The reac dynamics on Ba+BrCH_3→BaBr+CH_3 has been investigated in the first proposed potential energy surface of the generalized LEPS type,using the quasiclassical trajectory method.In simulation of the conditions in...The reac dynamics on Ba+BrCH_3→BaBr+CH_3 has been investigated in the first proposed potential energy surface of the generalized LEPS type,using the quasiclassical trajectory method.In simulation of the conditions in molecular beam experiments,the results of the present study show significant effect of the reagent collision energy on the dynamics of the reaction,and are in good agreement with the experimental ones.展开更多
Due to the large quasi-piezoelectric d33 coefficient in the film thickness direction, cellular piezoelectret has emerged as a new kind of compliant electromechanical transducer materials. The macroscopic piezoelectric...Due to the large quasi-piezoelectric d33 coefficient in the film thickness direction, cellular piezoelectret has emerged as a new kind of compliant electromechanical transducer materials. The macroscopic piezoelectric effect of cellular piezoelectret is closely related to the void microstructures as well as the material constants of host polymer. Complex void microstmctures are usually encountered in the optimum design of cellular piezoelectret polymer film with ad- vanced piezoelectric properties. Analysis of the effective electromechanical properties is generally needed. This article presents an overview of the recent progress on theoretical models and numerical simulation for the effective electromechanical properties of cellular piezoelectret. Emphasis is placed on our own works of cellular piezoelectret published in past several years.展开更多
This paper discusses the time-of-arrival(TOA) based indoor visible light communication(VLC) positioning system in a non-line-of-sight environment. The propagation delay is assumed to be gamma distributed. The generali...This paper discusses the time-of-arrival(TOA) based indoor visible light communication(VLC) positioning system in a non-line-of-sight environment. The propagation delay is assumed to be gamma distributed. The generalized Cramer–Rao lower bound for multipath propagation is derived as the theoretical accuracy limitation. The performance of the positioning system is affected by the shape parameter and the scale parameter of gamma distribution.The influences on positioning accuracy of multipath effects are analyzed through discussing the physical meaning of the gamma distribution parameters. It is concluded that the lower bound of positioning accuracy is attained when variance of the non-line-of-sight propagation-induced path lengths is zero. The simulation result provesthat the theoretical positioning accuracy is in the order of centimeters with the given scenario.展开更多
Starting from the linear shallow-water wave equations including in themselves the effect of a large-scale orograpny, two types of gravity wave solutions are derived on the assumption that the Qinghai-Xizang Plateau se...Starting from the linear shallow-water wave equations including in themselves the effect of a large-scale orograpny, two types of gravity wave solutions are derived on the assumption that the Qinghai-Xizang Plateau serves as an orography in question inclined from west to east at the same slope. One type contains two solutions of high-frequency inertia-gravitational waves and the other solution of low-frequency topography-excited gravity waves, bearing some similarity to Kelvin mode. Both types are similar, respectively, to the gravity waves of the front of the cold surge during the rapid southward advance, and to the strong velocity center of the surge when it propagates southward slowly along the east brim of the Plateau, as shown by the numerical study. Results indicate that the low-frequency wave vanishes whereas its counterpart remains especially in the absence of the orography. In addition, we find that the propagation of the gravity-wave rays is in the form of a trochoid equation, a result in good agreement with the curved path of the strong velocity center going down the east fringe of the Plateau as shown by the numerical study. And probably a waveguide tube of topographic gravity mode is present in the coastwise area downstream of the orography.展开更多
The substitution effect of fluorine on ethylene is investigated by means of studying the properties of the charge distribution at the bond critical points with the theory of atoms in molecules.It is found that fluorin...The substitution effect of fluorine on ethylene is investigated by means of studying the properties of the charge distribution at the bond critical points with the theory of atoms in molecules.It is found that fluorine atom acts not only as a σ electron acceptor,but also as a π electron donor,and these double effects are reflected in the quantity of ellipticity,Lap- lacian and the charge density of charge distribution at the bond critical points.For C—C,C—F bonds,the major axis of elliptical contours is perpendicular to the molecular plane,but for C—H bond,it is parallel to the molecular plane.Other effects originating from the substi- tution have also been discussed.展开更多
This paper summarizes the entire construction process of Guangzhou's new central axis, including planning, design, and decisionmaking. The relationships among master plan, action plan and urban design are discusse...This paper summarizes the entire construction process of Guangzhou's new central axis, including planning, design, and decisionmaking. The relationships among master plan, action plan and urban design are discussed in a practical case. And design principles which should be followed and factors relevant to desirable effect in the urban design for key areas are also explored.展开更多
文摘The reac dynamics on Ba+BrCH_3→BaBr+CH_3 has been investigated in the first proposed potential energy surface of the generalized LEPS type,using the quasiclassical trajectory method.In simulation of the conditions in molecular beam experiments,the results of the present study show significant effect of the reagent collision energy on the dynamics of the reaction,and are in good agreement with the experimental ones.
基金supported by National Natural Science Foundation of China (11072179,11090334)Shanghai Leading Academic Discipline Project (B302)
文摘Due to the large quasi-piezoelectric d33 coefficient in the film thickness direction, cellular piezoelectret has emerged as a new kind of compliant electromechanical transducer materials. The macroscopic piezoelectric effect of cellular piezoelectret is closely related to the void microstructures as well as the material constants of host polymer. Complex void microstmctures are usually encountered in the optimum design of cellular piezoelectret polymer film with ad- vanced piezoelectric properties. Analysis of the effective electromechanical properties is generally needed. This article presents an overview of the recent progress on theoretical models and numerical simulation for the effective electromechanical properties of cellular piezoelectret. Emphasis is placed on our own works of cellular piezoelectret published in past several years.
基金supported by the National Key Basic Research Program of China (973 program) under grant 2013CB32920the Natural Science Foundation of China under grant 61375083
文摘This paper discusses the time-of-arrival(TOA) based indoor visible light communication(VLC) positioning system in a non-line-of-sight environment. The propagation delay is assumed to be gamma distributed. The generalized Cramer–Rao lower bound for multipath propagation is derived as the theoretical accuracy limitation. The performance of the positioning system is affected by the shape parameter and the scale parameter of gamma distribution.The influences on positioning accuracy of multipath effects are analyzed through discussing the physical meaning of the gamma distribution parameters. It is concluded that the lower bound of positioning accuracy is attained when variance of the non-line-of-sight propagation-induced path lengths is zero. The simulation result provesthat the theoretical positioning accuracy is in the order of centimeters with the given scenario.
基金The study is supported by National Natural Science Foundation of ChinaMonsoon Research Funds, State Meteorological Administration of PRC.
文摘Starting from the linear shallow-water wave equations including in themselves the effect of a large-scale orograpny, two types of gravity wave solutions are derived on the assumption that the Qinghai-Xizang Plateau serves as an orography in question inclined from west to east at the same slope. One type contains two solutions of high-frequency inertia-gravitational waves and the other solution of low-frequency topography-excited gravity waves, bearing some similarity to Kelvin mode. Both types are similar, respectively, to the gravity waves of the front of the cold surge during the rapid southward advance, and to the strong velocity center of the surge when it propagates southward slowly along the east brim of the Plateau, as shown by the numerical study. Results indicate that the low-frequency wave vanishes whereas its counterpart remains especially in the absence of the orography. In addition, we find that the propagation of the gravity-wave rays is in the form of a trochoid equation, a result in good agreement with the curved path of the strong velocity center going down the east fringe of the Plateau as shown by the numerical study. And probably a waveguide tube of topographic gravity mode is present in the coastwise area downstream of the orography.
基金Project supported by the National Natural Science Foundation of China.
文摘The substitution effect of fluorine on ethylene is investigated by means of studying the properties of the charge distribution at the bond critical points with the theory of atoms in molecules.It is found that fluorine atom acts not only as a σ electron acceptor,but also as a π electron donor,and these double effects are reflected in the quantity of ellipticity,Lap- lacian and the charge density of charge distribution at the bond critical points.For C—C,C—F bonds,the major axis of elliptical contours is perpendicular to the molecular plane,but for C—H bond,it is parallel to the molecular plane.Other effects originating from the substi- tution have also been discussed.
文摘This paper summarizes the entire construction process of Guangzhou's new central axis, including planning, design, and decisionmaking. The relationships among master plan, action plan and urban design are discussed in a practical case. And design principles which should be followed and factors relevant to desirable effect in the urban design for key areas are also explored.