The so-called Goto's model was modified by introducing a parameter of the oxygen efficiency from industrial trials, as well as the selected and newly re-assessed thermodynamic data. The application of the model to...The so-called Goto's model was modified by introducing a parameter of the oxygen efficiency from industrial trials, as well as the selected and newly re-assessed thermodynamic data. The application of the model to copper converters in Guixi Smelter has been carried out by the combination of thermodynamic calculations with the mass and heat balance using the plant data obtained in industrial trials for many heats. For the slag-making stage, good agreements have been reached betWeen the calculated and measured temperature, blowing time as well as the contents for main elements in the matte and the slag. Relativel}'' large deviations for contents of Zn and Pb in the slag may be caused by the complex chemical composition of the real molten slag, which ma}; result in a large difference of γzn. and γPb,adopted with their real values. It is noted that the model can simulate the slag-making stage of copper converting process in industrial Pierce-Smith converters well.展开更多
We compute the thermodynamic and the kinetic properties for the reaction: HCOCN→HCH+CO using the statistical theory and the transition-state theory.The equi- librium constants and the rate coefficients of this reacti...We compute the thermodynamic and the kinetic properties for the reaction: HCOCN→HCH+CO using the statistical theory and the transition-state theory.The equi- librium constants and the rate coefficients of this reaction are also reported here,and the half lives of formyl cyanide at different temperatures are first estimated in this work.展开更多
Based on the quantum chemical study of the silylidyne insertion reaction with NH3 or PH3, the general statistical thermodynamics and Eyring transition state theory with Wigner correction are used to compute the change...Based on the quantum chemical study of the silylidyne insertion reaction with NH3 or PH3, the general statistical thermodynamics and Eyring transition state theory with Wigner correction are used to compute the changes of thermodynamic functions, equilibrium constants, A factors and rate constants of the two reactions in the temperature range 200-2000K. The results show that both of these reactions are thermodynamically dominant at low temperatures and kinetically favored at higher temperatures. The comparison between these two reactions shows that the SiH reaction with NH3 is more exothermic than SiH with PH3, while the rate constant of SiH reaction with NH3 is lower than that of SiH with PH3 at the same temperature.展开更多
In the present study,the thermodynamic and economic performance of a combined thermodynamic cycle formed by an ORC and a Kalina cycle,which can simultaneously recover waste heat of exhaust gas and cooling water of mar...In the present study,the thermodynamic and economic performance of a combined thermodynamic cycle formed by an ORC and a Kalina cycle,which can simultaneously recover waste heat of exhaust gas and cooling water of marine engine,has been analyzed.Two typical marine engines are selected to be the waste heat source.Six economic indicators are used to analyze the economic performance of this combined thermodynamic cycle system with different marine engine load and under practical comprehensive operating condition of marine engine.The results of the present study show that the combined thermodynamic cycle system with R123 as organic working fluid has the best performance.The system with cis-butene has the worst economic performance.Under practical comprehensive operating conditions of ships,R123 has the shortest Payback Periods,which are 8.51 years and 8.14 years for 8 S70 ME-C10.5 engine and 5G95 ME-C10.5 engine,respectively.Correspondingly,payback Periods of Cyclopentane are 11.95 years and 11.90 years.The above values are much shorter than 25 years which are the lifetime of a marine ship.Under practical comprehensive operating conditions of ships,the combined cycle system can provide output power which is at least equivalent to 25%of engine power.Considering that R123 will be phased out in near future,cyclopentane may be its good successor.Cyclopentane can be used safely by correct handling and installing according to manufacturer's instructions.展开更多
文摘The so-called Goto's model was modified by introducing a parameter of the oxygen efficiency from industrial trials, as well as the selected and newly re-assessed thermodynamic data. The application of the model to copper converters in Guixi Smelter has been carried out by the combination of thermodynamic calculations with the mass and heat balance using the plant data obtained in industrial trials for many heats. For the slag-making stage, good agreements have been reached betWeen the calculated and measured temperature, blowing time as well as the contents for main elements in the matte and the slag. Relativel}'' large deviations for contents of Zn and Pb in the slag may be caused by the complex chemical composition of the real molten slag, which ma}; result in a large difference of γzn. and γPb,adopted with their real values. It is noted that the model can simulate the slag-making stage of copper converting process in industrial Pierce-Smith converters well.
文摘We compute the thermodynamic and the kinetic properties for the reaction: HCOCN→HCH+CO using the statistical theory and the transition-state theory.The equi- librium constants and the rate coefficients of this reaction are also reported here,and the half lives of formyl cyanide at different temperatures are first estimated in this work.
文摘Based on the quantum chemical study of the silylidyne insertion reaction with NH3 or PH3, the general statistical thermodynamics and Eyring transition state theory with Wigner correction are used to compute the changes of thermodynamic functions, equilibrium constants, A factors and rate constants of the two reactions in the temperature range 200-2000K. The results show that both of these reactions are thermodynamically dominant at low temperatures and kinetically favored at higher temperatures. The comparison between these two reactions shows that the SiH reaction with NH3 is more exothermic than SiH with PH3, while the rate constant of SiH reaction with NH3 is lower than that of SiH with PH3 at the same temperature.
基金funded by the National Natural Science Foundation of China(Grant No.51506001)Beijing Municipal Education Commission(KM201710005029)。
文摘In the present study,the thermodynamic and economic performance of a combined thermodynamic cycle formed by an ORC and a Kalina cycle,which can simultaneously recover waste heat of exhaust gas and cooling water of marine engine,has been analyzed.Two typical marine engines are selected to be the waste heat source.Six economic indicators are used to analyze the economic performance of this combined thermodynamic cycle system with different marine engine load and under practical comprehensive operating condition of marine engine.The results of the present study show that the combined thermodynamic cycle system with R123 as organic working fluid has the best performance.The system with cis-butene has the worst economic performance.Under practical comprehensive operating conditions of ships,R123 has the shortest Payback Periods,which are 8.51 years and 8.14 years for 8 S70 ME-C10.5 engine and 5G95 ME-C10.5 engine,respectively.Correspondingly,payback Periods of Cyclopentane are 11.95 years and 11.90 years.The above values are much shorter than 25 years which are the lifetime of a marine ship.Under practical comprehensive operating conditions of ships,the combined cycle system can provide output power which is at least equivalent to 25%of engine power.Considering that R123 will be phased out in near future,cyclopentane may be its good successor.Cyclopentane can be used safely by correct handling and installing according to manufacturer's instructions.
