The continuously collected cores from the Permo-Carboniferous coal-bearing strata of the eastern Ordos Basin are essential for studying the hydrocarbon potential in this region.This study adopted sedimentological and ...The continuously collected cores from the Permo-Carboniferous coal-bearing strata of the eastern Ordos Basin are essential for studying the hydrocarbon potential in this region.This study adopted sedimentological and geochemical methods to analyze the sedimentary environment,material composition,and geochemical characteristics of the coal-bearing strata.The differences in depositional and paleoclimatic conditions were compared;and the factors influencing the organic matter content of fine-grained sediments were explored.The depositional environment of the Benxi and Jinci formations was lagoon to tidal flat with weakly reduced waters with low salinity and dry-hot paleoclimatic conditions;while that of the Taiyuan Formation was a carbonate platform and shallow water delta front,where the water was highly reductive.The xerothermic climate alternated with the warm and humid climate.The period of maximum transgression in the Permo-Carboniferous has the highest water salinity.The Shanxi Formation was deposited in a shallow water delta front with a brackish and fresh water environment and alternative weak reductiveness.And the paleoclimate condition is dry-hot.The TOC content in fine-grained samples was averaging 1.52%.The main controlling mechanism of organic matter in this area was the input conditions according to the analysis on input and preservation of organic matter.展开更多
The Longtan Formation was originally thought to belong to the Late Permian, but this study reveals that the lower part of this formation belongs to the Middle Permian. The study proposes the corresponding chro-nostrat...The Longtan Formation was originally thought to belong to the Late Permian, but this study reveals that the lower part of this formation belongs to the Middle Permian. The study proposes the corresponding chro-nostratigraphic boundary and new schemes for the correlation of geological sections. Based on these schemes a new understanding on the accumulation regularity of Permian coal measures in South China is reached.展开更多
Following tunnel excavation and lining completion,fractured surrounding rock deforms gradually over time;this results in a time-dependent evolution of the pressure applied to the lining structure by the surrounding ro...Following tunnel excavation and lining completion,fractured surrounding rock deforms gradually over time;this results in a time-dependent evolution of the pressure applied to the lining structure by the surrounding rock.Thus,the safety of the tunnel lining in weak strata is strongly correlated with time.In this study,we developed an analytical method for determining the time-dependent pressure in the surrounding rock and lining structure of a circular tunnel under a hydrostatic stress field.Under the proposed method,the stress–strain relationship of the fractured surrounding rock is assumed to conform to that of the Burgers viscoelastic component,and the lining structure is assumed to be an elastomer.Based on these assumptions,the viscoelastic deformation of the surrounding rock,the elastic deformation of the lining structure,and the coordinated deformation between the surrounding rock and lining structure were derived.The proposed analytical method,which employs a time-dependent safety coefficient,was subsequently used to estimate the durability of the lining structure of the Foling Tunnel in China.The derived attenuation curve of the safety coefficient with respect to time can assist engineers in predicting the remaining viable life of the lining structure.Unlike existing analytical methods,the method derived in this study considers the time dependency of the interaction between the surrounding rock and tunnel lining;hence,it is more suitable for the evaluation of lining lifetime.展开更多
The sharp increase in the demand for lithium(Li)for high-energy-storage battery materials due to its high specific energy and low negative chemical potential render Li a geopolitically significant resource.It is urgen...The sharp increase in the demand for lithium(Li)for high-energy-storage battery materials due to its high specific energy and low negative chemical potential render Li a geopolitically significant resource.It is urgent to develop a low-cost,efficient method to improve lithium extraction.Herein,Li ion(Li+)adsorption in coal-bearing strata kaolinite(CSK)was studied.The effects of pre-activation acid leaching(meta-kaolinite/H2SO4,MK-HS)and dimethyl sulfoxide intercalation(coal-bearing strata kaolinite/dimethyl sulfoxide,CSK-DMSO)on the Li+adsorption capacity were studied under the same adsorption conditions.The results indicated that the adsorption was completed in 60 min under alkaline conditions(pH=8.5),a high solution concentration(400 mg/L),and a low dosage(1 g/100 mL);and the comprehensive adsorption capacity is MK-HS>CSK-DMSO>CSK.Furthermore,the DMSO intercalation caused the interlayer spacing of the CSK to increase,which provided more space for Li+to enter and increase the adsorption capacity.After thermal pre-activation and acid leaching,structural failure and lattice collapse resulted in the presence of more micropores in the MK-HS,which resulted in a 10-fold increase in its specific surface area and caused coordination bond changes(Al(VI)to Al(IV))and leaching of aluminum(Al)from the lattice.It is proposed that these structural changes greatly improve the activity of CSK so that Li+cannot only adsorb onto the surface and between the layers but can also enter the lattice defects,which results in the MK-HS having the best adsorption performance.Combined with the adsorption kinetics analysis,the adsorption methods of CSK and two modified materials include physical adsorption and chemical adsorption.In this study,the adsorption capacity of CSK and its modified products to Li were explored,providing a new option for the reuse of CSK and the extraction of Li.展开更多
Subsidence analysis and prediction with measured data have been conducted and applied to local strata and mining conditions worldwide. Underground coal mines chose the most suitable analysis and prediction method for ...Subsidence analysis and prediction with measured data have been conducted and applied to local strata and mining conditions worldwide. Underground coal mines chose the most suitable analysis and prediction method for them. However, there was no study based on the measured data of subsidence induced by underground mining operation in Indonesia. This paper describes the condition of underground coal mine in Indonesia and then discusses the subsidence behavior due to longwall mining operation based on measured data in Balikpapan coal-bearing formation in Indonesia.展开更多
Multiple coal seams and interbedded rock assemblages formed in vertical progression due to the influence of multiple stages of sea level transgressions.Based on mercury injection experiment,low temperature liquid nitr...Multiple coal seams and interbedded rock assemblages formed in vertical progression due to the influence of multiple stages of sea level transgressions.Based on mercury injection experiment,low temperature liquid nitrogen experiment,porosity and permeability experiment and breakthrough pressure experiment,the vertical variation characteristics of coal-bearing strata in Gujiao block are explained in detail.The results of the mercury injection and low temperature liquid nitrogen experiments show that the pore structure characteristics fluctuate with increasing depth in the strata,with fewer micropores followed by transition pores.The BET specific surface area and average pore diameter of the Shanxi Formation are generally larger than those of the Taiyuan Formation.Due to the continuous cyclic sequence stratigraphy changes,the porosity,permeability,breakthrough pressure and breakthrough time of the samples show a certain cyclicity.Within the same sequence,the porosity is larger,and the permeability is smaller near the maximum flooding surface.Although the permeability of the sandstone samples is higher,the porosity is lower,and the breakthrough pressure and breakthrough times are greater.The strata in the study area formed in an oxidized environment that was affected by freshwater,and the pore structure of different lithologies is quite different.After the formation of sandstone,the intergranular pores generally underwent filling with secondary quartz,clay minerals and organic matter,resulting in low porosity and permeability.展开更多
基金founded by the National Natural Science Foundation of China(Grant No.41772130)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(Grant No.KYCX22_2602)+1 种基金the Graduate Innovation Program of China University of Mining and Technology(Grant No.2022WLKXJ035)the Fundamental Research Program of Shanxi Province(Grant No.202103021223283)。
文摘The continuously collected cores from the Permo-Carboniferous coal-bearing strata of the eastern Ordos Basin are essential for studying the hydrocarbon potential in this region.This study adopted sedimentological and geochemical methods to analyze the sedimentary environment,material composition,and geochemical characteristics of the coal-bearing strata.The differences in depositional and paleoclimatic conditions were compared;and the factors influencing the organic matter content of fine-grained sediments were explored.The depositional environment of the Benxi and Jinci formations was lagoon to tidal flat with weakly reduced waters with low salinity and dry-hot paleoclimatic conditions;while that of the Taiyuan Formation was a carbonate platform and shallow water delta front,where the water was highly reductive.The xerothermic climate alternated with the warm and humid climate.The period of maximum transgression in the Permo-Carboniferous has the highest water salinity.The Shanxi Formation was deposited in a shallow water delta front with a brackish and fresh water environment and alternative weak reductiveness.And the paleoclimate condition is dry-hot.The TOC content in fine-grained samples was averaging 1.52%.The main controlling mechanism of organic matter in this area was the input conditions according to the analysis on input and preservation of organic matter.
基金supported by the National Natural Science Foundation of China
文摘The Longtan Formation was originally thought to belong to the Late Permian, but this study reveals that the lower part of this formation belongs to the Middle Permian. The study proposes the corresponding chro-nostratigraphic boundary and new schemes for the correlation of geological sections. Based on these schemes a new understanding on the accumulation regularity of Permian coal measures in South China is reached.
基金supported by the National Natural Science Foundation of China(Nos.71631007 and 71771020)。
文摘Following tunnel excavation and lining completion,fractured surrounding rock deforms gradually over time;this results in a time-dependent evolution of the pressure applied to the lining structure by the surrounding rock.Thus,the safety of the tunnel lining in weak strata is strongly correlated with time.In this study,we developed an analytical method for determining the time-dependent pressure in the surrounding rock and lining structure of a circular tunnel under a hydrostatic stress field.Under the proposed method,the stress–strain relationship of the fractured surrounding rock is assumed to conform to that of the Burgers viscoelastic component,and the lining structure is assumed to be an elastomer.Based on these assumptions,the viscoelastic deformation of the surrounding rock,the elastic deformation of the lining structure,and the coordinated deformation between the surrounding rock and lining structure were derived.The proposed analytical method,which employs a time-dependent safety coefficient,was subsequently used to estimate the durability of the lining structure of the Foling Tunnel in China.The derived attenuation curve of the safety coefficient with respect to time can assist engineers in predicting the remaining viable life of the lining structure.Unlike existing analytical methods,the method derived in this study considers the time dependency of the interaction between the surrounding rock and tunnel lining;hence,it is more suitable for the evaluation of lining lifetime.
基金The authors gratefully acknowledge the financial support provided by the National Natural Science Foundation of China(Grant No.42172043)the Science and Technology Major Projects of Shanxi Province of China(No.20181101003)+1 种基金the Fundamental Research Funds for the Central Universities(No.300102299306)Scientific Innovation Practive Project of Postgraduates of Chang’an University(No.300103722045)。
文摘The sharp increase in the demand for lithium(Li)for high-energy-storage battery materials due to its high specific energy and low negative chemical potential render Li a geopolitically significant resource.It is urgent to develop a low-cost,efficient method to improve lithium extraction.Herein,Li ion(Li+)adsorption in coal-bearing strata kaolinite(CSK)was studied.The effects of pre-activation acid leaching(meta-kaolinite/H2SO4,MK-HS)and dimethyl sulfoxide intercalation(coal-bearing strata kaolinite/dimethyl sulfoxide,CSK-DMSO)on the Li+adsorption capacity were studied under the same adsorption conditions.The results indicated that the adsorption was completed in 60 min under alkaline conditions(pH=8.5),a high solution concentration(400 mg/L),and a low dosage(1 g/100 mL);and the comprehensive adsorption capacity is MK-HS>CSK-DMSO>CSK.Furthermore,the DMSO intercalation caused the interlayer spacing of the CSK to increase,which provided more space for Li+to enter and increase the adsorption capacity.After thermal pre-activation and acid leaching,structural failure and lattice collapse resulted in the presence of more micropores in the MK-HS,which resulted in a 10-fold increase in its specific surface area and caused coordination bond changes(Al(VI)to Al(IV))and leaching of aluminum(Al)from the lattice.It is proposed that these structural changes greatly improve the activity of CSK so that Li+cannot only adsorb onto the surface and between the layers but can also enter the lattice defects,which results in the MK-HS having the best adsorption performance.Combined with the adsorption kinetics analysis,the adsorption methods of CSK and two modified materials include physical adsorption and chemical adsorption.In this study,the adsorption capacity of CSK and its modified products to Li were explored,providing a new option for the reuse of CSK and the extraction of Li.
文摘Subsidence analysis and prediction with measured data have been conducted and applied to local strata and mining conditions worldwide. Underground coal mines chose the most suitable analysis and prediction method for them. However, there was no study based on the measured data of subsidence induced by underground mining operation in Indonesia. This paper describes the condition of underground coal mine in Indonesia and then discusses the subsidence behavior due to longwall mining operation based on measured data in Balikpapan coal-bearing formation in Indonesia.
基金the National Natural Science Foundation of China(No.41672149 and No.41672146)the Key Project of the Natural Science Foundation of China(No.41530314)+3 种基金the Application Research Plan of Key Scientific Research Projects in Colleges and Universities of Henan Province(20B610006)Scientific Research Foundation of the Shandong Provincial Key Laboratory of Depositional Mineralization&Sedimentary Mineralsthe Shandong University of Science and Technology(DMSM2017012)the National Science and Technology Major Project(2016ZX05044-002).
文摘Multiple coal seams and interbedded rock assemblages formed in vertical progression due to the influence of multiple stages of sea level transgressions.Based on mercury injection experiment,low temperature liquid nitrogen experiment,porosity and permeability experiment and breakthrough pressure experiment,the vertical variation characteristics of coal-bearing strata in Gujiao block are explained in detail.The results of the mercury injection and low temperature liquid nitrogen experiments show that the pore structure characteristics fluctuate with increasing depth in the strata,with fewer micropores followed by transition pores.The BET specific surface area and average pore diameter of the Shanxi Formation are generally larger than those of the Taiyuan Formation.Due to the continuous cyclic sequence stratigraphy changes,the porosity,permeability,breakthrough pressure and breakthrough time of the samples show a certain cyclicity.Within the same sequence,the porosity is larger,and the permeability is smaller near the maximum flooding surface.Although the permeability of the sandstone samples is higher,the porosity is lower,and the breakthrough pressure and breakthrough times are greater.The strata in the study area formed in an oxidized environment that was affected by freshwater,and the pore structure of different lithologies is quite different.After the formation of sandstone,the intergranular pores generally underwent filling with secondary quartz,clay minerals and organic matter,resulting in low porosity and permeability.