Based on the geochemical parameters and analytical data,the heat conservation equation,mass balance law,Rayleigh fractionation model and other methods were used to quantify the in-situ yield and external flux of crust...Based on the geochemical parameters and analytical data,the heat conservation equation,mass balance law,Rayleigh fractionation model and other methods were used to quantify the in-situ yield and external flux of crust-derived helium,and the initial He concentration and thermal driving mechanism of mantle-derived helium,in the Ledong Diapir area,the Yinggehai Basin,in order to understand the genetic source,migration and accumulation mechanisms of helium under deep thermal fluid activities.The average content of mantle-derived He is only 0.0014%,the ^(3)He/^(4)He value is(0.002–2.190)×10^(−6),and the R/Ra value ranges from 0.01 to 1.52,indicating the contribution of mantle-derived He is 0.09%–19.84%,while the proportion of crust-derived helium can reach over 80%.Quantitative analysis indicates that the crust-derived helium is dominated by external input,followed by in-situ production,in the Ledong diapir area.The crust-derived helium exhibits an in-situ 4 He yield rate of(7.66–7.95)×10^(−13)cm^(3)/(a·g),an in-situ 4 He yield of(4.10–4.25)×10^(−4)cm^(3)/g,and an external 4 He influx of(5.84–9.06)×10^(−2)cm^(3)/g.These results may be related to atmospheric recharge into formation fluid and deep rock-water interactions.The ratio of initial mole volume of 3 He to enthalpy(W)is(0.004–0.018)×10^(−11) cm^(3)/J,and the heat contribution from the deep mantle(X_(M))accounts for 7.63%–36.18%,indicating that deep hot fluid activities drive the migration of mantle-derived 3 He.The primary helium migration depends on advection,while the secondary migration is controlled by hydrothermal degassing and gas-liquid separation.From deep to shallow layers,the CO_(2/3) He value rises from 1.34×10^(9)to 486×10^(9),indicating large amount of CO_(2)has escaped.Under the influence of deep thermal fluid,helium migration and accumulation mechanisms include:deep heat driven diffusion,advection release,vertical hydrothermal degassing,shallow lateral migration,accumulation in traps far from faults,partial pressure balance and sealing capability.展开更多
This work restored the erosion thickness of the top surface of each Cretaceous formations penetrated by the typical well in the Hari sag, and simulated the subsidence burial history of this well with software BasinMod...This work restored the erosion thickness of the top surface of each Cretaceous formations penetrated by the typical well in the Hari sag, and simulated the subsidence burial history of this well with software BasinMod. It is firstly pointed out that the tectonic subsidence evolution of the Hari sag since the Cretaceous can be divided into four phases: initial subsidence phase, rapid subsidence phase,uplift and erosion phase, and stable slow subsidence phase. A detailed reconstruction of the tectonothermal evolution and hydrocarbon generation histories of typical well was undertaken using the EASY R% model, which is constrained by vitrinite reflectance(R) and homogenization temperatures of fluid inclusions. In the rapid subsidence phase, the peak period of hydrocarbon generation was reached at c.a.105.59 Ma with the increasing thermal evolution degree. A concomitant rapid increase in paleotemperatures occurred and reached a maximum geothermal gradient of about 43-45℃/km. The main hydrocarbon generation period ensued around 105.59-80.00 Ma and the greatest buried depth of the Hari sag was reached at c.a. 80.00 Ma, when the maximum paleo-temperature was over 180℃.Subsequently, the sag entered an uplift and erosion phase followed by a stable slow subsidence phase during which the temperature gradient, thermal evolution, and hydrocarbon generation decreased gradually. The hydrocarbon accumulation period was discussed based on homogenization temperatures of inclusions and it is believed that two periods of rapid hydrocarbon accumulation events occurred during the Cretaceous rapid subsidence phase. The first accumulation period observed in the Bayingebi Formation(Kb) occurred primarily around 105.59-103.50 Ma with temperatures of 125-150℃. The second accumulation period observed in the Suhongtu Formation(Ks) occurred primarily around84.00-80.00 Ma with temperatures of 120-130℃. The second is the major accumulation period, and the accumulation mainly occurred in the Late Cretaceous. The hydrocarbon accumulation process was comprehensively controlled by tectono-thermal evolution and hydrocarbon generation history. During the rapid subsidence phase, the paleo temperature and geothermal gradient increased rapidly and resulted in increasing thermal evolution extending into the peak period of hydrocarbon generation,which is the key reason for hydrocarbon filling and accumulation.展开更多
The Eocene Niubao Formation is the primary research target of oil exploration in the Lunpola Basin.Crude oil was extracted from Well Z1 on the northern margin of the basin in 1993.In this study,an integrated evaluatio...The Eocene Niubao Formation is the primary research target of oil exploration in the Lunpola Basin.Crude oil was extracted from Well Z1 on the northern margin of the basin in 1993.In this study,an integrated evaluation of the source rock geothermal,and maturity histories and the fluid inclusion and fluid potential distributions was performed to aid in predicting areas of hydrocarbon accumulation.Due to the abundance of organic matter,the kerogen types,maturity,and oil-sources correlate with the geochemical data.The middle submember of the second member of the Niubao Formation(E2n^2-2)is the most favorable source rock based on the amount of oil produced from the E2n^2-3and E2n^3-1reservoirs.One-and twodimensional basin modeling,using BasinMod software,shows that the E2n^2-2source rock started to generate hydrocarbon at 35-30 Ma,reached a maturity of Ro=0.7%at 25-20 Ma,and at present,it has reached the peak oil generation stage with a thermal maturity of Ro=0.8%to less than Ro=1.0%.By using fluid inclusion petrography,fluorescence spectroscopy,and microthermometry,two major periods of oil charging have been revealed at 26.1-17.5 and 32.4-24.6 Ma.The oil accumulation modeling results,conducted by using the Trinity software,show a good fit of the oil shows in the wells and predict that the structural highs and lithologic transitions within the Jiangriaco and Paco sags are potential oil traps.展开更多
基金Supported by the National Natural Science Foundation of China(41821002,42272163,42072167)Laoshan Laboratory Science and Technology Innovation Project(LSKJ202203403)Hainan Branch Project of CNOOC(KJZH-2021-0003-00).
文摘Based on the geochemical parameters and analytical data,the heat conservation equation,mass balance law,Rayleigh fractionation model and other methods were used to quantify the in-situ yield and external flux of crust-derived helium,and the initial He concentration and thermal driving mechanism of mantle-derived helium,in the Ledong Diapir area,the Yinggehai Basin,in order to understand the genetic source,migration and accumulation mechanisms of helium under deep thermal fluid activities.The average content of mantle-derived He is only 0.0014%,the ^(3)He/^(4)He value is(0.002–2.190)×10^(−6),and the R/Ra value ranges from 0.01 to 1.52,indicating the contribution of mantle-derived He is 0.09%–19.84%,while the proportion of crust-derived helium can reach over 80%.Quantitative analysis indicates that the crust-derived helium is dominated by external input,followed by in-situ production,in the Ledong diapir area.The crust-derived helium exhibits an in-situ 4 He yield rate of(7.66–7.95)×10^(−13)cm^(3)/(a·g),an in-situ 4 He yield of(4.10–4.25)×10^(−4)cm^(3)/g,and an external 4 He influx of(5.84–9.06)×10^(−2)cm^(3)/g.These results may be related to atmospheric recharge into formation fluid and deep rock-water interactions.The ratio of initial mole volume of 3 He to enthalpy(W)is(0.004–0.018)×10^(−11) cm^(3)/J,and the heat contribution from the deep mantle(X_(M))accounts for 7.63%–36.18%,indicating that deep hot fluid activities drive the migration of mantle-derived 3 He.The primary helium migration depends on advection,while the secondary migration is controlled by hydrothermal degassing and gas-liquid separation.From deep to shallow layers,the CO_(2/3) He value rises from 1.34×10^(9)to 486×10^(9),indicating large amount of CO_(2)has escaped.Under the influence of deep thermal fluid,helium migration and accumulation mechanisms include:deep heat driven diffusion,advection release,vertical hydrothermal degassing,shallow lateral migration,accumulation in traps far from faults,partial pressure balance and sealing capability.
基金supported by the project of "Constraints on Lithospheric Dynamic Evolution and Hydrocarbon Accumulation from Late Mesozoic Paleo-geothermal Field in Ordos and Qinshui Basins" (grant No. 41630312)the National Nature Science Foundation of China (grants No. 41372208 and 40534019)+1 种基金the Open Found of the State Key Laboratory of Ore Deposit Geochemistry, CAS (grant No. 201304)supported by international program for Ph.D. candidates, Sun Yat-Sen University
文摘This work restored the erosion thickness of the top surface of each Cretaceous formations penetrated by the typical well in the Hari sag, and simulated the subsidence burial history of this well with software BasinMod. It is firstly pointed out that the tectonic subsidence evolution of the Hari sag since the Cretaceous can be divided into four phases: initial subsidence phase, rapid subsidence phase,uplift and erosion phase, and stable slow subsidence phase. A detailed reconstruction of the tectonothermal evolution and hydrocarbon generation histories of typical well was undertaken using the EASY R% model, which is constrained by vitrinite reflectance(R) and homogenization temperatures of fluid inclusions. In the rapid subsidence phase, the peak period of hydrocarbon generation was reached at c.a.105.59 Ma with the increasing thermal evolution degree. A concomitant rapid increase in paleotemperatures occurred and reached a maximum geothermal gradient of about 43-45℃/km. The main hydrocarbon generation period ensued around 105.59-80.00 Ma and the greatest buried depth of the Hari sag was reached at c.a. 80.00 Ma, when the maximum paleo-temperature was over 180℃.Subsequently, the sag entered an uplift and erosion phase followed by a stable slow subsidence phase during which the temperature gradient, thermal evolution, and hydrocarbon generation decreased gradually. The hydrocarbon accumulation period was discussed based on homogenization temperatures of inclusions and it is believed that two periods of rapid hydrocarbon accumulation events occurred during the Cretaceous rapid subsidence phase. The first accumulation period observed in the Bayingebi Formation(Kb) occurred primarily around 105.59-103.50 Ma with temperatures of 125-150℃. The second accumulation period observed in the Suhongtu Formation(Ks) occurred primarily around84.00-80.00 Ma with temperatures of 120-130℃. The second is the major accumulation period, and the accumulation mainly occurred in the Late Cretaceous. The hydrocarbon accumulation process was comprehensively controlled by tectono-thermal evolution and hydrocarbon generation history. During the rapid subsidence phase, the paleo temperature and geothermal gradient increased rapidly and resulted in increasing thermal evolution extending into the peak period of hydrocarbon generation,which is the key reason for hydrocarbon filling and accumulation.
基金financially supported by the National Science and the Technology Major Project(Nos.2016ZX05024002-003,2017ZX05032-001-004,2016ZX05027-001-005)the National Science Foundation of China(No.41672136)the Branch of Exploration Project,SINOPEC(No.G0800-14-KK-169)
文摘The Eocene Niubao Formation is the primary research target of oil exploration in the Lunpola Basin.Crude oil was extracted from Well Z1 on the northern margin of the basin in 1993.In this study,an integrated evaluation of the source rock geothermal,and maturity histories and the fluid inclusion and fluid potential distributions was performed to aid in predicting areas of hydrocarbon accumulation.Due to the abundance of organic matter,the kerogen types,maturity,and oil-sources correlate with the geochemical data.The middle submember of the second member of the Niubao Formation(E2n^2-2)is the most favorable source rock based on the amount of oil produced from the E2n^2-3and E2n^3-1reservoirs.One-and twodimensional basin modeling,using BasinMod software,shows that the E2n^2-2source rock started to generate hydrocarbon at 35-30 Ma,reached a maturity of Ro=0.7%at 25-20 Ma,and at present,it has reached the peak oil generation stage with a thermal maturity of Ro=0.8%to less than Ro=1.0%.By using fluid inclusion petrography,fluorescence spectroscopy,and microthermometry,two major periods of oil charging have been revealed at 26.1-17.5 and 32.4-24.6 Ma.The oil accumulation modeling results,conducted by using the Trinity software,show a good fit of the oil shows in the wells and predict that the structural highs and lithologic transitions within the Jiangriaco and Paco sags are potential oil traps.
