The thermal stability of New Zealand culture rabbit muscle aldolase was investigated by differential scanning calorimetry in the water content range 0.23-3.70 g water per g protein.The experimental results showed that...The thermal stability of New Zealand culture rabbit muscle aldolase was investigated by differential scanning calorimetry in the water content range 0.23-3.70 g water per g protein.The experimental results showed that at water contents below 0.47g/g,an endothermic peak was observed and at water contents above 0.57g/g,an endothermic and an exothermic peak were both observed on DSC thermogram.Thermal denaturation result of the enzyme and the relationship between two transition temperatures and water contents were first reported in this paper.Up to now we have not seen any similar reports concerning the exothermic transition.展开更多
The concentrically layered thermal cloaks with isotropic materials could realize the equivalent thermal cloaking effect with Pendry's cloak, while the effectiveness is scarcely investigated quantitatively. Here we ex...The concentrically layered thermal cloaks with isotropic materials could realize the equivalent thermal cloaking effect with Pendry's cloak, while the effectiveness is scarcely investigated quantitatively. Here we examine the cloaking effectiveness quantitatively by evaluating the standard deviation of the temperature difference between the simulated plane with the layered thermal cloak and Pendry's thermal cloak. The design rules for the isotropic materials in terms of thermal conductivity and layer thickness are presented. The present method could quan- titatively evaluate the cloaking effectiveness, and could open avenues for analyzing the cloaking effect, detecting the (anti-) cloaks, etc.展开更多
A non-dimensional secondary circulation equation for typhoons has been derived and then 11-yr com- positing typhoon data were used to estimate the thermally forced secondary circulation.The main results have been obta...A non-dimensional secondary circulation equation for typhoons has been derived and then 11-yr com- positing typhoon data were used to estimate the thermally forced secondary circulation.The main results have been obtained as follows: (1)The diabatic heating and Cu vertical heat mixing are major thermal forcing factors.They have the same magnitude of order.(2)The effects of eddy flux and Cu horizontal mixing of heat are of minor im- portance.(3)Ekman pumping and Cu vertical heat mixing cooperatively work.This feedback process is favorable for the enhancement of the secondary circulation of typhoons.展开更多
The evolved gaseous analysis (EGA),infrared spectra,and XRD have been applied to the study of solid state reactions of KSCN with five cobalt(Ⅲ)-ammine complexes:[Co- (NH_3)_5N_3]Cl_2,[Co(NH_3)_5(NO_2)]Cl_2,[Co(NH_3)_...The evolved gaseous analysis (EGA),infrared spectra,and XRD have been applied to the study of solid state reactions of KSCN with five cobalt(Ⅲ)-ammine complexes:[Co- (NH_3)_5N_3]Cl_2,[Co(NH_3)_5(NO_2)]Cl_2,[Co(NH_3)_5(H_2O)]Cl_3,[Co(NH_3)_5Cl]Cl_2,and [Co(NH_3)_6]Cl_3 in a hydrogen atmosphere.It is found that the existence of KSCN shifts the thermal decom- position of these complexes to a lower temperature.The corresponding peak temperatures are near 140℃.The effect of KSCN is discussed and kinetic parameters of deammine reactions are calculated.展开更多
基金Supported by National Natural Science Fundation of China
文摘The thermal stability of New Zealand culture rabbit muscle aldolase was investigated by differential scanning calorimetry in the water content range 0.23-3.70 g water per g protein.The experimental results showed that at water contents below 0.47g/g,an endothermic peak was observed and at water contents above 0.57g/g,an endothermic and an exothermic peak were both observed on DSC thermogram.Thermal denaturation result of the enzyme and the relationship between two transition temperatures and water contents were first reported in this paper.Up to now we have not seen any similar reports concerning the exothermic transition.
基金Supported by the National Natural Science Foundation of China under Grant Nos 51576078 and 51376070
文摘The concentrically layered thermal cloaks with isotropic materials could realize the equivalent thermal cloaking effect with Pendry's cloak, while the effectiveness is scarcely investigated quantitatively. Here we examine the cloaking effectiveness quantitatively by evaluating the standard deviation of the temperature difference between the simulated plane with the layered thermal cloak and Pendry's thermal cloak. The design rules for the isotropic materials in terms of thermal conductivity and layer thickness are presented. The present method could quan- titatively evaluate the cloaking effectiveness, and could open avenues for analyzing the cloaking effect, detecting the (anti-) cloaks, etc.
文摘A non-dimensional secondary circulation equation for typhoons has been derived and then 11-yr com- positing typhoon data were used to estimate the thermally forced secondary circulation.The main results have been obtained as follows: (1)The diabatic heating and Cu vertical heat mixing are major thermal forcing factors.They have the same magnitude of order.(2)The effects of eddy flux and Cu horizontal mixing of heat are of minor im- portance.(3)Ekman pumping and Cu vertical heat mixing cooperatively work.This feedback process is favorable for the enhancement of the secondary circulation of typhoons.
文摘The evolved gaseous analysis (EGA),infrared spectra,and XRD have been applied to the study of solid state reactions of KSCN with five cobalt(Ⅲ)-ammine complexes:[Co- (NH_3)_5N_3]Cl_2,[Co(NH_3)_5(NO_2)]Cl_2,[Co(NH_3)_5(H_2O)]Cl_3,[Co(NH_3)_5Cl]Cl_2,and [Co(NH_3)_6]Cl_3 in a hydrogen atmosphere.It is found that the existence of KSCN shifts the thermal decom- position of these complexes to a lower temperature.The corresponding peak temperatures are near 140℃.The effect of KSCN is discussed and kinetic parameters of deammine reactions are calculated.