Atom-level modulation of the coordination environment for single-atom catalysts(SACs)is considered as an effective strategy for elevating the catalytic performance.For the MNxsite,breaking the symmetrical geometry and...Atom-level modulation of the coordination environment for single-atom catalysts(SACs)is considered as an effective strategy for elevating the catalytic performance.For the MNxsite,breaking the symmetrical geometry and charge distribution by introducing relatively weak electronegative atoms into the first/second shell is an efficient way,but it remains challenging for elucidating the underlying mechanism of interaction.Herein,a practical strategy was reported to rationally design single cobalt atoms coordinated with both phosphorus and nitrogen atoms in a hierarchically porous carbon derived from metal-organic frameworks.X-ray absorption spectrum reveals that atomically dispersed Co sites are coordinated with four N atoms in the first shell and varying numbers of P atoms in the second shell(denoted as Co-N/P-C).The prepared catalyst exhibits excellent oxygen reduction reaction(ORR)activity as well as zinc-air battery performance.The introduction of P atoms in the Co-SACs weakens the interaction between Co and N,significantly promoting the adsorption process of ^(*)OOH,resulting in the acceleration of reaction kinetics and reduction of thermodynamic barrier,responsible for the increased intrinsic activity.Our discovery provides insights into an ultimate design of single-atom catalysts with adjustable electrocatalytic activities for efficient electrochemical energy conversion.展开更多
The coordination problem of a supply chain comprising one supplier and one retailer under market demand disruption is studied in this article. A novel exponential demand function is adopted, and the penalty cost is in...The coordination problem of a supply chain comprising one supplier and one retailer under market demand disruption is studied in this article. A novel exponential demand function is adopted, and the penalty cost is introduced explicitly to capture the deviation production cost caused by the market demand disruption. The optimal strategies are obtained for different disruption scale under the centralized mode. For the decentralized mode, it is proved that the supply chain can be fully coordinated by adjusting the price discount policy appropriately when disruption occurs. Furthermore, the authors point out that similar results can be established for more general demand functions that represent different market circumstances if certain assumptions are satisfied.展开更多
The grey wolf optimizer(GWO)is a swarm-based intelligence optimization algorithm by simulating the steps of searching,encircling,and attacking prey in the process of wolf hunting.Along with its advantages of simple pr...The grey wolf optimizer(GWO)is a swarm-based intelligence optimization algorithm by simulating the steps of searching,encircling,and attacking prey in the process of wolf hunting.Along with its advantages of simple principle and few parameters setting,GWO bears drawbacks such as low solution accuracy and slow convergence speed.A few recent advanced GWOs are proposed to try to overcome these disadvantages.However,they are either difficult to apply to large-scale problems due to high time complexity or easily lead to early convergence.To solve the abovementioned issues,a high-accuracy variable grey wolf optimizer(VGWO)with low time complexity is proposed in this study.VGWO first uses the symmetrical wolf strategy to generate an initial population of individuals to lay the foundation for the global seek of the algorithm,and then inspired by the simulated annealing algorithm and the differential evolution algorithm,a mutation operation for generating a new mutant individual is performed on three wolves which are randomly selected in the current wolf individuals while after each iteration.A vectorized Manhattan distance calculation method is specifically designed to evaluate the probability of selecting the mutant individual based on its status in the current wolf population for the purpose of dynamically balancing global search and fast convergence capability of VGWO.A series of experiments are conducted on 19 benchmark functions from CEC2014 and CEC2020 and three real-world engineering cases.For 19 benchmark functions,VGWO’s optimization results place first in 80%of comparisons to the state-of-art GWOs and the CEC2020 competition winner.A further evaluation based on the Friedman test,VGWO also outperforms all other algorithms statistically in terms of robustness with a better average ranking value.展开更多
As new power systems and dual carbon policies develop,virtual power plant cluster(VPPC)provides another reliable way to promote the efficient utilization of energy and solve environmental pollution problems.To solve t...As new power systems and dual carbon policies develop,virtual power plant cluster(VPPC)provides another reliable way to promote the efficient utilization of energy and solve environmental pollution problems.To solve the coordinated optimal operation and low-carbon economic operation problem in multi-virtual power plant,a multi-virtual power plant(VPP)electricity-carbon interaction optimal scheduling model considering integrated demand response(IDR)is proposed.Firstly,a multi-VPP electricity-carbon interaction framework is established.The interaction of electric energy and carbon quotas can realize energy complementarity,reduce energy waste and promote low-carbon operation.Secondly,in order to coordinate the multiple types of energy and load in VPPC to further achieve low-carbon operation,the IDR mechanism based on the user comprehensive satisfaction(UCS)of electricity,heat as well as hydrogen is designed,which can effectively maintain the UCS in the cluster within a relatively high range.Finally,the unit output scheme is formulated to minimize the total cost of VPPC and the model is solved using theCPLEX solver.The simulation results showthat the proposed method effectively promotes the coordinated operation among multi-VPP,increases the consumption rate of renewable energy sources and the economics of VPPC and reduces carbon emissions.展开更多
基金supported by the National Natural Science Foundation of China(51872115,12234018 and 52101256)Beijing Synchrotron Radiation Facility(BSRF,4B9A)。
文摘Atom-level modulation of the coordination environment for single-atom catalysts(SACs)is considered as an effective strategy for elevating the catalytic performance.For the MNxsite,breaking the symmetrical geometry and charge distribution by introducing relatively weak electronegative atoms into the first/second shell is an efficient way,but it remains challenging for elucidating the underlying mechanism of interaction.Herein,a practical strategy was reported to rationally design single cobalt atoms coordinated with both phosphorus and nitrogen atoms in a hierarchically porous carbon derived from metal-organic frameworks.X-ray absorption spectrum reveals that atomically dispersed Co sites are coordinated with four N atoms in the first shell and varying numbers of P atoms in the second shell(denoted as Co-N/P-C).The prepared catalyst exhibits excellent oxygen reduction reaction(ORR)activity as well as zinc-air battery performance.The introduction of P atoms in the Co-SACs weakens the interaction between Co and N,significantly promoting the adsorption process of ^(*)OOH,resulting in the acceleration of reaction kinetics and reduction of thermodynamic barrier,responsible for the increased intrinsic activity.Our discovery provides insights into an ultimate design of single-atom catalysts with adjustable electrocatalytic activities for efficient electrochemical energy conversion.
基金This research was supported by National Science Foundation of China (60274048)
文摘The coordination problem of a supply chain comprising one supplier and one retailer under market demand disruption is studied in this article. A novel exponential demand function is adopted, and the penalty cost is introduced explicitly to capture the deviation production cost caused by the market demand disruption. The optimal strategies are obtained for different disruption scale under the centralized mode. For the decentralized mode, it is proved that the supply chain can be fully coordinated by adjusting the price discount policy appropriately when disruption occurs. Furthermore, the authors point out that similar results can be established for more general demand functions that represent different market circumstances if certain assumptions are satisfied.
文摘The grey wolf optimizer(GWO)is a swarm-based intelligence optimization algorithm by simulating the steps of searching,encircling,and attacking prey in the process of wolf hunting.Along with its advantages of simple principle and few parameters setting,GWO bears drawbacks such as low solution accuracy and slow convergence speed.A few recent advanced GWOs are proposed to try to overcome these disadvantages.However,they are either difficult to apply to large-scale problems due to high time complexity or easily lead to early convergence.To solve the abovementioned issues,a high-accuracy variable grey wolf optimizer(VGWO)with low time complexity is proposed in this study.VGWO first uses the symmetrical wolf strategy to generate an initial population of individuals to lay the foundation for the global seek of the algorithm,and then inspired by the simulated annealing algorithm and the differential evolution algorithm,a mutation operation for generating a new mutant individual is performed on three wolves which are randomly selected in the current wolf individuals while after each iteration.A vectorized Manhattan distance calculation method is specifically designed to evaluate the probability of selecting the mutant individual based on its status in the current wolf population for the purpose of dynamically balancing global search and fast convergence capability of VGWO.A series of experiments are conducted on 19 benchmark functions from CEC2014 and CEC2020 and three real-world engineering cases.For 19 benchmark functions,VGWO’s optimization results place first in 80%of comparisons to the state-of-art GWOs and the CEC2020 competition winner.A further evaluation based on the Friedman test,VGWO also outperforms all other algorithms statistically in terms of robustness with a better average ranking value.
基金supported by the National Natural Science Foundation of China (NSFC) (Grant No.52107107).
文摘As new power systems and dual carbon policies develop,virtual power plant cluster(VPPC)provides another reliable way to promote the efficient utilization of energy and solve environmental pollution problems.To solve the coordinated optimal operation and low-carbon economic operation problem in multi-virtual power plant,a multi-virtual power plant(VPP)electricity-carbon interaction optimal scheduling model considering integrated demand response(IDR)is proposed.Firstly,a multi-VPP electricity-carbon interaction framework is established.The interaction of electric energy and carbon quotas can realize energy complementarity,reduce energy waste and promote low-carbon operation.Secondly,in order to coordinate the multiple types of energy and load in VPPC to further achieve low-carbon operation,the IDR mechanism based on the user comprehensive satisfaction(UCS)of electricity,heat as well as hydrogen is designed,which can effectively maintain the UCS in the cluster within a relatively high range.Finally,the unit output scheme is formulated to minimize the total cost of VPPC and the model is solved using theCPLEX solver.The simulation results showthat the proposed method effectively promotes the coordinated operation among multi-VPP,increases the consumption rate of renewable energy sources and the economics of VPPC and reduces carbon emissions.
