Modeling the viscoelasto-plastic behavior of waxy crude

Waxy crude oil exhibits complex rheological behavior below the pour point temperature, such as viscoelasticity, yield stress, and thixotropy, owing to the formation of a three-dimensional spongelike interlock network structure. This viscoelasto-thixotropic behavior is an important rheologieal behavior of waxy crude oils, determining the flow recovery and safe restart of crude oil pipelines. Up to now, the thixotropic models for waxy crude have been all viscoplastic models, without considering the viscoelastic part before the yield point. In this work, based on analyzing the variation of the elastic stress and viscous stress in the Mujumbar model, a new viscoelasto-plastic model is proposed, whose shear stress is separated into an elastic component and a viscous component. The elastic stress is the product of the shear modulus and elastic strain; the shear modulus is proportional to the structural parameter. For the elastic strain, we followed the line of Zhu and his coauthors and assumed that it may be expressed by an algebraic equation. The model is validated by stepwise shear rate tests and hysteresis loop tests on Daqing and Zhongyuan waxy crude. The results show that the model＇s fitting and predictive capability is satisfactory.

Deformation mechanism and forming properties of 6061Al alloys during compression in semi-solid state

The 6061 semi-solid aluminium alloy feedstocks prepared by near-liquidus casting were compressed in semi-solid state by means of Gleeble-3500 thermal-mechanical simulator.The relationship between the true stress and the true strain at different temperatures and strain rates was studied with the deformation degree of 70%.The microstructures during the deformation process were characterized.The deformation mechanism and thixo-forming properties of the semi-solid alloys were analyzed.The results show that the homogeneous and non-dendrite microstructures of semi-solid 6061Al alloy manufactured by near-liquidus casting technology could be transformed into semi-solid state with the microstructure suitable for thixo-forming which are composed of near-spherical grains and liquid phase with eutectic composition through reheating process.The deformation temperature and strain rate affect the peak stress significantly rather than steady flow stress.The resistance to deformation in semi-solid state decreases with the increase of the deformation temperature and decrease of the strain rate.At steady thixotropic deformation stage, the thixotropic property is uniform, and the main deformation mechanism is the rotating or sliding between the solid particles and the plastic deformation of the solid particles.

Effect of Holding Time on Thixotropic Fluidity of Semi-solid AZ91D Magnesium Alloy

To investigate the thixotropic fluidities, microstructures and mechanical properties of semi-solid AZ91D magnesium alloy during reheating, a self-made die set with channels of different sizes were used. The results show that critical forming forces and maximal forming forces could be obtained and related to the holding times in the semi-solid forming process. In the holding time of 0-2700 s, with increasing the holding time, maximal forming force decreased sharply and critical forming force decreased slowly. In the whole thixotropic flowing process, the filling-in was steady and the surface fineness was good. The forming force increased when the slurry changed the flowing direction or flowed from the big-diameter chamber to the small-diameter one. The tensile strength and elongation to failure of the sample after holding time for 2700 s, compared to as-cast sample, are increased by approximately 42.7% and 180%, respectively, and the fractured surfaces presented dimple-like pattern.

Study on the thixotropy and structural recovery characteristics of waxy crude oil emulsion

Waxy crude oil emulsion has thixotropic properties at the temperature near gel point,which is a macromechanical characterization of the structure failure and recovery of waxy crude oil emulsion.In this paper,the thixotropic behaviors of waxy crude oil emulsion near gel point were studied using hysteresis loop formed by stress linear increase and decrease,as well as the structural recovery characteristics.The influence of the loading conditions and water content on the thixotropy of waxy crude oil emulsion were analyzed with hysteresis loop area.The concept of"structural recovery"was introduced to study the degree of structural recovery after different stewing,and influencing factors were taken into account.Results have shown that for waxy crude oil emulsion,the failure to fully restore of the structure after lysis is the cause of the formation of hysteresis loop,and the loading conditions will not affect the strength of thixotropy and the degree of structural recovery.Additionally,the dispersed phase droplets weaken the thixotropy and structure recovery characteristics of waxy crude oil emulsion,and the greater the water content,the weaker the thixotropy.The findings can help to better understand the safe and economic operation of waxy crude oil-water pipeline transportation.

Lathe process of AZ91D magnesium alloy chips used in semi-solid thixomolding

Based on the mechanism of chip breaking and the principle of semi-solid thixomolding, the lathe process of AZ91D magnesium alloys chips used in semi-solid thixotropic injection molding process was studied. With three kinds of turning tools, such as 31303C5, 31003C and 31303C, different chips were gotten. And by one tool with different lathe parameters, different chips were gotten. The results show that, under the needed condition of the thixotropic injection molding machine, the ideal chips are gotten and the size of magnesium alloy chips must be about 35mm, and the turning tool is chosen, whose chip breaker groove is narrower and the depth of cutting is more than 3mm as well as the amount of feed is larger than 0.3mm. The deformation occurs on the microstructure of the chips, and the residual stress is important to the later microstructure of semi-solid state in injection molding.

Optimal Homotopy Analysis of MHD Natural Convection Flow of Thixotropic Fluid under Subjection of Thermal Stratification: Boundary Layer Analysis

In this article, the model of a non-Newtonian fluid (Thixotropic) flow past a vertical surface in the presence of exponential space and temperature dependent heat source in a thermally stratified medium is studied. It is assumed that free convection is induced by buoyancy and exponentially decaying internal heat source across the space. The dynamic viscosity is taken to be constant and thermal conductivity of this particular fluid model is assumed to vary linearly with temperature. Thermal stratification has been properly incorporated into the governing equation so that its effect can be revealed and properly reported. The governing partial differential equations describing the model are transformed and parameterized to a system of non-linear ordinary differential equation using similarity transformations. Approximate analytic solutions were obtained by adopting Optimal Homotopy Analysis Method (OHAM). The results show that for both cases of non-Newtonian parameters (Thixotropic) (K1=K2=0?& K1=K2=1.0), increasing stratification parameters, relate to decreasing in the heat energy entering into the fluid region and thus reducing the temperature of the Thixotropic fluid as it flows.

Maintained Exposure to Spring Water but Not Double Distilled Water in Darkness and Thixotropic Conditions to Weak (~1 µT) Temporally Patterned Magnetic Fields Shift Photon Spectroscopic Wavelengths: Effects of Different Shielding Materials

Spring water but not double-distilled water was exposed, in darkness, to a temporally patterned weak magnetic field that has been shown to affect planarian behavior and slow the rate of cancer cell proliferation. Exposure to the magnetic field caused a reliable shift in the peak (longer) wave-length of ~10 nm for fluorescence emissions and a ~20% increase (~100 counts) in fluorescence intensity. Spectral analyses verified a shift of 5 and 10 nm, equivalent to ~1.5 × 10-20 J “periodicity” across the measured wavelengths, which could reflect a change in the an intrinsic energy as predicted by Del Giudice and Preparata and could correspond to two lengths of O-H bonds. Wrapping the water sample containers during exposure with copper foil, aluminum foil, or plastic altered these fluorescent profiles. The most conspicuous effect was the elimination of a ~280 nm peak in the UV-VIS emission spectra only for samples wrapped with copper foil but not aluminum or plastic. These results suggest that weak magnetic fields produce alterations in the water-ionic complexes sufficient to be reliably measured by spectrophotometry. Because the effect was most pronounced when the spring water was exposed in darkness and was not disturbed the role of thixotropic phenomena and Del Giudice entrapment of magnetic fields within coherent domains of Pollack virtual exclusion zones (EZ) may have set the conditions for subsequent release of the energy as photons.

Rheological Properties of Cement-Based Grouts Determined by Different Techniques

The rheological properties of cement-based grouts containing talc or palygorskite were investigated for optimizing fluidity and quick strengthening at injection. The fluidity controls the ability of grout to penetrate fractures and can be determined by pipe flow tests, Marsh funnel tests, mini-slump cone tests and rheometer tests. The grouts were 1) Talc for fluidity and strength by reacting with cement, 2) Palygorskite (attapulgite) for early gelation by being thixotropic, and 3) Powdered quartz for chemical integrity. The freshly prepared grouts behaved as Bingham fluids with viscosities from 0.151 to 0.464 Pas and yield stresses 5.2 Pa to 36.7 Pa. Statistical analysis of the flow test data converted Marsh flow time into viscosity. The pipe flow tests gave 26.5% higher values than the viscometer for grout with Portland cement and talc, and about 13.7% lower than the viscometer data for the grout with low-pH cement and talc. The big Marsh funnel gave values differing by 5.2% - 5.3% from those of the viscometer for grout with talc and Portland, and Merit 5000 cements. For grout with palygorskite the viscosity was at least twice that of the other grouts. Grout fluidity was positively affected by talc and negatively by palygorskite and early cement hydration.

Study on Thixotropic Properties of Waxy Crude Oil Based on Hysteresis Loop Area

Thixotropic properties are one of the low temperature rheology behaviors of gelled waxy crudes. In order to study the thixotropic behavior of gelled waxy crudes oil under cyclic loading of linear increasing and decreasing of shear rate, three different types of waxy crude oil were studied ex-perimentally by using MARSIII rheometer. It is found that hysteresis loop area could represent strength of thixotropic properties under that loading. With increasing of the rate of share rate sweep, the area of second hysteresis loop is much smaller than first one and began a slow decline from the third hysteresis loop. Areas of each hysteresis loops were decreased with increasing temperature, but it was different in decline rate—the lower the temperature, the greater the rate of decline. The maximum rate of decrease is the first hysteresis loop with exponential decline, and remaining hysteresis hoops approximately decrease linearly. In addition, based on the experi-mental results an empirical correlation is developed to describe the relationship of hysteresis loop area and rate of share rate sweep.

Upper bound analysis of thixotropic extrusion processes of semi-solid magnesium alloys

The methodology was used to conduct the upper bound analysis of thixotropic extrusion process of semi-solid metal. The calculated formulas of deformed power were derived. The relationship among relative stress, frictional factor and die semi-angle were obtained. The relative stress increases with increasing frictional factor, whose value increases with increasing area reduction ratio of a certain die semi-angle. The relative stress firstly decreases and then increases with increasing die semi-angle at a certain area reduction ratio. So, the optimal die semi-angle exists with the corresponding minimum relative stress. The calculated results are in agreement with the experimental ones, which are applied to directing technological practice of axis-symmetry forward extrusion of semi-solid magnesium alloys.

Thixotropic compression deformation behavior of SiC_p/AZ61 magnesium matrix composites

Compression tests on semi-solid SiCp/AZ61 magnesium matrix composites were carried out using Thermecmastor-Z dynamic material testing machine.Influences of strain-rate,strain,temperature and volume fraction of SiC particles on flow stress were analyzed.The results show that the flow stress of semi-solid SiCp/AZ61 composites is sensitive to temperature and strain rate.The lower the temperature and the larger the strain rate,the higher the flow stress.Meanwhile the flow stress increases with the increase of the volume fraction of SiC particles.This study helps establish the constitutive model of magnesium matrix composites and offers theoretic and experimental references for its thixoforming.

RESEARCH ON THE RHEOLOGY OF MAGNESIUM OXYCHLORIDE CEMENT Ⅰ—RHEOLOGICAL BEHAVIOR

The rheology of magnesium oxychloride cement (MOC) was presented. The rheological properties and thixotropic behaviors of the MOC pastes were determined with a rotating viscometer. The results have showed significant difference between the MOC and portland cement in terms of their rheological behaviors. The yield stress and plastic viscosity of the MOC pastes are much larger than those of portland cement pastes. Therefore, the MOC has a better cohesive property.

Development And Characterization of Ultra Low Cement Castable Cordierites by Thixotropic Properties Mixtures

The main target in this investigation was to take advantage of the reology properties of the tixotropic mixes in Ultra Low Cement Castables (ULCC). The cordierite phase in refractory mix can be obtained using raw materials with magnesium oxide in its composition, such as, Mg(OH)2 or H2Mg3(SiO3)4 (Talc mineral), with a content of? 63.5% SiO2, 31.7% MgO and 4.8% H2O. In this investigation, as magnesium source, a commercial calcined magnesite with 90% MgO was used.? This mineral was selected instead of Talc mineral, because this last contains more impurities in its composition that tend to form more amounts of liquid phases with low fusion points. For this work two different ULCC mixes were designed. These were fired at 1260 oC, the cordierite phase was quantified in each mix.

Evaluation of Thixotropic Models for Waxy Crudes

Thixotropy is a great rheological behavior of waxy crudes oils and is of great importance for hydraulic characteristics and security of oil pipeline restart. In this paper, through the experiment of four waxy crudes, three kinds of thixotropic rheology characteristics in the conditions that shear stress decays under a constant shear rate, shear stress decays after shear rate steps up and hysteresis loop of shear rate cycle changes are studied . For eight thixotropic models, experimental data are fitted in the method of least-squares and average deviation is taken as a statistical indicator to evaluate the thixotropic models. It shows that the model with the idea of Cheng that completely reversible and totally irreversible structures both exist in waxy oil products and based on Houska model can describe thixotropic behaviors of waxy crudes most well.

A Composite Cooling Powder and Its Thixotropic Hydrogel

Due to large volume and high hardness of thermal insulation materials mostly used in high temperature fields, a composite cooling powder and its thixotropic hydrogel for thermal protection are presented. The core of composite cooling material powder is super absorbent polymer, composing with metal salt, polysaccharide hydrosol and inorganic particles and other modifiers through a series of composite process, which can be easily stored for a long time. When needed, the powder can be mixed with water to obtain a kind of thixotropic hydrogel in a very short time. Experimental results show this thermal protection technology with thixotropic ability has excellent thermal protection performance, meanwhile flexible, adhesive and low cost, which exerts instantaneous cooling, efficient thermal protection and long-lasting flame-retardant protection.

Preparation of yttrium oxide coating with enhanced thermal shock resistance on refractories used for titanium alloy melting and casting

In order to enhance the service life of refractories for melting and casting of titanium alloy,preparation of yttrium oxide coatings on the refractories surface is an effective solution.The improvement of thermal shock stability of the coating is beneficial to its spalling resistance during the high-temperature service,and the available slurry with good performance is the prerequisite.The effects of the varieties and contents of dispersant(sodium tripolyphosphate,sodium hexametaphosphate,sodium pyrophosphate,citric acid and polycarboxylate ammonium salt)and binder(aluminum dihydrogen phosphate,zirconium acetate and yttria sol)on the stability,rheological and thixotropic properties of yttrium oxide waterbased slurry were investigated,and the effects of slurry composition design on the thermal shock resistance of the coating were focused.The results showed that the introduction of polycarboxylate ammonium salt as dispersant significantly improved the stability of the slurry,and the varieties of the binders had significant effects on the dispersibility of the slurry.When aluminum dihydrogen phosphate and polycarboxylate ammonium salt were used as binder and dispersant,respectively,the slurry had better stability,suitable rheological and thixotropic properties.By using aluminum dihydrogen phosphate as binder,the coating had good thermal shock resistance and no obvious cracks were observed for the coating after thermal shock,which was attributed to the yttrium aluminate binding phase generated in the coating.An effective method was provided for preparing yttrium oxide coatings with enhanced thermal shock resistance applied in the process of titanium alloy melting and casting.

Constitutive Modeling for Thixoforming of 9Cr18 Semi-solid Alloy and 3D Forecast Mapping

Thixotropic Compression tests were carried out on 9Cr18 semi-solid alloy through Gleeble-1500 thermal simulation machine. According to the experiment analysis, macro separation occurred during thixoforming. The liquid film was extruded outside to the surface and solidified to form eutectic structure. The solid particles were connected with each other and underwent plastic deformation. According to the comparison between Zhou-Guan model and modified Zhou-Guan model, it could be observed that the adding of thixotropic factor played an important role in the regression and the latter one was more credible. The modified Zhou-Guan model could well describe the thixoforming behavior. 3D forecast mapping was built for 9Cr18 semi solid alloy in thixoforming temperature range. It would provide valuable information for selecting process parameters during thixoforming in the manufacture process.