Emerging perovskite materials for supercapacitors:Structure,synthesis,modification,advanced characterization,theoretical calculation and electrochemical performance

As a new generation electrode materials for energy storage,perovskites have attracted wide attention because of their unique crystal structure,reversible active sites,rich oxygen vacancies,and good stability.In this review,the design and engineering progress of perovskite materials for supercapacitors(SCs)in recent years is summarized.Specifically,the review will focus on four types of perovskites,perovskite oxides,halide perovskites,fluoride perovskites,and multi-perovskites,within the context of their intrinsic structure and corresponding electrochemical performance.A series of experimental variables,such as synthesis,crystal structure,and electrochemical reaction mechanism,will be carefully analyzed by combining various advanced characterization techniques and theoretical calculations.The applications of these materials as electrodes are then featured for various SCs.Finally,we look forward to the prospects and challenges of perovskite-type SCs electrodes,as well as the future research direction.

Theoretical Modeling and Surface Roughness Prediction of Microtextured Surfaces in Ultrasonic Vibration-Assisted Milling

Textured surfaces with certain micro/nano structures have been proven to possess some advanced functions,such as reducing friction,improving wear and increasing wettability.Accurate prediction of micro/nano surface textures is of great significance for the design,fabrication and application of functional textured surfaces.In this paper,based on the kinematic analysis of cutter teeth,the discretization of ultrasonic machining process,transformation method of coordinate systems and the cubic spline data interpolation,an integrated theoretical model was established to characterize the distribution and geometric features of micro textures on the surfaces machined by different types of ultrasonic vibration-assisted milling(UVAM).Based on the theoretical model,the effect of key process parameters(vibration directions,vibration dimensions,cutting parameters and vibration parameters)on tool trajectories and microtextured surface morphology in UVAM is investigated.Besides,the effect of phase difference on the elliptical shape in 2D/3D ultrasonic elliptical vibration-assisted milling(UEVAM)was analyzed.Compared to conventional numerical models,the method of the cubic spline data interpolation is applied to the simulation of microtextured surface morphology in UVAM,which is more suitable for characterizing the morphological features of microtextured surfaces than traditional methods due to the presence of numerous micro textures.The prediction of surface roughness indicates that the magnitude of ultrasonic amplitude in z-direction should be strictly limited in 1D rotary UVAM,2D and 3D UEVAM due to the unfavorable effect of axial ultrasonic vibration on the surface quality.This study can provide theoretical guidance for the design and fabrication of microtextured surfaces in UVAM.

Evaluation of Medical Prescribers’ Theoretical Knowledge on Medical Imaging in the Northern Region of Burkina Faso

Introduction: Medical imaging is a medical specialty that involves producing images of the human body and interpreting them for diagnostic, therapeutic purposes, and for monitoring the progress of pathologies. We aimed to assess the theoretical knowledge of doctors and interns in medical imaging in the northern region of Burkina Faso. Methodology: This was a descriptive cross-sectional survey based on a self-administered questionnaire. Prescribers knowledge was estimated based on scores derived from questionnaire responses. Results: We collected 106 questionnaires out of 163, i.e. a participation rate of 65.03%. The average knowledge score was 81.71% for the contribution of medical imaging to patient management. It was 60.02% for the indications/counter-indications of radiological examinations and 72.56% for the risks associated with exposure to radiation during these examinations. The score was 59.83% for the methods used to select the appropriate radiological examination. As regards the completeness of the clinical and biological information on the forms requesting imaging examinations, the score was 96.65%. Specialist doctors had the highest overall level of knowledge (74.68%). Conclusion: Improved technical facilities, good initial and in-service training, and interdisciplinary collaboration will help to ensure that imaging tests are properly prescribed, leading to better patient care.

Systematic and Theoretical Unfolding of Research on Xi Jinping’s Discourses on Respecting and Protecting Human Rights

Xi Jinping’s discourses on respecting and protect-ing human rights stand as a shining example of the sinicization and modernization of Marxist human rights theory,embodying profound theoretical,political,practical,and cultural logic.Existing research has conducted comprehensive and systematic theoretical analysis and academic extractions on the following contents:the core essence in-herent in these important discourses,including the“theory of human rights concepts,”the“theory of human rights paths,”the“theory of human rights practices,”the“theory of human rights protection,”and the“theory of human rights governance,”along with their profound theoretical significance,practical significance,and global signifi-cance.In the future,researchers should emphasize efforts on studying the original texts and understanding the original principles.While focusing on the precision of concepts,the scientific nature of the prop-ositions,the maturity of theoretical systems,and the rigor of internal logic related to Xi Jinping’s discourses on respecting and protecting human rights,researchers should also pay attention to constructing a discourse system on human rights from the dimensions of discourse power,discourse cluster,and discourse field.Researchers should be adept at drawing innovative insights into human rights theory from China’s vibrant human rights practices and the vast masses of people.This approach will facilitate the systematic unfolding,academic trans-formation,and innovative development of Xi Jinping’s discourses on respecting and protecting human rights.

Evaluation of the Effectiveness of the “1 + 1 + 1” Method in Theoretical Teaching of Emergency Pericardiocentesis

Background: Pericardial effusion may progress to cardiac tamponade when pressure around the heart increases to a level comparable to that of the right and left atria. Patients with cardiac tamponade need timely completion of emergency pericardiocentesis to relieve the threat to the patient’s life, and to save valuable time for patients who need emergency thoracotomy and pericardial window drainage. Pericardiocentesis is a necessary clinical skill for residents in standardized training. In addition, nurses who are familiar with this technology can better assist clinicians to perform this operation. In order to make the medical staff quickly master the theoretical knowledge of emergency pericardiocentesis, we designed a “1 + 1 + 1” teaching method for the theoretical teaching of emergency pericardiocentesis. Objective: This study aims to explore the effectiveness of the “1 + 1 + 1” teaching method in the theoretical teaching of emergency pericardiocentesis. Methods: We used an English teaching video of emergency pericardiocentesis and applied the “1 + 1 + 1” teaching method for theoretical teaching. A questionnaire survey was conducted before and after the lecture among 19 medical staff of different years of service to understand their mastery of the theoretical content of emergency pericardiocentesis before and after the lecture. According to the years of service, the medical staff were divided into three groups: 1 - 3 years (Group A), 4 - 10 years (Group B), and over 10 years (Group C), and the changes in the mastery of various contents by the overall medical staff and each group were statistically analyzed. Results: Before the lecture, the number of people who mastered the indications, contraindications, most commonly used methods, and common complications of emergency pericardiocentesis were 15, 12, 16, and 17, respectively, whereas after the lecture, these numbers increased to 17, 19, 19, and 19, respectively. The overall mastery before and after the lecture was statistically significant (p Conclusion: The “1 + 1 + 1” teaching method can effectively improve the overall mastery level of medical staff’s theoretical knowledge of emergency pericardiocentesis, especially in improving the mastery of contraindications of this operation.

Research on the Upper Limit of Accuracy for Predicting Theoretical Tandem Mass Spectrometry

In recent years, numerous theoretical tandem mass spectrometry prediction methods have been proposed, yet a systematic study and evaluation of their theoretical accuracy limits have not been conducted. If the accuracy of current methods approaches this limit, further exploration of new prediction techniques may become redundant. Conversely, a need for more precise prediction methods or models may be indicated. In this study, we have experimentally analyzed the limits of accuracy at different numbers of ions and parameters using repeated spectral pairs and integrating various similarity metrics. Results show significant achievements in accuracy for backbone ion methods with room for improvement. In contrast, full-spectrum prediction methods exhibit greater potential relative to the theoretical accuracy limit. Additionally, findings highlight the significant impact of normalized collision energy and instrument type on prediction accuracy, underscoring the importance of considering these factors in future theoretical tandem mass spectrometry predictions.

Recent Progress in Atmospheric Chemistry Research in China: Establishing a Theoretical Framework for the “Air Pollution Complex”

Atmospheric chemistry research has been growing rapidly in China in the last 25 years since the concept of the“air pollution complex”was first proposed by Professor Xiaoyan TANG in 1997.For papers published in 2021 on air pollution(only papers included in the Web of Science Core Collection database were considered),more than 24000 papers were authored or co-authored by scientists working in China.In this paper,we review a limited number of representative and significant studies on atmospheric chemistry in China in the last few years,including studies on(1)sources and emission inventories,(2)atmospheric chemical processes,(3)interactions of air pollution with meteorology,weather and climate,(4)interactions between the biosphere and atmosphere,and(5)data assimilation.The intention was not to provide a complete review of all progress made in the last few years,but rather to serve as a starting point for learning more about atmospheric chemistry research in China.The advances reviewed in this paper have enabled a theoretical framework for the air pollution complex to be established,provided robust scientific support to highly successful air pollution control policies in China,and created great opportunities in education,training,and career development for many graduate students and young scientists.This paper further highlights that developing and low-income countries that are heavily affected by air pollution can benefit from these research advances,whilst at the same time acknowledging that many challenges and opportunities still remain in atmospheric chemistry research in China,to hopefully be addressed over the next few decades.

Synthesis, Crystal Structure and Theoretically Study of 2-(Dimethylamino)-1,3-dithiocyanatopropane and Its Isomer

2-（Dimethylamino）-1,3-dithiocyanatopropane（1） has been prepared as a key intermediate synthesizing a natural insecticide Cartap by the reaction of 1-dimethylamino-2,3-dichloropropane with sodium thiocyanate. The crystal structures of compound 1 and its isomer 1-（dimethylamino）-2,3-dithiocyanotopropane（2） formed during the reaction were determined by X-ray single-crystal diffraction. Bond lengths in both the compounds are common and fall within normal ranges. There are some weak C―H×××N hydrogen bonds in the lattice of compound 1, which makes it form a three-dimensional network, which stabilize the crystal structure. No classic hydrogen bonds were founded in its isomer（2）, only van der Waals forces contribute to the stability of the structure. In addition, DFT and MP2 calculations with 6-311＋G（d, p） basis set have also been carried out to investigate the thermodynamic properties of compounds 1 and 2. The research will be applied to the further investigation of the tautomerization of compounds 1 and 2.

Enhancing effect of choline chloride-based deep eutectic solvents with polyols on the aqueous solubility of curcumin–insight from experiment and theoretical calculation

The development of green solvents for enhancing aqueous solubility of drug curcumin remains a challenge. This study explores the enhancing effect of deep eutectic solvents(DESs) on the aqueous solubility of curcumin(CUR) via experiment and theoretical calculation. Choline chloride-based DESs with polyols 1,2-propanediol(1,2-PDO), 1,3-propanediol, ethylene glycol, and glycerol as hydrogen bond donors were prepared and used as co-solvents. The CUR aqueous solubility increased with increasing the DESs content at temperature of 303.15-318.15 K, especially in aqueous ChCl/1,2-PDO(mole ratio 1:4) solutions. The positive apparent molar volume values and reduced density gradient analysis confirmed the existence of strong interactions between CUR and solvent. The van der Waals interactions and hydrogen bonding coexisted in DESs monomer retained the stability of DESs structure after introducing CUR. Moreover,the lower interaction energy of DESs…CUR system than that of the counterpart DESs further proved the strong interaction between CUR and DESs. The lowest interaction energy of ChCl/1,2-PDO…CUR system indicated that this system was the most stable and ChCl/1,2-PDO was promising for CUR dissolution.This work provides efficient solvents for utilizing curcumin, contributing to a deep insight into the interactions between DES and CUR at the molecular level, and the role of DESs on enhancing drugs solubility.

Theoretical analyses on the one-dimensional charged particle transport in a decaying plasma under an electrostatic field

The spatiotemporal evolutions of a one-dimensional collisionless decaying plasma bounded by two electrodes with an externally applied electrostatic field are studied by theoretical analyses and particle-in-cell(PIC)simulations with the ion extraction process in a laser-induced plasma as the major research background.Based on the theoretical analyses,the transport process of the charged particles including electrons and ions can be divided into three stages:electron oscillation and ion matrix sheath extraction stage,sheath expansion and ion rarefaction wave propagation stage and the plasma collapse stage,and the corresponding criterion for each stage is also presented.Consequently,a complete analytical model is established for describing the ion extraction flux at each stage during the decaying of the laser-induced plasmas under an electrostatic field,which is also validated by the PIC modeling results.Based on this analytical model,influences of the key physical parameters,including the initial electron temperature and number density,plasma width and the externally applied electric voltage,on the ratio of the extracted ions are predicted.The calculated results show that a higher applied electric potential,smaller initial plasma number density and plasma width lead to a higher ratio of the extracted ions during the first stage;while in this stage,the initial electron temperature shows little effect on it.Meanwhile,more ions will be extracted before the plasma collapse once a higher electric potential is applied.The theoretical model presented in this paper is helpful not only for a deep understanding to the charged particle transport mechanisms for a bounded decaying plasma under an applied electrostatic field,but also for an optimization of the ion extraction process in practical applications.

Theoretical Transplantation into Translation Studies——An Analysis on the Pragmatic Application of Hofstede’s

The deepening process of globalization has given rise to restless cultural exchanges among people from different regions of the world through newspapers,books,and other written media.However,the significant differences in languages and cultures have become an insurmountable gap in intercultural communication.To lubricate cultural exchanges,new translation theories that focus on the transformation of different cultural concepts shall be introduced and adopted.This paper aims to extract applicable notions from Hofstede’s Cultural Dimensions for pragmatic translation studies by laying emphasis on its pragmatic value through case study.By such theoretical transplantation,valuable suggestions are proposed to tackle cultural misunderstandings and conflicts encountered amid cultural exchanges.

数字赋能文旅深度融合的理论逻辑与研究框架

数字赋能文旅深度融合既是数字经济时代文旅发展的重要方式,又是文旅研究的重要课题。文章在阐述文旅深度融合内涵的基础上,探究了数字赋能文旅深度融合的基本逻辑,认为数字技术嵌入支撑文旅数字化,促进文旅信息融合化,带来文旅产业新变革,形成文旅共生体和数字文旅新形态。从理论研究、数字赋能和融合实践3个维度,初步构建了数字赋能文旅深度融合的研究框架,强调要创新性地运用文旅IP理论、融合共生理论、文旅场景理论、产业演化理论、系统动力学等理论,阐释文旅融合学理及其内在逻辑、演化过程和动力机制,深化文旅深度融合主要科学问题研究。文章提出要把握数字赋能文旅融合的关键技术、文旅资源普查与评价、文旅融合场景建构、文旅产业融合创新生态体系、国家文化公园与文旅融合示范区建设、科技创新与数字文旅人才培养等关键问题,推动文旅融合应用实践和学术研究持续创新,更好地服务于新时代中国式现代化建设和文旅高质量发展。

教育促进新质生产力发展的理论逻辑与路径

新质生产力是以新质劳动力、新质生产工具和新质劳动对象为构成要素,以科技创新为内核,以推动高质量发展为目标的生产力新质态。新质生产力的发展离不开教育的高质量发展,教育通过人才创新、知识创新、技术创新以及产业创新分别作用于新质生产力三要素,从而对新质生产力发展形成基础性、战略性支撑。因此,在微观层面,以科技创新人才自主培养夯实新质生产力发展的劳动力基础;在中观层面,以产学研深度融合加速适应新质生产力发展的创新集聚;在宏观层面,以高水平教育对外开放为新质生产力发展注入外部动力。

习近平文化思想的内涵、特征与核心要义

习近平文化思想是新时代党领导宣传思想文化建设经验的理论总结与思想提升,极大丰富和发展了马克思主义文化理论,在党的文化事业发展史上具有里程碑意义。从内涵看,习近平文化思想是以文化使命为统领,由文化传承、文化创新、文化权益、文化共识、文化引领等方面构成的完备理论体系。从特征看,习近平文化思想具有鲜明的科学性、人民性、实践性、发展性,不仅体现了习近平文化思想的本质,而且展现了习近平文化思想的理论形象。从核心要义看,习近平文化思想主要围绕保障文化安全、坚定文化自信、建设文化强国、增强文化影响等价值目标为新时代宣传思想文化建设提供思想武器和行动指南,为以中国式现代化全面推进中华民族伟大复兴坚定信念、振奋人心、凝聚力量。

“中西交融”的管理理论建构与创新

基于理论与情境的匹配来建立管理理论分析框架,管理研究可以划分为成熟理论研究、拓展理论研究、新创理论研究和深入理论研究,分别解决不同的现实问题。中国管理理论的建构与创新主要延续着从“再情境化”到“去情境化”的动态循环,并在情境化理论和理论化情境的交替作用下,形成“成熟理论—拓展理论—新创理论—深入理论”的演进路径。中国情境不仅可以修正和完善西方管理理论并将其运用于本土情境,而且可以立足本土情境的独特性来建构中国管理理论,还能通过理论的持续创新进行扩散和传播,以形成能得到中西方共同接受与认可的管理理论体系,最终确立管理理论的“中国话语体系”和贡献中国管理智慧。

管理学范式视角下理论融合的内在逻辑与理论建构

理论融合属于基于范式的一般理论创新,是推动中层理论发展的重要基础。从管理学范式的视角对理论融合的内在逻辑和理论建构进行分析,利用多中心性思想辨析不同范式间的复杂关联,并构建新的范式研究体系来调和观点纷争以实现“求同存异”。不同的范式会依据兼容性与一致性的逻辑规则来推动理论融合,围绕边界分别形成范式分离、范式连接、范式互补和范式叠加的关联形式。这决定了源于不同范式产生的单一理论在融合过程中的结构关系,有助于完成理论建构并产生新的视角来增强对管理活动的解释力度。

大模型伦理失范的理论解构与治理创新

ChatGPT系列和Sora等大模型作为人工智能技术的发展前沿,在助力人类生产生活的数字化和智能化转型提速的同时,也引发一系列伦理失范现象,成为全球性治理难题。本文对大模型伦理失范进行理论解构发现:大模型伦理失范的缘起是其区别于传统生产力和生产工具的技术非中性、内嵌人类伦理和将人类伦理与机器伦理糅合其中等属性特征,技术起点是算法,关键中介是数据,行为主体是人类。大模型所引发的诸如模型黑箱、数据版权侵害且主体责任难确定、冲击人类主体资格等伦理失范现象对现行伦理治理模式提出挑战。因此,本文以大模型生命周期为时间维度,以关键要素为核心,构建了基于大模型关键要素的全生命周期伦理治理框架。同时,为推动新伦理治理框架的有效运行,本文构建了包含两层行为主体的自我治理、两级守门人和全球性合作治理网络等子体系的大模型伦理治理生态体系。

以制度型开放助推新质生产力发展:理论机制与政策建议

发展新质生产力需要扩大高水平对外开放、全面深化改革,形成与之相适应的新型生产关系。通过制度型开放推动中国全面深化改革,构建高标准的市场体系,是形成与新质生产力发展相适应的生产关系的重要途径。文章首先介绍了新质生产力的内涵及其提出的历史逻辑,然后分析了当前制度型开放的具体表现和中国的实践成效。在此基础上,揭示了制度型开放主要通过吸引和聚集全球高端生产资源、畅通和强化技术创新激励机制、参与并引领数字经贸规则制定、发挥市场优化配置资源的作用,以及提升生产性服务业的竞争力等途径推动新质生产力的发展。最后,对如何加快推进制度型开放,促进新质生产力发展提出了有针对性的政策建议。

教育赋能新质生产力:理论逻辑与实践路径

新质生产力是以科技创新为驱动,以高层次创新型人才为支撑,以战略性新兴产业和未来产业为载体,以数字化、智能化、绿色化为基石形成的高效能、高质量生产力,具有更显创新性、更具数字化、更富跨越性、更重高质量等时代特征。新质生产力与教育发展有着双向驱动的内在逻辑:一方面,新质生产力引发教育理念、目标、内容、方式、体系和治理的系统性变革;另一方面,教育通过促进劳动力再生产提升新质生产力、促进科技创新锻造新质生产力、促进知识再生产升级新质生产力,是新质生产力形成的关键要素和积极变量。随着当前新一轮科技革命和产业变革的加速推进,教育赋能新质生产力亟待促进教育理念的更新、培养模式的升级、供需匹配的优化以及国际链接的畅通。基于问题提出四个方面建议:一要坚持系统观念,树立教育、科技、人才一体化统筹推进的“大教育观”;二要坚持协同创新,以产学研深度融合培养高层次创新型人才;三要坚持动态调整,促进高等教育、职业教育供给侧与产业结构需求侧协同发展;四要坚持对外开放,加快建成具有强大影响力的世界重要教育中心。

习近平文化思想的科学性与实践性

党的十八大以来,习近平总书记高度重视党的宣传思想文化工作,主持召开一系列重要会议、发表一系列重要讲话、提出一系列新思想新观点新论断,形成了习近平文化思想。这一思想是一个内涵丰富、逻辑严密的理论体系,科学回答了关于党的宣传思想文化工作的一系列方向性、根本性、战略性的重大问题。这一思想具有深厚的实践基础,新时代十余年来党的宣传思想文化工作在习近平新时代中国特色社会主义思想的指引下,经过“正本清源”与“守正创新”接续努力,取得了历史性成就、发生了历史性变革,也积累了一系列宝贵经验。这一思想正是对党的宣传思想文化工作经验,尤其是新时代实践经验的科学总结。从新时代党的宣传思想文化工作重要经验及其背后逻辑来看,习近平文化思想的科学性和实践性得到进一步彰显和印证,我们党对宣传思想文化工作的规律性认识也进一步深化。