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COMPARISON AND EVALUATION OF CURRENT REFERENCE GENERATION STRATEGIES FOR ACTIVE POWER FILTERS IN THREE-PHASE FOUR-WIRE SYSTEMS
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作者 陈东华 郭涛 +1 位作者 谢少军 周波 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2005年第4期298-306,共9页
For three phase four-wire active power filters (APFs), several typical power theories and corresponding current reference generation strategies are induced, p-q, d-q, unify power factor (UPF) and instantaneous act... For three phase four-wire active power filters (APFs), several typical power theories and corresponding current reference generation strategies are induced, p-q, d-q, unify power factor (UPF) and instantaneous active current (IAC) methods are analyzed and compared with each other. The interpretation of active and reactive currents in non-sinusoidal and unbalanced three-phase four-wire systems is given based on the generalized instantaneous reactive power theory. The performance and the characteristic are evaluated, and the application conditions of current reference generation strategies are concluded. Simulation results under different source voltages and loads verify the evaluation result. 展开更多
关键词 active power filters instantaneous reactive power current reference three-phase four wire power
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Phase equilibria of slag systems“FeO”−SiO_(2)−CaO−Al_(2)O_(3)and“FeO”−SiO_(2)−CaO−MgO at 1200℃and p(O_(2))of 10^(−7)kPa
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作者 Sui XIE Qin-meng WANG +2 位作者 Xue-yi GUO Chun-fa LIAO Bao-jun ZHAO 《中国有色金属学报》 北大核心 2025年第1期338-348,共11页
High-temperature experiments were carried out for the slag systems of“FeO”−SiO_(2)−CaO−Al_(2)O_(3)and“FeO”−SiO_(2)−CaO−MgO at 1200℃and p(O_(2))of 10^(−7)kPa.The equilibrated samples were quenched,and the phase co... High-temperature experiments were carried out for the slag systems of“FeO”−SiO_(2)−CaO−Al_(2)O_(3)and“FeO”−SiO_(2)−CaO−MgO at 1200℃and p(O_(2))of 10^(−7)kPa.The equilibrated samples were quenched,and the phase compositions were measured by electron probe microanalysis(EPMA).A series of pseudo-ternary and pseudo-binary phase diagrams are constructed to demonstrate their applications in copper smelting process and evaluation of the thermodynamic database.Spinel and tridymite are identified to be the major primary phases in the composition range related to the copper smelting slags.It is found that the operating window of the smelting slag is primarily determined by w_(Fe)/w_(SiO_(2))ratio in the slag.Both MgO and Al_(2)O_(3)in the slag reduce the operating window which requires extra fluxing agent to keep the slag to be fully liquid.Complex spinel solid solutions cause inaccurate predictions of the current thermodynamic database. 展开更多
关键词 phase equilibrium “FeO”−SiO_(2)−CaO−Al_(2)O_(3)slag system “FeO”−SiO_(2)−CaO−MgO slag system oxygen partial pressure copper smelting slag FactSage
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Robust interface and excellent as-built mechanical properties of Ti–6Al–4V fabricated through laser-aided additive manufacturing with powder and wire
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作者 Fei Weng Guijun Bi +5 位作者 Youxiang Chew Shang Sui Chaolin Tan Zhenglin Du Jinlong Su Fern Lan Ng 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS 2025年第1期154-168,共15页
The feasibility of manufacturing Ti-6Al-4V samples through a combination of laser-aided additive manufacturing with powder(LAAM_(p))and wire(LAAM_(w))was explored.A process study was first conducted to successfully ci... The feasibility of manufacturing Ti-6Al-4V samples through a combination of laser-aided additive manufacturing with powder(LAAM_(p))and wire(LAAM_(w))was explored.A process study was first conducted to successfully circumvent defects in Ti-6Al-4V deposits for LAAM_(p) and LAAM_(w),respectively.With the optimized process parameters,robust interfaces were achieved between powder/wire deposits and the forged substrate,as well as between powder and wire deposits.Microstructure characterization results revealed the epitaxial prior β grains in the deposited Ti-6Al-4V,wherein the powder deposit was dominated by a finerα′microstructure and the wire deposit was characterized by lamellar α phases.The mechanisms of microstructure formation and correlation with mechanical behavior were analyzed and discussed.The mechanical properties of the interfacial samples can meet the requirements of the relevant Aerospace Material Specifications(AMS 6932)even without post heat treatment.No fracture occurred within the interfacial area,further suggesting the robust interface.The findings of this study highlighted the feasibility of combining LAAM_(p) and LAAM_(w) in the direct manufacturing of Ti-6Al-4V parts in accordance with the required dimensional resolution and deposition rate,together with sound strength and ductility balance in the as-built condition. 展开更多
关键词 laser-aided additive manufacturing powder deposition wire deposition interfacial characteristic mechanical behavior
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Experimental Study and a Modified Model for Temperature-Recovery Stress of Shape Memory Alloy Wire under Different Temperatures
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作者 Zhi-Xiang Wei Wen-Wei Wang +1 位作者 Yan-Jie Xue Wu-Tong ZhangQiu-Di Huang 《Structural Durability & Health Monitoring》 2025年第2期347-364,共18页
To investigate the performance of utilizing the shape memory effect of SMA(Shape Memory Alloy)wire to generate recovery stress,this paper performed single heating recovery stress tests and reciprocating heating-coolin... To investigate the performance of utilizing the shape memory effect of SMA(Shape Memory Alloy)wire to generate recovery stress,this paper performed single heating recovery stress tests and reciprocating heating-cooling recovery stress tests on SMA wire under varying initial strain conditions.The effects of various strains and different energized heating methods on the recovery stress of SMA wires were explored in the single heating tests.The SMA wire was strained from 2%to 8%initially,and two distinct heating approaches were employed:one using a large current interval for rapid heating and one using a small current interval for slower heating.The experimental outcomes reveal that during a single heating cycle,the temperature-recovery stress relationship of SMA wire exhibits three distinct stages:the martensite phase stage,the transition stage from martensite to austenite phase,and the austenite phase stage.Notably,the choice of heating method does not influence the maximum recovery stress value,and the correlation between initial strain and maximum recovery stress is predominantly linear.Moreover,conducting the reciprocating temperature rise and fall performance test is important to better simulate the scenario in practical engineering where multiple recovery stress in SMA wires for structural repair.In this test,two temperature cycling methods were studied:interval rise and fall,as well as direct rise and fall.In the case of utilizing the interval temperature rise and fall method,it was observed that the recovery stress associated with cooling was significantly higher than that corresponding to heating at the same temperature.Furthermore,the recovery stress was lower upon subsequent heating than that measured during the previous heating cycle.Based on the experimental results,a prediction model for the temperature-recovery stress relationship has been proposed to simplify numerical calculations.It is hoped that an approximate temperaturerecovery stress curve can be obtained from the parameters of the SMA wire.The calculated values derived from this model show good alignment with the measured values,indicating its reliability. 展开更多
关键词 SMA wire TEMPERATURE recovery stress modified model phase transition
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Robust adaptive leaderless consensus of unknown non-minimum phase linear multi-agent systems subject to disturbances and/or unmodeled dynamics 被引量:1
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作者 Wenji Cao Gang Feng 《Journal of Automation and Intelligence》 2024年第2期92-100,共9页
This article investigates the problem of robust adaptive leaderless consensus for heterogeneous uncertain nonminimumphase linear multi-agent systems over directed communication graphs. Each agent is assumed tobe of un... This article investigates the problem of robust adaptive leaderless consensus for heterogeneous uncertain nonminimumphase linear multi-agent systems over directed communication graphs. Each agent is assumed tobe of unknown nominal dynamics and also subject to external disturbances and/or unmodeled dynamics. Anovel distributed robust adaptive control strategy is proposed. It is shown that the robust adaptive leaderlessconsensus problem is solved with the proposed control strategy under some sufficient conditions. Two examplesare provided to demonstrate the efficacy of the proposed control strategy. 展开更多
关键词 Cooperative control Non-minimum phase Leaderless consensus Multi-agent systems Robust adaptive control
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The First Five Years of a Phase Theory for Complex Systems and Networks
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作者 Dan Wang Wei Chen Li Qiu 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2024年第8期1728-1743,共16页
In this paper,we review the development of a phase theory for systems and networks in its first five years,represented by a trilogy:Matrix phases and their properties;The MIMO LTI system phase response,its physical in... In this paper,we review the development of a phase theory for systems and networks in its first five years,represented by a trilogy:Matrix phases and their properties;The MIMO LTI system phase response,its physical interpretations,the small phase theorem,and the sectored real lemma;The synchronization of a multi-agent network using phase alignment.Towards the end,we also summarize a list of ongoing research on the phase theory and speculate what will happen in the next five years. 展开更多
关键词 Consensus and synchronization matrix phases multi-agent systems phase theory sectored real lemma small phase theorem.
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Theory and verification of moiréfringes for x-ray three-phase grating interferometer
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作者 单雨征 葛永帅 +5 位作者 杨君 郭大育 蔡学宝 刘晓珂 侯晓文 郭金川 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期532-540,共9页
Dual-phase and three-phase grating x-ray interference is a promising new technique for grating-based x-ray differential phase contrast imaging.Dual-phase grating interferometers have been relatively completely studied... Dual-phase and three-phase grating x-ray interference is a promising new technique for grating-based x-ray differential phase contrast imaging.Dual-phase grating interferometers have been relatively completely studied and discussed.In this paper,the corresponding imaging fringe formula of the three-phase grating interferometer is provided.At the same time,the similarities and differences between the three-phase grating interferometer and the dual-phase grating interferometer are investigated and verified,and that the three-phase grating interferometer can produce large-period moiréfringes without using the analyzing grating is demonstrated experimentally.Finally,a simple method of designing three-phase grating and multi-grating imaging systems from geometric optics based on the thin-lens theory of gratings is presented.These theoretical formulas and experimental results provide optimization tools for designing three-phase grating interferometer systems. 展开更多
关键词 x-ray phase contrast phase grating moiréfringe
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Solideliquid phase equilibria in the aqueous system containing the chlorides of potassium,ammonium,and calcium at 298.2,323.2,and 348.2 K
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作者 Fuyu Zhuge Nan Zhang +3 位作者 Haiying Tang Qi Li Niancu Chen Xudong Yu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第12期83-94,共12页
In order to obtain the crystalline forms of the salts of the potassium,ammonium,calcium coexisting chloride system,the phase equilibria relationship of quaternary system K^(+),NH_(4)^(+),Ca^(2+)//Cl^(-)-H_(2)O at 298.... In order to obtain the crystalline forms of the salts of the potassium,ammonium,calcium coexisting chloride system,the phase equilibria relationship of quaternary system K^(+),NH_(4)^(+),Ca^(2+)//Cl^(-)-H_(2)O at 298.2,323.2,and 348.2 K was studied by isothermal dissolution equilibrium method.The solubility and density of equilibrium liquid phases of the system were experimentally determined;X-ray powder diffractometer was used to determine the compositions of the equilibrium solid phase at the quaternary invariant point.It is found that the quaternary system is a complex system at these three temperatures.The phase diagram at 298.2 K consists of three invariant points,seven univariate curves and five crystalline phase regions,forming the solid solutions(NH_(4)Cl)_(x)(KCl)_(1-x) and(KCl)_(x)(NH_(4)Cl)_(1-x);while at 323.2 and 348.2 K the phase diagram consists of five invariant points,eleven univariate curves and seven crystalline phase regions,the double salts(KClCaCl_(2))and(2NH_(4)Cl·CaCl_(2)·3H_(2)O),solid solutions(KCl)_(x)(NH_(4)Cl)_(1-x) and(NH_(4)Cl)_(x)(KCl)_(1-x) were formed.Among them,the crystalline phase region of solid solution(KCl)_(x)(NH_(4)Cl)_(1-x) is the largest at three temperatures,indicating that it is the easiest to crystallize in this system.Comparing the phase diagrams of the quaternary system at 298.2,323.2,and 348.2 K,it can be seen that the crystalline form of CaCl_(2) changes with the increase of temperature:CaCl_(2)·6H_(2)O at 298.2 K,CaCl_(2)·2H_(2)O at 323.2 and 348.2 K.From 323.2 to 348.2 K,the crystalline phase regions of(KCl·CaCl_(2))and(2NH_(4)Cl·CaCl_(2)·3H_(2)O)increased gradually. 展开更多
关键词 phase equilibria SOLUBILITY HYDRATE Deep brine Double salt Solid solution
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On the global L^(1)-boundedness of Fourier integral operators with rough amplitude and phase functions
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作者 Joachim Sindayigaya WU Xiao-mei HUANG Qiang 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2024年第4期604-613,共10页
Let T_(ϕ,a)be a Fourier integral operator with amplitude a and phase functions ϕ.In this paper,we study the boundedness of Fourier integral operator of rough amplitude a∈L^(∞)S_(ρ)^(m)and rough phase functionsϕ∈L^... Let T_(ϕ,a)be a Fourier integral operator with amplitude a and phase functions ϕ.In this paper,we study the boundedness of Fourier integral operator of rough amplitude a∈L^(∞)S_(ρ)^(m)and rough phase functionsϕ∈L^(m)ϕ^(2)with some measure condition.We prove the global L^(1)boundedness for T_(ϕ,a),when 1/<ρ≤1 and m<ρ-n+1/2.Our theorem improves some known results. 展开更多
关键词 fourier integral operators L1-Boundedness rough amplitude rough phase functions
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Design of a Three-Phase Grid Connector System Using Power Transfer from Park’s Transformation
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作者 Birtukan Yenealem Elias Mamushet 《Smart Grid and Renewable Energy》 2024年第5期123-138,共16页
Instabilities in grid-connected inverters can arise from a number of sources, including mismatched parameters, grid impedance, faults, and feedback delays. Park’s transformation provides accurate control over reactiv... Instabilities in grid-connected inverters can arise from a number of sources, including mismatched parameters, grid impedance, faults, and feedback delays. Park’s transformation provides accurate control over reactive and active (real) power. This enhances the overall efficiency of the system by enabling operators to control reactive power compensation and optimize energy flow. In dynamic settings, this guarantees greater system stability and faster response times. The current paper aims to improve the grid system by utilizing the dq0 controller. The current work focuses on the analysis based on simulations and theory, where the state space equation serves as the basis for dq-axis current decoupling. A MATLAB platform was used to simulate the complete system. TDH values of 2.45%, or less than 5%, in the given results are acceptable. The suggested controller was hence appropriate for grid system applications. 展开更多
关键词 Grid system INVERTER Optimization ENERGY three phase
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Enhanced entropy generation and heat transfer characteristics of magnetic nano-encapsulated phase change materials in latent heat thermal energy storage systems
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作者 P.S.REDDY P.SREEDEVI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第6期1051-1070,共20页
The objective of the current study is to investigate the importance of entropy generation and thermal radiation on the patterns of velocity,isentropic lines,and temperature contours within a thermal energy storage dev... The objective of the current study is to investigate the importance of entropy generation and thermal radiation on the patterns of velocity,isentropic lines,and temperature contours within a thermal energy storage device filled with magnetic nanoencapsulated phase change materials(NEPCMs).The versatile finite element method(FEM)is implemented to numerically solve the governing equations.The effects of various parameters,including the viscosity parameter,ranging from 1 to 3,the thermal conductivity parameter,ranging from 1 to 3,the Rayleigh parameter,ranging from 102 to 3×10^(2),the radiation number,ranging from 0.1 to 0.5,the fusion temperature,ranging from 1.0 to 1.2,the volume fraction of NEPCMs,ranging from 2%to 6%,the Stefan number,ranging from 1 to 5,the magnetic number,ranging from 0.1 to 0.5,and the irreversibility parameter,ranging from 0.1 to 0.5,are examined in detail on the temperature contours,isentropic lines,heat capacity ratio,and velocity fields.Furthermore,the heat transfer rates at both the cold and hot walls are analyzed,and the findings are presented graphically.The results indicate that the time taken by the NEPCMs to transition from solid to liquid is prolonged inside the chamber region as the fusion temperatureθf increases.Additionally,the contours of the heat capacity ratio Cr decrease with the increase in the Stefan number Ste. 展开更多
关键词 volume fraction of nano-encapsulated phase change material(NEPCM) RADIATION Stefan number heat capacity ratio entropy generation
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Exploring Corporate Tax Compliance in the Era of Digital Tax Collection and Administration:Insights from the“Golden Tax Phase Four”Project
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作者 Kai Fan Yujin Xie +1 位作者 Wenjun Xu Haopeng Wei 《Proceedings of Business and Economic Studies》 2024年第2期151-156,共6页
This article primarily examines the current state of tax collection and management,alongside other associated issues.It integrates insights from China’s“14th Five-Year Plan”and anticipates the imminent implementati... This article primarily examines the current state of tax collection and management,alongside other associated issues.It integrates insights from China’s“14th Five-Year Plan”and anticipates the imminent implementation of the“Golden Tax Phase Four.”With this backdrop,the article offers recommendations for advancing the reform of the tax collection and management system,fostering the development of intelligent taxation,and accelerating the modernization of tax collection and management in China. 展开更多
关键词 Golden Tax phase four Modernization of tax collection and administration Tax compliance
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Quantum Fourier Transform and Phase Estimation in Qudit System 被引量:4
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作者 曹业 彭世国 +1 位作者 郑超 龙桂鲁 《Communications in Theoretical Physics》 SCIE CAS CSCD 2011年第5期790-794,共5页
The quantum Fourier transform and quantum phase estimation are the key components for many quantum algorithms, such as order-finding, factoring, and etc. In this article, the general procedure of quantum Fourier trans... The quantum Fourier transform and quantum phase estimation are the key components for many quantum algorithms, such as order-finding, factoring, and etc. In this article, the general procedure of quantum Fourier transform and phase estimation are investigated for high dimensional case run in a qudit quantum computer, and the quantum circuits are They can be seen as subroutines in a main program given. 展开更多
关键词 quantum fourier transform qudit system phase estimation
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Neural adaptive PSD decoupling controller and its application in three-phase electrode adjusting system of submerged arc furnace 被引量:4
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作者 贺建军 刘郁乔 +1 位作者 喻寿益 桂卫华 《Journal of Central South University》 SCIE EI CAS 2013年第2期405-412,共8页
Taking three-phase electrode adjusting system of submerged arc furnace as study object which has nonlinear, time-variant, multivariable and strong coupling features, a neural adaptive PSD(proportion, sum and different... Taking three-phase electrode adjusting system of submerged arc furnace as study object which has nonlinear, time-variant, multivariable and strong coupling features, a neural adaptive PSD(proportion, sum and differential) dispersive decoupling controller was developed by combining neural adaptive PSD algorithm with dispersive decoupling network. In this work, the production technology process and control difficulties of submerged arc furnace were simply introduced, the necessity of establishing a neural adaptive PSD dispersive decoupling controller was discussed, the design method and the implementation steps of the controller are expounded in detail, and the block diagram of the controlled system is presented. By comparison with experimental results of the conventional PID controller and the adaptive PSD controller, the decoupling ability, adaptive ability, self-learning ability and robustness of the neural adaptive PSD dispersive decoupling controller have been testified effectively. The controller is applicable to the three-phase electrode adjusting system of submerged arc furnace, and it will play an important role for achieving the power balance of three-phrase electrodes, saving energy and reducing consumption in the process of smelting. 展开更多
关键词 PSD algorithm decoupling controller submerged arc furnace three phase electrode
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Single-phase earth fault current distribution between optical fiber composite overhead ground wire and ordinary ground wire in transmission system
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作者 许高雄 《Journal of Chongqing University》 CAS 2011年第2期78-83,共6页
It is important for the safety of transmission system to accurately calculate single-phase earth fault current distribution.Features of double sided elimination method were illustrated.Quantitative calculation of sing... It is important for the safety of transmission system to accurately calculate single-phase earth fault current distribution.Features of double sided elimination method were illustrated.Quantitative calculation of single-phase earth fault current distribution and case verification were accomplished by using the loop method.Influences of some factors,such as single-phase earth fault location and ground resistance of poles,on short-circuit current distribution were discussed.Results show that:1) results of the loop method conform to those of double sided elimination method;2) the fault location hardly influences macro-distribution of short-circuit current.However,current near fault location is evidently influenced;and 3) the short-circuit current distribution is not so sensitive to the ground resistance of poles. 展开更多
关键词 loop method single-phase earth fault short-circuit current distribution optical fiber composite overhead ground wire ordinary ground wire
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Modeling and Analysis of Airlift System Operating in Three-Phase Flow 被引量:6
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作者 胡东 康勇 +1 位作者 唐川林 王晓川 《China Ocean Engineering》 SCIE EI CSCD 2015年第1期121-132,共12页
Based on the momentum theorem, the fluid governing equation in a lifting pipe is proposed by use of the method combining theoretical analysis with empirical correlations related to the previous research, and the perfo... Based on the momentum theorem, the fluid governing equation in a lifting pipe is proposed by use of the method combining theoretical analysis with empirical correlations related to the previous research, and the performance of an airlift pump can be clearly characterized by the triangular relationship among the volumetric flux of air, water and solid particles, which are obtained respectively by using numerical calculation. The meso-scale river sand is used as tested particles to examine the theoretical model. Results of the model are compared with the data in three-phase flow obtained prior to the development of the present model, by an independent experimental team that used the physical conditions of the present approach. The analytical error can be controlled within 12% for predicting the volumetric flux of water and is smaller than that (±16%) of transporting solid particles in three-phase flow. The experimental results and computations are in good agreement for air-water two-phase flow within a margin of ±8%. Reasonable agreement justifies the use of the present model for engineering design purposes. 展开更多
关键词 airlift pump momentum theorem three-phase flow volumetric flux relative error
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Analysis and optimization of power spectrum on EBPSK modulation in throughput-efficient wireless system 被引量:6
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作者 冯熳 戚晨浩 吴乐南 《Journal of Southeast University(English Edition)》 EI CAS 2008年第2期143-148,共6页
In order to satisfy increasingly greater demand for the performance of communication systems, a throughput efficient wireless system based on the extended binary phase shift keying (EBPSK) modulation is presented. S... In order to satisfy increasingly greater demand for the performance of communication systems, a throughput efficient wireless system based on the extended binary phase shift keying (EBPSK) modulation is presented. Simultaneously, corresponding analysis of power spectra is also given with a brief process. The optimal waveform is proposed without useful information loss, by removing linear spectra presenting periodic components. On this basis, the reasonable definition of bandwidth is discussed, which indicates that the EBPSK belongs to the category of the ultra narrow band (UNB) throughput-efficient communication. Meanwhile, the modulation parameters' effects on bandwidth, transmission rate and transmission performance are analyzed. Results illustrate the validity of theoretical analysis and spectrum optimization. Results also prove that this UNB system can obtain good bit error rate (BER) performance with high spectra efficiency. 展开更多
关键词 extended binary phase shift keying power spectrum ultra narrow band spectra efficiency
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Holographic alloy positioning design system and holographic network phase diagrams of Au-Cu system 被引量:3
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作者 谢佑卿 刘心笔 +2 位作者 李小波 彭红建 聂耀庄 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第3期885-906,共22页
Taking Au?Cu system as an example, three discoveries and two methods were presented. First, a new way for boosting sustainable progress of systematic metal materials science (SMMS) and alloy gene engineering (AGE) is ... Taking Au?Cu system as an example, three discoveries and two methods were presented. First, a new way for boosting sustainable progress of systematic metal materials science (SMMS) and alloy gene engineering (AGE) is to establish holographic alloy positioning design (HAPD) system, of which the base consists of measurement and calculation center, SMMS center, AGE center, HAPD information center and HAPD cybernation center; Second, the resonance activating-sychro alternating mechanism of atom movement may be divided into the located and oriented diffuse modes; Third, the equilibrium and subequilibrium holographic network phase diagrams are blueprints and operable platform for researchers to discover, design, manufacture and deploy advanced alloys, which are obtained respectively by the equilibrium lever numerical method and cross point numerical method of isothermal Gibbs energy curves. As clicking each network point, the holographic information of three structure levels for the designed alloy may be readily obtained: the phase constitution and fraction, phase arranging structure and properties of organization; the composition, alloy gene arranging structure and properties of each phase and the electronic structures and properties of alloy genes. It will create a new era for network designing advanced alloys. 展开更多
关键词 Au-Cu system holographic alloy positioning design system equilibrium and subequilibrium holographic network phase diagrams systematic metal materials science network designing advanced alloys
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Alloy gene Gibbs energy partition function and equilibrium holographic network phase diagrams of AuCu_3-type sublattice system 被引量:3
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作者 谢佑卿 李小波 +2 位作者 刘心笔 聂耀庄 彭红建 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第11期3585-3610,共26页
Taking AuCu3-type sublattice system as an example, three discoveries have been presented: First, the third barrier hindering the progress in metal materials science is that researchers have got used to recognizing exp... Taking AuCu3-type sublattice system as an example, three discoveries have been presented: First, the third barrier hindering the progress in metal materials science is that researchers have got used to recognizing experimental phenomena of alloy phase transitions during extremely slow variation in temperature by equilibrium thinking mode and then taking erroneous knowledge of experimental phenomena as selected information for establishing Gibbs energy function and so-called equilibrium phase diagram. Second, the equilibrium holographic network phase diagrams of AuCu3-type sublattice system may be used to describe systematic correlativity of the composition?temperature-dependent alloy gene arranging structures and complete thermodynamic properties, and to be a standard for studying experimental subequilibrium order-disorder transition. Third, the equilibrium transition of each alloy is a homogeneous single-phase rather than a heterogeneous two-phase, and there exists a single-phase boundary curve without two-phase region of the ordered and disordered phases; the composition and temperature of the top point on the phase-boundary curve are far away from the ones of the critical point of the AuCu3 compound. 展开更多
关键词 AuCu3 compound AuCu3-type sublattice system alloy gene Gibbs energy partition function equilibrium holographic network phase diagram systematic metal materials science
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Alloy gene Gibbs energy partition function and equilibrium holographic network phase diagrams of Au_3Cu-type sublattice system 被引量:3
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作者 谢佑卿 聂耀庄 +2 位作者 李小波 彭红建 刘心笔 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第1期211-240,共30页
Taking Au3Cu-type sublattice system as an example, three discoveries have been presented. First, the fourth barrier to hinder the progress of metal materials science is that today’s researchers do not understand that... Taking Au3Cu-type sublattice system as an example, three discoveries have been presented. First, the fourth barrier to hinder the progress of metal materials science is that today’s researchers do not understand that the Gibbs energy function of an alloy phase should be derived from Gibbs energy partition function constructed of alloy gene sequence and their Gibbs energy sequence. Second, the six rules for establishing alloy gene Gibbs energy partition function have been discovered, and it has been specially proved that the probabilities of structure units occupied at the Gibbs energy levels in the degeneracy factor for calculating configuration entropy should be degenerated as ones of component atoms occupied at the lattice points. Third, the main characteristics unexpected by today’s researchers are as follows. There exists a single-phase boundary curve without two-phase region coexisting by the ordered and disordered phases. The composition and temperature of the top point on the phase-boundary curve are far away from those of the critical point of the Au3Cu compound; At 0 K, the composition of the lowest point on the composition-dependent Gibbs energy curve is notably deviated from that of the Au3Cu compounds. The theoretical limit composition range of long range ordered Au3Cu-type alloys is determined by the first jumping order degree. 展开更多
关键词 Au3Cu compound Au3Cu-type sublattice system alloy gene Gibbs energy partition function equilibrium holographic network phase diagrams systematic metal materials science
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