Theoretical design of thermal spin molecular logic gates by using a combinational molecular junction

Based on the density functional theory combined with the nonequilibrium Green function methodology,we have studied the thermally-driven spin-dependent transport properties of a combinational molecular junction consisting of a planar four-coordinate Fe molecule and a 15,16-dinitrile dihydropyrene/cyclophanediene molecule,with single-walled carbon nanotube bridge and electrode.Our results show that the magnetic field and light can effectively regulate the thermallydriven spin-dependent currents.Perfect thermal spin-filtering effect and good thermal switching effect are realized.The results are explained by the Fermi-Dirac distribution function,the spin-resolved transmission spectra,the spatial distribution of molecular projected self-consistent Hamiltonian orbitals,and the spin-resolved current spectra.On the basis of these thermally-driven spin-dependent transport properties,we have further designed three basic thermal spin molecular AND,OR,and NOT gates.

Thermal performance analysis of advanced partial gasification combined cycle

This paper presents the thermodynamic performance analysis and comparison of four kinds of advanced pressurized fluidized bed combustion combined cycle (APFBC-CC) system schemes, two based on pressurized fluidized bed (PFB) combustion and the other two based on atmospheric circulating fluidized bed (CFB) combustion. The results show that the first scheme avoids high temperature gas filter, but has the lower cycle efficiency and syngas heating value. The second scheme can gain the highest cycle efficiency, however it is better to now lower the filter operating temperature. The third and fourth schemes, based on CFB, have lower efficiencies than the second one. But the fourth one, with preheating air/steam for gasification, can obtain the highest heating value of syngas and gain higher efficiency than the third one.

Thermal-environment characteristics and comfort of combined radiant-floor (Korean heating system ondol) and convective cooling system

The thermal-environment characteristics of the existing forced-convection cooling system were compared with those of the convective cooling system, which combined the radiant-floor cooling system using floor-heating panel typically applied to apartments in South Korea with the forced-convection cooling system using improved fan coil unit. The subjective warm/cool-feeling responses to the combined radiant-floor and convective cooling system in the questionnaire survey conducted among the test subjects were analyzed to establish the basic data for the combined cooling system. The results show that in the thermal-equilibrium condition, the vertical air temperature difference in the model living room is larger in the forced-convection-cooling condition. Most of the subjects feel a proper warm/cool feeling on their entire body, but they feel colder on the foot and lower body in the combined-cooling condition.

Fast Calculation Method of Energy Flow for Combined Electro-Thermal System and Its Application

In recent years, Combined electro-thermal system has developed rapidly. In order to provide the initial data for the analysis of the combined electro-thermal system, a practical energy flow calculation method for the combined electro-thermal system is proposed in this paper. Based on the detailed analysis of the topology structure of the heating network and its hydraulic and thermodynamic model, the forward-backward sweep method for the heat flow of the heating network is established, which is more suitable for the actual radial heating network. The electric and thermal coupling model for heating source, such as thermoelectric unit and electric boiler is established, and the heat flow of heating network and the power flow of power grid are calculated orderly, thus a fast calculation method for the combined electro-thermal system is formed. What’s more, a combined electro-thermal system with two-stage peak-shaving electric boiler is used as the example system. This paper validates the effectiveness and rapidity of this method through the example system, and analyzes the influence for the energy flow of combined electro-thermal system caused by the operating parameters such as the installation location of electric boiler, the outlet water temperature of heat source and the outlet flow rate, etc.

Thermal Analyses of Combined Utilization Process of Seawater by Solar Chimney

It is promising to simultaneously develop multiple products through the combined utilization of seawater by solar chimney technology. A small scale experimental system was set up. The collector temperature, the seawater temperature, and the temperature and humidity of the airflow under the collector were measured. Thermal network analysis of the system was carried out. The results show that the airflow is nearly saturated at the entrance of the chimney, and the mean dry-bulb and wet-bulb temperatures of the airflow have increased by 8.4 ℃ and 9.6 ℃, respectively. The radiation heat transfer between the collector and the sky is the biggest heat loss in the system, which is up to 29.1% on average of the solar energy. However, the water evaporation heat is about 23.6% on average of the solar energy. To reduce the heat loss and enhance the water evaporation, it is necessary to reduce the emissivity and thermal conductivity of the collector and increase the evaporation areas.

Application of Combined Cycle in Modernized Retrofit of Old Thermal Power Plants

This article expounds the advantages and three schemes of applying combined cycle to the modernized retrofit of old thermal power plants. Through analyzing and comparing technical economics of these three schemes, it is concluded that to use feedwater heating and heat recovery steam generator (HRSG) is suitable for the units with unit capacity below 100 MW, while to use exhaust gas reburning is suitable for units with unit capacity of 125 MW, 200 MW and above.

Study on Non-Isothermal Decomposition Kinetics of Ephedrini Hydrochloridum

The thermal decomposition processes of ephedrini hydrochloridum and its kinetics are studied by TG-DTG techniques. A combined method, which includes Achar method, Coats-Redfera method, and Ozawa method, is put forward for determining kinetic model under non-isothermal conditions. By applying the combined method, it is determined that the thermal decomposition of ephedrini hydrochloridum is subjected to cylindrical symmetric diffusion. And the reaction function isƒ(α)=2(1-α)?, apparent activation energy (115.26±3.55) kJ·mol−1, pre-exponential factor 4.62×108 s−1. Results show that the combined method is feasible and simple.

Simulation and performance analysis of organic Rankine cycle combined heat and power system

To improve the overall thermal efficiency of the organic Rankine cycle（ ORC）, a simulation study was carried out for a combined heat and power（ CHP） system, using the Redlich-Kuang-Soave（ RKS） equation of state. In the system,R245 fa was selected as the working fluid. A scroll expander was modeled with empirical isentropic expansion efficiency.Plate heat exchangers were selected as the evaporator and the condenser, and detailed heat transfer models were programmed for both one-phase and two-phase regions. Simulations were carried out at seven different heat source temperatures（ 80,90, 100, 110, 120, 130, 140 ℃） in combination with eight different heat sink temperatures（ 20, 25, 30, 35, 40, 45, 50,55 ℃）. Results showthat in the ORC without an internal heat exchanger（ IHE）, the optimum cycle efficiencies are in the range of 7. 0% to 7. 3% when the temperature differences between the heat source and heat sink are in the range of 70 to90 ℃. Simulations on CHP reveal that domestic hot water can be produced when the heat sink inlet temperature is higher than40 ℃, and the corresponding exergy efficiency and overall thermal efficiency are 29% to 56% and 87% to 90% higher than those in the non-CHP ORC, respectively. It is found that the IHE has little effect on the improvement of work output and efficiencies for the CHP ORC.

POSTBUCKLING OF IMPERFECT STIFFENED CYLINDRICAL SHELLS UNDER COMBINED EXTERNAL PRESSURE AND HEATING

A postbuckling analysis is presented for a stiffened cylindrical shell of finite length subjected to combined loading of external pressure and a uniform temperature rise. The formulations are based on a boundary layer theory of shell buckling, which includes the effects of nonlinear prebuckling deformations, nonlinear large deflections in the postbuckling range and initial geometrical imperfections of the shell. The 'smeared stiffener' approach is adopted for the stiffeners. The analysis uses a singular perturbation technique to determine the interactive buckling loads and the postbuckling equilibrium paths. Numerical examples cover the performances of perfect and imperfect, stringer and ring stiffened cylindrical shells. Typical results are presented in dimensionless graphical form.

Successful treatment of eyebrow intradermal nevi by shearing combined with electrocautery and curettage:Two case reports

BACKGROUND An intradermal nevus is a common skin tumour,and the classical method of removal has a risk of recurrence and scarring.It is a challenge for dermatologists to treat eyebrow intradermal nevi quickly and efficiently.This study focused on investigating the efficacy and safety of shearing combined with electrocautery and curettage in the treatment of eyebrow intradermal nevi.CASE SUMMARY We describe two adult patients with eyebrow intradermal nevi treated by shearing combined with electrocautery and curettage.Both patients were followed up regularly after surgery.At follow-up,no recurrence of eyebrow intradermal nevus and no obvious scars or hypopigmentation were found in either patient.The results indicated that shearing combined with electrocautery and curettage could remove eyebrow intradermal nevus without side effects and confirmed the efficacy and safety of this modality for treating these skin lesions.CONCLUSION Shearing combined with electrocautery and curettage has superior merits,including simple operation,good cosmetic effects,and high patient satisfaction,presenting great application potential for treating intracutaneous nevus.

太阳能辅助热电联产机组供热、发电及调峰性能分析

针对新能源存在不稳定性导致电网调峰问题日益严重的现状,结合较为成熟的光煤互补发电技术及多热源联合供热调峰系统,设计光煤混合供热发电系统,使热电联产机组具有一定的调峰能力。以某300 MW热电联产机组为研究对象,利用Ebsilon Professional软件搭建发电、供热可灵活调节的太阳能辅助热电联产系统,基于供热机组实际双机运行工况,在保证供热负荷前提下,分析太阳能辅助双机热电联产机组耦合方式,比较耦合前后双机调峰性能。结果表明:凝汽器出口与太阳能集热系统换热器间的管道上设置动态节流阀,改变太阳能集热系统辅助供热机组的运行模式,能够实现发电、供热、调峰一体系统的灵活运行;其中,以太阳能集热系统仅用于补充供暖的运行方式调峰能力最强,太阳能辅助单机供热前后调峰容量比值为0.76,太阳能辅助双机供热前后调峰容量比值为0.55,太阳能辅助承担最大供热负荷的1号机组在调峰容量及调峰补偿上效果最佳。

针刺联合艾灸治疗急性期周围性面瘫的疗效观察

目的 观察针刺联合艾灸治疗急性期周围性面瘫的临床疗效。方法 将60例急性期周围性面瘫患者随机分为治疗组和对照组,每组30例。对照组采用针刺联合药物治疗,治疗组在此基础上采用按摩灸治疗。观察两组治疗前后面部House-Brackmann(H-B)面神经功能分级、肌电图、面部残疾指数(facial disability index,FDI)量表评分变化,比较两组治疗前后炎性因子[超敏C反应蛋白(hypersensitive C-reactive protein,hs-CRP)、白细胞(white blood cell, WBC)计数、中性粒细胞与淋巴细胞的比值(neutrophil-to-lymphocyte ratio, NLR)和血小板与淋巴细胞的比值(platelet-to-lymphoccyte ratio, PLR)]变化,并比较两组临床疗效。结果 治疗组总有效率为96.7%,对照组总有效率为86.7%,两组比较差异有统计学意义(P<0.01)。两组治疗后H-B面神经功能分级优于治疗前(P<0.05),且治疗组的H-B面神经功能分级优于对照组(P<0.05)。两组治疗后口轮匝肌、眼轮匝肌、额肌肌电图潜伏期明显低于治疗前(P<0.05),治疗组低于对照组(P<0.01)。两组治疗后口轮匝肌、眼轮匝肌、额肌患健侧肌电图波幅比值高于治疗前(P<0.01),治疗组高于对照组(P<0.01)。两组治疗后FDI躯体功能评分(facial disability index physical function,FDIP)和社会功能评分(facial disability index social function, FDIS)评分优于治疗前(P<0.01),治疗组优于对照组(P<0.01)。两组治疗后炎性因子水平低于治疗前(P<0.05),治疗组低于对照组(P<0.05)。结论 在药物治疗的基础上,针刺联合艾灸可有效促进急性期周围性面瘫患者面神经功能和社会功能的恢复,疗效优于单纯针刺治疗,其机制可能与改善急性期面神经炎症反应有关。

SFCC现场导热系数与温度场实测及预测方法研究

为确定钢纤维页岩陶粒混凝土(SFCC)现场实际的导热系数,与桥面板施工同步制作了不同钢纤维体积分数的SFCC试件,采用热板法进行测定,校核并扩展了导热系数预测公式,并且对高温沥青摊铺时SFCC桥面板的温度场进行了实测和数值模拟.结果表明:环境湿度为67%时,SFCC的实测导热系数为0.915~1.409 W/(m·K),增加钢纤维体积分数可提高SFCC导热系数;考虑湿度和钢纤维影响后的扩展Maxwell公式预测值与实测值吻合良好;高温沥青摊铺时桥面板SFCC混凝土内的温度梯度可达20.5℃,超过规范日温差,采用数值模拟可有效计算桥面板温度场.

基于预测负荷的暖通空调系统优化调度

随着我国“双碳”目标的提出,公共建筑能耗低碳化成为重点研究领域,其中基于冷热负荷预测结果优化供能系统调度策略是实现“按需供能”的有效技术手段。针对公共建筑,基于热阻法构建了冷热负荷预测模型,根据负荷预测结果,采用改进粒子群优化(PSO)算法对复合冷热源供能系统的负载、水网供回水温度和流量、阀门开度以及泵组启用台数进行迭代寻优,以供能系统运行成本、机组寿命和环保性为优化目标提出全工况最佳运行策略。基于研究成果对某公共建筑冬季供热系统进行节能改造,可在满足建筑热负荷、平衡水力工况和延长机组运行寿命的同时,分别实现降低泵组功耗10.66%、系统运行成本21.52%。结果符合理论实际,证明了所提方法的可行性与有效性,为公共建筑的按需供热、节能运行提供了有效参考。

基于组合边界条件的固体材料热扩散系数测试方法

提出了一种组合边界条件下结合传热反问题思想测算固体材料热扩散系数的方法.建立了正问题理论模型,基于有限体积法和交替方向隐式方法的思想利用MATLAB软件对正问题温度场进行数值求解,利用共轭梯度法结合软件编程求解反问题,反演得到材料的热扩散系数.设计了实验方案并搭建了完整的测试系统,利用测试装置对亚克力板(PMMA)、硼硅玻璃(Pyrex7740)、大理石3种材料进行了综合实验,结果表明导热系数测试结果与文献值的最大相对偏差为3.45%,小于5%,验证了测试方法和装置的可行性与准确性.进一步对PMMA热扩散系数实验的不确定度进行了分析,得到扩展不确定度为4.86%,处于较低水平,说明实验数据可靠,测试方法科学.

胜利油田油藏数值模拟技术新进展及发展方向

油藏数值模拟技术是油藏分析的重要手段,是油田开发人员编制开发方案、开展动态跟踪调整、进行提高油藏采收率研究等工作的有力工具。为明确胜利油田油藏数值模拟技术的未来发展方向,回顾了胜利油田60年以来油藏数值模拟应用技术和自主知识产权软件研发的发展历程,着重总结了“十三五”以来适配油田当前地质及开发特征的特高含水期精细油藏描述、低渗透油藏压驱开发、非均相复合驱、稠油油藏多元热复合驱、CO_(2)高压混相驱、页岩油大规模压裂整体开发等多个领域的数值模拟应用技术创新性进展;介绍了涵盖水驱、化学驱、微观、智能模拟等不同方向的多款胜利特色油藏数值模拟软件的研发及应用情况。最后指出在当前胜利油田的开发形势下,油藏数值模拟在精细程度、规模、效率和协作方式等方面面临着更大的挑战,油藏数值模拟需要进一步向一体化、并行化、智能化方向发展,为胜利油田开发提质增效提供技术支撑。

计及最小惯量约束的风光火储联合系统优化调度

风、光、储多种新能源并网使系统常常处在低惯量运行场景下,给考虑频率稳定的系统优化调度带来极大挑战。为此提出了一种计及最小惯量约束的多源联合电力系统优化调度模型。首先,综合考虑两项频率指标,计算满足频率指标的系统最小惯量需求,将非线性的频率稳定约束转化为线性的最小惯量约束加入调度模型之中。其次,利用含模糊参数的机会约束表达源荷不确定性对于联合系统的影响,建立模糊参数下的系统优化调度模型。最后,通过IEEE 30节点系统验证了该模型的经济性与安全性。

考虑风-光不确定性的风-光-蓄-火联合调度研究

在当前风电和光伏大规模并网的背景下,要确保能源供应的稳定性和高效性,关键任务是确定合适的可再生能源渗透率,并精确配比可再生能源与储能系统的容量。因此,在考虑风、光不确定性的基础上,构建风-光-蓄-火优化调度模型,使用拉丁超立方抽样法模拟模型中风电和光伏出力场景,再基于Kantorovich距离的同步回代消除算法对生成的风、光出力场景进行缩减,并通过改进的粒子群算法对模型进行求解。以白莲河抽水蓄能电站为例,结合当地的实测风速、光照数据,探究有无抽蓄参与以及不同能源容量配比下的调度结果,得到以下结论:①抽蓄电站的加入使得联合系统收益增加了428.06万元,风、光出力的波动性降低了12.24%,可再生能源的弃电率下降了5.62%,污染物排放也得到了减少。②抽蓄与可再生能源装机容量比例在1∶8.33范围内配置较为合理,在1∶5.21时可再生能源弃电率达到最低。③当可再生能源渗透率为71.09%,抽蓄与可再生能源装机容量比例为1∶6.25时,风-光-蓄-火联合运行边际效益最大。

柔性隔热毡高温拉伸作用下的热力响应

飞行器在超高速飞行时表面温度高达几千甚至上万摄氏度,因而需要通过对其表面进行热防护设计来保护其内部人员和设备。为了适应小型化和低发射成本的要求,热防护材料不仅要具有较好的隔热性能,还应具有较低的密度。柔性隔热毡因具有轻质、隔热能力强、高温下性能稳定等特点,可以对飞行器内部的结构和仪器设备起到良好的热防护作用。开展柔性隔热毡热力联合作用下的数值模拟并通过实验进行验证,分析隔热毡内部的热传递规律。

黑曲霉耐热型葡聚糖酶纤维素结合结构域的替换与融合体酶性质

该文旨在通过更换纤维素结合结构域(cellulose binding domain, CBD)的方式探索获得具有纤维素水解能力的耐热型葡聚糖酶的方法。黑曲霉(Aspergillus niger)来源的葡聚糖酶AnEglA6具有优越的耐热性能,在禽类饲料生产中具有应用前景。通过更换不同家族来源的碳水化合物结合结构域(carbohydrate binding module, CBM)编码区,构建了融合体葡聚糖酶基因,分别在巴斯德毕赤酵母(Pichia pastoris)中进行异源表达。AnEglA6催化结构域与分别来源于嗜热菌(Caldicellulosiruptor kristjanssonii)和荧光假单胞菌(Pseudomonas fluorescens)的木聚糖酶的底物结合结构域CBM9、CBM10结合获得的融合体酶AnEg-CBM9和AnEg-CBM10均具有较高的纤维素水解能力,并且底物范围进一步扩大,对微晶纤维素也具有一定的水解能力。AnEg-CBM10热稳定性有显著的提高,在85℃下酶活力半衰期达到40 min左右,能短时耐受90℃高温。融合体酶AnEg-CBM10是一种热稳定性提高、具有纤维素水解能力的新型葡聚糖酶。