The thermal degradation of poly(arylene sulfide sulfone)/N-methylpyrrolidone (PASS/NMP) crystal solvate was studied by thermogravimetric analysis (TGA) and was compared with pure PASS in order to determine the w...The thermal degradation of poly(arylene sulfide sulfone)/N-methylpyrrolidone (PASS/NMP) crystal solvate was studied by thermogravimetric analysis (TGA) and was compared with pure PASS in order to determine the way in which the formation of the crystal solvate affected the thermal properties of the polymer. The activation energy of the solid state process was determined using Kissinger's method, which does not require knowledge of the reaction mechanism (RM), to be 174.18 kJ/mol which was lower than that for pure PASS (E = 214 kJ/mol). The study of master curves together with interpretation of integral methods, allows confirmation that the thermal degradation mechanism for PASS in the crystal solvate system is a decelerated Rn type, which is a solid-state process based on a phase boundary controlled reaction, in the conversion range considered. Whereas, the pure PASS follows a decelerated Dn thermodegradation mechanism in the same conversion range.展开更多
The thermal stability and decomposition kinetics of polysuccinimide (PSI) were investigated using analyzer DTG-60 under high purity nitrogen atmosphere at different heating rates (3, 6, 9, 12 K/min). The thermal decom...The thermal stability and decomposition kinetics of polysuccinimide (PSI) were investigated using analyzer DTG-60 under high purity nitrogen atmosphere at different heating rates (3, 6, 9, 12 K/min). The thermal decomposition mechanism of PSI was determined by Coats-Redfern method. The kinetic parameters such as activation energy (E), pre-exponential factor (A) and reaction order (n) were calculated by Flynn-Wall-Ozawa and Kissinger methods. The results show that the thermal decomposition of PSI under nitrogen atmosphere mainly occurs in the temperature range of 619.15-693.15 K, the reaction order (n) was , the activation energy (E) and pre-exponential factor (A) were obtained to be 106.585 kJ/mol and 4.644 × 109 min-1, the integral and differential forms of the thermal decomposition mechanism of PSI were found to be and , respectively. The results play an important role in understanding the thermodynamic properties of polysuccinimide.展开更多
In the present investigation an effort has been made to understand the thermal decomposition and burn rate characteristics of AP as oxidizer and PVC and HTPB as fuel binder in composite solid propellant. The burning r...In the present investigation an effort has been made to understand the thermal decomposition and burn rate characteristics of AP as oxidizer and PVC and HTPB as fuel binder in composite solid propellant. The burning rate study has been carried out at ambient and different pressures of 2.068 Mpa, 4.760 Mpa,6.895 Mpa. The mechanism of thermal decomposition of each composition have also been determined by NETZSCH simultaneous thermal analyser, comprising differential scanning calorimeter(DSC) and thermo-gravimetric analyser(TGA). An effort has been made to study the burn rate and decomposition of fuel binder and oxidizer in presence of Fe_2O_3 and also their overall impact on combustion of propellant.展开更多
The heated process of raw materials for electron trapping materials (ETM) is investigated by thermo-analysis method. The temperature ranges of raw materials experienced some physical and chemical change processes, suc...The heated process of raw materials for electron trapping materials (ETM) is investigated by thermo-analysis method. The temperature ranges of raw materials experienced some physical and chemical change processes, such as dehydration, organic solvent removal, crystal sulphur burning, oxidation of alkaline earth sulfides and solid phase reaction (rare earth doped) and so on, are obtained. The experimental results also show that the presence of trace oxygen in shielded gas is very harmful to prepare the ETM.The raw material thermo-analysis results provide very important experimental reference for optimizing the ETM preparation techniques.展开更多
The single crystals of tristhiourea lanthanum nitrate (TTLaN) have been grown by solution growth using slow evaporation technique. The optical study revealed that the crystal has high transmission with lower cut-off w...The single crystals of tristhiourea lanthanum nitrate (TTLaN) have been grown by solution growth using slow evaporation technique. The optical study revealed that the crystal has high transmission with lower cut-off wavelength of 235.78 nm. The EDAX analysis confirmed the grown compound elements. The presence of functional groups was identified through Fourier transform-infrared technique. The thermal stability of the crystal was determined from thermo gravimetric and differential thermal analysis curve. The second harmonic generation behavior of TTLaN crystal was tested by Kurtz-Perry powder technique. This single novel semiorganic crystal of TTLaN showed very good optical transmission property, high thermal stability and large non-linearity nature.展开更多
The compound lead oxide sulfate PbSO4.PbO was prepared in our laboratory. The Thermal behavior of PbSO4 was studied using techniques of Thermogravimetry under air atmosphere from 25 to 1200°C. The identity of bot...The compound lead oxide sulfate PbSO4.PbO was prepared in our laboratory. The Thermal behavior of PbSO4 was studied using techniques of Thermogravimetry under air atmosphere from 25 to 1200°C. The identity of both compounds was confirmed by XRD technique. Results obtained using both techniques support same decomposition stages for this compound. The electron microscopic investigations are made by SEM and TEM. The compound is characterized by XRD and the purity was determined by analytical Methods. Also a series of thermogravimetric analysis is made and the ideal condition is determined to convert this compound to pure lead oxide.展开更多
This paper presents the thermal analysis of artificial sweeteners, and natural sugar substitutes. Thermal analysis was done on commercial compositions of sweeteners using simultaneous DSC/TGA (SDT). Heat flow, and mas...This paper presents the thermal analysis of artificial sweeteners, and natural sugar substitutes. Thermal analysis was done on commercial compositions of sweeteners using simultaneous DSC/TGA (SDT). Heat flow, and mass vs. temperature and time thermograms, along with DSC peak enthalpies and transition temperatures are reported. A number of the sweeteners were found to undergo transitions and reactions before or at 190°C (375°F, normal baking temperatures) and all dextrose containing sweeteners show an endothermic peak around 80°C due to the liberation of bound water molecules. The major components of sweeteners studied were found to be generally thermostable at or below 100°C.展开更多
Through this study, the humus produced in the breeding place of Universidad Autonoma de Occidente was thermally characterized. The humus was submitted to a heating program controlled by the Differential Scanning Calor...Through this study, the humus produced in the breeding place of Universidad Autonoma de Occidente was thermally characterized. The humus was submitted to a heating program controlled by the Differential Scanning Calorimetry (DSC) technique to characterize the type of transition, Thermogravimetry (TGA) to study the equilibrium of phasesand Mass Spectrometry (MS) coupled to TGA to identify detached elements in a temperature range. The temperature range used in this study was 30℃ ℃. The energy required for the water desorption in the humus has been found in this study. The humus showed a quick desorption between 30℃ ≤ TDesorption ≤ 110℃ at a heating rate of 10℃/min and presented decomposition around 250℃. Moreover, the kinetics of the desorption of the humus was studied to obtain the activation energy three TGA measures for three different heating rates. The average activation energy was about 26 kJ/Mol. This result was carried out to obtain an estimation of the desorption time of water in the range from room temperature to the decomposition temperature around 350℃.展开更多
随着科技的发展,我国的交通运输水平已处于世界前列,特别是轨道车辆的发展,为我国人员流通、物资运输和经济的发展作出重大贡献。轨道交通列车运行过程中,车辆内部运行控制信号及电力的输送保障至关重要。在轨道交通列车上使用的薄壁控...随着科技的发展,我国的交通运输水平已处于世界前列,特别是轨道车辆的发展,为我国人员流通、物资运输和经济的发展作出重大贡献。轨道交通列车运行过程中,车辆内部运行控制信号及电力的输送保障至关重要。在轨道交通列车上使用的薄壁控制电缆的外层护套绝缘材料种类中,有一种为乙烯-醋酸乙烯共聚物(EVA),该材料在酸性、潮湿等恶劣条件下易发生黄变、开裂、鼓包等现象,从而影响电缆的剩余寿命,使得电缆出现传输异常,影响列车正常运行,严重时可能出现短路发生火灾造成重大事故及人员伤亡。为对轨道车辆用乙烯-醋酸乙烯共聚物(EVA)电缆的剩余寿命进行快速评估,文章采用热重分析法(TGA)研究了不同老化程度的EVA绝缘材料的热分解特性,计算出了其对应的热分解活化能。在此基础上,参照ASTM E 1877-00:2021标准中的方法建立了EVA绝缘材料的热寿命方程。研究结果表明:热分解特性能够用来评估轨道车辆用EVA电缆的实际老化情况,结合建立的热寿命方程能完成电缆使用状况的快速评估,与传统评估方法相比,该方法操作更加简单。展开更多
基金supported by the 863 program of China(No.2007AA 03Z561)
文摘The thermal degradation of poly(arylene sulfide sulfone)/N-methylpyrrolidone (PASS/NMP) crystal solvate was studied by thermogravimetric analysis (TGA) and was compared with pure PASS in order to determine the way in which the formation of the crystal solvate affected the thermal properties of the polymer. The activation energy of the solid state process was determined using Kissinger's method, which does not require knowledge of the reaction mechanism (RM), to be 174.18 kJ/mol which was lower than that for pure PASS (E = 214 kJ/mol). The study of master curves together with interpretation of integral methods, allows confirmation that the thermal degradation mechanism for PASS in the crystal solvate system is a decelerated Rn type, which is a solid-state process based on a phase boundary controlled reaction, in the conversion range considered. Whereas, the pure PASS follows a decelerated Dn thermodegradation mechanism in the same conversion range.
文摘The thermal stability and decomposition kinetics of polysuccinimide (PSI) were investigated using analyzer DTG-60 under high purity nitrogen atmosphere at different heating rates (3, 6, 9, 12 K/min). The thermal decomposition mechanism of PSI was determined by Coats-Redfern method. The kinetic parameters such as activation energy (E), pre-exponential factor (A) and reaction order (n) were calculated by Flynn-Wall-Ozawa and Kissinger methods. The results show that the thermal decomposition of PSI under nitrogen atmosphere mainly occurs in the temperature range of 619.15-693.15 K, the reaction order (n) was , the activation energy (E) and pre-exponential factor (A) were obtained to be 106.585 kJ/mol and 4.644 × 109 min-1, the integral and differential forms of the thermal decomposition mechanism of PSI were found to be and , respectively. The results play an important role in understanding the thermodynamic properties of polysuccinimide.
文摘In the present investigation an effort has been made to understand the thermal decomposition and burn rate characteristics of AP as oxidizer and PVC and HTPB as fuel binder in composite solid propellant. The burning rate study has been carried out at ambient and different pressures of 2.068 Mpa, 4.760 Mpa,6.895 Mpa. The mechanism of thermal decomposition of each composition have also been determined by NETZSCH simultaneous thermal analyser, comprising differential scanning calorimeter(DSC) and thermo-gravimetric analyser(TGA). An effort has been made to study the burn rate and decomposition of fuel binder and oxidizer in presence of Fe_2O_3 and also their overall impact on combustion of propellant.
文摘The heated process of raw materials for electron trapping materials (ETM) is investigated by thermo-analysis method. The temperature ranges of raw materials experienced some physical and chemical change processes, such as dehydration, organic solvent removal, crystal sulphur burning, oxidation of alkaline earth sulfides and solid phase reaction (rare earth doped) and so on, are obtained. The experimental results also show that the presence of trace oxygen in shielded gas is very harmful to prepare the ETM.The raw material thermo-analysis results provide very important experimental reference for optimizing the ETM preparation techniques.
文摘The single crystals of tristhiourea lanthanum nitrate (TTLaN) have been grown by solution growth using slow evaporation technique. The optical study revealed that the crystal has high transmission with lower cut-off wavelength of 235.78 nm. The EDAX analysis confirmed the grown compound elements. The presence of functional groups was identified through Fourier transform-infrared technique. The thermal stability of the crystal was determined from thermo gravimetric and differential thermal analysis curve. The second harmonic generation behavior of TTLaN crystal was tested by Kurtz-Perry powder technique. This single novel semiorganic crystal of TTLaN showed very good optical transmission property, high thermal stability and large non-linearity nature.
文摘The compound lead oxide sulfate PbSO4.PbO was prepared in our laboratory. The Thermal behavior of PbSO4 was studied using techniques of Thermogravimetry under air atmosphere from 25 to 1200°C. The identity of both compounds was confirmed by XRD technique. Results obtained using both techniques support same decomposition stages for this compound. The electron microscopic investigations are made by SEM and TEM. The compound is characterized by XRD and the purity was determined by analytical Methods. Also a series of thermogravimetric analysis is made and the ideal condition is determined to convert this compound to pure lead oxide.
文摘This paper presents the thermal analysis of artificial sweeteners, and natural sugar substitutes. Thermal analysis was done on commercial compositions of sweeteners using simultaneous DSC/TGA (SDT). Heat flow, and mass vs. temperature and time thermograms, along with DSC peak enthalpies and transition temperatures are reported. A number of the sweeteners were found to undergo transitions and reactions before or at 190°C (375°F, normal baking temperatures) and all dextrose containing sweeteners show an endothermic peak around 80°C due to the liberation of bound water molecules. The major components of sweeteners studied were found to be generally thermostable at or below 100°C.
文摘Through this study, the humus produced in the breeding place of Universidad Autonoma de Occidente was thermally characterized. The humus was submitted to a heating program controlled by the Differential Scanning Calorimetry (DSC) technique to characterize the type of transition, Thermogravimetry (TGA) to study the equilibrium of phasesand Mass Spectrometry (MS) coupled to TGA to identify detached elements in a temperature range. The temperature range used in this study was 30℃ ℃. The energy required for the water desorption in the humus has been found in this study. The humus showed a quick desorption between 30℃ ≤ TDesorption ≤ 110℃ at a heating rate of 10℃/min and presented decomposition around 250℃. Moreover, the kinetics of the desorption of the humus was studied to obtain the activation energy three TGA measures for three different heating rates. The average activation energy was about 26 kJ/Mol. This result was carried out to obtain an estimation of the desorption time of water in the range from room temperature to the decomposition temperature around 350℃.
文摘随着科技的发展,我国的交通运输水平已处于世界前列,特别是轨道车辆的发展,为我国人员流通、物资运输和经济的发展作出重大贡献。轨道交通列车运行过程中,车辆内部运行控制信号及电力的输送保障至关重要。在轨道交通列车上使用的薄壁控制电缆的外层护套绝缘材料种类中,有一种为乙烯-醋酸乙烯共聚物(EVA),该材料在酸性、潮湿等恶劣条件下易发生黄变、开裂、鼓包等现象,从而影响电缆的剩余寿命,使得电缆出现传输异常,影响列车正常运行,严重时可能出现短路发生火灾造成重大事故及人员伤亡。为对轨道车辆用乙烯-醋酸乙烯共聚物(EVA)电缆的剩余寿命进行快速评估,文章采用热重分析法(TGA)研究了不同老化程度的EVA绝缘材料的热分解特性,计算出了其对应的热分解活化能。在此基础上,参照ASTM E 1877-00:2021标准中的方法建立了EVA绝缘材料的热寿命方程。研究结果表明:热分解特性能够用来评估轨道车辆用EVA电缆的实际老化情况,结合建立的热寿命方程能完成电缆使用状况的快速评估,与传统评估方法相比,该方法操作更加简单。