A mathematical method called Modifled Function Transformation Method(MFTM) for linearizing thermistors is proposed.Theoretically,the method has unified many schemes of linearizing thermistors into a mathematical ratio...A mathematical method called Modifled Function Transformation Method(MFTM) for linearizing thermistors is proposed.Theoretically,the method has unified many schemes of linearizing thermistors into a mathematical rational frame,and explained the reason of different circuits having the same capabilities for linearizing the thermistor characteristics.展开更多
A new type of miniature negative temperature coefficient (NTC) thermistors has been developed and manufactured with Mn-Ni-Cu-Fe oxides. The prepared NTC thermistors were calibrated in the temperature range from 77 K t...A new type of miniature negative temperature coefficient (NTC) thermistors has been developed and manufactured with Mn-Ni-Cu-Fe oxides. The prepared NTC thermistors were calibrated in the temperature range from 77 K to 300 K with 1 μA exciting currents. The automatic calibration apparatus as well as thermometric characteristics, stability, calibration equations and interchangeability of the manufactured thermistors were investigated. A mean fit equation was obtained: 1/<em>T</em> = 8.60 × 10<sup><span style="white-space:nowrap;">−</span>4</sup> + 6.54 × 10<sup><span style="white-space:nowrap;">−</span>4</sup> ln(<em>R/R</em><sub>ref</sub>) + 2.46 × 10<sup><span style="white-space:nowrap;">−</span>5</sup> ln(<em style="white-space:normal;">R/R</em><sub style="white-space:normal;">ref</sub>)<sup>2</sup> + 9.48 × 10<sup><span style="white-space:nowrap;">−</span>7</sup> ln(<em style="white-space:normal;">R/R</em><sub style="white-space:normal;">ref</sub>)<sup>3</sup> <span style="white-space:nowrap;">−</span> 2.16 × 10<sup><span style="white-space:nowrap;">−</span>8</sup> ln(<em style="white-space:normal;">R/R</em><sub style="white-space:normal;">ref</sub>)<sup>4</sup>. All the prepared NTC thermistors agreed with this fit with an error of 1.5 K. If the greater accuracy is required, a calibration is necessary, and the calibration accuracy is estimated to be ±10 mK.展开更多
The electrical properties of high-entropy ceramics(HECs)have been extensively studied in recent years due to their unique structural characteristics and fascinating functional properties induced by entropy engineering...The electrical properties of high-entropy ceramics(HECs)have been extensively studied in recent years due to their unique structural characteristics and fascinating functional properties induced by entropy engineering.Novel high-entropy(Sm_(0.2)Eu_(0.2)Gd_(0.2)Ho_(0.2)Yb_(0.2))CrO_(3)(HE-RECrO_(3))nanofibers were prepared by electro spinning.This work demonstrates that HE-RECrO_(3)nanofibe rs were successfully synthesized at a low temperature(800℃),which is approximately 400℃lower than the temperatures at which chromate ceramics were synthesized via the sol-gel method and the solid-state reaction method.The resistivity of HE-RECrO_(3)nanofibers decreases exponentially with increasing temperature from 25 to600℃.The logarithm of the resistivity is linearly related to the inverse of the temperature,confirming the negative temperature coefficient property of HE-RECrO_(3)nanofibers.The B_(25/50)value of the HERECrO_(3)nanofibers reaches 4072 K.In conclusion,HE-RECrO_(3)nanofibers are expected to be potential candidates for negative-temperature-coefficient(NTC)thermistors.展开更多
In the present study, Zn-doped CaTiO_3 nanocrystalline was synthesized to study the thermistor behavior with temperature. The X-ray powder diffraction analysis showed the formation of a single-phase orthorhombic struc...In the present study, Zn-doped CaTiO_3 nanocrystalline was synthesized to study the thermistor behavior with temperature. The X-ray powder diffraction analysis showed the formation of a single-phase orthorhombic structure at room temperature. The electrical resistance of the Zn-doped CaTiO_3 increased with increasing doping concentration and decreased at higher measuring temperature, showing a negative temperature coefficient of resistance(NTCR) behavior. Different thermistor parameters were calculated using Steinhart–Hart equations, whilst time domain analysis confirmed faster response towards applied voltage.展开更多
It is possible to fabricate highly sensitive NTCR(negative temperature coefficient of resistance)thermistor using nano crystalline CaTiO_(3) synthesized by high energy ball milling.Disc shaped green pellets were prepa...It is possible to fabricate highly sensitive NTCR(negative temperature coefficient of resistance)thermistor using nano crystalline CaTiO_(3) synthesized by high energy ball milling.Disc shaped green pellets were prepared and effects of sintering on the disc pellets were studied as thermistor by sintering the samples at 1000℃,1100℃and 1200℃.The as-prepared samples were characterized by X-ray diffraction(XRD),impedance analysis and electrical measurement.The resistivity of the prepared samples varies predictably with temperature:this makes them promising material for temperature sensor.The experimental results prove that nano crystalline CaTiO_(3) ceramic is one kind of thermistor with exponential negative temperature coefficient of resistance in the temperature range of 300-500℃.The samples have the advantages of rapid response,high sensitivity and capability to withstand thermal surges over the temperature range of 300-500℃.Resistance-temperature characteristics are described by thermistor equation with thermistor constant around 4003 K to 10795 K and thermal coefficient of resistanceαaround-1%/℃to-13%/℃.The activation energy is in the range of 0.34-0.93 eV.The observed thermistor parameters are found to be comparable with many of the known thermistor materials.This suggests that the electrical properties can be adjusted to desirable values by controlling the temperature parameter.The influence of fabrication process of disc thermistor and electrical properties are discussed.The study shows the potential of nano crystalline CaTiO_(3) to act as an NTCR material for thermistor applications.展开更多
Dense nano-grained Ni_(0.7)Mn_(2.3O4) negative temperature coefficient(NTC) thermistors were fabricated by a novel two-step sintering approach that combines rapid sintering and principle of conventional two-step sinte...Dense nano-grained Ni_(0.7)Mn_(2.3O4) negative temperature coefficient(NTC) thermistors were fabricated by a novel two-step sintering approach that combines rapid sintering and principle of conventional two-step sintering technique.Samples were sintered at 1042℃ for 30 s in the first rapid step and then at 850-950℃ for 20 h in the second soaking step.Crystal phase,microstructure and electrical properties of sintered samples were studied by X-ray diffraction(XRD),scanning electron microscopy(SEM),resistance temperature relationship and aging performance.Sintered samples show a single-phase cubic spinel structure and indicate a high relative density ranging from 84% to 91% of the theoretical density.Moreover,average grain sizes of sintered samples under SEM are distributed between 254 and 570 nm.Meanwhile,the resistivity and the aging coefficient significantly decrease when soaking sintering temperature rises.In addition,the obtained material constant(B) ranges from 3931 to 3981 K.Ni_(0.7)Mn_(2.3)O_(4)-3(soaking at 900℃) and Ni_(0.7)Mn_(2.3O4)-4(soaking at 950℃) present little aging behavior,implying great electrical stability.展开更多
The thermistor problem is a coupled system of nonlinear PDEs which consists of the heat equation with the Joule heating as a source, and the current conservation equation with temperature dependent electrical conducti...The thermistor problem is a coupled system of nonlinear PDEs which consists of the heat equation with the Joule heating as a source, and the current conservation equation with temperature dependent electrical conductivity. In this paper we make a numerical analysis of the nonsteady thermistor problem. L(infinity)(OMEGA), W1,infinity(OMEGA) stability and error bounds for a piecewise linear finite element approximation are given.展开更多
As functional materials, PTC thermistor ceramics characterized by a drastic increase in resistivity at its transition temperature have been widely used in high-technology areas such as temperature measurement and indi...As functional materials, PTC thermistor ceramics characterized by a drastic increase in resistivity at its transition temperature have been widely used in high-technology areas such as temperature measurement and indication, temperature control, protective switches and so on. At present, the PTC thermistors are fabricated by means of doping BaTiO<sub>3</sub> and their PTC effects result from the existence of acceptor state or electronic trap on grain boundary. But the fabrication process展开更多
文摘A mathematical method called Modifled Function Transformation Method(MFTM) for linearizing thermistors is proposed.Theoretically,the method has unified many schemes of linearizing thermistors into a mathematical rational frame,and explained the reason of different circuits having the same capabilities for linearizing the thermistor characteristics.
文摘A new type of miniature negative temperature coefficient (NTC) thermistors has been developed and manufactured with Mn-Ni-Cu-Fe oxides. The prepared NTC thermistors were calibrated in the temperature range from 77 K to 300 K with 1 μA exciting currents. The automatic calibration apparatus as well as thermometric characteristics, stability, calibration equations and interchangeability of the manufactured thermistors were investigated. A mean fit equation was obtained: 1/<em>T</em> = 8.60 × 10<sup><span style="white-space:nowrap;">−</span>4</sup> + 6.54 × 10<sup><span style="white-space:nowrap;">−</span>4</sup> ln(<em>R/R</em><sub>ref</sub>) + 2.46 × 10<sup><span style="white-space:nowrap;">−</span>5</sup> ln(<em style="white-space:normal;">R/R</em><sub style="white-space:normal;">ref</sub>)<sup>2</sup> + 9.48 × 10<sup><span style="white-space:nowrap;">−</span>7</sup> ln(<em style="white-space:normal;">R/R</em><sub style="white-space:normal;">ref</sub>)<sup>3</sup> <span style="white-space:nowrap;">−</span> 2.16 × 10<sup><span style="white-space:nowrap;">−</span>8</sup> ln(<em style="white-space:normal;">R/R</em><sub style="white-space:normal;">ref</sub>)<sup>4</sup>. All the prepared NTC thermistors agreed with this fit with an error of 1.5 K. If the greater accuracy is required, a calibration is necessary, and the calibration accuracy is estimated to be ±10 mK.
基金Project supported by the National Key Research and Development Program of China(2019YFC0605000)the"Transformational Technologies for Clean Energy and Demonstration",Strategic Priority Research Program of the Chinese Academy of Sciences(XDA21000000)+4 种基金the Independent Deployment Project of Ganjiang Innovation Research Institute of Chinese Academy of Sciences(E055A002)the Independent Deployment Project of China Fujian Innovation Laboratory of Optoelectronic Information Technology(2021ZZ109)the Fujian Provincial Natural Fund(2021J05101)the National Natural Science Foundation of China(21771196,62275276)Advanced Energy Science and Technology Guangdong Laboratory(HND20TDGFDC00)。
文摘The electrical properties of high-entropy ceramics(HECs)have been extensively studied in recent years due to their unique structural characteristics and fascinating functional properties induced by entropy engineering.Novel high-entropy(Sm_(0.2)Eu_(0.2)Gd_(0.2)Ho_(0.2)Yb_(0.2))CrO_(3)(HE-RECrO_(3))nanofibers were prepared by electro spinning.This work demonstrates that HE-RECrO_(3)nanofibe rs were successfully synthesized at a low temperature(800℃),which is approximately 400℃lower than the temperatures at which chromate ceramics were synthesized via the sol-gel method and the solid-state reaction method.The resistivity of HE-RECrO_(3)nanofibers decreases exponentially with increasing temperature from 25 to600℃.The logarithm of the resistivity is linearly related to the inverse of the temperature,confirming the negative temperature coefficient property of HE-RECrO_(3)nanofibers.The B_(25/50)value of the HERECrO_(3)nanofibers reaches 4072 K.In conclusion,HE-RECrO_(3)nanofibers are expected to be potential candidates for negative-temperature-coefficient(NTC)thermistors.
文摘In the present study, Zn-doped CaTiO_3 nanocrystalline was synthesized to study the thermistor behavior with temperature. The X-ray powder diffraction analysis showed the formation of a single-phase orthorhombic structure at room temperature. The electrical resistance of the Zn-doped CaTiO_3 increased with increasing doping concentration and decreased at higher measuring temperature, showing a negative temperature coefficient of resistance(NTCR) behavior. Different thermistor parameters were calculated using Steinhart–Hart equations, whilst time domain analysis confirmed faster response towards applied voltage.
文摘It is possible to fabricate highly sensitive NTCR(negative temperature coefficient of resistance)thermistor using nano crystalline CaTiO_(3) synthesized by high energy ball milling.Disc shaped green pellets were prepared and effects of sintering on the disc pellets were studied as thermistor by sintering the samples at 1000℃,1100℃and 1200℃.The as-prepared samples were characterized by X-ray diffraction(XRD),impedance analysis and electrical measurement.The resistivity of the prepared samples varies predictably with temperature:this makes them promising material for temperature sensor.The experimental results prove that nano crystalline CaTiO_(3) ceramic is one kind of thermistor with exponential negative temperature coefficient of resistance in the temperature range of 300-500℃.The samples have the advantages of rapid response,high sensitivity and capability to withstand thermal surges over the temperature range of 300-500℃.Resistance-temperature characteristics are described by thermistor equation with thermistor constant around 4003 K to 10795 K and thermal coefficient of resistanceαaround-1%/℃to-13%/℃.The activation energy is in the range of 0.34-0.93 eV.The observed thermistor parameters are found to be comparable with many of the known thermistor materials.This suggests that the electrical properties can be adjusted to desirable values by controlling the temperature parameter.The influence of fabrication process of disc thermistor and electrical properties are discussed.The study shows the potential of nano crystalline CaTiO_(3) to act as an NTCR material for thermistor applications.
基金financially supported by the National Natural Science Foundation of China(Nos.51302138 and 21663001)the Western Light Talent Training Program of Chinese Academy of Sciences。
文摘Dense nano-grained Ni_(0.7)Mn_(2.3O4) negative temperature coefficient(NTC) thermistors were fabricated by a novel two-step sintering approach that combines rapid sintering and principle of conventional two-step sintering technique.Samples were sintered at 1042℃ for 30 s in the first rapid step and then at 850-950℃ for 20 h in the second soaking step.Crystal phase,microstructure and electrical properties of sintered samples were studied by X-ray diffraction(XRD),scanning electron microscopy(SEM),resistance temperature relationship and aging performance.Sintered samples show a single-phase cubic spinel structure and indicate a high relative density ranging from 84% to 91% of the theoretical density.Moreover,average grain sizes of sintered samples under SEM are distributed between 254 and 570 nm.Meanwhile,the resistivity and the aging coefficient significantly decrease when soaking sintering temperature rises.In addition,the obtained material constant(B) ranges from 3931 to 3981 K.Ni_(0.7)Mn_(2.3)O_(4)-3(soaking at 900℃) and Ni_(0.7)Mn_(2.3O4)-4(soaking at 950℃) present little aging behavior,implying great electrical stability.
文摘The thermistor problem is a coupled system of nonlinear PDEs which consists of the heat equation with the Joule heating as a source, and the current conservation equation with temperature dependent electrical conductivity. In this paper we make a numerical analysis of the nonsteady thermistor problem. L(infinity)(OMEGA), W1,infinity(OMEGA) stability and error bounds for a piecewise linear finite element approximation are given.
文摘As functional materials, PTC thermistor ceramics characterized by a drastic increase in resistivity at its transition temperature have been widely used in high-technology areas such as temperature measurement and indication, temperature control, protective switches and so on. At present, the PTC thermistors are fabricated by means of doping BaTiO<sub>3</sub> and their PTC effects result from the existence of acceptor state or electronic trap on grain boundary. But the fabrication process