Al2O3 -MgO castables have been widely used for working linings of steel ladle due to their superior hot strength and corrosion resistance. In this- work, effects of＂ microsilica, ultrafine alumina and MgO fines addit...Al2O3 -MgO castables have been widely used for working linings of steel ladle due to their superior hot strength and corrosion resistance. In this- work, effects of＂ microsilica, ultrafine alumina and MgO fines additions on the rh, eological behavior of the castables were investi- gated by means of IBB rheometer V1. 0 to measure torque （shear stress） under varying shear rates. The re- sults show that rheological properties of castables at varying shear rates are significantly improved with increase of microsilica additions （from 1 mass% to 5 mass% ） and corresponding decrease in water addition; there is only little change in rheological behavior with variation of ultrafine alumina and MgO fines additions. Optimum ultrafine alumina and microsilica additions are recommended for castables with good rheological behavior.展开更多
Influences of different superplasticizers （ STP. KSJSTO and LMS-P） on rheological behavior of low-cement castables and the mechanisms were analyzed. The shear stress and viscosity under different shear rates of matr...Influences of different superplasticizers （ STP. KSJSTO and LMS-P） on rheological behavior of low-cement castables and the mechanisms were analyzed. The shear stress and viscosity under different shear rates of matrix slurry were determined using a NXS-I IA rotary viscometer. Effects of different admixtures on the rheological properties of slurry was analyzed theoretically. Sodium tripolyphosphate and poly＇carboxylate superplasticizers KS-JSTO and LMS-P） can improve the fluidity and initial setting time. With STP. the slurry is plastic flow. With KS-JS70 or LMS-P increasing, the slurrv changes from plastic.flow, pseudoplastic flow to dilatant flow successively. Th, e optimum dosages of STP. KS-JSTO and LMS-P are 0. 15%. 0. 25% and 0. 40%, respectively. KS-JS70 and LMS-P can significantly reduce the slurry viscosity and shear stress to improve the workability of construction. Both shear stress and viscosity shall be taken into account for on-site construction.展开更多
The rheological behavior of polyhexamethylene guanidine hydrochloride (PHGC) and polyhexamethylene guanidine stearate (PHGS) has been investigated using the capillary rheometer. It is shown that the polyelectrolyte me...The rheological behavior of polyhexamethylene guanidine hydrochloride (PHGC) and polyhexamethylene guanidine stearate (PHGS) has been investigated using the capillary rheometer. It is shown that the polyelectrolyte melts are non-Newtonian of shear-thinning fluid. The melt viscosity, die flow activation energy and the flow temperature are high even if the molecular weight is not high. The melting viscosity of PHGC is higher than that of PHGS at the same experimental conditions. By comparison with the case of PHGS the non-Newtonian index of PHGC is smaller, the flow activation energy and die flow temperature of PHGC are higher, which was caused by the difference in their molecular structure.展开更多
文摘Al2O3 -MgO castables have been widely used for working linings of steel ladle due to their superior hot strength and corrosion resistance. In this- work, effects of＂ microsilica, ultrafine alumina and MgO fines additions on the rh, eological behavior of the castables were investi- gated by means of IBB rheometer V1. 0 to measure torque （shear stress） under varying shear rates. The re- sults show that rheological properties of castables at varying shear rates are significantly improved with increase of microsilica additions （from 1 mass% to 5 mass% ） and corresponding decrease in water addition; there is only little change in rheological behavior with variation of ultrafine alumina and MgO fines additions. Optimum ultrafine alumina and microsilica additions are recommended for castables with good rheological behavior.
文摘Influences of different superplasticizers （ STP. KSJSTO and LMS-P） on rheological behavior of low-cement castables and the mechanisms were analyzed. The shear stress and viscosity under different shear rates of matrix slurry were determined using a NXS-I IA rotary viscometer. Effects of different admixtures on the rheological properties of slurry was analyzed theoretically. Sodium tripolyphosphate and poly＇carboxylate superplasticizers KS-JSTO and LMS-P） can improve the fluidity and initial setting time. With STP. the slurry is plastic flow. With KS-JS70 or LMS-P increasing, the slurrv changes from plastic.flow, pseudoplastic flow to dilatant flow successively. Th, e optimum dosages of STP. KS-JSTO and LMS-P are 0. 15%. 0. 25% and 0. 40%, respectively. KS-JS70 and LMS-P can significantly reduce the slurry viscosity and shear stress to improve the workability of construction. Both shear stress and viscosity shall be taken into account for on-site construction.
文摘The rheological behavior of polyhexamethylene guanidine hydrochloride (PHGC) and polyhexamethylene guanidine stearate (PHGS) has been investigated using the capillary rheometer. It is shown that the polyelectrolyte melts are non-Newtonian of shear-thinning fluid. The melt viscosity, die flow activation energy and the flow temperature are high even if the molecular weight is not high. The melting viscosity of PHGC is higher than that of PHGS at the same experimental conditions. By comparison with the case of PHGS the non-Newtonian index of PHGC is smaller, the flow activation energy and die flow temperature of PHGC are higher, which was caused by the difference in their molecular structure.
