HgCr2S4 is a typical compound manifesting competing ferromagnetic (FM) and antiferromagnetic (AFM) exchanges as well as strong spin-lattice coupling. Here we study these effects by intentionally choosing a combina...HgCr2S4 is a typical compound manifesting competing ferromagnetic (FM) and antiferromagnetic (AFM) exchanges as well as strong spin-lattice coupling. Here we study these effects by intentionally choosing a combination of magnetization under external hydrostatic pressure and thermal conductivity at various magnetic fields. Upon applying pressure up to 10 kbar at 1 kOe, while the magnitude of magnetization reduces progressively, the AFM ordering temperature TN enhances concomitantly at a rate of about 1.5 K/kbar. Strikingly, at lO kOe the field polarized FM state is found to be driven readily back to an AFM one even at only 5kbar. In addition, the thermal conductivity exhibits drastic increments at various fields in the temperature range with strong spin fluctuations, reaching about 30% at 50 kOe. Consequently, the results give new experimental evidence of spin-lattice coupling. Apart from the colossal magnetoeapacitance and colossal magnetoresistance reported previously, the findings here may enable new promising functionalities for potential applications.展开更多
High luminous efficiency and high color rendering index(CRI) are both the foremost factors for white organic lightemitting diodes(WOLEDs) to serve as next generation solid-state lighting sources. In this paper, we sho...High luminous efficiency and high color rendering index(CRI) are both the foremost factors for white organic lightemitting diodes(WOLEDs) to serve as next generation solid-state lighting sources. In this paper, we show that both luminous efficiency and CRI can be improved by adjusting the green/red spectra of WOLEDs. With green emission spectra matching with the human photopic curve, the WOLEDs exhibit higher luminous efficiency and higher CRI. Theoretical calculation shows that by tuning the white emission spectra to maximally match with the human photopic curve, the luminous efficiency can be improved by 41.8% without altering the color coordinates, the color correlated temperature(CCT) and the external quantum efficiency(EQE) of the WOLEDs.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos U1332143 and 11574323
文摘HgCr2S4 is a typical compound manifesting competing ferromagnetic (FM) and antiferromagnetic (AFM) exchanges as well as strong spin-lattice coupling. Here we study these effects by intentionally choosing a combination of magnetization under external hydrostatic pressure and thermal conductivity at various magnetic fields. Upon applying pressure up to 10 kbar at 1 kOe, while the magnitude of magnetization reduces progressively, the AFM ordering temperature TN enhances concomitantly at a rate of about 1.5 K/kbar. Strikingly, at lO kOe the field polarized FM state is found to be driven readily back to an AFM one even at only 5kbar. In addition, the thermal conductivity exhibits drastic increments at various fields in the temperature range with strong spin fluctuations, reaching about 30% at 50 kOe. Consequently, the results give new experimental evidence of spin-lattice coupling. Apart from the colossal magnetoeapacitance and colossal magnetoresistance reported previously, the findings here may enable new promising functionalities for potential applications.
基金supported by the National Natural Science Foundation of China(No.61405089)the Innovation of Science and Technology Committee of Shenzhen(No.JCYJ20140417105742713)
文摘High luminous efficiency and high color rendering index(CRI) are both the foremost factors for white organic lightemitting diodes(WOLEDs) to serve as next generation solid-state lighting sources. In this paper, we show that both luminous efficiency and CRI can be improved by adjusting the green/red spectra of WOLEDs. With green emission spectra matching with the human photopic curve, the WOLEDs exhibit higher luminous efficiency and higher CRI. Theoretical calculation shows that by tuning the white emission spectra to maximally match with the human photopic curve, the luminous efficiency can be improved by 41.8% without altering the color coordinates, the color correlated temperature(CCT) and the external quantum efficiency(EQE) of the WOLEDs.