Effect of safety valve types on the gas venting behavior and thermal runaway hazard severity of large-format prismatic lithium iron phosphate batteries

The safety valve is an important component to ensure the safe operation of lithium-ion batteries(LIBs).However,the effect of safety valve type on the thermal runaway(TR)and gas venting behavior of LIBs,as well as the TR hazard severity of LIBs,are not known.In this paper,the TR and gas venting behavior of three 100 A h lithium iron phosphate(LFP)batteries with different safety valves are investigated under overheating.Compared to previous studies,the main contribution of this work is in studying and evaluating the effect of gas venting behavior and TR hazard severity of LFP batteries with three safety valve types.Two significant results are obtained:(Ⅰ)the safety valve type dominates over gas venting pressure of battery during safety venting,the maximum gas venting pressure of LFP batteries with a round safety valve is 3320 Pa,which is one order of magnitude higher than other batteries with oval or cavity safety valve;(Ⅱ)the LFP battery with oval safety valve has the lowest TR hazard as shown by the TR hazard assessment model based on gray-fuzzy analytic hierarchy process.This study reveals the effect of safety valve type on TR and gas venting,providing a clear direction for the safety valve design.

Miscibility of light oil and flue gas under thermal action

The miscibility of flue gas and different types of light oils is investigated through slender-tube miscible displacement experiment at high temperature and high pressure.Under the conditions of high temperature and high pressure,the miscible displacement of flue gas and light oil is possible.At the same temperature,there is a linear relationship between oil displacement efficiency and pressure.At the same pressure,the oil displacement efficiency increases gently and then rapidly to more than 90% to achieve miscible displacement with the increase of temperature.The rapid increase of oil displacement efficiency is closely related to the process that the light components of oil transit in phase state due to distillation with the rise of temperature.Moreover,at the same pressure,the lighter the oil,the lower the minimum miscibility temperature between flue gas and oil,which allows easier miscibility and ultimately better performance of thermal miscible flooding by air injection.The miscibility between flue gas and light oil at high temperature and high pressure is more typically characterized by phase transition at high temperature in supercritical state,and it is different from the contact extraction miscibility of CO_(2) under conventional high pressure conditions.

Research on thermal insulation materials properties under HTHP conditions for deep oil and gas reservoir rock ITP-Coring

Deep oil and gas reservoirs are under high-temperature conditions,but traditional coring methods do not consider temperature-preserved measures and ignore the influence of temperature on rock porosity and permeability,resulting in distorted resource assessments.The development of in situ temperaturepreserved coring(ITP-Coring)technology for deep reservoir rock is urgent,and thermal insulation materials are key.Therefore,hollow glass microsphere/epoxy resin thermal insulation materials(HGM/EP materials)were proposed as thermal insulation materials.The materials properties under coupled hightemperature and high-pressure(HTHP)conditions were tested.The results indicated that high pressures led to HGM destruction and that the materials water absorption significantly increased;additionally,increasing temperature accelerated the process.High temperatures directly caused the thermal conductivity of the materials to increase;additionally,the thermal conduction and convection of water caused by high pressures led to an exponential increase in the thermal conductivity.High temperatures weakened the matrix,and high pressures destroyed the HGM,which resulted in a decrease in the tensile mechanical properties of the materials.The materials entered the high elastic state at 150℃,and the mechanical properties were weakened more obviously,while the pressure led to a significant effect when the water absorption was above 10%.Meanwhile,the tensile strength/strain were 13.62 MPa/1.3%and 6.09 MPa/0.86%at 100℃ and 100 MPa,respectively,which meet the application requirements of the self-designed coring device.Finally,K46-f40 and K46-f50 HGM/EP materials were proven to be suitable for ITP-Coring under coupled conditions below 100℃ and 100 MPa.To further improve the materials properties,the interface layer and EP matrix should be optimized.The results can provide references for the optimization and engineering application of materials and thus technical support for deep oil and gas resource development.

Assessment of gas tungsten arc welding thermal cycles on Inconel 718 alloy

Heat moving source models along with transient heat analysis by finite element method were used to determine weld thermal cycles and isothermal sections obtained from the application of a gas tungsten arc welding beads on Inconel 718 plates. Analytical (Rosenthal’s thick plate model) and finite element results show an acceptable approximation with the experimental weld thermal cycles. The isothermal sections determined by numerical simulation show a better approximation with the experimental welding profile for double-ellipse model heat distribution than Gauss model. To analyze the microstructural transformation produced by different cooling rates in the fusion and heat affected zones, Vickers microhardness measurements (profile and mapping representation) were conducted. A hardness decrement for the heat affected zone (~200 HV0.2) and fusion zone (~240 HV0.2) in comparison with base material (~350 HV0.2) was observed. This behavior has been attributed to the heterogeneous solubilization process of the γ″ phase (nickel matrix), which, according to the continuous-cooling-transformation curve, produced the Laves phase,δ and MC transition phases, generating a loss in hardness close to the fusion zone.

Utilization of Thermally Treated Flue Gas Desulfurization (FGD) Gypsum and Class-C Fly Ash (CFA) to Prepare CFA-Based Geopolymer

The feasibility of utilization of flue gas desulfurization （FGD） gypsum and Class-C fly ash （CFA） to prepare CFA-based geopolymer were studied. The results showed that geopolymer made from 90% CFA and 10% FGD gypsum （FGDG） which was thermally treated at 800 ℃ for 1 h obtained the better compressive strength of 37.0 MPa. The micro characteristics and structures of the geopolymer samples of CFA and CFA-FGDG were tested by XRD, FT-IR, and SEM-EDXA after these samples cured at 75 ℃ for 8 h followed by 23 ℃ for 28 d. Both the geopolymer samples of CFA and CFA-FGDG have significant asymmetric stretching of A1-O/Si-O bonds and Si-O-Si / Si-O-A1 bending band. In geopolymer sample of CFA-FGDG, a small quantity of lathy products probably being the ettringite wrapped over the spherical fly ash particle, and the concentration of sulfur is much more than that in geopolymer sample of CFA. It is indicated that FGD gypsum may react during alkali-activated and geopolymeric process.

The Model of Thermal Response of Liquefied Petroleum Gas Tanks Partially Exposed to Jet Fire

This paper describes a mathematical model developed to study the behavior of liquefied petroleum gas (LPG) tanks when subjected to jet fire. The model consists of a number of field and zone sub-models which are used to simulate the various physical phenomena taking place during the tank engulfment period. The model can be used to predict the pressure and temperature of the LPG in the tank, the temperature of the wall of tank, and the time of tank explosion. The comparisons between the model predicted results and the test data show good agreement. The results show that the jet fire partially impinging on tank wall led to higher wall temperature and the time to failure was shorter than that in engulfing pool fire. And the exposure of the upper wall in the vapor zone to the fire is more dangerous than that of the LPG contacted wall.

Influence of deep magma-induced thermal effects on the regional gas outburst risk of coal seams

The thermal effect caused by deep magma intrusion can not only accelerate the metamorphism of coal body,but also bring additional thermal field that changes the mechanical environment of coal seams,thereby affecting the permeability of coal seams.Different from shallow coal resources,deep coal resources are in a mechanical environment characterized by limited stress and strain.Thus,the thermal effect has a more significant influence on the distribution and permeability characteristics of deep coal seams.In this study,the evolution history of highly metamorphic coal seams in Yangquan mining area was analyzed,and the main effect of magmatic activity on coal seams was obtained.Based on the determined vitrinite reflectance data of typical mines in Yangquan mining area,the maximum paleotemperature was calculated by adopting the Barker’s method.Furthermore,the paleotemperature distribution in Yangquan mining area was summarized,and its relationship with the metamorphic degree was acquired.Then,a new permeability model considering the thermal strain was proposed to analyze the permeability evolution in deep coal seams at different ground temperatures.Finally,through a combination of the results of gas pressure and outburst number in Sijiazhuang Mine,Yangquan No.5 Mine and Xinjing Mine,the influence of ground temperature on the gas outburst risk in Yangquan mining area was explored.The following conclusions were drawn:The maximum paleotemperature in Yangquan area can be 303C.In addition,the paleotemperature in the south is higher than that in the north of Yangquan mining area.The various temperatures at different depths bring about different degrees of thermal stress to different coal seams,leading to different strains.Under the fixed displacement boundary conditions in the deep,the coal seam folds and bends to varying degrees.Moreover,the difference in the ground temperature raises the a value of coal seams and lowers the permeability,which promotes the formation of gas-rich zones and increases the risk of coal seam outburst.The research results can help mines to make proper gas disaster prevention plan for different zones.

Influence of gas flow on thermal field and stress during growth of sapphire single crystal using Kyropoulos method

The professional modeling software package CrysVUn was employed to study the process of a large sapphire single crystal growth using Kyropoulos method.The influence of gas pressure on thermal field,solid-liquid interface shape,gas velocity field and von Mises stress were studied for the first time.It is found that the root of the seed melt when gas pressure equals to one atmosphere or more than one atmosphere,especially during the seeding period,this result is consistent with the experimental observation,and this paper presents three ways to solve this problem.The temperature gradient and stress decreases significantly as the gas pressure increases.The convexity of the solid-liquid interface slightly increases when the gas pressure increases.Numerical analysis was used to optimize the hot zone design.

Effects of different combustion modes on the thermal efficiency and emissions of a diesel pilot-ignited natural gas engine under low-medium loads

Research on dual-fuel(DF)engines has become increasingly important as engine manufacturers seek to reduce carbon dioxide emissions.There are significant advantages of using diesel pilot-ignited natural gas engines as DF engines.However,different combustion modes exist due to variations in the formation of the mixture.This research used a simulation model and numerical simulations to explore the combustion characteristics of high-pressure direct injection(HPDI),partially premixed compression ignition(PPCI),and double pilot injection premixed compression ignition(DPPCI)combustion modes under a low-medium load.The results revealed that the DPPCI combustion mode provides higher gross indicated thermal efficiency and more acceptable total hydrocarbon(THC)emission levels than the other modes.Due to its relatively good performance,an experimental study was conducted on the DPPCI mode engine to evaluate the impact of the diesel dual-injection strategy on the combustion process.In the DPPCI mode,a delay in the second pilot ignition injection time increased THC emissions(a maximum value of 4.27g/(kW·h)),decreased the emission of nitrogen oxides(a maximum value of 7.64 g/(kW·h)),increased and then subsequently decreased the gross indicated thermal efficiency values,which reached 50.4%under low-medium loads.

Application of Supercritical CO2 Gas Turbine for the Fossil Fired Thermal Plant

A supercritical CO2 gas turbine cycle can produce power at high efficiency and the gas turbine is compact compared with the steam turbine. Therefore, it is very advantageous power cycle for the medium temperature range less than 650 ℃. The purpose of this paper is to show how it can be effectively applied not only to the nuclear power but also to the fossil fired power plant. A design of 300 MWe plant has been carried out, where thermal energy of flue gas leaving a CO2 heater is utilized effectively by means of economizer and a high cycle thermal efficiency of 43.4 % has been achieved. Since the temperature and the pressure difference of the CO2 heater are very high, the structural design becomes very difficult. It is revealed that this problem can be effectively solved by introducing a double expansion turbine cycle. The component designs of the CO2 heater, the economizer, supercritical CO2 turbines, compressors and the recuperators are given and it is shown that these components have good performances and compact sizes.

Effects of Syngas Particulate Fly Ash Deposition on the Mechanical Properties of Thermal Barrier Coatings on Simulated Film-Cooled Turbine Vane Components

Research is being conducted to study the effects of particulate deposition from contaminants in coal synthesis gas (syngas) on the mechanical properties of thermal barrier coatings (TBC) employed on integrated gasification combined cycle (IGCC) turbine hot section airfoils. West Virginia University (WVU) had been working with US Department of Energy, National Energy Technology Laboratory (NETL) to simulate deposition on the pressure side of an IGCC turbine first stage vane. To model the deposition, coal fly ash was injected into the flow of a combustor facility and deposited onto TBC coated, angled film-cooled test articles in a high pressure (approximately 4 atm) and a high temperature (1560 K) environment. To investigate the interaction between the deposition and the TBC, a load-based multiple-partial unloading micro-indentation technique was used to quantitatively evaluate the mechanical properties of materials. The indentation results showed the Young’s Modulus of the ceramic top coat was higher in areas with deposition formation due to the penetration of the fly ash. This corresponds with the reduction of strain tolerance of the 7% yttria-stabilized zirconia (7YSZ) coatings.

Microstructural Degradation of Thermal Barrier Coatings on an Integrated Gasification Combined Cycle (IGCC) Simulated Film-Cooled Turbine Vane Pressure Surface Due to Particulate Fly Ash Deposition

Research is being conducted to study the degradation of thermal barrier coatings (TBC) employed on IGCC turbine hot section airfoils due to particulate deposition from contaminants in coal syn-thesis gas (syngas). West Virginia University (WVU) had been working with US Department of Energy, National Energy Technology Laboratory (NETL) to simulate deposition on the pressure side of an IGCC turbine first stage vane. To simulate the contaminant deposition, several TBC coated, angled film-cooled test articles were subjected to accelerated coal fly ash, which was injected into the flow of a combustor facility with a high pressure (approximately 4 atm) and a high temperature (1560 K) environment. To investigate the degradation of the TBCs due to particulate deposition, non-destructive tests were performed using scanning electron microscopy (SEM) evaluation and energy dispersive X-ray spectroscopy (EDS) examinations. The SEM evaluation was used to display the microstructure change within the layers of the TBC system directly related to the fly ash deposition. The SEM micrographs showed that deposition-TBC interaction made the YSZ coating more susceptible to delamination and promoted a dissolution-reprecipitation mechanism that changed the YSZ morphology and composition. The EDS examination provided elemental maps of the shallow infiltration depth of the fly ash and chemical composition spectrum results which showed yttria migration from the YSZ into the deposition.

Numerical Analysis of Thermal Distortion and Residual Stresses in H13 Steel Due to Vacuum Gas Quenching

Heat treated steel components often suffer distortion and residual stress effects when cooled to room temperature. A numerical analysis of a vacuum gas quenched die block made of H 13 was carried out utilising a nonlinear thermoelastic-plastic stress model together with the fluid flow and thermal profiles within the furnace. Simulation procedures for stress behaviour of the die were developed for both direct quench and marquench processes. Results of the initial thermal analysis indicated that the temperature difference between the surface and core of the die during direct quenching (gas pressure is 4 bar) was larger than that due to marquenching ( gas pressure is 4 bar at the beginning and 2 bar near isothermal hold). Simulation of the cooling rates at the surface and core of the die during marquenching correlated well with the experimental data. Further stress simulation indicated that the final thermal distortion and residual stresses in the die after direct quenching were larger than those due to marquenching. The findings of the numerical analysis suggested that marquenching is recommended for this die because it could reduce the temperature difference in the die and thus result in less thermal distortion and residual stresses.

Synthesis of Tin Oxide Through Thermal Decomposition of Sn_2(NH_4)_2(C_2O_4)_3 and Its Gas Sensing Property

Nanocrystalline tin oxide samples were prepared by using Sn2 （NH4 ）2 （C2O4）3 as the precursor. The thermal decompositions were respectively conducted at 250,450 and 650 ℃. TG-DTA, XRD, TEM, FTIR were used to characterize the samples. The indirect heating sensors by using these materials as sensitive bodies were fabricated on an alumina tube with Au electrodes and platinum wires. Sensing properties of these sensors were investigated. It was found that the tin oxide sample obtained by thermal decomposition at 450 ℃ has a higher sensitivity to C2H5OH and a higher selectivity to hexane and ammonia than those obtained via the conventional precipitate method and the working temperatures needed were greatly decreased.

Influence of pipe parameters and heat input on thermal cycle of in-service welding onto active gas pipeline

The software of SYSWELD was used to build model and simulate thermal cycle of in-service welding onto active gas pipeline. Influence of pipe diameter, wall thickness and heat input on thermal cycle was studied. The results show that t8/5 , t8/3 and peak temperature of inner surface decrease when wall thickness increases from 5 mm to 12 mm. But t8/1 will increases with the increase of wall thickness and will decrease after the wall thickness is larger than 7 mm. Pipe diameter has little influence on thermal cycle and that influence can be ignored when pipe diameter is greater than 273 mm. t8/5 , t8/3 , t8/1 and peak temperature of inner surface will increase with the increase of heat input.

Surface Temperatures Determination with Influencing Convective and Radiative Thermal Resistance Parameters of Combustor of Gas Turbine

Surface temperatures were determined with due consideration of the influencing thermal conditions of conductive, convective and radiative heat. A general condition of heat influx to a point was formulated with the end effect of such influx to the receiving point. It was noted that the heat flow will cause a rate of change of internal energy of the point. Based on the theory of the rate of change of internal energy, a combustor model of cylindrical cross-section was used to generate out the timely temperature equation. Further work was done on this model equation to convert it to non-dimensional. The conversion of this equation was very essential in summing up the parameters that can influence the timely generation of the temperatures. Interestingly, it is noted that when a material withstands temperatures, it will equally withstand the thermal stresses that inherently will be developed in it. From the results, the work came up with a table showing the range of these slope figures of equations, a point was also found for a vital recommendation for further studies, where such figures can be used to check the suitability for thermal stress levels and the lifetime of combustor of such thickness.

Mechanisms of carbon isotopic fractionation in the process of natural gas generation: Geochemical evidence from thermal simulation experiment

Low maturity coal samples were taken from the Ordos Basin to conduct gold tube thermal simulation experiment in a closed system,and the characteristics of the products were analyzed to find out the fractionation mechanism of carbon isotopes and the causes of abnormal carbon isotopic compositions of natural gas.At the heating rates of 2℃/h(slow)and 20℃/h(rapid),the low maturity coal samples of the Ordos Basin had the maximum yields of alkane gas of 302.74 mL/g and 230.16 mL/g,theδ13C1 ranges of-34.8‰to-23.6‰and-35.5‰to-24.0‰;δ13C2 ranges of-28.0‰to-9.0‰and-28.9‰to-8.3‰;andδ13C3 ranges of-25.8‰to-14.7‰and-26.4‰to-13.2‰,respectively.Alkane gas in the thermal simulation products of rapid temperature rise process showed obvious partial reversal of carbon isotope series at 550℃,and at other temperatures showed positive carbon isotope series.In the two heating processes,theδ13C1 turned lighter first and then heavier,and the non-monotonic variation of theδ13C1 values is because the early CH4 is from different parent materials resulted from heterogeneity of organic matter or the carbon isotope fractionation formed by activation energy difference of early enriched 12CH4 and late enriched 13CH4.The reversal of carbon isotope values of heavy hydrocarbon gas can occur not only in high to over mature shale gas(oil-type gas),but also in coal-derived gas.Through thermal simulation experiment of toluene,it is confirmed that the carbon isotope value of heavy hydrocarbon gas can be reversed and inversed at high to over mature stage.The isotope fractionation effect caused by demethylation and methyl linkage of aromatic hydrocarbons may be an important reason for carbon isotope inversion and reversal of alkane gas at the high to over mature stage.

Broadening Thermal Energy Levels and Density States Quasi One-Dimensional Electron Gas

We have investigated the energy states of a one-dimensional electron gas and analyzed the temperature dependence of the density of states. It is shown that with increasing temperature due to thermal broadening of quantum, levels are blurred.

CFD modeling of gas−liquid flow phenomenon in lead smelting oxygen-enriched side-blown furnace

A validated numerical model was established to simulate gas−liquid flow behaviors in the oxygen-enriched side-blown bath furnace.This model included the slip velocity between phases and the gas thermal expansion effect.Its modeling results were verified with theoretical correlations and experiments,and the nozzle-eroded states in practice were also involved in the analysis.Through comparison,it is confirmed that the thermal expansion effect influences the flow pattern significantly,which may lead to the backward motion of airflow and create a potential risk to production safety.Consequently,the influences of air injection velocity and furnace width on airflow behavior were investigated to provide operating and design guidance.It is found that the thin layer melt,which avoids high-rate oxygen airflow eroding nozzles,shrinks as the injection velocity increases,but safety can be guaranteed when the velocity ranges from 175 to 275 m/s.Moreover,the isoline patterns and heights of thin layers change slightly when the furnace width increases from 2.2 to 2.8 m,indicating that the furnace width shows a limited influence on production safety.

Low-Volatile Binder Enables Thermal Shock-Resistant Thin-Film Cathodes for Thermal Batteries

Manufacturing thin-film components is crucial for achieving high-efficiency and high-power thermal batteries(TBs).However,developing binders with low-gas production at the operating temperature range of TBs(400-550°C)has proven to be a significant challenge.Here,we report the use of acrylic acid derivative terpolymer(LA136D)as a low-volatile binder for thin-film cathode fabrication and studied the chain scission and chemical bondbreaking mechanisms in pyrolysis.It is shown LA136D defers to randomchain scission and cross-linking chain scission mechanisms,which gifts it with a low proportion of volatile products(ψ,ψ=39.2 wt%)at even up to 550°C,well below those of the conventional PVDF(77.6 wt%)and SBR(99.2 wt%)binders.Surprisingly,LA136D contributes to constructing a thermal shock-resistant cathode due to the step-by-step bond-breaking process.This is beneficial for the overall performance of TBs.In discharging test,the thin-film cathodes exhibited a remarkable 440%reduction in polarization and 300%enhancement in the utilization efficiency of cathode materials,while with just a slight increase of 0.05 MPa in gas pressure compared with traditional“thick-film”cathode.Our work highlights the potential of LA136D as a low-volatile binder for thin-film cathodes and shows the feasibility of manufacturing high-efficiency and high-power TBs through polymer molecule engineering.