Study on the Adhesive for the Production of High Strength Four Layer Composite Corrugated Board

In order to study of adhesive which is applicable to the production of high strength four layer composite corrugated board,the composite corrugated medium was respectively coated with cassava starch adhesive,environmental-friendly modified water glass binder,CP-88 starch adhesive,polyvinyl alcohol adhesive and polyvinyl acetate adhesive,then the edgewise crush resistance and flat crush resistance contrast experiment on produced corrugated board samples was tested.The experiment results demonstrated that the produced corrugated board with environmental-friendly modified water glass binder had high edgewise crush resistance,general flat crush resistance and more economic,so the environmental-friendly modified water glass binder can be used for the production of high strength four layer composite corrugated board.

Effect of Nanoparticles Reinforced Adhesive Layers on Microleakage of Tooth Restorations

Adhesive layer is an essential part of tooth colored restorations which play an important role in decreasing the microleakage between the tooth and restoration material after polymerization shrinkage. The purpose of this study was to evaluate the effect of deferent adhesive system of bonding agent on microleakage of nanocomposite resin in class II cavities. Two different types of adhesive systems: universal adhesive (ExciTE) and a newly developed adhesive (Nano-Bond) and one type of light-cured resin restorative material (nanocomposite resin) were used in this study. These adhesives were applied to prepared tooth cavities by either manufactures’ instructions or by an experimental method (single or double application). Nanocomposite resin was then placed and light-cured for 40 seconds. Teeth were subjected to 500 thermal cycles between 5&degC and 55&degC and were immersed in 3% methylene blue solution for 24 hours;microleakage was observed microscopically. The data were analyzed by a two-way ANOVA. For comparison between groups, Tukey’s post-hoc test was used. Nanoparticles reinforced adhesive system shows low microleakage in compare with universal adhesive system, and application of two adhesive layers also can decrease the microleakage. The ability of stress absorption by adhesive layer after polymerization shrinkage of restoration material will reduce the microleakage.

Influence of Phosphoric Acid Etching on the Bond Strength of a Universal Adhesive System to Caries-Affected Dentin

The purpose of this study was to evaluate the influence of acid etching on the bond strength of a universal adhesive system (Single Bond Universal, 3M) to caries-affected dentin. Forty permanent third molars were selected and carious lesions were induced by the microbiological method with?S. mutans?ATCC25175. Teeth were allocated randomly across four experimental designs (n?=?10): PA-I: phosphoric acid etching and application of the adhesive system, followed by immediate microtensile bond strength testing;PA-CC: phosphoric acid etching and application of the adhesive system, followed by microtensile bond strength testing after a 14-day cariogenic challenge;NPA-I: application of the adhesive system without acid etching, followed by immediate bond strength testing and NPA-CC: application of the adhesive system without acid etching followed by bond strength testing after 14-day cariogenic challenge. For microtensile bond strength testing,?a restoration with Charisma composite resin was made and each specimen was sectioned with a cross-sectional area of 1 mm2. Only adhesive and mixed fractures were considered for bond strength calculation. Results were evaluated by the Kruskal-Wallis and Friedman tests. The highest bond strengths were observed in the phosphoric acid etching groups (p??0.05). Cariogenic challenge did not affect bond strength (p?>?0.05). The predominant fracture type was adhesive. We conclude that phosphoric acid increased the bond strength of the Single Bond Universal system to caries-affected dentin, and that cariogenic challenge did not interfere with this bond strength.

The Adhesion and Formation Mechanism of Blast Furnace Gunning Layer

Basing on the study of the equilibrium relationship of interfacial tension among gunning particles, repaired surface and atmosphere, this test is in a position to draw a conclusion concerning the adhesion mechanism of the grinning refractory and the repaired surface, which illustrates the formation of the bottom gunning layer by moist fine gunning particles on the repaired surface. Also involved within the scope of discussion and probe are the patterns formed under this contacting effect and the formation mechanism of gunning layer. The analytic research regarding the behavior of gunning interface has ascribed the influence upon adhesion intensity to the quality of furnace gunning refractory, the state of the repaired surface and the gunning techniques.

Research on the Shrinking of 2-components Adhesive with Automatically Calculating Hologram

In this paper, used BSO(Bi12SiO（20）) crystal as a hologram recording material,TV-camera as a detector, and a holographic setup controlled by a computer, automatically calculating hologram of 3-interferograms method is theoretically and experimentally studied. This new holographic recording material and automatically calculating hologram make it possible to use real-time holography in an industry. As a practical example, the shrinking of 2-components adhesive in 4 h is measured.

Effect of Different Pretreatments to Post-space on Bonding Strength of Fiber Posts Luted with a Self-adhesive Resin Cement

The effects of different post-space pretreatments on the retentive force of fiber posts cemented with a self-adhesive resin cement were investigated. Twenty-eight single-canal premolars were obturated by Resilon using warm vertical compaction and treated with distilled water, 2.5% NaOCl, 17% EDTA and 2.5% NaOCI; or 17% EDTA, 2.5% NaOCI, and ultrasonic agitation （U/E/N treatment）. Subsequently, radicular dentin surfaces were observed under scanning electron microscopy （SEM）. RelyX Fiber Posts were cemented in the treated canals by using RelyX U100, and thin-slice push-out test and SEM observation of coronal and apical regions of the specimens were performed. Data were analyzed using two-way ANOVA and Tukey＇s HSD post- hoc tests, and the percentage of failure type was calculated. Ultrasonic/EDTA/NaOC1 irrigation showed the maximum effectiveness in removing the smear layer and debris on the dentin surface. The apical bond strength of the experimental groups was significantly higher than that of the control group （P〈 0.05）. Adhesive failure between cement and dentin was the most common mode of failure. No obvious RDIZ or resin tag was detected. Chemical irrigants facilitated the bonding of these fiber posts, and ultrasonic activation improved retention. Future studies should evaluate the effectiveness of irrigation on fiber post push-out strength in fatigue cycling condition.

Preparation and characterization of diamond film on Cu substrate using Cu-diamond composite interlayer

Large area diamond films were fabricated on copper substrates by a multi-step process comprised of electroplating Cu-diamond composite layer on Cu substrate, plating a Cu layer to fix the protruding diamond particles, and depositing continuous diamond film on composite interlayer by hot-filament chemical vapor deposition （HFCVD）. The interface characteristics, internal stress and adhesion strength were investigated by scanning electron microscopy, Raman analysis and indentation test. The results show that the continuous film without cracks is successfully obtained. The microstructure of the film is a mixture of large cubo-octahedron grains grown from homo-epitaxial growth and small grains with （111） apparent facets grown from lateral second nuclei. The improved adhesion between diamond film and substrate results from the deep anchoring of the diamond particles in the Cu matrix and the low residual stress in the film.

Corrosion behavior of high-strength spring steel for high-speed railway

The corrosion resistance and evolution of corrosion products in medium-carbon high-strength spring steels were investigated in a neutral salt spray(5 wt% Na Cl solution). A formation model of γ-Fe OOH and a transformation model describing the conversion of γ-Fe OOH to α-Fe OOH were constructed. The results indicated that, at the initial corrosion stage, the corrosion resistance was gradually improved with the addition of Cr; however, with the addition of alloying element V, the corrosion resistance decreased. These results were attributed mainly to the initial corrosion stage being closely related to the matrix microstructure parameters such as grain-boundary character and dislocation density. After the rust layer was formed at a later corrosion stage, the corrosion resistance was reinforced with the addition of Cr and V because Cr strongly influenced the composition, structure, and morphology of the corrosion products. The results presented herein show that Cr was conducive to the transformation of γ-Fe OOH into α-Fe OOH. Moreover, V and Cr exhibited obvious synergy and were enriched in the inner layer of the corrosion products.

Highly integrated sulfur cathodes with strong sulfur/high-strength binder interactions enabling durable high-loading lithium-sulfur batteries

The development of high-sulfur-loading Li-S batteries is a key prerequisite for their commercial applications.This requires to surmount the huge polarization,severe polysulfide shuttling and drastic volume change caused by electrode thickening.High-strength polar binders are ideal for constructing robust and long-life high-loading sulfur cathodes but show very weak interfacial interaction with non-polar sulfur materials.To address this issue,this work devises a highly integrated sulfur@polydopamine/highstrength binder composite cathodes,targeting long-lasting and high-sulfur-loading Li-S batteries.The super-adhesion polydopamine(PD)can form a uniform nano-coating over the graphene/sulfur(G-S)surface and provide strong affinity to the cross-linked polyacrylamide(c-PAM)binder,thus tightly integrating sulfur with the binder network and greatly boosting the overall mechanical strength/conductivity of the electrode.Moreover,the PD coating and c-PAM binder rich in polar groups can form two effective blockades against the effusion of soluble polysulfides.As such,the 4.5 mg cm−2 sulfur-loaded G-S@PD-c-PAM cathode achieves a capacity of 480 mAh g−1 after 300 cycles at 1 C,while maintaining a capacity of 396 mAh g−1 after 50 cycles at 0.2 C when the sulfur loading rises to 9.1 mg cm−2.This work provides a system-wide concept for constructing high-loading sulfur cathodes through integrated structural design.

Interfacial electrokinetic characteristics before and after bioleaching microorganism adhesion to pyrite

Zeta potentials of pyrite and Acidithiobacillus ferrooxidans cultured by sulfur in different levels of ionic strength and pH values were measured by Coulter Delsa 440SX zeta potential determinator. Meanwhile, the effects of bacterial adhesion and bacterial concentration on zeta potential of pyrite after adsorption were investigated. The results show that with the increase of ionic strength, zeta potentials of pyrite decrease in the range of pH 2.5?10.5 and the isoelectric point(IEP) of mineral shifts to the left. It is also found that the specific adsorption on pyrite of chloride ion can affect zeta potentials of pyrite sharply. As bacterial adsorption occurs, IEP of pyrite shifts towards that of Acidithiobacillus ferrooxidans; as bacterial concentration is increscent, this tendency is even larger and more obvious. Finally, a reasonable explanation for above-mentioned experimental phenomena was given by electrical double layer model and surface ionization model.

Silver-Doped Layers of Implants Prepared by Pulsed Laser Deposition

Physical and mechanical properties of silver-doped layers of titanium alloy Ti6Al4V and 316L steel prepared by pulsed laser deposition were studied. Metallic silver-doped coatings could be a new way for antibacterial protection in medicine. Thin films of silver and silver-doped materials were synthesized using KrF excimer laser deposition. The material was ablated from two targets, which composed either from titanium alloy with silver segments or from steel with silver segments. The concentration of silver ranged from 1.54 at.% to 4.32 at.% for steel and from 3.04 at.% to 13.05 at.% for titanium alloy. The layers properties such as silver content, structure, and adhesion were measured. Adhesion was stu- died using scratch test.

Adhesion Improvement of Zirconium Coating on Polyurethane Modified by Plasmas

In order to improve the adhesion of the middle frequency magnetic sputtered zirconium coating on a polyurethane film,an anode layer source was used to pretreat the polyurethane film with nitrogen and oxygen ions.SEMs and AFM roughness profiles of treated samples and the contrast groups were obtained.Besides,XPS survey spectrums and high resolution spectrums were also investigated.The adhesion test revealed that ion bombardment could improve the adhesion to the polyurethane coating substrate.A better etching result of oxygen ions versus nitrogen predicts a higher bonding strength of zirconium coating on polyurethane and,indeed,the highest bonding strengths are for oxygen ion bombardment upto 13.3 MPa.As demonstrated in X-ray photoelectron spectroscopy,the oxygen ion also helps to introduce more active groups,and,therefore,it achieves a high value of adhesion strength.

Improving wear resistance of magnesium alloy AZ91D by TiN-CrN multilayer coating

Applying a novel method of arc-glow plasma depositing, a 2μm-thick coating with 12 sub-layers of TiN and CrN was deposited alternately on the surface of magnesium alloy AZ91D to improve its wear resistance. The wear behavior was investigated by test of ball on disc sliding. The composition and microstructure of the coating were also analyzed by means of X-ray diffraction (XRD) and glow discharge spectrum (GDS), and the morphology of TiN-CrN film was surveyed through scanning electronic microscopy (SEM) and atom force microscopy (AFM).The adhesion strength between film and matrix was evaluated by ways of stick-peeling test. The surface micro-hardness of the coating is above HK0.011 433, and the specific wear ratio of specimens coated with TiN-CrN films tested decreases greatly compared to that of the bare metal.

钯薄膜光纤光栅氢气传感器的研究

在长距离管道输氢过程中,氢泄漏的精确本安监测是氢能安全输送的关键。基于光纤布拉格光栅(FBG)传感技术,采用磁控溅射方法溅射钯金属氢敏薄膜,实现了氢泄漏传感器的制备。在此基础上,首先开展光纤光栅腐蚀前、后光栅波长漂移对照实验,结果表明:腐蚀后的光纤光栅可以显著提高传感器的灵敏度;然后研究了氢浓度在0%~5%时,不同薄膜厚度对FBG氢气传感器波长漂移量的影响规律;最后开展了不同氢浓度下的FBG氢气传感器响应重复性实验及温度补偿实验,结果显示该传感器能够有效、准确地进行氢浓度测量,灵敏度达到12.20 pm/%,且重复性良好。

蓄盐沥青混合料与冰层粘结程度评价方法探究

为了能更精确地评价蓄盐沥青混合料与冰层的粘结程度,通过对拉拔头、冰层冻结方式、拉拔方式等方面进行改进,采用粘结强度和残冰率作为蓄盐沥青混合料与冰层粘结程度的评价指标,开发出一种基于马歇尔试件全断面的试验方法。试验结果表明,试件与冰层之间的粘结强度及残冰率随温度降低而增加,蓄盐沥青混合料在-10℃以内能降低试件与冰层的粘结强度30%以上,-7℃的粘结强度相比于普通沥青混合料减小约50%,-9℃以内残冰率减小比例均大于50%。冰层与试件粘结强度的测量准确度随残冰率的增大而降低,建议在-10℃内采用本试验方法。开发的评价试件与冰层粘结程度的试验方法区分度较高,试验的变异系数在10%以内,稳定性较好。

雅赛尔11.8 tex弹力包芯纱生产实践

为了提高雅赛尔纤维弹力纱纺纱质量,以纺雅赛尔11.8 tex弹力包芯纱为例,介绍雅赛尔、氨纶弹力丝的性能指标及工艺流程;详细分析纺纱各生产工序采取的技术措施、工艺配置及注意事项;通过对细纱、筒纱质量指标的测试,说明雅赛尔11.8 tex弹力包芯纱成纱指标良好、质量稳定。指出:提高雅赛尔纤维品种强力、减少其成纱毛羽、控制氨纶丝包覆质量是保证成纱质量的关键;生产过程中,要优选各工序工艺,明确控制要点及参数,合理配置相关器材和车间温湿度,加强各工序过程控制和设备维护保养。

C/SiC复合材料表面SiC过渡层的包埋法制备与性能

[目的]碳/碳化硅(C/SiC)复合材料是航空航天领域最有发展前景的高温热防护结构材料之一,但其表面由于制备过程中化学气相渗透而造成粗糙度低、与涂层间结合强度差的问题有待解决。[方法]以Si粉、C粉和少量Al_(2)O_(3)粉为原料,通过包埋法在C/SiC基体表面制备了SiC涂层。[结果]该涂层与基体之间具有较好的化学亲和性,热膨胀系数匹配度高,表面状态改善情况好。SiC涂层的表面粗糙度(Ra)相较于C/SiC基体实现了从1.732μm到5.531μm超2倍的提升,且涂层与基体结合良好,平均抗拉结合强度达到了4.946 MPa。[结论]该方法处理后的C/SiC复合材料满足了后续制备功能化涂层的要求。

汉麻蜡提高F-SiO_(2)超疏水涂层粘附稳定性的研究

由于纳米级超疏水涂层的粘附性较差,提出一种改善F-SiO_(2)超疏水涂层粘附性的方法,将汉麻蜡与F-SiO_(2)纳米粒子物理复合,在钢材表面形成汉麻蜡-纳米粒子供价网络,与不添加汉麻蜡的涂层相比,表现出更高的水接触角和更好的粘附性。汉麻蜡复合F-SiO_(2)纳米粒子具有制备工艺简单、原料易得的优势,同时还能提高汉麻的综合利用率。

防钛火隔热层抗开裂界面粗糙化设计制备研究

钛合金在航空发动机中应用广泛,但它们在遇到剧烈冲击、摩擦等极端情况时易发生钛火,继而引起整台发动机着火,造成严重后果。在钛合金表面涂覆阻燃涂层是目前解决钛火问题的主要方法之一。然而,阻燃涂层是由陶瓷隔热层与金属基可磨耗面层组成的多层复合结构,在服役过程中,陶瓷/金属异质界面常发生剥落失效。基于此,主要开展陶瓷隔热层表面粗糙化设计,提升涂层抗开裂能力。首先,为确定喷涂工艺对粉末熔化程度的影响规律,采用模拟与试验相结合的方法,研究了空心与实心两种YSZ粉末粒子在等离子束流内的加热加速过程,明确了调控粉末熔化状态的控制参数,试验沉积单个扁平粒子验证了模拟结果的合理性。其次,开展了陶瓷隔热层表面形貌调控研究。基于模拟结果,确定隔热层主体应采用高功率,以保证粉末充分熔化;表面粗化层采用较低功率以获得半熔化态氧化锆球壳,从而制备得到表面具有较大粗糙度、内部具有良好隔热防钛火功能的新型隔热层结构。涂层表面的粗糙化设计,有利于提高金属陶瓷的异质界面结合强度,支撑涂层的长寿命防护。