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Evolution of Annealing Twins and Recrystallization Texture in Thin-Walled Copper Tube During Heat Treatment 被引量:5
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作者 Song-Wei Wang Hong-Wu Song +2 位作者 Yan Chen Shi-Hong Zhang Hai-Hong Li 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2020年第12期1618-1626,共9页
Thin-walled copper tubes are usually produced by multi-pass float-plug drawing deformation.In general,the annealing treatment subsequently is necessary to release the stored energy and adjusts the microstructure.In th... Thin-walled copper tubes are usually produced by multi-pass float-plug drawing deformation.In general,the annealing treatment subsequently is necessary to release the stored energy and adjusts the microstructure.In this study,an investigation on the evolution of annealing twins as well as textures in the thin-walled(Φ6 mm×0.3 mm)copper tube underwent holding time-free heat treatment was reported.Electron backscattered diffraction analysis reveals that a large number ofΣ3 boundaries(600<111>twin relationship)are produced at the early stage of heat treatment,which is due to the lower boundary energy.With the recrystallization proceeding,the migration rate of grain boundaries decreases on account of the grain growth;meanwhile,the uniqueΣ9 boundaries(38.9°<110>relationship)are formed due to the interaction of theΣ3 boundaries.As a result,the number fractions ofΣ3 boundaries and high-angle grain boundaries decrease rapidly.During the grain growth stage,a strong recrystallization texture was formed due to the fact that the grains of Goss orientation have a growth advantage over the others.As a result,the initial copper texture was transferred into the Goss texture in domination. 展开更多
关键词 copper tube Annealing twin Heat treatment Electron backscattered diffraction(EBSD)analysis Recrystallization texture
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Deformation Calculation of Cross-section Based on Virtual Force in Thin-walled Tube Bending Process 被引量:5
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作者 LIU Jingyao TANG Chengtong NING Ruxin 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2009年第5期696-701,共6页
Cross-section deformation is one of important factors affecting the quality of tube formation, and the tube's capability of transporting liquid and gas will be reduced because of the cross-section ellipse deformation... Cross-section deformation is one of important factors affecting the quality of tube formation, and the tube's capability of transporting liquid and gas will be reduced because of the cross-section ellipse deformation due to the effect of shear load in plastic bending process. When the tube is bent, the extrados-wall bears the tension stress and the intrados-wall bears the compression stress, synchronously the cross-section is affected by the circumferential stress. According to the above, the distribution function and curve of tangential stress can be obtained according to force balance differential equations on circumferential direction and Trasca rule. Subsequently the real state and virtual state moment equations were established, a new method was presented adopting the virtual principle of deformation system to calculate the x-axis and y-axis displacement of arbitrary point on cross-section. So the major and minor axes of deformed cross-section can be calculated according to the displacements of each point, and the variety value of major and minor axes will be obtained further. Finally the theoretical calculating result is compared with NC tube rotary-bending experiment results to verify the rationality of theoretical analysis, and the cross-section deformation rule of thin-walled tube can be received. 展开更多
关键词 thin-walled tube stress analysis major and minor axes cross-section deformation virtual force
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Optimizing the Qusai-static Folding and Deploying of Thin-Walled Tube Flexure Hinges with Double Slots 被引量:6
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作者 YANG Hui DENG Zongquan +2 位作者 LIU Rongqiang WANG Yan GUO Hongwei 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2014年第2期279-286,共8页
The thin-walled tube flexure(TWTF) hinges have important potential application value in the deployment mechanisms of satellite and solar array, but the optimal design of the TWTF hinges haven't been completely solv... The thin-walled tube flexure(TWTF) hinges have important potential application value in the deployment mechanisms of satellite and solar array, but the optimal design of the TWTF hinges haven't been completely solved, which restricts their applications. An optimal design method for the qusai-static folding and deploying of TWTF hinges with double slots is presented based on the response surface theory. Firstly, the full factorial method is employed to design of the experiments. Then, the finite element models of the TWTF hinges with double slots are constructed to simulate the qusai-static folding and deploying non-linear analysis. What's more, the mathematical model of the TWTF flexure hinge quasi-static folding and deploying properties are derived by the response surface method. Considering of small mass and high stability, the peak moment of quasi-static folding and deploying as well as the lightless are set as the objectives to get the optimal performances. The relative errors of the objectives between the optimal design results and the FE analysis results are less than 7%, which demonstrates the precision of the surrogate models. Lastly, the parameter study shows that both the slots length and the slots width both have significant effects to the peak moment of quasi-static folding and deploying of TWTF hinges with double slots. However, the maximum Mises stress of quasi-static folding is more sensitive to the slots length than the slots width. The proposed research can be applied to optimize other thin-walled flexure hinges under quasi-static folding and deploying, which is of great importance to design of flexure hinges with high stability and low stress. 展开更多
关键词 design optimization quasi-static folding and deploying flexure hinges thin-walled tube response surface method numerical simulation
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Study on buffering performance of thin-walled metal tube with different angles 被引量:3
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作者 Qun Liu Wen-tao Wang Wen-feng Zhang 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2018年第6期702-708,共7页
High frequency shock load is often generated during pyrotechnic device working, which is detrimental to spacecraft structures and electric devices. Therefore, it is valuable to reduce the shock load in pyrotechnic dev... High frequency shock load is often generated during pyrotechnic device working, which is detrimental to spacecraft structures and electric devices. Therefore, it is valuable to reduce the shock load in pyrotechnic device design. Actually, there are several ways to decrease pyroshock loads, such as reduction of powder,installation of buffering structure, insulation of damageable devices, and so on. Considered assuring the function of pyrotechnic device and minimum of structure modification, shock absorbing structure is more propitious to be introduced in pyrotechnic device. In this paper, based on the method of thinwalled metal tube diameter-expanding, a thin-walled tube shock buffering structure was designed on a separate bolt. Built on the simplified structure of a separate bolt, the model of cone piston impacting thin-walled tube absorber was established, and the thin-walled tube shock absorbing characteristics and the relation between cone angles and absorber performance were analyzed. The results showed that the change of buffering force of thin-walled tube could be divided into four phases, and each phase was correspondent to the cone piston structure. In addition, as the cone angle increases, the max shock acceleration changes in the style of decrease-increase-decrease-increase, which is the result of coupled effects of cone piston max enter depth, buffering force and energy loss. In short, these results could establish the relationships between thin-walled tube absorbing performance and its structure, which is of significance to develop low-shock pyrotechnic device. 展开更多
关键词 Pyroshock Shock absorbing thin-walled METAL tube
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A Numerical-analytic Method for Quickly Predicting Springback of Numerical Control Bending of Thin-walled Tube 被引量:3
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作者 Mei ZHAN He YANG Liang HUANG 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2006年第5期713-720,共8页
Springback is one of important factors influencing the forming quality of numerical control (NC) bending of thin-walled tube. In this paper, a numerical-analytic method for springback angle prediction of the process... Springback is one of important factors influencing the forming quality of numerical control (NC) bending of thin-walled tube. In this paper, a numerical-analytic method for springback angle prediction of the process was put forward. The method is based on springback angle model derived using analytic method and simulation results from three-dimensional (3D) rigid-plastic finite element method (FEM). The method is validated through comparison with experimental results. The features of the method are as follows: (1) The method is high in efficiency because it combines advantages of rigid-plastic FEM and analytic method. (2) The method is satisfactory in accuracy, since the field variables used in the model is resulting from 3D rigid-plastic FEM solution, and the effects both of axial force and strain neutral axis shift have been included. (3) Research on multi-factor effects can be carried out using the method due to its advantage inheriting from rigid-plastic FEM. The method described here is also of general significance to other bending processes. 展开更多
关键词 thin-walled tube Numerical control bending SPRINGBACK Numerical-analytic method 3D rigid-plastic FEM
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Combined stress waves with phase transition in thin-walled tubes 被引量:3
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作者 宋卿争 唐志平 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2014年第3期285-296,共12页
The incremental constitutive relation and governing equations with combined stresses for phase transition wave propagation in a thin-walled tube are established based on the phase transition criterion considering both... The incremental constitutive relation and governing equations with combined stresses for phase transition wave propagation in a thin-walled tube are established based on the phase transition criterion considering both the hydrostatic pressure and the deviatoric stress. It is found that the centers of the initial and subsequent phase transition ellipses are shifted along the sigma-axis in the sigma tau-plane due to the tension-compression asymmetry induced by the hydrostatic pressure. The wave solution offers the 'fast' and 'slow' phase transition waves under combined longitudinal and torsional stresses in the phase transition region. The results show some new stress paths and wave structures in a thin-walled tube with phase transition, differing from those of conventional elastic-plastic materials. 展开更多
关键词 combined stress phase transition wave thin-walled tube shape memory alloy(SMA)
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A STUDY ON THE EFFECT OF RADIAL INERTIA ON THE ELASTO-PLASTIC COMBINED STRESS WAVE PROPAGATION IN THIN-WALLED TUBES 被引量:2
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作者 Li Yongchi Huang Chengyi Yuan Fuping Jin Yongmei 《Acta Mechanica Solida Sinica》 SCIE EI 2001年第1期58-66,共9页
An in-depth analysis of propagation characteristics ofelasto-plastic combined stress waves in circular thin-walled tubeshas been made. In obtaining the simple-wave solution, however, mostresearches have ignored the in... An in-depth analysis of propagation characteristics ofelasto-plastic combined stress waves in circular thin-walled tubeshas been made. In obtaining the simple-wave solution, however, mostresearches have ignored the influence of the circumferential stressrelated to the radial inertial ef- fect in the tubes. In this paperthe incremental elasto-plastic constitutive relations which areconve- nient for dynamic numerical analysis are adopted, and thefinite-difference method is used to study the evolution adpropagation of elasto-plastic combined stress waves in a thin-walledtube with the radial inertial effect of the tube considered. Thecalculation results are compared with those obtained when the radialinertial effect is not considered. The calculation results show thatthe radial inertial effect of a tube has a fairly great influence onthe propagation of elasto-plastic combined stress waves. 展开更多
关键词 circular thin-walled tube elasto-plastic combined stress waves radialinertial effect
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Torsional Behavior Design of UHPC Box Beams Based on Thin-Walled Tube Theory 被引量:6
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作者 Imjong Kwahk Changbin Joh Jung Woo Lee 《Engineering(科研)》 2015年第3期101-114,共14页
This study proposed a prediction formula for the torsional strength enabling to reflect the tensile strength of ultra high performance concrete (UHPC) beams based upon the thin-walled tube theory. The remarkable ducti... This study proposed a prediction formula for the torsional strength enabling to reflect the tensile strength of ultra high performance concrete (UHPC) beams based upon the thin-walled tube theory. The remarkable ductile behavior of UHPC can also be attributed to the steel fiber reinforcement. This feature must be considered to provide rational explanation of the torsional behavior of UHPC structures. In this study, the proposed torsional design adopts a modified thin-walled tube theory so as to consider the tensile behavior of UHPC. And torsion test was conducted on thin-walled UHPC box beams to validate the proposed formula through comparison of the predicted torsional strength with the experimental results. The comparison of the predicted values of the cracking torque and torsional moment resistance with those observed in the torsional test of UHPC verified the validity of the design method. The contribution of the steel fibers to the torsional strength and cracking load was larger than that of the stirrups, but the stirrups appeared to contribute additionally to the torsional ductility. Accordingly, it is recommended that design should exploit effectively the contribution of the steel fiber rather than arrange a larger number of stirrups in UHPC structures subjected to torsion. 展开更多
关键词 TORSION Behavior Ultra High Performance Concrete (UHPC) thin-walled tube Torsional Strength DIAGONAL CRACK
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Viscous Inner and Outer Pressure Forming Method of Thin-walled Tube and Its Application 被引量:3
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作者 高铁军 LIU Yang WANG Zhongjin 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2015年第2期404-407,共4页
Aiming at overcoming the difficulties in integral forming of thin-walled tubes with complex shapes, a novel forming method by inner and outer pressure through viscous was proposed. In this method, by dividing large de... Aiming at overcoming the difficulties in integral forming of thin-walled tubes with complex shapes, a novel forming method by inner and outer pressure through viscous was proposed. In this method, by dividing large deformation of the part into inner and outer pressure forming deformations, the limit deformation of tube part can be increased by several times. Meanwhile, the principle of viscous inner and outer pressure forming was provided, and key problems during the forming process such as reduction of the wall-thickness and instability wrinkling were analyzed. Thereby, the complex curved surface super-alloy GH3044 thin-walled tube with varying diameter ratio of 1.35(the ratio between the maximum and minimum diameters of the part) can be integrally formed by this method. The experimental surface of the formed part is superior in quality and the wall-thickness distribution is uniform. The results show that the viscous inner and outer pressure forming can provide a new approach for integral forming of thin-walled tubes with complex shapes. 展开更多
关键词 thin-walled tube inner and outer pressure forming viscous medium integral forming
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Novel approach for analysis of deformation behavior of thin-walled tube in free hydro-bulging process
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作者 杨连发 郭成 《中国有色金属学会会刊:英文版》 CSCD 2005年第S3期299-304,共6页
Based on the assumption that profile of thin walled tube in free hydro-bulging process is a quadratic curve and any point on the profile moves vertically to the profile, mathematical models were deduced for analyzing ... Based on the assumption that profile of thin walled tube in free hydro-bulging process is a quadratic curve and any point on the profile moves vertically to the profile, mathematical models were deduced for analyzing the deformation behavior. The critical pressure and the maximum bulge coefficient(height) at bursting can be determined based on the models, in which a shape factor a is introduced to tightly communicate the material property and geometric parameters to plastic deformation. Free hydro-bulging experiments of stainless steel and low carbon steel tubes were conducted to validate the models, and the experimental data indicate that the theoretical predictions are reliable and accurate. The results display that the profile, dependent on the material and geometric parameters, can be hyperbola, parabola, arc and ellipse or alternative among them; moreover, the forming pressure and forming limit are both closely connected with material and geometric parameters. 展开更多
关键词 hydro-bulging thin-walled tube deformation forming pressure formability
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ENERGY ABSORPTION CONTROL CHARACTERISTICS OF AL THIN-WALLED TUBES UNDER IMPACT LOAD
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作者 Kil-Stmg Lee Yong-Jun Yang +1 位作者 Sun-Kyu Kim In-Young Yang 《Acta Mechanica Solida Sinica》 SCIE EI 2008年第4期383-388,共6页
An experimental investigation was carried out to study the energy absorption characteristics of thin-walled square tubes subjected to dynamic crushing by impact loading to develop the optimum structural members. Here,... An experimental investigation was carried out to study the energy absorption characteristics of thin-walled square tubes subjected to dynamic crushing by impact loading to develop the optimum structural members. Here, the controller is introduced to improve and control the absorbed energy of thin-walled square tubes in this paper. When the controller were used, the experimental results of crushing of square tubes controlled by the controller's elements showed a good candidate for a controllable energy absorption capability in impact crushing. 展开更多
关键词 impact load Al thin-walled tubes energy absorption controller
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Fin formation model during pre-roll ploughing of copper 3D outside fin tube 被引量:15
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作者 汤勇 夏伟 +2 位作者 曾志新 刘树道 叶帮彦 《中国有色金属学会会刊:英文版》 CSCD 2001年第5期712-716,共5页
The mechanism of pre roll ploughing for 3D fins on the outside surface of copper tube was studied systematically, and especially the process and conditions of 3D fin formation were analyzed. The right mathematical mod... The mechanism of pre roll ploughing for 3D fins on the outside surface of copper tube was studied systematically, and especially the process and conditions of 3D fin formation were analyzed. The right mathematical model was also established. Based on the volume of fin ploughed out is equal to the volume of the metal extruded up by the extruding face of the tool, the relations between fin height, pre roll ploughing feed and pre roll ploughing depth have been achieved. With the increase of pre roll ploughing depth which must be equal to groove depth, the fin height gradually becomes larger. There are different critical feeds with the various depths of pre roll ploughing. The pre roll ploughing feed is the critical one, the height of fin is largest. And when the feed is above the critical one, the fin height will reduce with the increase of feed. The theoretical analysis basically accords with experimental results. 展开更多
关键词 pre roll ploughing copper 3D outside fin tube heat transfer
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Macrostructure and properties of thin walled copper tubes prepared by the downward continuous unidirectional solidification method 被引量:2
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作者 Xi Shen Hong Zhang +3 位作者 Zi-dong Wang Hua-fen Lou Yi-ming Jia Ping-xia Hu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2010年第1期63-68,共6页
The macrostructure and properties of the thin walled copper tube prepared by the downward continuous unidirectional solidification (DCUS) method were studied. The result shows that the macrostructure is closely rela... The macrostructure and properties of the thin walled copper tube prepared by the downward continuous unidirectional solidification (DCUS) method were studied. The result shows that the macrostructure is closely related to the solid-liquid interface profile, which is influenced by the distance between the cooling water location and the solidification front. The mechanical properties of the thin walled copper tube prepared by the DCUS method are near those of the normal cast copper, and it has good relative density, electrical conductivity, and elongation, which are not greatly affected by casting speed. The thin walled copper tube prepared by the DCUS method also has good processing properties that can be taken to further drawing procedures directly without an intermediate process, and obtains good mechanical properties with the total processing rate of 89.8%. 展开更多
关键词 unidirectional solidification copper tube short process MACROSTRUCTURE mechanical properties
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Microstructure and properties of TP2 copper tube with La microalloying by horizontal continuous casting 被引量:2
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作者 Jin-hu Wu Shi-hong Zhang +4 位作者 Yan Chen Hai-hong Li Hong-wu Song Ming Cheng Jin-song Liu 《China Foundry》 SCIE 2018年第1期31-36,共6页
The TP2 copper tube was prepared with La microalloying by horizontal continuous casting(HCC). The absorptivity of La and its effects on microstructure, tensile and corrosion properties of HCC TP2 copper tube were stud... The TP2 copper tube was prepared with La microalloying by horizontal continuous casting(HCC). The absorptivity of La and its effects on microstructure, tensile and corrosion properties of HCC TP2 copper tube were studied by means of the inductively coupled plasma optical emission spectrometer(ICP-OES), optical microscope(OM), scanning electron microscope(SEM) and potentiodynamic polarization measurements. The results show that the absorptivity of La in the HCC TP2 copper tube is about 15% under antivacuum conditions due to the good chemical activities of La. The impurity elements in copper tube such as O, S, Pb and Si can be significantly reduced, and the average columnar dendrite spacing of the copper tube can also be reduced from 2.21 mm to 0.93 mm by adding La. The ultimate tensile strength and the elongation with and without La addition are almost unchanged. However, the annual corrosion rate of the HCC TP2 copper tube is reduced from 10.18 mm·a^(-1) to 9.37 mm·a^(-1) by the purification effect of trace La. 展开更多
关键词 rare earth microstructure mechanical properties corrosion resistance HCC TP2 copper tube
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AXIAL LOADS ACTING ON MANDREL IN COPPER RIFLED TUBE DRAWING PROCESS 被引量:1
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作者 Peng Dashu Yang Bin +1 位作者 Wang Feiyong Yang Linbin 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 1996年第1期54-56,共3页
Stresses and axial loads acting on the mandrel in the copper rifled tube drawing process were analysed,and factors affecting on the axial loads on mandrel were discussed.Results show that the depth of the mandrel drag... Stresses and axial loads acting on the mandrel in the copper rifled tube drawing process were analysed,and factors affecting on the axial loads on mandrel were discussed.Results show that the depth of the mandrel dragged into sizing zone and lubrication have major influence on drawing loads and fin shapes. 展开更多
关键词 DRAWING copper rifled tube LUBRICATION FIN
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A Study of Water Treatment Chemical Effects on Type I” Pitting Corrosion of Copper Tubes 被引量:1
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作者 Takashi Iyasu Motoki Kuratani +3 位作者 Itaru Ikeda Noriyuki Tanaka Yutaka Yamada Osamu Sakurada 《Materials Sciences and Applications》 2020年第7期494-504,共11页
It is known that one of the causes of pitting corrosion of copper tubes is residual carbon on the inner surface. It was confirmed that type I” pitting corrosion of the copper tube is suppressed by keeping the residua... It is known that one of the causes of pitting corrosion of copper tubes is residual carbon on the inner surface. It was confirmed that type I” pitting corrosion of the copper tube is suppressed by keeping the residual carbon amount at 2 mg/m<sup>2</sup> or less, which is lower than that of the type I’ pitting corrosion, or by removing the fine particles that are the corrosion product of galvanized steel pipes. The developed water treatment chemical was evaluated using three types of copper tubes with residual carbon amounts of 0 mg/m<sup>2</sup>, 0.5 mg/m<sup>2</sup>, and 6.1 mg/m<sup>2</sup>. The evaluation was conducted for three months in an open-circulation cooling water system and compared with the current water treatment chemical. Under the current water treatment chemical conditions, only the copper tube with a residual carbon amount of 6.1 mg/m<sup>2</sup> showed a significant increase in the natural corrosion potential after two weeks, and pitting corrosion occurred. No pitting corrosion and no increase in the natural corrosion potential were observed in any of the copper tubes that were treated with the developed water treatment chemical. In addition, the polarization curve was measured using the cooling water from this field test, and the anodic polarization of two cooling waters was compared. For copper tubes with a large amount of residual carbon, the current density near 0 mV vs. Ag/AgCl electrode (SSE) increased when the developed water treatment chemical was added. 展开更多
关键词 copper tube Pitting Corrosion Residual Carbon Cooling Water System Water Treatment
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Compound forming technology of outside 3D integral fin of copper tubes 被引量:3
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作者 向建化 汤勇 +3 位作者 叶邦彦 周伟 燕辉 胡志华 《中国有色金属学会会刊:英文版》 EI CSCD 2009年第2期335-340,共6页
Using rolling-ploughing-extrusion compound processing methods,a 3D integral-fin structure on outside surface of red copper tube with diameter of 16.0 mm and wall thickness of 1.5 mm was obtained. When both rolling dep... Using rolling-ploughing-extrusion compound processing methods,a 3D integral-fin structure on outside surface of red copper tube with diameter of 16.0 mm and wall thickness of 1.5 mm was obtained. When both rolling depth and ploughing-extrusion(P-E) depth were 0.2 mm,rotating speed was 50 r/min,feed speed was 0.16 mm/r,3D fin structures with height of 0.25 mm were gotten. Two different fin structures were obtained in grooves formed with rolling-ploughing-extrusion compound forming technology and observed by scanning electron microscope(SEM). One is the compound structure with V-shaped groove and U-shaped groove,and the other is the single structure with V-shaped grooves. Two kinds of groove structures obtained by rolling processing and ploughing extrusion processing are restricted together by groove interval and rolling depth,and pitch and P-E depth,respectively. Based on the analysis of interaction of rolling and P-E processing,it is found from the result that the outside 3D integral-fin can be achieved by rolling-ploughing-extrusion compound processing when single V-shaped groove structures are formed by both rolling and P-E processing. 展开更多
关键词 整体翅片 挤出复合 成形技术 三维 铜管 扫描电子显微镜 复合结构 挤压工艺
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Localized Corrosion in Copper Tubes by Volatile Organic Substance
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作者 Takenori Notoya(Laboratory of Corrosion Engineering, Graduate School of Engineering, Hokkaido University, Sapporo, Japan) 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 1999年第2期129-132,共4页
An unusual form of localized corrsion in copper tubes was detected early in service and in leakage tests after manufacturing.The morphology of this corrosion is similar to that of an ant's nest when viewed in cros... An unusual form of localized corrsion in copper tubes was detected early in service and in leakage tests after manufacturing.The morphology of this corrosion is similar to that of an ant's nest when viewed in cross section. The corrosion mechanisms, cases ofant's nest corrosion, and preventive measures are presented. 展开更多
关键词 copper tubes localized corrosion volatile organic substance heat-transfer units
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Simple Measurement of Carbon Films on Copper Tubes and Their Effects on Corrosion
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作者 Takashi Iyasu Motoki Kuratani +3 位作者 Itaru Ikeda Noriyuki Tanaka Yutaka Yamada Osamu Sakurada 《Open Journal of Composite Materials》 2021年第1期12-22,共11页
It has been reported that pitting corrosion in copper tubes occurs due to the effect of a carbon film produced by the influence of undergoing an oil and heat treatment. As a quantitative method for determining the res... It has been reported that pitting corrosion in copper tubes occurs due to the effect of a carbon film produced by the influence of undergoing an oil and heat treatment. As a quantitative method for determining the residual carbon amount, it has been reported that the inner surface of a copper tube can be dissolved with a mixed acid to collect and analyze the adhering carbon;however, this method is dangerous and difficult. Therefore, two methods were examined as a simple quantitative method for obtaining the residual carbon amount using copper tubes with known residual carbon amounts. One method utilizes X-ray photoelectron spectroscopy (XPS), and the other method utilizes the potential difference between the carbon film-adhered surface and carbon film-removed surface. In regard to XPS measurement, a linear correlation was found between the spectral intensity of C and the residual carbon amount;therefore, XPS measurements were considered to be effective as a simple measurement method for the carbon film on the inner surface of a copper tube. In the evaluation method by measuring the corrosion potential, a correlation was observed between the potential difference ΔE and the residual carbon amount of the inner surface of the tube and the outer surface of the polished tube. It is considered possible to estimate the residual carbon amount from the prepared calibration curve. Through these studies, it is suggested that the carbon film was non-uniformly present on the surface of the copper tube. Therefore, the galvanic current was measured, and the effect of a non-uniform carbon film on corrosion behavior was investigated. As a result, in the measurement of galvanic current, the current flowed from the copper tube with a large amount of residual carbon (cathode) to the copper tube with a small amount of residual carbon (anode). In addition, the higher the area ratio of the carbon film was, the larger the galvanic current tended to be. 展开更多
关键词 copper tube Residual Carbon Pitting Corrosion Cooling Water System Re-frigerator XPS
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Ammonia corrosion analysis of copper tubes and experimental research on non-copper improvement for heat exchanger in power plant
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作者 ZENG Zhou-hua LONG Xin-feng LIANG Ping 《Journal of Chemistry and Chemical Engineering》 2009年第12期30-36,共7页
关键词 燃煤电厂 实验测试 换热器 氨腐蚀 铜管 腐蚀分析 螺旋槽管 传热系数
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