Suppress oxygen evolution of lithium-rich manganese-based cathode materials via an integrated strategy

Improving the reversibility of anionic redox and inhibiting irreversible oxygen evolution are the main challenges in the application of high reversible capacity Li-rich Mn-based cathode materials.A facile synchronous lithiation strategy combining the advantages of yttrium doping and LiYO_(2) surface coating is proposed.Yttrium doping effectively suppresses the oxygen evolution during the delithiation process by increasing the energy barrier of oxygen evolution reaction through strong Y–O bond energy.LiYO_(2) nanocoating has the function of structural constraint and protection,that protecting the lattice oxygen exposed to the surface,thus avoiding irreversible oxidation.As an Li^(+) conductor,LiYO_(2) nano-coating can provide a fast Li^(+) transfer channel,which enables the sample to have excellent rate performance.The synergistic effect of Y doping and nano-LiYO_(2) coating integration suppresses the oxygen release from the surface,accelerates the diffusion of Li^(+)from electrolyte to electrode and decreases the interfacial side reactions,enabling the lithium ion batteries to obtain good electrochemical performance.The lithium-ion full cell employing the Y-1 sample(cathode)and commercial graphite(anode)exhibit an excellent specific energy density of 442.9 Wh kg^(-1) at a current density of 0.1C,with very stable safety performance,which can be used in a wide temperature range(60 to-15℃)stable operation.This result illustrates a new integration strategy for advanced cathode materials to achieve high specific energy density.

Research on the Spatio-Temporal Evolution and Driving Forces of Green Spaces in the Central Urban Area of Zunyi City

Green space,as a medium for carrying out urban functions and guiding urban development,is becoming a scarce resource along with the urbanization process and the intensification of environmental problems.In the face of the spatial mismatch between high demand and low supply,it is of great significance to clarify the evolution mechanism of green space to undertake national spatial planning,protect the natural strategic resources in the urban fringe area,and promote the sustainable development of the“three living spaces.”The study focuses on the Zunyi City Center,selecting the 20 years of rapid development following its establishment as a city as the study period.It explores the dynamic evolution of green space and the main driving forces during different periods using remote-sensing image data.The study shows that from 2003 to 2023,the total scale of green space has an obvious decreasing trend along with the expansion of the urban built-up area.A large amount of arable land is being converted to construction land,resulting in a sudden decrease in arable land area.In the past 10 years,the comprehensive land use dynamics have accelerated.Still,the spatial difference has gradually narrowed,indicating that the overall development intensity of Zunyi City’s central urban area has increased.There is a gradual spread of the trend to the hilly areas.The limiting effect of the mountainous natural environment on the city’s development has gradually diminished under the superposition of external factors,such as economic development,industrial technological upgrading,and policy orientation so the importance of the effective protection and rational utilization of urban green space has become more prominent.

A guidance strategy for rendezvous and docking to the space station in the Earth-Moon NRHO orbit

With the development of space technology,it is possible to build a space station in Earth-Moon space as a transit for Earth-Moon round-trip and entering in the deep space.Rendezvous and docking is one of the key technologies for building an Earth-Moon space station.A guidance strategy for rendezvous and docking from the Earth orbit to the space station in the Earth-Moon NRHO orbit is proposed in this paper,which is suitable for engineering applications.Firstly,the rendezvous and docking process is divided into three sections,i.e.,the large-range orbit transfer section,far-range guidance section,and close-range approaching section.The suitable terminal of large-range orbit transfer is selected according to the eigenvalue of NRHO orbit state transition matrix.The two-impulse guidance method based on the relative motion equation in the three-body problem is adopted for the far-range guidance section.The impulse time and amplitude are solved with the optimization algorithm.The linear constant three-body relative motion equation is proposed for the close-range approaching section,and the rendezvous and docking is completed by a two-stage linear approximation.Finally,a simulation analysis is carried out,and the simulation results show that the adopted dynamics equations and the designed guidance law are effective,and the three flight phases are naturally connected to accomplish the rendezvous and docking mission from the Earth orbit to the space station on the Earth-Moon NRHO.

Electrocatalytic oxygen evolution activities of metal chalcogenides and phosphides:Fundamentals,origins,and future strategies

The development of inexpensive and efficient electrocatalysts is key to commercializing energy-related electrocatalytic techniques such as water electrolyzers and metal-air batteries.In particular,novel oxygen evolution reaction(OER)pre-catalysts,such as transition metal chalcogenides(TMCs)and phosphides(TMPs),have evolved in recent years from traditional stable OER electrocatalysts,which show superior OER electrocatalytic performance compared with transition metal oxides(TMOs)or(oxy)hydroxides(TMOHs).In this feature article,we summarize recent advances in the development of TMCand TMP-based OER electrocatalysts,as well as approaches to improve the OER performance in terms of morphology,structure,composition,surface engineering,lattice-strained and in-situ transformation in the electrolysis process.In particular,the electrochemical stability of TMCs and TMPs in alkaline electrolytes and the evolution of morphology,structure and composition under OER conditions are discussed.In the last section,we discuss the challenges that need to be addressed in this specific area of research and the implications for further research.

Analysis of Urban Public Building Space Design Strategies in the Digital Age

Urban public building spaces involve various aspects of people’s daily activities and interactions,making the rationality and scientific nature of the design of these spaces crucial.This article first discusses the role and impact of digitization in the design of public building spaces,covering aspects such as digital design methods,visual expression and presentation,augmented reality’s spatial interaction experience,and integrated design and construction.Following that,it analyzes the process of digitized urban public building space design by exploring topics like digital space design and modeling,visual representation of digital spaces,digital performance analysis of spaces,and the integration of digital projects.This article aims to provide insights and references for urban public building space design in the digital era.

Productive functional evolution of rural settlements:analysis of livelihood strategy and land use transition in eastern China

In China, rural settlements are usually multifunctional complex of natural societies and they also play important productive function. This study explored the spatiotemporal evolution of the productive function of three rural settlements, i.e.,Hetaoyuan, Dawengshan, and Gaoqiao, in the Yimeng Mountain in Shandong province of eastern China.Residents lived in this three types of rural settlements were all involved in agricultural production(i.e., grain threshing, drying and storage), which had remained dominant in Hetaoyuan. Dawengshan became an industrial-oriented settlement, while Gaoqiao became a commercial-oriented settlement. This evolution was reflected in the livelihood strategy changes of rural households and the transition of rural settlements changes. The choice of livelihood strategy was affected by the livelihood assets and policies, which resulted in the spatiotemporal evolution of the productive function of rural settlements. This study can provide references for the implementation and adjustment of rural residential land consolidation policies and the improvement of production and the quality of rural life in future.

Strategies on improving the electrocatalytic hydrogen evolution performances of metal phosphides

Among the sustainable energy sources,hydrogen is the one most promising for alleviating the pollution issues related to the usage of conventional fuels,as it can be produced in an efficient and eco-friendly way via electrocatalytic water splitting.The hydrogen evolution reaction(HER,a half-reaction of water splitting)plays a pivotal role in decreasing the price and increasing the catalytic efficiency of hydrogen production and is efficiently promoted by metal phosphides in different electrolytes.Herein,we summarize the recent advances in the development of metal phosphides as HER electrocatalysts,focus on their synthesis(post-treatment,in situ generation,and electrodeposition methods)and the enhancement of their electrocatalytic activity(via elemental doping,interface and vacancy engineering,construction of specific supports and nanostructures,and the design of bior polymetallic phosphides),and highlight the crucial issues and challenges of future development.

Zero-determinant strategy:An underway revolution in game theory

Repeated games describe situations where players interact with each other in a dynamic pattern and make decisions ac- cording to outcomes of previous stage games. Very recently, Press and Dyson have revealed a new class of zero-determinant （ZD） strategies for the repeated games, which can enforce a fixed linear relationship between expected payoffs of two play- ers, indicating that a smart player can control her unwitting co-player＇s payoff in a unilateral way [Proc. Acad. Natl. Sci. USA 109, 10409 （2012）]. The theory of ZD strategies provides a novel viewpoint to depict interactions among players, and fundamentally changes the research paradigm of game theory. In this brief survey, we first introduce the mathematical framework of ZD strategies, and review the properties and constrains of two specifications of ZD strategies, called pinning strategies and extortion strategies. Then we review some representative research progresses, including robustness analysis, cooperative ZD strategy analysis, and evolutionary stability analysis. Finally, we discuss some significant extensions to ZD strategies, including the multi-player ZD strategies, and ZD strategies under noise. Challenges in related research fields are also listed.

Phase control of 2D binary hydroxides nanosheets via controlling-release strategy for enhanced oxygen evolution reaction and supercapacitor performances

An OH^--slow-release strategy was established to controllably tune the( α-and β-) phase of nickel cobalt binary hydroxide in the presence of ammonium chloride. Ammonium chloride is added to the ionic solution to regulate the p H of the solution and slow down the release of OH^-, effectively regulating the phase, nanostructure, interlayer spacing, surface area, thickness, and the performance of binary Ni –Co hydroxide. The ion-slow-release mechanism is conducive to the formation of α-phase with larger interlayer spacing and thinner flakes rather than β-phase. Attributed to the enlarged interlayer spacing, thinner nanosheets, and more exposed active sites, the resultant α-phase hydroxides(NCNS-5.2), displayed much lower over potential of 285 mV with respect to the dense-stacked β-phase hydroxides(362 mV) for OER at 10 mA/cm^2. It also exhibited high specific capacitance of 1474.2 F/g, when tested at 0.5 A/g within a voltage range of 0–0.45 Vvs. Hg/Hg O. This composite was also stable for water oxidation reaction and supercapacitor. The proof-of-concept of using controlled-release agent may provide suggestive insights for the material innovation and a variety of applications.

Route strategy of satellite network in GNSS based on topology evolution law

As each type of satellite network has different link features, its data transmission must be designed based on its link features to improve the efficiency of data transferring. The transmission of navigation integrated services information （NISI） in a global navigation satellite system （GNSS） with inter-satellite links （ISLs） is studied by taking the real situation of inter-satellite communication links into account. An on-demand computing and buffering centralized route strategy is proposed based on dynamic grouping and the topology evolution law of the GNSS network within which the satellite nodes are operated in the manner of dynamic grouping. Dynamic grouping is based on satellites spatial relationships and the group role of the satellite node changes by turns due to its spatial relationships. The route strategy provides significant advantages of high efficiency, low complexity, and flexi- ble configuration, by which the established GNSS can possess the features and capabilities of feasible deployment, efficient transmission, convenient management, structural invulnerability and flexible expansion.

Regional Evolution Features and Coordinated Development Strategies for Northeast China

Northeast China, as the most important production base of agriculture, forestry, and livestock-breeding as well as the old industrial base in the whole country, has been playin a key role in the construction and development of China＇s economy. However, after the policy of reform and open-up was taken in China. the economic development speed and efficiency ofthis area have turned to be evidently lower than those of coastal area and the national average level as well, which is so-called ＇Northeast Phenomenon＇ and ＇Neo-Northeast Phenomenon＇. In terms of those phenomena, this paper firstly reviews the spatial and temporal features of the regional evolution of this area so as to unveil the profound forming causes of ＇Northeast Phenomena＇ and ＇Neo-Northeast Phenomena＇. And then the paper makes a further exploration into the status quo of this region and its forming causes by analyzing its economy gross, industrial structure, product structure, regional eco-categories, etc. At the end of the paper, the authors put forward the basic coordinated development strategies for Northeast China. namely we can revitalize this area by means of adjustment of economic structure, regional coordination, planning urban and rural areas as a whole, institutional innovation, etc.

Precursor-modified strategy to synthesize thin porous amino-rich graphitic carbon nitride with enhanced photocatalytic degradation of RhB and hydrogen evolution performances

The photocatalytic activity of carbon nitride(CN)materials is mainly limited to small specific surface areas,limited solar absorption,and low separation and mobility of photoinduced carriers.In this study,we developed a precursor-modified strategy for the synthesis of graphitic CN with highly efficient photocatalytic performance.The precursor dicyandiamide reformed by different acids undergoes a basic structural change and transforms into diverse new precursors.The thin porous amino-rich HNO_(3)-CN(5H-CN)was calcined by dicyandiamidine nitrate,formed by concentrated nitric acid modified dicyandiamide,and presented the best photocatalytic degradation rate of Rh B,more than 34 times that of bulk graphitic CN.Moreover,the photocatalytic hydrogen evolution rate of 5H-CN significantly improved.The TG-DSC-FTIR analyses indicated that the distinguishing thermal polymerization process of 5H-CN led to its thin porous amino-rich structure,and the theoretical calculations revealed that the negative conduction band potential of 5H-CN was attributed to its amino-rich structure.It is anticipated that the thin porous structure and the negative conduction band position of 5H-CN play important roles in the improvement of the photocatalytic performance.This study demonstrates that precursor modification is a promising project to induce a new thermal polycondensation process for the synthesis of CN with enhanced photocatalytic performance.

Evolution Performance of Symbolic Radial Basis Function Neural Network by Using Evolutionary Algorithms

Radial Basis Function Neural Network(RBFNN)ensembles have long suffered from non-efficient training,where incorrect parameter settings can be computationally disastrous.This paper examines different evolutionary algorithms for training the Symbolic Radial Basis Function Neural Network(SRBFNN)through the behavior’s integration of satisfiability programming.Inspired by evolutionary algorithms,which can iteratively find the nearoptimal solution,different Evolutionary Algorithms(EAs)were designed to optimize the producer output weight of the SRBFNN that corresponds to the embedded logic programming 2Satisfiability representation(SRBFNN-2SAT).The SRBFNN’s objective function that corresponds to Satisfiability logic programming can be minimized by different algorithms,including Genetic Algorithm(GA),Evolution Strategy Algorithm(ES),Differential Evolution Algorithm(DE),and Evolutionary Programming Algorithm(EP).Each of these methods is presented in the steps in the flowchart form which can be used for its straightforward implementation in any programming language.With the use of SRBFNN-2SAT,a training method based on these algorithms has been presented,then training has been compared among algorithms,which were applied in Microsoft Visual C++software using multiple metrics of performance,including Mean Absolute Relative Error(MARE),Root Mean Square Error(RMSE),Mean Absolute Percentage Error(MAPE),Mean Bias Error(MBE),Systematic Error(SD),Schwarz Bayesian Criterion(SBC),and Central Process Unit time(CPU time).Based on the results,the EP algorithm achieved a higher training rate and simple structure compared with the rest of the algorithms.It has been confirmed that the EP algorithm is quite effective in training and obtaining the best output weight,accompanied by the slightest iteration error,which minimizes the objective function of SRBFNN-2SAT.

Identification, evolution and geological indications of solid bitumen in shales: A case study of the first member of Cretaceous Qingshankou Formation in Songliao Basin, NE China

On the basis of sorting out current understanding of solid bitumen (SB) in shales and taking organic-rich shales in the first member of the Cretaceous Qingshankou Formation in the Songliao Basin as an example, the definition, classification, occurrence and evolution path of SB are systemtically studied, and the indicative significance of SB reflectance (Rob) on maturity and its influence on the development of reservoir space are discussed and summarized. The results show that the difference of primary maceral types is primarily responsible for the different evolution paths of SB. Most of the pre-oil bitumen is in-situ SB with only a small amount being of migrated SB, while most of the post-oil bitumen and pyrobitumen are migrated SB. From the immature to early oil maturity stage, bituminite, vitrinite, and inertinite can be distinguished from SB based on their optical characteristics under reflected light, and alginite can be differentiated from SB by their fluorescence characteristics. Under scanning electron microscope, in-situ SB and migrated SB can be effectively identified. Rob increases linearly with increasing vitrinite reflectance (Ro), as a result of a decrease of aliphatic structure and the enhancement of aromatization of SB. Within the oil window three types of secondary pores may develop in SB, including modified mineral pores, devolatilization cracks and bubble holes. At a high maturity stage spongy pores may develop in pyrobitumen. Scanning electron microscopy combined with in-situ SEM-Raman spectroscopy can further reveal the structral information of different types of SB, thus providing crucial data for understanding for understanding OM migration paths, dynamics, and distances at micro-scale.

Spatial Evolution of Tourism-Oriented Rural Residential Space: A Case Study of Xiaochuanfangyu Village, Dongshuichang Village and Maojiayu Village in Jizhou District, Tianjin

Currently, rural residential space can't continue to meet the growing demand for tourism receptions because of the development of rural tourism, resulting in the evolution and reconstruction of residential space in rural areas. In the past decade, rural tourism has become the main driving force for industrial transformation and economic growth in rural areas of China. Taking three tourism-oriented villages in Jizhou District, Tianjin, namely Xiaochuanfangyu Village, Dongshuichang Village and Maojiayu Village, as the objects of the research, this paper analyzed the influence of rural tourism on the evolution of rural residential space from the perspectives of the spatial pattern and architectural style at the microscopic scale.

Design Strategy of Underground Space of Urban Rail Transit Complex Based on Integration Concept

With the accelerated development and utilization of urban underground space,the underground space design of complex based on rail transit has attracted much attention.By sorting out the integration concept and constructing the logical framework of integrated design,the integrated design strategy is proposed from the aspects of function,transportation,space and environment on the urban scale,and the evaluation points of integrated design effect are put forward from the aspects of accessibility,coordination,openness and symbolism.

A planetary perspective on Earth's space environment evolution

The planet Earth is an integrated system, in which its multi-spheres are coupled, from the space to the inner core. Whether the space environment in short to long terms has been controlled by the earth's interior process is contentious. In the past several decades,space weather and space climate have been extensively studied based on either observation data measured directly by man-made instruments or ancient data inferred indirectly from some historical medium of past thousands of years. The acquired knowledge greatly helps us to understand the dynamic processes in the space environment of modern Earth, which has a strong magnetic dipole and an oxygen-rich atmosphere. However, no data is available for ancient space weather and climate(>5 ka). Here, we propose to take the advantage of " space-diversity" to build a " generalized planetary space family", to reconcile the ancient space environment evolution of planet Earth from modern observations of other planets in our solar system. Such a method could also in turn give us a valuable insight into other planets' evolution.

Space-time evolution rules of acoustic emission location of unloaded coal sample at different loading rates

By using MTS815 rock mechanics test system,a series of acoustic emission(AE) location experiments were performed under unloading confining pressure,increasing the axial stress.The AE space-time evolution regularities and energy releasing characteristics during deformation and failure process of coal of different loading rates are compared,the influence mechanism of loading rates on the microscopic crack evolution were studied,combining the AE characteristics and the macroscopic failure modes of the specimens,and the precursory characteristics of coal failure were also analyzed quantitatively.The results indicate that as the loading rate is higher,the AE activity and the main fracture will begin earlier.The destruction of coal body is mainly the function of shear strain at lower loading rate and tension strain at higher rate,and will transform from brittleness to ductility at critical velocities.When the deformation of the coal is mainly plasticity,the amplitude of the AE ringing counting rate increases largely and the AE energy curves appear an obvious ''step'',which can be defined as the first failure precursor point.Statics of AE information shows that the strongest AE activity begins when the axial stress level was 92-98%,which can be defined as the other failure precursor point.As the loading rate is smaller,the coal more easily reaches the latter precursor point after the first one,so attention should be aroused to prevent dynamic disaster in coal mining when the AE activity reaches the first precursor point.

Evolution of Living Space in Traditional Villages in the Pearl River Delta under the Influence of Urbanization:A Case Study of Xiaozhou Village in Guangzhou City

Traditional villages in the Pearl River Delta are known as "Lingnan water village".Urbanization affects the style of traditional villages in three ways.It also presents a positive side under the background of new urbanization.The living space of Xiaozhou Village has the unique characteristics of Lingnan water village.At the same time,it is obviously affected by urbanization.Industrialization and commercialization continue to promote the villagers to dismantle the old and build new ones until it becomes a village in the city.The evolution of the traditional living space is reflected in three aspects:being nibbled away or even disappeared,destroying the traditional style,function disappearance or transformation.In the later stage of urbanization,some living spaces have been repaired and updated.