The feasibility of employing shell powder as a novel bio-filler to prepare fluorocarbon coating is demonstrated.According to the relevant Chinese standards, the thermal and mechanical properties of the shell powder-fi...The feasibility of employing shell powder as a novel bio-filler to prepare fluorocarbon coating is demonstrated.According to the relevant Chinese standards, the thermal and mechanical properties of the shell powder-filled fluorocarbon coating were evaluated, and compared with those filled by commercial calcium carbonate. All the shell powder-filled coatings can meet the requirements stated in the relevant standards, and with decreasing the particle size of the shell powders, the performance of the thermal insulation coating is enhanced. The coating(SC3) filled by shell powders with an average particle size of 2.81 μm possesses a better thermal insulation performance than the coating(CC) filled by commercial calcium carbonate. The coating SC3 has comparable adhesive force and washing resistance with the coating CC, and in the washing resistance test, after 2000 cycles, the coating SC3 was still able to cover totally their substrates. This work demonstrates a high value-added disposal method for the aquacultural wastes.展开更多
This study was designed to evaluate the thermal performance and mechanical properties of coatings with different gradations of TiO2 pigments. The solar reflectance, cooling performance, wash resistance, and film adhes...This study was designed to evaluate the thermal performance and mechanical properties of coatings with different gradations of TiO2 pigments. The solar reflectance, cooling performance, wash resistance, and film adhesion strength of the coatings were investigated. The influence of TiO2 powder gradation on the final properties of the coatings was studed. The solar reflectance and the thermal insulation were observed to increase with increasing content of nanosized TiO2. The mechanical properties of the coatings, such as their wash resistance and film adhesion strength, were observed to increase with increased incorporation of nanosized TiO2. Such improvements in the properties of the coatings were attributed to the greater specific surface area and lower thermal conductivity of nanosized TiO2 particles compared to normal TiO2 particles.展开更多
Plasma spray physical vapor deposition(PS-PVD)(Gd_(0.9)Yb_(0.1))_(2)Zr_(2)O_(7)(GYbZ)thermal barrier coatings(TBCs)exhibited better silicate-phobicity than coatings produced by electron beam physical vapor depo-sition...Plasma spray physical vapor deposition(PS-PVD)(Gd_(0.9)Yb_(0.1))_(2)Zr_(2)O_(7)(GYbZ)thermal barrier coatings(TBCs)exhibited better silicate-phobicity than coatings produced by electron beam physical vapor depo-sition.In combination with PS-PVD and ultrafast laser direct writing technology,biomimetic structured GYbZ TBCs,with a triple-scale micro/nano surface microstructure,were obtained.Laser ablating on the PS-PVD GYbZ coating enhanced the surface roughness,improving its wear resistance without increasing the surface hardness.Furthermore,during the laser ablation processing,numerous nanoparticles were deposited in-situ in the gaps between columns of the coating,reducing the coating Young’s modulus.The simulated temperature field and heat flux field demonstrated that the presence of numerous interfaces between small columns of the PS-PVD coatings is beneficial to thermal insulation.However,laser ablation decreased the coating thickness,reducing the thermal insulation by around 20%-30%as compared to its PS-PVD counterpart,suggesting that a moderate increase in the coating thickness should be considered when designing an efficient TBC system.展开更多
The insulation effect of ceramic coating in a turbine blade is of great importance for the service of engine in the field of aviation industry. Fabricating microstructure in the thermal barrier coatings(TBCs) is consi...The insulation effect of ceramic coating in a turbine blade is of great importance for the service of engine in the field of aviation industry. Fabricating microstructure in the thermal barrier coatings(TBCs) is considered to be able to enhance the thermal insulation effect. In this study, the traditional three-layer structure, containing ceramic top coat, bonding coat and substrate, is firstly simplified into a double-layer structure, where only ceramic layer and substrate are left, for analyzing the thermal insulation. Afterwards, the thermal insulation effect of the designed microstructure in the bonding coat of the three-layer structure is further studied. Column-like microstructures, filled with hollow ceramic microspheres in the interspace, are designed to improve the thermal insulation effect. The size parameters of the designed microstructure were optimized. The existence of the designed microstructure can significantly prolong the efficiency of thermal barrier coatings. The insulation temperature between the heating surface and lower surface of the substrate can exceed 300℃ and the thermal balance time has a big improvement of 240 s, more than 50%, than the traditional TBCs structure. Compared with the TBCs structure without microstructure, the designed microstructure can significantly improve the insulation temperature of more than 110℃.展开更多
基金Supported by the National Natural Science Foundation of China(51501038,51731004,51671054)the Fundamental Research Funds for the Central Universities(3212007203)
文摘The feasibility of employing shell powder as a novel bio-filler to prepare fluorocarbon coating is demonstrated.According to the relevant Chinese standards, the thermal and mechanical properties of the shell powder-filled fluorocarbon coating were evaluated, and compared with those filled by commercial calcium carbonate. All the shell powder-filled coatings can meet the requirements stated in the relevant standards, and with decreasing the particle size of the shell powders, the performance of the thermal insulation coating is enhanced. The coating(SC3) filled by shell powders with an average particle size of 2.81 μm possesses a better thermal insulation performance than the coating(CC) filled by commercial calcium carbonate. The coating SC3 has comparable adhesive force and washing resistance with the coating CC, and in the washing resistance test, after 2000 cycles, the coating SC3 was still able to cover totally their substrates. This work demonstrates a high value-added disposal method for the aquacultural wastes.
基金financially supported by the National Natural Science Foundation of China(No.51272043)
文摘This study was designed to evaluate the thermal performance and mechanical properties of coatings with different gradations of TiO2 pigments. The solar reflectance, cooling performance, wash resistance, and film adhesion strength of the coatings were investigated. The influence of TiO2 powder gradation on the final properties of the coatings was studed. The solar reflectance and the thermal insulation were observed to increase with increasing content of nanosized TiO2. The mechanical properties of the coatings, such as their wash resistance and film adhesion strength, were observed to increase with increased incorporation of nanosized TiO2. Such improvements in the properties of the coatings were attributed to the greater specific surface area and lower thermal conductivity of nanosized TiO2 particles compared to normal TiO2 particles.
基金supported by Nature Science Foun-dations of China(NSFC)under grant Nos.U21B2052 and 52102057。
文摘Plasma spray physical vapor deposition(PS-PVD)(Gd_(0.9)Yb_(0.1))_(2)Zr_(2)O_(7)(GYbZ)thermal barrier coatings(TBCs)exhibited better silicate-phobicity than coatings produced by electron beam physical vapor depo-sition.In combination with PS-PVD and ultrafast laser direct writing technology,biomimetic structured GYbZ TBCs,with a triple-scale micro/nano surface microstructure,were obtained.Laser ablating on the PS-PVD GYbZ coating enhanced the surface roughness,improving its wear resistance without increasing the surface hardness.Furthermore,during the laser ablation processing,numerous nanoparticles were deposited in-situ in the gaps between columns of the coating,reducing the coating Young’s modulus.The simulated temperature field and heat flux field demonstrated that the presence of numerous interfaces between small columns of the PS-PVD coatings is beneficial to thermal insulation.However,laser ablation decreased the coating thickness,reducing the thermal insulation by around 20%-30%as compared to its PS-PVD counterpart,suggesting that a moderate increase in the coating thickness should be considered when designing an efficient TBC system.
基金financially supported by the National Natural Science Foundation of China(11372037,11572041,and 11232008)
文摘The insulation effect of ceramic coating in a turbine blade is of great importance for the service of engine in the field of aviation industry. Fabricating microstructure in the thermal barrier coatings(TBCs) is considered to be able to enhance the thermal insulation effect. In this study, the traditional three-layer structure, containing ceramic top coat, bonding coat and substrate, is firstly simplified into a double-layer structure, where only ceramic layer and substrate are left, for analyzing the thermal insulation. Afterwards, the thermal insulation effect of the designed microstructure in the bonding coat of the three-layer structure is further studied. Column-like microstructures, filled with hollow ceramic microspheres in the interspace, are designed to improve the thermal insulation effect. The size parameters of the designed microstructure were optimized. The existence of the designed microstructure can significantly prolong the efficiency of thermal barrier coatings. The insulation temperature between the heating surface and lower surface of the substrate can exceed 300℃ and the thermal balance time has a big improvement of 240 s, more than 50%, than the traditional TBCs structure. Compared with the TBCs structure without microstructure, the designed microstructure can significantly improve the insulation temperature of more than 110℃.
