[Pb（HL）（phen）]n （1） and [Cd3L2（phen）]n （2）, where phen = 1,10-phenanthroline and L = 4,4＇-（2-carboxylatopropane-1,3-diyl）dibenzoate, were hydrothermally prepared and fully characterized by X-ray single-cr...[Pb（HL）（phen）]n （1） and [Cd3L2（phen）]n （2）, where phen = 1,10-phenanthroline and L = 4,4＇-（2-carboxylatopropane-1,3-diyl）dibenzoate, were hydrothermally prepared and fully characterized by X-ray single-crystal diffraction, infrared spectroscopy and thermogravimetric analyses. The decomposition temperature of 1 and 2 was measured to be ca. 304 and 416 ℃, respectively. The charge transfer transition based absorption of 1 and 2 was also verified by the powder scattering spectra and theoretical analyses.展开更多
基金supported by the National Natural Science Foundation of China(No.21271033)
文摘[Pb（HL）（phen）]n （1） and [Cd3L2（phen）]n （2）, where phen = 1,10-phenanthroline and L = 4,4＇-（2-carboxylatopropane-1,3-diyl）dibenzoate, were hydrothermally prepared and fully characterized by X-ray single-crystal diffraction, infrared spectroscopy and thermogravimetric analyses. The decomposition temperature of 1 and 2 was measured to be ca. 304 and 416 ℃, respectively. The charge transfer transition based absorption of 1 and 2 was also verified by the powder scattering spectra and theoretical analyses.
