In this study, gold nanoparticles and thermochromic composite films modified screen-printed carbon electrodes (TM-AuNPsSPCEs) were developed as a platform for the simultaneous detection of protein and temperature. The...In this study, gold nanoparticles and thermochromic composite films modified screen-printed carbon electrodes (TM-AuNPsSPCEs) were developed as a platform for the simultaneous detection of protein and temperature. The TM-AuNPs composited film had better sensitivity resulting from the gold nanoparticles amplification effect. A phase transition model analysis of TM-AuNPs films found that the TM-AuNPs films had three-phase transition intervals (<45℃, 45℃ to 80℃ and >80℃) which accommodated the temperature requirements for protein denaturation. When used to detect different concentrations of haemoglobin (Hb) solution, the TM-AuNPs modified SPCEs had a better sensitivity in detecting the different concentrations in comparison to TM and AuNP modified SPCEs which showed no clear sensitivity towards the different Hb concentrations. The dual detection and excellent sensitivity show a good application prospect for the study of the TM-AuNPs composite film.展开更多
Thermochromic material is a kind of smart material whose color will vary as the result of the phase transition caused by the temperature change. The characteristics of thermochromic materials are the memory functions ...Thermochromic material is a kind of smart material whose color will vary as the result of the phase transition caused by the temperature change. The characteristics of thermochromic materials are the memory functions to the temperature, having great potential applications in aerospace, military, anticounterfeiting technology, construction and other fields. In recent years, many kinds of thermochromic materials have been prepared by different methods and their discoloration mechanisms are various according to published literatures. In this paper, the classification, discoloration mechanism, preparation methods, application fields and development trend of thermochromic materials are reviewed.展开更多
This paper aims to investigate thermal radiative characteristics of thermochrornic material La0.825Sr0.175MnO3(LSMO) with one-dimensional grating structured surfaces. The dielectric function of LSMO was calculated b...This paper aims to investigate thermal radiative characteristics of thermochrornic material La0.825Sr0.175MnO3(LSMO) with one-dimensional grating structured surfaces. The dielectric function of LSMO was calculated by K-K approach. Numerical calculation was conducted to obtain spectral emittance distribution of such surfaces with different structural parameters using the finite difference time domain (FDTD) method. It was found that the spectral emittance of LSMO structured surface exhib- ited the feature of selective enhancement due to the excitation of microcavity effect. The effects of structural parameters on spectral emittance indicated that the desired radiative enhancement could be achieved by the rational design of the structural parameters of grating. The temperature dependence of averaged emittance of LSMO was also calculated, The results showed that LSMO with grating structured surface had a better thermochromic performance compared with LSMO with smooth surface.展开更多
文摘In this study, gold nanoparticles and thermochromic composite films modified screen-printed carbon electrodes (TM-AuNPsSPCEs) were developed as a platform for the simultaneous detection of protein and temperature. The TM-AuNPs composited film had better sensitivity resulting from the gold nanoparticles amplification effect. A phase transition model analysis of TM-AuNPs films found that the TM-AuNPs films had three-phase transition intervals (<45℃, 45℃ to 80℃ and >80℃) which accommodated the temperature requirements for protein denaturation. When used to detect different concentrations of haemoglobin (Hb) solution, the TM-AuNPs modified SPCEs had a better sensitivity in detecting the different concentrations in comparison to TM and AuNP modified SPCEs which showed no clear sensitivity towards the different Hb concentrations. The dual detection and excellent sensitivity show a good application prospect for the study of the TM-AuNPs composite film.
基金the National Natural Science Foundation of China(Grant Nos.51372200 and 51772243)the Foundation of the State Key Laboratory of Solidification Processing in NWPU(Grant No.SKLSP201753)+2 种基金Scientific Research Plan Projects of Shaanxi Education Department(Grant No.16JK1551)Technology Innovation Programme of Xi’an University of Technology(Grant No.2016CX030)China Postdoctoral Science Foundation(Grant No.2016M592824)
文摘Thermochromic material is a kind of smart material whose color will vary as the result of the phase transition caused by the temperature change. The characteristics of thermochromic materials are the memory functions to the temperature, having great potential applications in aerospace, military, anticounterfeiting technology, construction and other fields. In recent years, many kinds of thermochromic materials have been prepared by different methods and their discoloration mechanisms are various according to published literatures. In this paper, the classification, discoloration mechanism, preparation methods, application fields and development trend of thermochromic materials are reviewed.
基金supported by the National Natural Science Foundation of China (Grant No.50936002,50876044)
文摘This paper aims to investigate thermal radiative characteristics of thermochrornic material La0.825Sr0.175MnO3(LSMO) with one-dimensional grating structured surfaces. The dielectric function of LSMO was calculated by K-K approach. Numerical calculation was conducted to obtain spectral emittance distribution of such surfaces with different structural parameters using the finite difference time domain (FDTD) method. It was found that the spectral emittance of LSMO structured surface exhib- ited the feature of selective enhancement due to the excitation of microcavity effect. The effects of structural parameters on spectral emittance indicated that the desired radiative enhancement could be achieved by the rational design of the structural parameters of grating. The temperature dependence of averaged emittance of LSMO was also calculated, The results showed that LSMO with grating structured surface had a better thermochromic performance compared with LSMO with smooth surface.