Al2 O3 - SiC - SiAION composite specimens have been prepared using fused alumina, ultra fine α-Al2O3, Si and Al powders as starting materials and liquid phenol formaldehyde resin as binder and firing at 1 500 ℃ for ...Al2 O3 - SiC - SiAION composite specimens have been prepared using fused alumina, ultra fine α-Al2O3, Si and Al powders as starting materials and liquid phenol formaldehyde resin as binder and firing at 1 500 ℃ for 3 h in carbon embedded condition. Thermo-mechanical properties of Al2 O3 - SiC - SiAlON composites have been studied. The results show ： （ 1 ） Al2 O3 - SiC - SiAION composites can be prepared and sintered at 1 500 ℃ under carbon embedded condition. When Si/Al ratio is 8/0 and 7/1, the prepared composite is Al2O3 - SiC - O＇ -SiAlON; when Si/Al ratio is 5/3 and 3/5, the pre- pared composite is Al2 O3 - SiC - β-SiAION. （ 2 ） The composites possess high temperature strength properties. Hot modulus of rupture at 1 400 ℃ is 10 - 30 MPa. They are in elastic range up to 1 000 ℃, after which plastic deformation is observed; even at 1 400 ℃, amount of deformation is relatively low. （3） The com- posites possess good thermal shock resistance, their resid- ual strength ratio （AT = 1 100 ℃ ） is 65% - 80%. （4） The marked improvement in thermo-mechanical properties of Al2O3 - SiC - SiAlON composites may be at- tributed to the in-situ formation of SiC, SiAlON and AIN, the fibrous SiC, columnar SiAlON and tabular-like AlN fill in the corundum skeleton structure creating strengthening and toughening effects.展开更多
基金the financial support of Science Fund for International Cooperation Project(No.152102410014)the Education Department of Henan Province Foundation(14A430030)Research Foundation of Zhengzhou City(131PPTGG-409-3)
文摘Al2 O3 - SiC - SiAION composite specimens have been prepared using fused alumina, ultra fine α-Al2O3, Si and Al powders as starting materials and liquid phenol formaldehyde resin as binder and firing at 1 500 ℃ for 3 h in carbon embedded condition. Thermo-mechanical properties of Al2 O3 - SiC - SiAlON composites have been studied. The results show ： （ 1 ） Al2 O3 - SiC - SiAION composites can be prepared and sintered at 1 500 ℃ under carbon embedded condition. When Si/Al ratio is 8/0 and 7/1, the prepared composite is Al2O3 - SiC - O＇ -SiAlON; when Si/Al ratio is 5/3 and 3/5, the pre- pared composite is Al2 O3 - SiC - β-SiAION. （ 2 ） The composites possess high temperature strength properties. Hot modulus of rupture at 1 400 ℃ is 10 - 30 MPa. They are in elastic range up to 1 000 ℃, after which plastic deformation is observed; even at 1 400 ℃, amount of deformation is relatively low. （3） The com- posites possess good thermal shock resistance, their resid- ual strength ratio （AT = 1 100 ℃ ） is 65% - 80%. （4） The marked improvement in thermo-mechanical properties of Al2O3 - SiC - SiAlON composites may be at- tributed to the in-situ formation of SiC, SiAlON and AIN, the fibrous SiC, columnar SiAlON and tabular-like AlN fill in the corundum skeleton structure creating strengthening and toughening effects.
