing,Queen Mother’s love never ceases.展开更多
The density of states (DOS) of 17 kinds of rare earths (RE) doped rutile TiO2 was by using first-principles density functional theory (DFT) calculation. The band gap widths of RE doped futile TiO2 were important...The density of states (DOS) of 17 kinds of rare earths (RE) doped rutile TiO2 was by using first-principles density functional theory (DFT) calculation. The band gap widths of RE doped futile TiO2 were important factors for altering their absorbing wavelengths. The results show that RE ions could obviously reduce the band gap widths and form of energy of ruffle TiO2 except Lu, Y, Yb and Sc, and the order of absorbing wavelengths of RE doped ruffle TiO2 were the same as that of the results of calculation. The ratio of RE dopant was another important factor for the photo catalytic 'activity of RE doped rutile TiO2, and there was an optimal ratio of dopant. There was a constant for predigesting the calculation difficulty, respectively, which were 0.5mol.% and 100 mol^-1 under supposition. The band gap widths of RE doped rutile TiOz by DFT calculation were much larger than that by experiment. Finally, by transferring the calculation values to experiment values, it could be found and predicted that RE enlarged obviously the absorbing wavelengh of ruffle TiO2. In addition, the degree of RE ions edging out the Ti atom using the parameters of RE dements was computed.展开更多
Two kinds of Eu-complexes, Eu(TTA)2(Phen)(AA) and Eu(TTA)2(Phen)(MA) (HTTA=2-Thenoyltrifluoroacetone, Phen=1,10- phenanthroline, AA=acrylic acid, MA=Maleic anhydride), which combined the excellent fluore...Two kinds of Eu-complexes, Eu(TTA)2(Phen)(AA) and Eu(TTA)2(Phen)(MA) (HTTA=2-Thenoyltrifluoroacetone, Phen=1,10- phenanthroline, AA=acrylic acid, MA=Maleic anhydride), which combined the excellent fluorescence properties of Eu(TTA)2(Phen)(H2O) and the reactivity of acrylic acid and maleic anhydride with radicals, were synthesized. The two complexes were characterized by elemental analysis, infrared (IR) spectra, and X-ray photoelectron spectroscopy (XPS). Based on the data shown from the fluorescent spectra of the Eu-MA and Eu-AA complexes, the Ωλ (λ=2 and 4) experimental intensity parameters were calculated. The results demonstrated that the Ω2 intensity parameters for the two complexes were smaller than those for the Eu(TTA)2(Phen)(H2O) complex, indicating that a less symmetrical chemical environment existed in the complexes. It implied that the radiative efficiency of the ^5D0 of these two complexes could be enhanced by ligand of MA and AA, respectively. The luminescent lifetime of the Eu-AA (r=-7.26×10^-4 s) or Eu-MA complex (r=-8.12×10^-4 s) was higher than that of the Eu(TTA)2(Phen)(H2O) complex, which was attributed to the substitution of the water molecule (H2O) in Eu(TTA)2(Phen)(H2O) by the MA or AA ligand.展开更多
The fundamental theoretical framework of the Multisphere Tectonics of the Earth System is as follows:(1)It intends to extend the geotectonic studies from the crustal and lithospheric tectonics to the multisphere tecto...The fundamental theoretical framework of the Multisphere Tectonics of the Earth System is as follows:(1)It intends to extend the geotectonic studies from the crustal and lithospheric tectonics to the multisphere tectonics of the Ear th system as a whole.(2)The global dynamics driven by both the Earth system and the cosmic celestial system:solar energy,multispheric interactions of the Earth system and the combined effects of the motions of celestial bodies in the cosmos syste m are the driving forces of various geological processes.(3)The Continent-Ocean transformation theory:the continent and ocean are two opposite yet unified geological units,which can be transformed into each other;neither continent nor ocean wi ll survive forever;there is no one-way development of continental accretion or ocean extinction;the simple theory of one-way continental accretion is regarded as invalid.(4)The continental crust and mantle are characterized by multiple layers,with different layers liable to slide along the interfaces between them,but corroboration is needed that continents move as a who le or even drift freely.(5)The cyclic evolution theory:the development of Earth’s tectonics is not a uniform change,but a spiral forward evolution,characterized by a combination of non-uniform,non-linear,gradual and catastrophic changes;different evolutionary stages(tectonic cycles)of Earth have distinctive global tectonic patterns and characteristics,one tectonic mo del should not be applied to different tectonic cycles or evolutionary stages.(6)The structure and evolution of Earth are asymmetric and heterogeneous,thus one tectonic model cannot be applied to different areas of the world.(7)The polycyclic evolution of the continental crust:the continental crust is formed by polycyclic tectonics and magmatism,rather than simply lateral or vertical accretion.(8)The role of deep faults:the deep fault zones cutting through different layers of the crus t a nd mantle usually play important roles in tectonic evolution.For example,the present-day mid-ocean ridge fault zones,transform fault zones and Benioff zones outline the global tectonic framework.Different tectonic cycles and stages of Earth’s evolutio n must have their own distinctive deep fault systems which control the global tectonic framework and evolutionary processes during different tectonic cycles and stages.Starting from the two mantle superplumes Jason(Pacific)and Tuzo(Africa),the study of the evolutionary process of the composition and structure of the crust and mantle during the great transformation an d reorganization of the Meso-Cenozoic tectonic framework in China and the other regions of Asia is a good demonstration of theory of Multisphere Tectonics of the Earth System.展开更多
Determination of distribution and magnitude of active earth pressure is crucial in retaining wall designs. A number of analytical theories on active earth pressure were presented. Yet, there are limited studies on com...Determination of distribution and magnitude of active earth pressure is crucial in retaining wall designs. A number of analytical theories on active earth pressure were presented. Yet, there are limited studies on comparison between the theories. In this work, comparison between the theories with finite element analysis is done using the PLAXIS software. The comparative results show that in terms of distribution and magnitude of active earth pressure, RANKINE's theory possesses the highest match to the PLAXIS analysis. Parametric studies were also done to study the responses of active earth pressure distribution to varying parameters Increasing soil friction angle and wall friction causes decrease in active earth pressure. In contrast, active earth pressure increases with increasing soil unit weight and height of wall. RANK/NE's theory has the highest compatibility to finite element analysis among all theories, and utilization of this theory leads to proficient retaining wall design.展开更多
This study aims to evaluate the significance of the Earth' s triaxiality to the polar motion theory. First of all, we compare the polar motion theories for both the triaxial and rotationally-symmetric Earth models, w...This study aims to evaluate the significance of the Earth' s triaxiality to the polar motion theory. First of all, we compare the polar motion theories for both the triaxial and rotationally-symmetric Earth models, which is established on the basis of the EGM2008 global gravity model and the MHB2000 Earth model. Then, we use the atmospheric and oceanic data (the NCEP/NCAR reanalyses and the ECCO assimulation products) to quantify the triaxiality effect on polar motion excitations. Numerical results imply that triaxiality only cause a small correction ( about 0. 1 - 0. 2 mas) to the geophysical excitations for the rotationally-symmetric case. The triaxiality correction is much smaller than the errors in the atmospheric and oceanic data, and thus can be neglected for recent studies on polar motion excitations.展开更多
The theoretical calculation of LaNi4Co, in which Co substituted for Ni at various sites, was performed by adopting the method of total energy based on the Density Functional Theory. The augmented plane wave function w...The theoretical calculation of LaNi4Co, in which Co substituted for Ni at various sites, was performed by adopting the method of total energy based on the Density Functional Theory. The augmented plane wave function was selected as a basis set in combination with Ultra-soft Pseudopotential technology. The geometry of LaNi5 was optimized and the parameters and properties of the structure were given. The theoretical results accord well with experiments. This method provides a theoretical approach for the structure prediction of such alloy. The calculations of total energy, electronic density of states and Mulliken population of LaNi4Co were carried out. The electronic structure of LaNi4Co and the change of the electronic structure due to the Co-substitution in LaNi5 alloy were analyzed from the calculated results. The stability of the alloy in which Ni was partially substituted by Co at various sites was compared and the factors controlling stability were discussed. The theoretical value of formation heat was calculated.展开更多
By the application of earth ecosystem theory, three complementary mechanisms of earth ecosystem and ecological power of North Pacific are elaborated fully. Aided by three ecological sub-systems of earth ecosystem: te...By the application of earth ecosystem theory, three complementary mechanisms of earth ecosystem and ecological power of North Pacific are elaborated fully. Aided by three ecological sub-systems of earth ecosystem: terrestrial ecosystem, marine ecosystem and atmospheric ecosystem, running track of Si is showed. Under the theoretical guidance of three complementary mechanisms of earth ecosystem, we predict future climate mode of the earth, and climate in 2010 gave confirm. Therefore, the theoretical system of earth ecosystem is conductive to studying global issues, including change processes and tendencies of resource, ecology, environment and disaster. Then, it is beneficial to human healthy survival and sustainable development of the earth ecosystem.展开更多
The Deep Resources Exploration and Mining(DREAM)grant program,within the framework of The National Key Research and Development Program grants,is a pillar to implement China’s science and technology strategy in the a...The Deep Resources Exploration and Mining(DREAM)grant program,within the framework of The National Key Research and Development Program grants,is a pillar to implement China’s science and technology strategy in the area of deep resources exploitation.To tackle the insufficient of theories and technologies for the 1000-meter-deep mining,a section of mining,covering the research of basic theories,general technologies and application demonstration,was arranged in the layout of DREAM under the principle of"whole chain design,integrated implementation".In the aspect of basic research,DREAM mainly focused on the deep rock mechanics and mining theory,such as the in-situ mechanical behavior of deep rock,deep high stress induction and energy regulation theory.For the general and key technologies,DREAM supported the research on the mine construction and hoisting,excavation,rock breaking,mining methods and mining safety according to the characteristics of coal and metal mines.For the demonstration application,taking green,safe and efficient as the starting point,DREAM aimed at the green,safe and high efficiency mining,and the demonstration and leading role projects such as the low-waste and high-efficiency back fill mining.Since 2016,10 R&D projects have been funded,and 122 institutional participants with a total budget of RMB 235 million from the central government and RMB 480 million from enterprises as well as local governments have been involved.It is expected that the mining section of DREAM would contribute to establishing the theory and technology system in the area of deep mining and promoting the ability of deep resource exploitation in China.展开更多
Time dependent nucleation theory was applied to calculate the incubation time required for α Al nucleation in rapid solidified (RS) Al Fe V Si Nd alloys. The nucleation rates were calculated as a function of tem...Time dependent nucleation theory was applied to calculate the incubation time required for α Al nucleation in rapid solidified (RS) Al Fe V Si Nd alloys. The nucleation rates were calculated as a function of temperature, and the critical cooling rates required for the formation of amorphous α Al at different neodymium concentrations were calculated too. The addition of neodymium increases the amorphizablity of α Al by increasing the incubation time and decreasing the nucleation rate and the critical cooling rate. The calculations are fitted to experimental results when liquidus temperatures are estimated from an approximation, which treats Al Fe V Si Nd as quasi binary Al Fe system.展开更多
We used density functional theory(DFT)calculations to study the influence of alkali earth metal element(AE)doping on the crystal structure and electronic band structure ofα-Si3N4.The diversity of atomic radii of alka...We used density functional theory(DFT)calculations to study the influence of alkali earth metal element(AE)doping on the crystal structure and electronic band structure ofα-Si3N4.The diversity of atomic radii of alkaline earth metal elements results in structural expansion when they were doped into theα-Si3N4 lattice.Formation energies of the doped structures indicate that dopants prefer to occupy the interstitial site under the nitrogen-deficient environment,while substitute Si under the nitrogen-rich environment,which provides a guide to synthesizingα-Si3N4 with different doping types by controlling nitrogen conditions.For electronic structures,energy levels of the dopants appear in the bottom of the conduction band or the top of the valence band or the forbidden band,which reduces the bandgap ofα-Si3N4.展开更多
基金The Fundamental Research Funds for the Central Universities under contract No.B220201024.
文摘An analysis of a 68-year monthly hindcast output from an eddy-resolving ocean general circulation model reveals the relationship between the interannual variability of the Kerama Gap transport(KGT)and the Kuroshio/Ryukyu Current system.The study found a significant difference in the interannual variability of the upstream and downstream transports of the East China Sea-(ECS-)Kuroshio and the Ryukyu Current.The interannual variability of the KGT was found to be of paramount importance in causing the differences between the upstream and downstream ECS-Kuroshio.Additionally,it contributed approximately 37%to the variability of the Ryukyu Current.The interannual variability of the KGT was well described by a two-layer rotating hydraulic theory.It was dominated by its subsurface-intensified flow core,and the upper layer transport made a weaker negative contribution to the total KGT.The subsurface flow core was found to be mainly driven by the subsurface pressure head across the Kerama Gap,and the pressure head was further dominated by the subsurface density anomalies on the Pacific side.These density anomalies could be traced back to the eastern open ocean,and their propagation speed was estimated to be about 7.4 km/d,which is consistent with the speed of the local first-order baroclinic Rossby wave.When the negative(positive)density anomaly signal reached the southern region of the Kerama Gap,it triggered the increase(decrease)of the KGT towards the Pacific side and the formation of an anticyclonic(cyclonic)vortex by baroclinic adjustment.Meanwhile,there is an increase(decrease)in the upstream transport of the entire Kuroshio/Ryukyu Current system and an offshore flow that decreases(increases)the downstream Ryukyu Current.
文摘With the introduction of Poisson's ratio in the expression of Young's modulus,nearly all the theoretical values of the various elastic moduli for the alkaline earth metals and rare earth elements can be greatly refined, with the single exception of the theoreticalvalue of Young's modulus for Pr which is slightly increased This points to the validityof the new theory, that the bulk modulus is independent of the Poisson's ratio, and further that the valency electron structures of solids as determined by Yu's theory are correct.
文摘A modern view of the properties of chemical elements has confirmed the theory of the hot origin of the Earth. The next step in developing this theory was the hypothesis of the initial hydride Earth. In this work, we attempted to find additional evidence for this hypothesis and show additional effects that flow from it. The effect of the physical properties of atoms and ions on their behavior during the formation of the Earth was studied. The maximum contribution to the distribution of elements was made by those elements whose content in the original protoplanets of the disk was the maximum. Correlation dependence is obtained, which allows one to calculate the distribution of elements in the protoplanetary disk. It was shown that hydrogen was the main element in the proto substance located in the zone of the Earth’s formation. In this case, various chemical compounds formed, most represented by hydrogen compounds—hydrides. Since the pressure inside the Earth is 375 GPa, this factor forces the chemical compounds to adopt stoichiometry and structure that would not be available in atmospheric conditions. It is shown that many chemical elements at high pressure in a hydrogen medium form simple hydrides and super hydrides—polyhydrides with high hydrogen content. Pressure leads to a higher density of matter inside the planet. Given the possibility of forming polyhydrides, there is the possibility of binding the initially available hydrogen in an amount that can reach 49.3 mole%. Young Earth could contain about 10.7 mass% of hydrogen in hydrides, polyhydrides, and adsorbed form is almost twice higher than previous estimates. This fact additionally confirms the theory of the original hydride Earth. In hydrides, the occurrence of the phenomenon of superconductivity was discovered. Polyhydrides were shown as potential superconductors with a high critical temperature above 200 K. We, based on these data, hypothesized the presence of superconducting properties in the Earth’s core, which explains the presence of a magnetic field in the Earth, as well as the unevenness and instability of this field and the possibility of migration of the Earth’s poles. The fact that the Earth has a hydroid core causes its change in time due to the instability of hydrides. Arranged several possible models of the destruction of the Earth’s core. The calculations showed that both models give close results. These results give predictions that can be measured. The proposed models also made it possible to estimate the initial size of the Earth. Possible ways of further testing the hypothesis of the initial hydride Earth is shown.
基金supported by Grant-in-Aid for JSPS Fellows (No2008025)Basic Research Foundation from Institute of Earthquake Science (No0210240101)
文摘Recently, effects of Earth's curvature and radial heterogeneity on coseismic deformations are often investi- gated based on the 2004 Sumatra earthquake. However, such effects are strongly related to earthquake types. As a low dip angle event, the 2004 Sumatra earthquake is not a good seismic case for such a topic since the effects for moderate dip angle events are much bigger. In this study, the half-space and spherical dislocation theories are used, respectively, to calculate co- seismic displacements caused by the 2008 Wenchuan earthquake and the 2004 Sumatra earthquake. Effects of Earth's curva- ture and stratification are investigated through the discrepancies of results calculated using the two dislocation theories. Re- sults show that the effects of Earth's curvature and stratification for the 2008 Wenchuan earthquake are much larger than those for the 2004 Sumatra earthquake. Ignoring the effects will cause errors up to 100%-200% in far field displacements for a moderate dip angle event like the 2008 Wenchuan earthquake. Such great effects are much bigger than those conclusions of previous studies. Besides, comparison with observations verifies that spherical dislocation theories yield better results than half-space ones in far fields.
文摘Er^(3+)-doped heavy metal oxyfluoride silicate glass was fabricated and characterized, and the absorption spectrum and fluorescence spectrum of the glass were studied. The Judd-Ofelt intensity parameters Ω_t (t =2, 4, 6), spontaneous transition probability, fluorescence branching ratio and radiative lifetime of each energy levels for Er^(3+) were calculated by Judd-Ofelt theory, and stimulated emission cross-section of (()~4I_(13/2))→(()~4I_(15/2)) transition was calculated by McCumber theory. The results show that fluorescence full width at half maximum and stimulated emission cross-section of Er^(3+)-doped heavy metal oxyfluoride silicate glass are broad and large, respectively. Compared with other host glasses, the gain bandwidth property of Er^(3+)-doped heavy metal oxyfluoride silicate glass is close to those of tellurite and bismuth glasses, and has advantage over those of silicate, phosphate and germante glasses.
基金Project supported by the DST-SERB,Dy(Grant No.SERB/3586/2013-14)the UGCBSR,FRPS(Grant No.F.30-52/2014)+2 种基金the UGC(New Delhi,India)Inspire Fellowship DST(India)the Deanship of Scientific Research at King Saud University(Grant No.RPG-VPP-088)M P Ghimire thanks the Alexander von Humboldt Foundation,Germany for the financial support
文摘The structural,electronic,and magnetic properties of the Nd-doped Rare earth aluminate,La1-xNdxAlO3(x = 0%to 100%) alloys are studied using the full potential linearized augmented plane wave(FP-LAPW) method within the density functional theory.The effects of the Nd substitution in La AlO3 are studied using the supercell calculations.The computed electronic structure with the modified Becke–Johnson(m BJ) potential based approximation indicates that the La1-xNdxAlO3 alloys may possess half-metallic(HM) behaviors when doped with Nd of a finite density of states at the Fermi level(EF).The direct and indirect band gaps are studied each as a function of x which is the concentration of Nddoped La AlO3.The calculated magnetic moments in the La1-xNdxAlO3 alloys are found to arise mainly from the Nd-4f state.A probable half-metallic nature is suggested for each of these systems with supportive integral magnetic moments and highly spin-polarized electronic structures in these doped systems at EF.The observed decrease of the band gap with the increase in the concentration of Nd doping in La AlO3 is a suitable technique for harnessing useful spintronic and magnetic devices.
基金Funded by the Natural Science Foundation of Education Committee of Anhui Province(No.KJ2016B003)the National Key Laboratory Fund for Shock Wave and Detonation Physics Research of the China Academy of Engineering Physics(No.9140C671101110C6709)+1 种基金the Defense Industrial Technology Development Program of China(No.B1520110002)the National Basic Research Program of China(No.2010CB731600)
文摘We put forward a first-principles density-functional theory about the impact of pressure on the structural and elastic properties of bulk CaN2,SrN2 and BaN2.The ground state properties of three alkaline earth diazenides were obtained,and these were in good agreement with previous experimental and theoretical data.By using the quasi-harmonic Debye model,the thermodynamic properties including the debye temperature ΘD,thermal expansion coefficient α,and gruneisen parameter y are successfully obtained in the temperature range from 0 to 100 K and pressure range from 0 to 100 GPa,respectively.The optical properties including dielectric function ε(ω),absorption coefficient α(ω),reflectivity coefficient R(ω),and refractive index n(ω) are also calculated and analyzed.
文摘The authors have proposed a new of magnetic isotope theory of life on Earth. According to this theory the initial impetus for the beginning of the synthesis of organic compounds is the impact of electromagnetic radiation from the sun and energy radioactive isotopes.
文摘Kuo,Yeh-Tzu founded Taiwan’s Sung Shan Tsu Huei Temple in 1970.She organized more than 200 worshipers as a group named“Taiwan Tsu Huei Temple Queen Mother of the West Delegation to China to Worship at the Ancestral Temples”in 1990.At that time,the temple building of the Queen Mother Palace in Huishan of Gansu Province was in disrepair,and Temple Master Kuo,Yeh-Tzu made a vow to rebuild it.Rebuilding the ancestral temple began in 1992 and was completed in 1994.It was the first case of a Taiwan temple financing the rebuilding of a far-away Queen Mother Palace with its own donations.In addition,Sung Shan Tsu Huei Temple celebrated its 45th anniversary and hosted Yiwei Yuanheng Lizhen Daluo Tiandi Qingjiao(Momentous and Fortuitous Heaven and Earth Prayer Ceremony)in 2015.This is the most important and the grandest blessing ceremony of Taoism,a rare event for Taoism locally and abroad during this century.Those sacred rituals were replete with unprecedented grand wishes to propagate the belief in Queen Mother of the West.Stopping at nothing,Queen Mother’s love never ceases.
基金supported by the Education Commission of Sichuan Province of China (2006A099)the National Defense Basic Research Foundation of China (A3120080126)
文摘The density of states (DOS) of 17 kinds of rare earths (RE) doped rutile TiO2 was by using first-principles density functional theory (DFT) calculation. The band gap widths of RE doped futile TiO2 were important factors for altering their absorbing wavelengths. The results show that RE ions could obviously reduce the band gap widths and form of energy of ruffle TiO2 except Lu, Y, Yb and Sc, and the order of absorbing wavelengths of RE doped ruffle TiO2 were the same as that of the results of calculation. The ratio of RE dopant was another important factor for the photo catalytic 'activity of RE doped rutile TiO2, and there was an optimal ratio of dopant. There was a constant for predigesting the calculation difficulty, respectively, which were 0.5mol.% and 100 mol^-1 under supposition. The band gap widths of RE doped rutile TiOz by DFT calculation were much larger than that by experiment. Finally, by transferring the calculation values to experiment values, it could be found and predicted that RE enlarged obviously the absorbing wavelengh of ruffle TiO2. In addition, the degree of RE ions edging out the Ti atom using the parameters of RE dements was computed.
基金supported by the National Natural Science Foundation of China, China Energy Conservation Investment Corporation (50173004 and 50503002)Beijing New Star Project (2003A11)+3 种基金the National High-Tech Research Developing Foundation (863) (2003AA324030)Beijing Municipal Commission of Education (JD100100403)National Key Project of Scientific, Technical Supporting Programs Funded by the Ministry of Science & Technology of China (2006BAE03B)Program for New Century Excellent Talentsin University (NCET)
文摘Two kinds of Eu-complexes, Eu(TTA)2(Phen)(AA) and Eu(TTA)2(Phen)(MA) (HTTA=2-Thenoyltrifluoroacetone, Phen=1,10- phenanthroline, AA=acrylic acid, MA=Maleic anhydride), which combined the excellent fluorescence properties of Eu(TTA)2(Phen)(H2O) and the reactivity of acrylic acid and maleic anhydride with radicals, were synthesized. The two complexes were characterized by elemental analysis, infrared (IR) spectra, and X-ray photoelectron spectroscopy (XPS). Based on the data shown from the fluorescent spectra of the Eu-MA and Eu-AA complexes, the Ωλ (λ=2 and 4) experimental intensity parameters were calculated. The results demonstrated that the Ω2 intensity parameters for the two complexes were smaller than those for the Eu(TTA)2(Phen)(H2O) complex, indicating that a less symmetrical chemical environment existed in the complexes. It implied that the radiative efficiency of the ^5D0 of these two complexes could be enhanced by ligand of MA and AA, respectively. The luminescent lifetime of the Eu-AA (r=-7.26×10^-4 s) or Eu-MA complex (r=-8.12×10^-4 s) was higher than that of the Eu(TTA)2(Phen)(H2O) complex, which was attributed to the substitution of the water molecule (H2O) in Eu(TTA)2(Phen)(H2O) by the MA or AA ligand.
基金This work was funded by the Geological Survey Fund of the China Geological Survey(Grant Nos.DD20190358,DD20221646)the National Natural Science Foundation of China(Grant Nos.42172218,41772195).
文摘The fundamental theoretical framework of the Multisphere Tectonics of the Earth System is as follows:(1)It intends to extend the geotectonic studies from the crustal and lithospheric tectonics to the multisphere tectonics of the Ear th system as a whole.(2)The global dynamics driven by both the Earth system and the cosmic celestial system:solar energy,multispheric interactions of the Earth system and the combined effects of the motions of celestial bodies in the cosmos syste m are the driving forces of various geological processes.(3)The Continent-Ocean transformation theory:the continent and ocean are two opposite yet unified geological units,which can be transformed into each other;neither continent nor ocean wi ll survive forever;there is no one-way development of continental accretion or ocean extinction;the simple theory of one-way continental accretion is regarded as invalid.(4)The continental crust and mantle are characterized by multiple layers,with different layers liable to slide along the interfaces between them,but corroboration is needed that continents move as a who le or even drift freely.(5)The cyclic evolution theory:the development of Earth’s tectonics is not a uniform change,but a spiral forward evolution,characterized by a combination of non-uniform,non-linear,gradual and catastrophic changes;different evolutionary stages(tectonic cycles)of Earth have distinctive global tectonic patterns and characteristics,one tectonic mo del should not be applied to different tectonic cycles or evolutionary stages.(6)The structure and evolution of Earth are asymmetric and heterogeneous,thus one tectonic model cannot be applied to different areas of the world.(7)The polycyclic evolution of the continental crust:the continental crust is formed by polycyclic tectonics and magmatism,rather than simply lateral or vertical accretion.(8)The role of deep faults:the deep fault zones cutting through different layers of the crus t a nd mantle usually play important roles in tectonic evolution.For example,the present-day mid-ocean ridge fault zones,transform fault zones and Benioff zones outline the global tectonic framework.Different tectonic cycles and stages of Earth’s evolutio n must have their own distinctive deep fault systems which control the global tectonic framework and evolutionary processes during different tectonic cycles and stages.Starting from the two mantle superplumes Jason(Pacific)and Tuzo(Africa),the study of the evolutionary process of the composition and structure of the crust and mantle during the great transformation an d reorganization of the Meso-Cenozoic tectonic framework in China and the other regions of Asia is a good demonstration of theory of Multisphere Tectonics of the Earth System.
基金Project(RG086/10AET) supported by the Institute of Research Management and Monitoring,University of Malaya,Malaysia
文摘Determination of distribution and magnitude of active earth pressure is crucial in retaining wall designs. A number of analytical theories on active earth pressure were presented. Yet, there are limited studies on comparison between the theories. In this work, comparison between the theories with finite element analysis is done using the PLAXIS software. The comparative results show that in terms of distribution and magnitude of active earth pressure, RANKINE's theory possesses the highest match to the PLAXIS analysis. Parametric studies were also done to study the responses of active earth pressure distribution to varying parameters Increasing soil friction angle and wall friction causes decrease in active earth pressure. In contrast, active earth pressure increases with increasing soil unit weight and height of wall. RANK/NE's theory has the highest compatibility to finite element analysis among all theories, and utilization of this theory leads to proficient retaining wall design.
基金supported by the National Natural Science Foundation of China (41174011)
文摘This study aims to evaluate the significance of the Earth' s triaxiality to the polar motion theory. First of all, we compare the polar motion theories for both the triaxial and rotationally-symmetric Earth models, which is established on the basis of the EGM2008 global gravity model and the MHB2000 Earth model. Then, we use the atmospheric and oceanic data (the NCEP/NCAR reanalyses and the ECCO assimulation products) to quantify the triaxiality effect on polar motion excitations. Numerical results imply that triaxiality only cause a small correction ( about 0. 1 - 0. 2 mas) to the geophysical excitations for the rotationally-symmetric case. The triaxiality correction is much smaller than the errors in the atmospheric and oceanic data, and thus can be neglected for recent studies on polar motion excitations.
文摘The theoretical calculation of LaNi4Co, in which Co substituted for Ni at various sites, was performed by adopting the method of total energy based on the Density Functional Theory. The augmented plane wave function was selected as a basis set in combination with Ultra-soft Pseudopotential technology. The geometry of LaNi5 was optimized and the parameters and properties of the structure were given. The theoretical results accord well with experiments. This method provides a theoretical approach for the structure prediction of such alloy. The calculations of total energy, electronic density of states and Mulliken population of LaNi4Co were carried out. The electronic structure of LaNi4Co and the change of the electronic structure due to the Co-substitution in LaNi5 alloy were analyzed from the calculated results. The stability of the alloy in which Ni was partially substituted by Co at various sites was compared and the factors controlling stability were discussed. The theoretical value of formation heat was calculated.
基金Supported by Education Ministry's New Century Excellent Talents Supporting Plan(NCET-12-0659)Project of Outstanding Technological Educators of Governor of Guizhou([2012]71)+3 种基金Project of Low Carbon Technology Plan of Guiyang(2012205)Project of Science and Technology Foundation of Guiyang(LKM[2012]05)Special Research Projects of High Level Talents of Guizhou Province(TZJF-2011-44)Research Projects of Guizhou Minzu University([2014]02)
文摘By the application of earth ecosystem theory, three complementary mechanisms of earth ecosystem and ecological power of North Pacific are elaborated fully. Aided by three ecological sub-systems of earth ecosystem: terrestrial ecosystem, marine ecosystem and atmospheric ecosystem, running track of Si is showed. Under the theoretical guidance of three complementary mechanisms of earth ecosystem, we predict future climate mode of the earth, and climate in 2010 gave confirm. Therefore, the theoretical system of earth ecosystem is conductive to studying global issues, including change processes and tendencies of resource, ecology, environment and disaster. Then, it is beneficial to human healthy survival and sustainable development of the earth ecosystem.
基金Research project supported by the Implementation Rules of the Interim Measures for National Key R&D Program of China。
文摘The Deep Resources Exploration and Mining(DREAM)grant program,within the framework of The National Key Research and Development Program grants,is a pillar to implement China’s science and technology strategy in the area of deep resources exploitation.To tackle the insufficient of theories and technologies for the 1000-meter-deep mining,a section of mining,covering the research of basic theories,general technologies and application demonstration,was arranged in the layout of DREAM under the principle of"whole chain design,integrated implementation".In the aspect of basic research,DREAM mainly focused on the deep rock mechanics and mining theory,such as the in-situ mechanical behavior of deep rock,deep high stress induction and energy regulation theory.For the general and key technologies,DREAM supported the research on the mine construction and hoisting,excavation,rock breaking,mining methods and mining safety according to the characteristics of coal and metal mines.For the demonstration application,taking green,safe and efficient as the starting point,DREAM aimed at the green,safe and high efficiency mining,and the demonstration and leading role projects such as the low-waste and high-efficiency back fill mining.Since 2016,10 R&D projects have been funded,and 122 institutional participants with a total budget of RMB 235 million from the central government and RMB 480 million from enterprises as well as local governments have been involved.It is expected that the mining section of DREAM would contribute to establishing the theory and technology system in the area of deep mining and promoting the ability of deep resource exploitation in China.
基金Project supported by the National Natural Science Foundation of China(55791020)
文摘Time dependent nucleation theory was applied to calculate the incubation time required for α Al nucleation in rapid solidified (RS) Al Fe V Si Nd alloys. The nucleation rates were calculated as a function of temperature, and the critical cooling rates required for the formation of amorphous α Al at different neodymium concentrations were calculated too. The addition of neodymium increases the amorphizablity of α Al by increasing the incubation time and decreasing the nucleation rate and the critical cooling rate. The calculations are fitted to experimental results when liquidus temperatures are estimated from an approximation, which treats Al Fe V Si Nd as quasi binary Al Fe system.
基金Funded by National Key Research and Development Program of China(No.2017YFB0310400)the National Natural Science Foundation of China(Nos.51872217,51932006,51972246 and 51521001)+3 种基金Fundamental Research Funds for the Central Universities in ChinaState Key Laboratory of Advanced Electromagnetic Engineering and Technology(Huazhong University of Science and Technology),the Joint Fund(No.6141A02022255)the Major Program of the Specialized Technological Innovation of HuBei Province,China(No.2019AFA176)the“111”Project(No.B13035)。
文摘We used density functional theory(DFT)calculations to study the influence of alkali earth metal element(AE)doping on the crystal structure and electronic band structure ofα-Si3N4.The diversity of atomic radii of alkaline earth metal elements results in structural expansion when they were doped into theα-Si3N4 lattice.Formation energies of the doped structures indicate that dopants prefer to occupy the interstitial site under the nitrogen-deficient environment,while substitute Si under the nitrogen-rich environment,which provides a guide to synthesizingα-Si3N4 with different doping types by controlling nitrogen conditions.For electronic structures,energy levels of the dopants appear in the bottom of the conduction band or the top of the valence band or the forbidden band,which reduces the bandgap ofα-Si3N4.