Crystal Structure of a Mn(Ⅱ) Coordination Polymer:[Mn(TP)(TBZH)_(2n)(TBZH=Thiabendazole,TP=Terephthalic Acid)

The structure of a manganese（Ⅱ） polymer,[Mn（TP）（TBZH）]2n 1（TBZH=thiabendazole,TP=terephthalic acid）,has been determined by X-ray crystallography and characterized by elemental analysis,IR spectrum and thermogravimetric analysis.It crystallizes in the orthorhombic system,space group Pbcn with a=12.7813（12）,b=10.7544（10）,c=20.1270（19）A,V=2766.6（4）A^3,Z=8,C14H9Mn0.50N3O2S,Mr=310.77,Dc=1.492g/cm^3,F（000）=1268,μ=0.674 mm^-1 and S=1.064.The 1-D chain architecture of 1 is constructed from terephthalic acid and manganese atoms.Hydrogen bonds and aryl ring π-π stacking interactions in 1 contribute to form a 3-D supramo-lecular structure.

Crystal Structure of a Cu(Ⅱ) Coordination Polymer: [Cu(IP)(TBZH)]_(2n) (TBZH = Thiabendazole, IP = Isophthalic Acid)

The structure of a copper（Ⅱ） polymer, [Cu（IP）（TBZH）]2n 1 （TBZH = thiabendazole, IP = isophthalic acid）, has been determined by X-ray crystallography and characterized by elemental analysis, IR spectrum and thermogravimetric analysis. It crystallizes in the monoclinic system, space group P21/n with a = 11.76, b = 10.41, c = 14.08A^°, β = 104.80°, V= 1666.0（3）A^°^3, Z = 4, Mr= 428.90, Dc= 1.710 g/cm^3, F（000） = 868,μ = 1.468 mm^-1 and S = 1.001. The 2-D layered gridding architecture of 1 is constructed from isophthalic acid and binuclear copper atoms. Hydrogen bonds and aryl ring π-π stacking interactions in 1 contribute to a supramolecular structure.

Synthesis and Crystal Structure of a Manganese(Ⅱ) Complex with 2-(4′-Chlorine-benzoyl)-benzoic Acid and 1,10-Phenanthroline

A new metal-organic complex Mn2（cbba）4（phen）2 （Hcbba = 2-（4＇-chlorine-benzoyl）- benzoic acid, phen = 1,10-phenanthroline） 1 has been hydrotherrnally synthesized and structurally characterized by single-crystal X-ray diffraction, elemental analyses and IR spectroscopy. The compound crystallizes in orthorhombic, space group Pbcn with α = 12.154（5）, b = 18.166（7）, c = 31.197（13） A, V = 6887（5） A^3, C80H48Cl4Mn2N4O12, Mr= 1508.90, Dc = 1.455 g/cm^3, μ（MoKα） = 0.591 mm^-1, F（000） = 3080, Z = 4, the final R = 0.0408 and wR = 0.0873 for 4033 observed reflections （I 〉 2σ（I））. In the crystal structure, the manganese atom is six-coordinated with four carboxylate oxygen atoms from three different cbba ligands and two nitrogen atoms from phen ligands, showing a distorted octahedral geometry. Furthermore, it exhibits a 3D supramolecular network through π-π interactions.

Synthesis, Crystal Structure and Theoretical Calculation of a Novel 2D Network of Manganese(Ⅱ) Complex

A novel complex, [Mn（2-NCP）（H2BTC）（H2O）]n（1, 1,3,5-H3BTC = 1,3,5-benzenetricarboxylic acid, 2-HNCP = 2-（2-carboxyphenyl）-1 H-imidazo（4,5-f）-（1,10）phenanthroline）, was hydrothermally synthesized and structurally characterized by elemental analysis, IR, XRD and single-crystal X-ray diffraction. Structural analyses reveal that complex 1 exhibits a（6, 6）-connected topology network with a Schl?fli symbol of（63）. The adjacent 2 D layers are further stacked via strong hydrogen-bonding interactions, giving a 3 D supramolecular framework. In addition, the structure of complex 1 was calculated by the B3LYP/LANL2 DZ method by Gaussian program. The results from natural bond orbital（NBO） analysis shows obvious covalent interaction between the coordinated atoms and Mn（Ⅱ） ion.

Synthesis and Crystal Structure of a Three-dimensional Manganese(Ⅱ)Complex Constructed via Covalent and Hydrogen Bonds

The assembly of 1,4-benzenedicarboxylic acid (H2bdc), 4,4?bipyridine (4,4?bipy), trimethyltin chloride and MnBr24H2O in hydrothermal conditions gave rise to a hydrogen-bonded three-dimensional complex {[Mn(4,4?bipy)4H2O](bdc)}n which has been characterized by single- crystal X-ray diffraction. The complex crystallizes in the monoclinic system, space group P2/n with a = 7.0001(2), b = 11.5540(3), c = 11.4192(1) ? = 101.754(2)? V = 904.21(4) 3, Z = 2, C18H20MnN2O8, Mr = 447.30, Dc = 1.643 g/cm3, F(000) = 462 and m(MoK? = 0.783 mm-1. The final R and wR are 0.0499 and 0.1301, respectively for 1335 observed reflections with I ≥ 2(I). The Mn (Ⅱ) is six-coordinated in a distorted octahedral geometry. 4,4?Bipyridine in a m-bridge mode links [Mn(H2O)4]2+ into a linear cation chain. bdc acts as a counter anion and links the linear chains into a three-dimensional structure through hydrogen bonds.

Synthesis and Crystal Structure of a Bimetallic Cyanide-bridged Complex Derived from Manganese(Ⅲ) Schiff-base Complex and Pentacyanidonitrosylferrate(Ⅱ) Building Blocks

A new cyanide-bridged bimetallic assembly [Mn（3-meosalpn）（H2O）]2[Fe（CN）5NO]（1） was obtained by the reaction of [Fe（CN）5NO]2-with [Mn（3-meosalpn）]＋,and characterized by elemental analysis,IR and single-crystal X-ray structure analysis.The complex crystallizes in the monoclinic system,space group P21/c with a = 12.992（5）,b = 13.274（6）,c = 14.644（6） ,β = 115.198（4）o,V = 2285.2（16）3,Z = 2,C43H44FeMn2N10O11,Mr = 1042.61,Dc = 1.515 g/cm3,F（000） = 1072,μ = 0.928 mm-1,S = 1.052,the final R = 0.0347 and wR = 0.0957 for 17377 observed reflections（Ⅰ 〉 2σ（Ⅰ））.X-ray single-crystal diffraction analysis reveals that 1 has a trinuclear molecular structure,in which the two [Mn（3-meosalpn）（H2O）]＋ cations are linked by the central [Fe（CN）5NO]2-anion via two trans CN-groups.Furthermore,the two [Mn（3-meo-salpn）（H2O）]＋ cations and [Fe（CN）5NO]2-anion are connected into a one-dimensional zigzag chain through hydrogen bonding interactions.

Hydrothermal Synthesis, Crystal Structure and Magnetic Properties of a Novel Zero-dimensional Manganese(Ⅱ) Complex with 2,2′-Diphenic Acid and 1,10-Phenanthroline Ligands

A novel metal-organic coordination polymer [Mn3（2,2′-dipha）3（phen）6]n·3nH2O （2,2′-dipha = 2,2′-diphenic acid, phen = 1,10-phenanthroline） 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy, and magnetic susceptibility measurements. The crystal crystallizes in triclinic, space group P1 with a = 16.921（5）, b = 18.307（5）, c = 18.450（5）A , α = 113.369（5）, β = 108.529（5）, γ = 102.984（5）°, V = 4553（2）A^ 3, C114H72Mn3N12O14.25, Mr = 2002.66, Dc = 1.461 g/cm^3, μ（MoKα） = 0.488 mm^-1, the final F（000） = 2058, Z = 2, R = 0.0491 and wR = 0.0980 for 9087 observed reflections （I 〉 2σ（I））. In the crystal structure, the manganese atom is six-coordinated with two carboxylate oxygen atoms from different carboxylate groups of the same dipha and four nitrogen atoms from two different phen ligands, showing a slightly distorted octahedral geometry. Fur- thermore, it exhibits a zero-dimensional structure with dipha-Mn-phen- as building units. Variable- temperature magnetic measure shows an overall anti-ferromagnetic behavior for compound 1.

Hydrothermal Synthesis and Crystal Structure of a New Manganese(II) Complex with 2,4-Pyridine-dicarboxylic Acid and 2,2′-Bipyridine Ligands

A new metal-organic complex [Mn2（PDC）2（bipy）2（H2O）2] （H2PDC = 2,4-pyridine-dicarboxylic acid, bipy = 2,2′-bipyridine） 1 has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. The compound crystallizes in triclinic, space group P ^-1 with a = 7.376（3）, b = 9.990（4）, c = 11.950（5） A^°, α= 75.217（5）, β = 78.052（5）, γ = 70.655（5）°, V = 796.0（5）A^°3, C34HE6Mn2N6O10, Mr = 788.49, De = 1.645 g/cm^3,μ（MoKa） = 0.866 mm^-1, F（000） = 235, Z = 1, the final R = 0.0425 and wR = 0.0700 for 1971 observed reflections （I 〉 2σ（I））. In the crystal structure, the manganese atom is six-coordinated by two carboxylate oxygen atoms from two different PDC ligands, one aqua ligand, and three nitrogen atoms from 2,2′-bipy and PDC ligands, giving a distorted octahedral geometry. It exhibits a three-dimensional supramolecular network defined by O-H…O hydrogen-bonding interactions.

Synthesis and Crystal Structure of a Three-dimensional Manganese(II) Complex (tataH)_2[Mn(pydc)_2]·4H_2O (tata = 2,4,6-Triamino-1,3,5-triazine, pydcH_2 = Pyridine-2,6-dicarboxylic Acid)

A manganese（Ⅱ） complex （tataH）2[Mn（pydc）2]·4H2O （C20H28MBN14O12, Mr = 711.50, tata = 2,4,6-triamino-1,3,5-triazine, pydcH2 = pyridine-2,6-dicarboxylic acid） has been synthesized and its crystal structure was determined by single-crystal X-ray diffraction. The crystal belongs to the triclinic system, space group P1^-, with a = 9.9847（3）, b = 10.9813（3）, c = 15.2616（5）A, a = 101.5310（10）, β = 90.2610（10）, γ = 116.4600（ 10）% V = 1459.44（8）A^3, Z = 2, Dc = 1.619 g/cm^3,μ = 0.539 mm^-1, F（000） = 734, the final R = 0.0292 and wR = 0.0745. In the crystal the Mnn atom is six-coordinated by four carbonyl oxygen atoms and two pyridine nitrogen atoms from two tridentate pydc ligands to furnish a distorted octahedral geometry. The complex shows the A…D…D＇…A＇ H-bonded tetramer. The molecules are packed in a three-dimensional framework structure by the combination of O-H…O, N-H…O and N-H…N hydrogen bonds between （tataH）^＋, [Mn（pydc）2]^2- and crystal water.

Synthesis and Characterization of a Homochrial Manganese(Ⅱ)Complex Constructed from (1R,2R)-(-)-Diaminocyclohexane-N,N biscarboxyl-salicylidene)

A homochrial manganese（Ⅱ） complex derived from chiral salen ligand （1R,2R）-（-）diaminocyclohexane-N,N-biscarboxyl-salicylidene） （1） has been synthesized through solvothermal procedure and characterized by IR,elemental analysis,TGA,circular dichroism （CD）,powder and single-crystal X-ray crystallography.It crystallizes in monoclinic,space group C2 with a=32.987（7）,b=7.4662（15）,c=17.931（4）,β=97.82（3）°,V=4375.0（15） 3,Z=8,D c=1.544 g/cm 3,F（000）=2096,M r=508.36,μ=0.658 mm-1,the final GOOF=0.975,R=0.0676 and wR=0.2068 for 6357 observed reflections with I 2σ（Ⅰ）.The coordination polymer 1 possesses a 1D infinite zigzag chain architecture constructed by the dicarboxyl-functionalized metallosalen ligand （MnSalen）,and the polymeric chains are further assembled into a 2D supramolecular network structure via strong intermolecular hydrogen bonding interactions between the adjacent zigzag chains.

Crystal Structure and Characterization of a Binuclear Cd(Ⅱ) Quaternary Coordination Complex [Cd_2(phen)_2Q_2(BP)]_n(phen=1,10-Phenanthroline,BP = Biphenyl-4,4'-dicarboxylic acid,Q=8-Hydroxyquinoline Anion)

The structure of a binuclear cadmium（Ⅱ） quaternary complex, [Cd2（phen）2- Q2（BP）]n 1 （phen = 1,10-phenanthroline, BP = biphenyl-4,4′-dicarboxylic acid, Q = 8-hydroxy- quinoline-anion）, has been determined by X-ray crystallography and characterized by elemental analysis, IR spectrum and thermogravimetric analysis. It crystallizes in the monoclinic system, space group P21/n with a = 13.1906（18）, b = 10.9623（15）, c = 16.947（2）A, β = 111.3430（10）°, V = 2282.5（5）A^3, Z = 4, Mr = 556.85, Dc = 1.620 g/cm^3, F（000） = 1116,μ= 0.994 mm^-1 and S = 1.056. In the structure, 1D chains are connected via biphenyl-4,4′-dicarboxylic acid, 8-hydroxy quinoline anion and binuclear cadmium atoms into an infinite 1-D molecular chain architecture. Via aryl ring π-π stacking interactions a supramolecular structure is formed in 1.

Crystal Structure of Catena-poly-[2,2'-bisbenzimidazole Mn(Ⅱ)-μ-Benzene-1,3-dicarboxylato]

The title complex,[（BBI）Mn（BDC）]n 1（BBI = 2,2＇-bisbenzimidazole（C14H10N4）,BDC=benzene-1,3-dicarboxylate dianion（C8H10O4））,crystallizes in the monoclinic system,space group C2/c,with a=17.822（8）,b=16.181（7）,c=13.355（6）A,β=92.112（5）°,V=3848.67（304）A^3,Z=8,C22H14MnN4O4,Mr=453.31,Dc=1.565 g/cm^3,F（000）=1848,μ=0.725 mm^-1,S=1.000,the final R=0.0310 and wR=0.0589.1 contains hydrogen bonds and π-π stacking interactions between the neighboring aryl-ring of BBI＇s,which helps to form a three-dimensional crystal structure.

Hydrothermal Synthesis, Crystal Structure and Electrochemical Properties of Complex Mn_2(phen)_2(p-CBA)_4(H_2O)

One novel complex Mn2（phen）2（p-CBA）4（H2O） has been hydrothermally synthesized from p-chlorobenzoic acid （p-CBA）, 1,10-phenanthroline （phen） and anhydrous manganese（Ⅱ） sulfate and then characterized. Crystal data for this complex： monoclinic, space group C2/c, with a = 2.3416（3）, b = 1.5604（2）, c =1.5605（2） nm, β = 121.048（2）°, V = 4.8849（12） nm^3, Dc = 1.510 g/cm^3, Mr = 555.26, Z = 8, μ = 0.798 mm^-1, F（000） = 2256, GOOF = 1.032, the final R = 0.0393 and wR = 0.0816. The crystal structure shows that two neighboring manganese（Ⅱ） ions are linked together by two bridge-chelating p-chlorobenzoic groups and one bridging water molecule, forming a cage structure with the Mn–Mn bond distance of 0.3512 nm. Each manganese（Ⅱ ） ion is coordinated by two nitrogen atoms of one 1,10-phenanthroline molecule and four oxygen atoms from three p-chlorobenzoic acid anions and one water molecule, giving a distorted octahedral coordination geometry. The cyclic voltammetric behavior of the complex was also investigated.

Hydrothermal Syntheses and Crystal Structures of Two Complexes with 3,5-Dinitrosalicylate and 2,2′-Bipyridine Ligands

The two title complexes, [Cd{3,5-（NO2）2sal}（2,2′-bipy）]n 1 and [Mn{3,5- （NO2）2sal}（2,2′-bipy）]n 2 （3,5-（NO2）2sal = 3,5-dinitrosalicylate, 2,2＇-bipy = 2,2′-bipyridine）, were synthesized by the hydrothermal reaction and structurally characterized. Complex 1 crystallizes in triclinic, space group P1, a = 5.581（4）, b = 12.071（8）, c = 12.88（1）A, α= 92.10（3）,β= 96.73（3）, γ = 102.02（2）°, C17H10N407Cd, Mr = 494.69, V= 841（1）A3, Z = 2, Dc = 1.954 g/cm3, F（000） = 488, μ= 1.353 mm^-1, R = 0.0248 and wR = 0.0761. Complex 2 crystallizes in monoclinic with space group P21/c, a = 8.604（3）, b = 23.88（1）, c = 8.894（3） A, β = 102.45（1）°, C17H10N407Mn, Mr = 437.23, V= 1785（1） A3, Z=.4, Dc = 1.627 g/cm3, F（000） = 884, μ = 0.791 mm^-1, R = 0.0471 and wR = 0.1250. Complex 1 possesses an infinite 1D polymeric chain structure consisting of the repeated basic four-membered ring units （Cd2O2） and eight-membered ring units （CdOCO）2. Compound 2displays a linear 1D chain through Mn（Ⅱ） atoms and bridging carboxylate groups of 3,5-dinitrosalicylic acid ligands with the Mn…Mn separation of 4.472（2）A. The fluorescence properties and cyclic voltammetric behaviors of the complexes are also reported.

Synthesis and Structure of Bis(indene-1,2,3-trione 2-oximato)bis(aqua)Mn(Ⅱ): Mn(C_9H_4NO_3)_2(H_2O)_2

The title complex, bis(indene-1,2,3-trione 2-oximato)bis(aqua)Mn(Ⅱ), crystallizes in the monoclinic system, space group P21/c with a = 5.201(1), b = 16.547(3), c = 9.914(2) ? ?= 100.30(3), V = 839.4(3) 3, Dc = 1.738 g/cm3, F(000) = 446, C18H12N2O8Mn, Mr = 439.24, m(MoKa) = 0.842 mm-1, Z = 2, the final R = 0.0228 and wR = 0.0782 for 1762 observed reflections (I ≥ 2s(I)). The geometry around Mn(Ⅱ) is a distorted octahedral configuration with the basal plane consisting of two oximo-oxygen and two carbonyl-oxygen atoms from ligand indene-1,2,3-trione 2-oximato, while the axial coordination sites are occupied by two water- oxygen atoms. A plane network is formed by the intermolecular hydrogen bonds. The title complex is the first example of metal complex containing ligand indene-1,2,3-trione 2-oxime.

Hydrothermal Synthesis,Crystal Structure and Thermal Stability of a Novel Water Cluster [Mn(phen)_2·H_2O·Cl]·p-FBA·3H_2O

A novel water cluster [Mn（phen）2·H2O·Cl]·p-FBA·3H2O （p-FBA = p-fluorobenzoic acid and phen = 1,10-phenanthroline） was synthesized by the hydrothermal reaction of MnCl2 with p-FBA and phen at 150 ℃ and characterized by elemental analysis,IR spectra and TG. Its crystal structure was determined by X-ray single-crystal diffraction study. The crystal belongs to the triclinic system,space group P1,with a = 10.5768（1）,b = 11.5960（1）,c = 12.9916（2） ,α = 101.816（2）,β = 95.397（2）,γ = 103.052（2）o,V = 1502.8（3） 3,Z = 2,Dc = 1.463 g/cm3,R = 0.0399 and wR = 0.0997. The crystal structure shows that the manganese（Ⅱ ） ion is six-coordinated by four nitrogen atoms,one chloride ion and one oxygen atom forming a distorted octahedral coordination geometry. The structure includes three acyclically connected water molecules and one coordinated water molecule thus forming a （H2O）4 water cluster. This water pattern forms a cross-linked discrete ring. The steady （H2O）4 is further extended into a cage-like structure by the hydrogen-bonding interaction formed by dissociative aqua molecule and Cl-ligand. The dimer structure is further extended into a one-dimensional （1D） structure through C-H···O interaction. π···π Stacking interaction among adjacent phen aromatic rings further stabilizes the crystal structure.

Synthesis, characterization and crystal structures of manganese (Ⅱ) complexes containing nitronyl nitroxide and its reduced derivative

Two novel adducts of formula Mn(hfac)2( NITPhCl )2 (1) and [Mn(hfac)2(IMHPhCl)]2(NIT-PhCl)·0.5H2O (2), where hfac = hexafluoroacetylacetonate, NITPhCl = 2-(3-chlorophenyl)-4,4,5,5-tetram-ethylimidazolyl-1-oxyl-3-oxide, IMHPhCl = 2-(3-chlorophenyl)-4, 4, 5, 5-tetramethylimidazolyl-3-oxide, have been prepared by the reaction of Mn(hfac)2·2H2O with NITPhCl. Compound 1 is triclinic, space group P-1with a = 1.3003(3) nm, 6 = 1.3138(3) nm,c = 1.4931 (3) nm, α = 83.74(3)°, β = 77.77(3)°, γ = 60.59(3)°, V=2.171(1)nm3, Z = 2. Compound 2 is triclinic, space group P-1 with a = 1.2994(3) nm, b = 1.4841(3) nm, c = 2.1031 (4) nm, a = 92.30(3)° ,p = 98.68(3)°, γ = 97.89(3)°, V= 3.964(2)nm3, Z = 2. Each manganese atom is hexacoordinated in both compounds and compound 2 is organized inchains by hydrogen bonds between neighboring pairs of NITPhCl and IMHPhCl.

Comparison and Relation between Crystal Structures and Magnetic Properties of Two Manganese(Ⅱ)Coordination Polymers Based on(Triazol-1-yl)iso/terephthalic Acid

One new Mn(Ⅱ)coordination polymer,[Mn(Htia)_(2)(H_(2)O)_(2)]_(n)·2nH_(2)O(1,H_(2)tia=4-(1,2,4-triazol-1-yl)isophthalic acid)has been synthesized in mixed solvents under solvothermal conditions.Further characterizations including single-crystal XRD,elemental analysis,IR spectroscopy,thermogravimetric analysis and powder XRD were performed to verify the structure.Complex 1 displays a one-dimensional(1D)chain and is similar to a reported Mn(II)complex 2{[Mn(Htta)_(2)(H_(2)O)_(2)]·2H_(2)O}_(n).It crystallizes in triclinic P1 space group,with a=7.5557(3),b=7.5974(3),c=11.8448(4)Å,α=90.088(1)°,β=95.863(1)°,γ=113.668(1)°,V=618.81(4)Å^(3),Z=1,M_(r)=591.36 g/mol,D_(c)=1.587 mg/m^(3),μ=0.609 mm^(-1),F(000)=303,GOOF=1.062,the final R=0.0359and w R=0.0818 for 4272 observed reflections with I>2σ(I).Based on two similar structures,Hirshfeld surface analysis confirmed both structures are mainly stabilized by O···H/H···O and C···H/H···C hydrogen bonds.Further,weak ferromagnetic behaviors between adjacent Mn(II)ions in 1D chain are obtained.

一种新型双核锰(Ⅱ)配合物的合成、表征及磁性能研究

以Mn(CH3COO)2·4H2O和邻羟基苯甲醛缩4-氨基安替比林为原料,采用溶剂热法成功合成出一个新型双核锰(II)配合物([Mn(L-)(CH3COO)2]HL=邻羟基苯甲醛缩4-氨基安替比林),并通过X射线单晶衍射、红外光谱、元素分析、热重分析、X-粉末衍射、磁性分析和紫外分析等手段对该配合物进行表征及性质研究。结果表明双核锰配合物属于三斜晶系,空间群为P1,晶胞参数:a=0.81298(7)nm,b=0.95766(9)nm,c=1.32046(12)nm,α=100.9290(10)°,β=90.3510(10)°,γ=108.7220(10)°,V=0.95351(15)nm3,Z=1,Dc=1.464 Mg/m3,F(000)=434,μ=0.724 mm-1,R1=0.0346,wR2=0.1106[I>2σ(I)]。

二维Mn(Ⅱ)配位聚合物的水热合成、晶体结构和性质(英文)

通过水热方法合成了一个二维配位聚合物[Mn(NIPA)(L)]n(1)(L=二(5,6-二甲基苯并咪唑基)-1,3-丙烷、H2NIPA=5-硝基间苯二甲酸),并通过元素分析、IR、单晶X-射线衍射对其进行了结构表征。结果表明化合物1(MnC29H27N5O6)属三斜晶系:P1,a=1.029 41(10),b=1.057 10(10),c=1.324 91(12)nm,Z=2,V=1.395 5(2)nm3,Mr=596.50,Dc=1.420 g.cm-3,F(000)=618,μ=0.525 mm-1,S=1.027,R=0.041 7,wR=0.097 5。结构分析表明每个Mn髤与2个L配体上的2个氮原子、来自3个不同NIPA上的2个螯合氧原子以及2个单齿氧原子形成六配位模式。相邻的由2个羧基连接成的双核Mn髤簇通过成对的NIPA连接成一维双链结构,进而通过成对的L配体拓展成二维(4,4)网络。此外,还研究了该化合物的热稳定性和荧光性质。