This paper focuses on determining total organic carbon(TOC)from boreholes in the Kalahari Basin,Botswana,using Passey's method.The Kalahari Karoo basin is one of several basins in southern Africa filled with Late ...This paper focuses on determining total organic carbon(TOC)from boreholes in the Kalahari Basin,Botswana,using Passey's method.The Kalahari Karoo basin is one of several basins in southern Africa filled with Late Carboniferous to Jurassic sedimentary strata that host Permian age coal seams.Nine exploration boreholes(wells)drilled in the central Kalahari Karoo basin are used to determine the Total Organic Carbon potential.Vitrinite reflectance(Ro),proximate and ultimate analyses were conducted on cored coal intervals.Passey's DLogR method applied in this study employs resistivity and porosity logs to identify and quantify potential source rocks.Results of Passey's method compared with laboratorymeasured carbon showed that Passey's method effectively identifies coal intervals.In terms of TOC calculations,the method works poorly in coal metamorphosed by dolerite intrusions.The heat affected coal samples had Ro from 0.77% to 5.53% and increased in maturity from primarily maceral controlled to high volatile bituminous and anthracite coal.Results from proximate analysis showed compositional changes in the coal were controlled by proximity to sill intrusion,with a decrease in Fixed Carbon and an increase in ash yield in the contact metamorphism zone(2-12 m from sill).For the unaltered coal that has undergone burial maturation displaying Ro of 0.44%-0.65%,the method works well.In unintruded boreholes,correlations between Carbon and calculated TOC indicate strong relationships.Passey's DLogR method proved to be a suitable method of estimating TOC on coal that has undergone burial maturation.This study has demonstrated that TOC calculated from the sonic log is more reliable in coal not affected by contact metamorphism than TOC calculated from the density log.展开更多
Sillimanite is a brittle mineral as a metamorphic mineral product which is generally derived from clay, along with an increase in pressure and high temperature (600°C - 900°C), and kaliophilite is also a bri...Sillimanite is a brittle mineral as a metamorphic mineral product which is generally derived from clay, along with an increase in pressure and high temperature (600°C - 900°C), and kaliophilite is also a brittle mineral as a potassium bearing in the sand-shale series, which contributes to the clay diagenesis process. In the development of shale hydrocarbon in the Brownshale formation in the Bengkalis Trough, Central Sumatra Basin, using the correlation of the XRD (bulk and clay oriented), TOC, Ro, and MBT analysis results from the drill cuttings of well BS-03, so that the fracable zone interval can be determined. From this correlation, it shows that the presence of sillimanite and kaliophilite minerals as minor minerals greatly affects the changes in shale character and hydrocarbon generation, where at depth intervals of 10,780 ft downward (sand series-shale) there is an interesting phenomenon, <i>i.e. </i> low MBT, low TOC, and high Ro, so it is believed that the depth interval of 10,780 ft downward is a fracable zone interval (brittle shale) which is a good candidate for hydraulic fracking planning, while the upper depth interval is a fracture barrier.展开更多
文摘This paper focuses on determining total organic carbon(TOC)from boreholes in the Kalahari Basin,Botswana,using Passey's method.The Kalahari Karoo basin is one of several basins in southern Africa filled with Late Carboniferous to Jurassic sedimentary strata that host Permian age coal seams.Nine exploration boreholes(wells)drilled in the central Kalahari Karoo basin are used to determine the Total Organic Carbon potential.Vitrinite reflectance(Ro),proximate and ultimate analyses were conducted on cored coal intervals.Passey's DLogR method applied in this study employs resistivity and porosity logs to identify and quantify potential source rocks.Results of Passey's method compared with laboratorymeasured carbon showed that Passey's method effectively identifies coal intervals.In terms of TOC calculations,the method works poorly in coal metamorphosed by dolerite intrusions.The heat affected coal samples had Ro from 0.77% to 5.53% and increased in maturity from primarily maceral controlled to high volatile bituminous and anthracite coal.Results from proximate analysis showed compositional changes in the coal were controlled by proximity to sill intrusion,with a decrease in Fixed Carbon and an increase in ash yield in the contact metamorphism zone(2-12 m from sill).For the unaltered coal that has undergone burial maturation displaying Ro of 0.44%-0.65%,the method works well.In unintruded boreholes,correlations between Carbon and calculated TOC indicate strong relationships.Passey's DLogR method proved to be a suitable method of estimating TOC on coal that has undergone burial maturation.This study has demonstrated that TOC calculated from the sonic log is more reliable in coal not affected by contact metamorphism than TOC calculated from the density log.
文摘Sillimanite is a brittle mineral as a metamorphic mineral product which is generally derived from clay, along with an increase in pressure and high temperature (600°C - 900°C), and kaliophilite is also a brittle mineral as a potassium bearing in the sand-shale series, which contributes to the clay diagenesis process. In the development of shale hydrocarbon in the Brownshale formation in the Bengkalis Trough, Central Sumatra Basin, using the correlation of the XRD (bulk and clay oriented), TOC, Ro, and MBT analysis results from the drill cuttings of well BS-03, so that the fracable zone interval can be determined. From this correlation, it shows that the presence of sillimanite and kaliophilite minerals as minor minerals greatly affects the changes in shale character and hydrocarbon generation, where at depth intervals of 10,780 ft downward (sand series-shale) there is an interesting phenomenon, <i>i.e. </i> low MBT, low TOC, and high Ro, so it is believed that the depth interval of 10,780 ft downward is a fracable zone interval (brittle shale) which is a good candidate for hydraulic fracking planning, while the upper depth interval is a fracture barrier.
