We calculate the Rydberg and autoionization Rydberg spectra of antimony （Sb） from first principles by relativistic multichannel theory within the framework of multichannel quantum defect theory. Our calculation can ...We calculate the Rydberg and autoionization Rydberg spectra of antimony （Sb） from first principles by relativistic multichannel theory within the framework of multichannel quantum defect theory. Our calculation can be used to classify and assign the atomic states described in recently reported three Rydberg series and four autoionizing states. The perturbation effects on line intensity, variation and line profile are discussed. Assignments of the perturber states and autoionizing states are presented.展开更多
基金Supported by the Beijing Natural Science Foundation under Grant No 1164016the National Natural Science Foundation of China under Grant No 11604334the Funding from TRIUMF which receives Federal Funding via a Contribution Agreement with the National Research Council of Canada and through a Natural Sciences and Engineering Research Council of Canada under Grant No 386343-2011
文摘We calculate the Rydberg and autoionization Rydberg spectra of antimony （Sb） from first principles by relativistic multichannel theory within the framework of multichannel quantum defect theory. Our calculation can be used to classify and assign the atomic states described in recently reported three Rydberg series and four autoionizing states. The perturbation effects on line intensity, variation and line profile are discussed. Assignments of the perturber states and autoionizing states are presented.
