Design of ground-airborne TEM three-component air-core coil sensor

Transient electromagnetic method (TEM),as a non-seismic geophysical exploration mainstream electromagnetic method,is widely used in oil,gas,mineral and other underground resources exploration areas. The coil sensor is generally used to collect data. In view of the problems of incomplete information of the abnormal body and the data loss in the existing TEM single-component coil sensor,a three-component TEM coil sensor is designed. By analyzing the relationship between sensor sensitivity and coil structure parameters,the coil structure and turns are designed. By analyzing the frequency response characteristics of the TEM magnetic field sensor,the signal distortion is reduced by using the under-damped matching mode. By analyzing the distribution of various noise sources of the magnetic sensor,the appropriate amplifier is selected to reduce the background noise. Finally,a three-component TEM induction magnetic field sensor is designed. The weight of the sensor is controlled at 3.2 kg and the working frequency is 10 mHz-10 kHz. The background noises of X and Y components probably keep in 1.5×10^-8 V/ Hz and sensitivities are 8.4 and 9.8 nT/s,respectively,the background noise of vertical component is 2.1× 10^-7 V/ Hz and sensitivity is 18.5 nT/s. Compared with the existing single-component TEM receiving magnetic field sensor,the designed sensor realizes the signal acquisition of three components. Without too much increase in volume and total weight,it improves the sensitivity of the sensor and reduces the background noise,thus the signal-to-noise ratio (SNR) of the signal is improved.

Three-Component Model for Bidirectional Reflection Distribution Function of Thermal Coating Surfaces

We present a bidirectional reflection distribution function （BRDF） model for thermal coating surfaces based on a three-component reflection assumption, in which the specular reflection is given according to the microfacet theory and Snell＇s law, the multiple reflection is considered Nth cosine distributed, and the volume scattering is uniformly distributed in reflection angles according to the experimental results. This model describes the reflection characteristics of thermal coating surfaces more completely and reasonably. Simulation and measurement results of two thermal coating samples SR107 and S781 are given to validate that this three-component model significantly improves the modeling accuracy for thermal coating surfaces compared with the existing BRDF models.

Low-Frequency Waves in Cold Three-Component Plasmas

The dispersion relation and electromagnetic polarization of the plasma waves are comprehensively studied in cold electron, proton, and heavy charged particle plasmas. Three modes are classified as the fast, intermediate, and slow mode waves according to different phase velocities. When plasmas contain positively-charged particles, the fast and intermediate modes can interact at the small propagating angles, whereas the two modes are separate at the large propagating angles. The near-parallel intermediate and slow waves experience the linear polarization, circular polarization, and linear polarization again, with the increasing wave number. The wave number regime corresponding to the above circular polarization shrinks as the propagating angle increases. Moreover, the fast and intermediate modes cause the reverse change of the electromagnetic polarization at the special wave number. While the heavy particles carry the negative charges, the dispersion relations of the fast and intermediate modes are always separate, being independent of the propagating angles. Furthermore, this study gives new expressions of the three resonance frequencies corresponding to the highly-oblique propagation waves in the general three-component plasmas, and shows the dependence of the resonance frequencies on the propagating angle, the concentration of the heavy particle, and the mass ratio among different kinds of particles.

Statistical Average of Spin Operators for Calculation of Three-Component Magnetization （II）： Solution of Equation

In this paper, the solution of Chebyshev equation with its argument being greater than 1 is obtained. The initial value of the derivative of the solution is the expression of magnetization, which is valid for any spin quantum number S. The Chebyshev equation is transformed from an ordinary differential equation obtained when we dealt with Heisenberg model, in order to calculate all three components of magnetization, by many-body Green＇s function under random phase approximation. The Chebyshev functions with argument being greater than 1 are discussed. This paper shows that the Chebyshev polynomials with their argument being greater than 1 have their physical application.

Dark and multi-dark solitons in the three-component nonlinear Schrodinger equations on the general nonzero background

We exhibit some new dark soliton phenomena on the general nonzero background for a defocusing three-component nonlinear Schrodinger equation. As the plane wave background undergoes unitary transformation SU(3), we obtain the general nonzero background and study its modulational instability by the linear stability analysis. On the basis of this background, we study the dynamics of one-dark soliton and two-dark-soliton phenomena, which are different from the dark solitons studied before. Furthermore, we use the numerical method for checking the stability of the one-dark-soliton solution. These results further enrich the content in nonlinear Schrodinger systems, and require more in-depth studies in the future.

Three-Component Coupling Catalyzed by Phosphine: Preparation of α-Amino γ-Oxo Acid Derivatives

The three-component coupling reaction of ethyl propiolate (1), phthalimide (2), and aldehyde (3) catalyzed by tripheny- lphosphine, was developed. A solution of an equivalent amount of 1 and 2 in benzaldehyde (3a) in the presence of 30 mol% of PPh3 was heated at 100?C for 48 h to give N-(1-ethoxycarbonyl-3-oxo-3-phenylpropyl)phthalimide (4a) in 83% yield. This reaction was thought to proceed via vinylphosphonium salt formed from the reaction of ethyl propiolate (1) with triphenylphosphine in situ.

Localized waves in three-component coupled nonlinear Schrdinger equation

We study the generalized Darboux transformation to the three-component coupled nonlinear Schr ¨odinger equation.First-and second-order localized waves are obtained by this technique.In first-order localized wave,we get the interactional solutions between first-order rogue wave and one-dark,one-bright soliton respectively.Meanwhile,the interactional solutions between one-breather and first-order rogue wave are also given.In second-order localized wave,one-dark-one-bright soliton together with second-order rogue wave is presented in the first component,and two-bright soliton together with second-order rogue wave are gained respectively in the other two components.Besides,we observe second-order rogue wave together with one-breather in three components.Moreover,by increasing the absolute values of two free parameters,the nonlinear waves merge with each other distinctly.These results further reveal the interesting dynamic structures of localized waves in the three-component coupled system.

Statistical Average of Spin Operators for Calculation of Three-Component Magnetization

When one wants to calculate all the three components of magnetization of Heisenberg model under random phase approximation, at least one of the components should be the solution of an ordinary differential equation. In this paper such an equation is established. It is argued that the general expressions of magnetization for any spin quantum number S suggested before are the solution of the ordinary differential equation.

Cooperative NHC/Photoredox Catalysis:Three-Component Reaction of Aroyl Fluorides,Styrenes and Oxalates

Cooperative NHC/photoredox catalysis has emerged as an important research field in recent years.Herein,this article describes the use of cesium salt derivatives of tert-alcohols as alkyl radical precursors in a three-component reaction with styrene and aromatic acyl fluorides to synthesizeα-arylalkyl aryl ketones.The aroyl fluoride reacts with the NHC catalyst,leading to the formation of an acyl azolium ion.This acyl azolium ion can then be reduced by the photoredox catalyst,generating the corresponding ketyl radical anion.The C-radical generated from oxalate oxidation undergoes an addition reaction with the styrene derivative,followed by cross-coupling of the addition radical with the ketone radical,which is fragmented by NHC to give the target ketone.

Metallaphotoredox-Catalyzed Three-Component Couplings for Practical Synthesis of Ureas and Carbamates

Ureas are widely used in drugs,materials and catalysts because of their diamide structure,which can form strong hydrogen bonds.Therefore,it is of great scientific significance to develop efficient and green methods for the synthesis of urea compounds,especially unsymmetrical ureas.Here,we have disclosed novel and highly efficient three-component coupling reactions of organic halides,sodium cyanate and amines enabled by nickel/photoredox dual catalysis for the preparation of unsymmetrical ureas.The reaction features simple and safe operations,broad substrate scopes,and product diversities.It allows the facile synthesis of N-aryl/vinyl ureas from readily available,user-friendly feedstocks under mild conditions(27 examples,36%—98%yields).In addition,this method is further derived to alcohols as nucleophiles to synthesize a series of carbamates(15 examples,40%—95%yields).The mechanism experiment shows that the isocyanate produced by the coupling of halide and sodium cyanate may be the key intermediate in this reaction.

Light-responsive Self-Immolative L-glutamic Acid-based Polyester Nanoparticles for Controlled Drug Release via Passerini Three-Component Polymerization

L-glutamic acid(LA)is a bio-based,non-toxic,environmentally friendly material derived from biomass.The present study reports the application of Passerini three-component polymerization(P-3CP)for the straightforward preparation of LA-based light-responsive polyesters(PLTDs)under mild conditions.PLTDs with molar masses up to 8500 g/mol and high yields exceeding 90%are obtained.The chemical structures and light-responsive self-immolative behavior of PLTDs are comprehensively characterized by employing ultraviolet-visible(UV-Vis)spectroscopy,size exclusion chromatography(SEC),nuclear magnetic resonance(NMR)spectroscopy,and liquid chromatography mass spectrometry(LC-MS).Meanwhile,monodisperse PLTD-based doxorubicin-loaded nanoparticles(PLTD-DOX-NP)(size=193 nm,PDI=0.018)are formulated by nanoprecipitation method.Upon light-induced depolymerization,the PLTD-DOX-NP undergoes rapid decomposition,resulting in a burst release of 80%cargo within 13 s.Furthermore,according to biological toxicity tests,the PLTD-NP possesses adequate biosafety,both before and after irradiation.Overall,the incorporation of P-3CP with biorenewable LA-based monomer adheres to the principles of green chemistry,significantly simplifying the synthetic pathway of light-responsive polymers.

A H_(4)SiW_(12)O_(40)-catalyzed three-component tandem reaction for the synthesis of 3,3-disubstituted isoindolinones

A H_(4)SiW_(12)O_(40)-catalyzed three-component tandem reaction of 2-acylbenzoic acids,primary amines and phosphine oxides to form 3,3-disubstituted isoindolinones was developed.By employing A H_(4)SiW_(12)O_(40)as the catalyst and dimethyl carbonate(DMC)as the solvent,a diverse range of 2-acylbenzoic acid derivatives and primary amines worked well to give the C3-phosphinoyl-functionalized 3,3-disubstituted isoindolinones with the yield range of 61%-87%.Advantages of this transformation include green catalyst and solvent,available starting materials,broad substrate scope,high efficiency and operational simplicity with water as the sole by-product.The strategy achieved an efficient and green molecular fragment assembly to access isoindolinones,which would provide opportunities for the synthesis of potential biologically active molecules in a green manner.

Three-Component Transformation of CO_(2),Propargyl Alcohols and Secondary Amines intoβ-Oxopropylcarbamates Promoted by a Noble Metal-Free Metal–Organic Framework Catalyst

The three-component reaction of CO_(2),propargyl alcohols,and secondary amines frequently applies noble metal or homogeneous catalysts,therefore it is necessary and important to seek a recyclable catalyst without noble metals for this reaction,despite the multitude of challenges.Herein,a unique framework{[Ce3(Cu4I4)2(CNA)8(DMF)8](NO3)}n(CuCe-CNA)with two kinds of metal cluster nodes[Ce3]and[Cu4I4]was synthesized,displaying high thermal and chemical stabilities.CuCe-CNA-300 was obtained by removing the coordinated DMF molecules with[Ce3]cluster at 300°C,in which more metal sites are exposed and the pores are enlarged,but the three-dimensional framework still remains intact.CuCe-CNA-300 can effectively catalyze the three-component reaction of 2-methyl-3-butyn-2-alcohol,CO_(2),and pyrrolidine toβ-oxopropylcarbamates with a yield of 98%under mild conditions,and the catalytic activity is higher than those of noble metal catalysts.Additionally,CuCe-CNA-300 exhibits high catalytic efficiency for various kinds of propargyl alcohols and secondary amines,and also shows good recyclability.Mechanistic studies suggest that theα-alkylidene cyclic carbonates derived from the cycloaddition of propargyl alcohols and CO_(2) are the intermediates,which further react with secondary amines through ammonolysis reaction to generateβ-oxopropylcarbamates.Importantly,this work may open a new avenue for the one-pot transformation of CO_(2) with two or more components into value-added chemicals activated by noble metal-free metal–organic frameworks catalysts.

Robust adaptive polarization analysis method for eliminating ground roll in 3C land seismics

To improve the data quality of converted waves, and better identify and suppress the strong ground-roll interference in three-component （3C） seismic recordings on land, we present an adaptive polarization filtering method, which can effectively separate the ground- roll interference by combining complex polarization and instantaneous polarization analysis. The ground roll noise is characterized by elliptical plane polarization, strong energy, low apparent velocity, and low frequency. After low-pass filtering of the 3C data input within a given time-window of the ground roll, the complex covariance matrix is decomposed using the sliding time window with overlapping data and length that depends on the dominant ground-roll frequency. The ground-roll model is established using the main eigenvectors, and the ground roll is detected and identified using the instantaneous polarization area attributes and average energy constraints of the ground-roll zone. Finally, the ground roll is subtracted. The threshold of the method is stable and easy to select, and offers good ground- roll detection. The method is a robust polarization filtering method. Model calculations and actual data indicate that the method can effectively identify and attenuate ground roll while preserving the effective signals.

Vector transformation and reduction to the pole for regional magnetic data with variable field direction

The vector transformation and pole reduction from the total-field anomaly are signifi cant for the interpretation.We examined these industry-standard processing procedures in the Fourier domain.We propose a novel iteration algorithm for regional magnetic anomalies transformations to derive the vertical-component data from the total-field measurements with the variation in the core-fi eld direction over the region.Additionally,we use the same algorithm to convert the calculated vertical-component data into the corresponding data at the pole and realize the processing of diff erential reduction to the pole(DRTP).Unlike Arkani-Hamed’s DRTP method,the two types of iterative algorithms have the same forms,and DRTP is realized by implementing this algorithm twice.The synthetic model’s calculation results show that the method has high accuracy,and the fi eld data processing confi rms its practicality.

Design and optimization of vector coil sensor suited to magnetometric resistivity method

Magnetometric resistivity(MMR)method is a new way to detect dam leakage.The coil sensor is generally used to collect data in geophysical exploration methods.Given the characteristics of accurate vector data requirements and high sensitivity requirement,a three-component MMR air-core coil sensor is designed.Through the analysis of sensor sensitivity and coil structure parameters,the coil structure and turn number are designed.By analyzing the noise source of the sensor,a suitable amplifier is selected to reduce the background noise of the system.Through the analysis of the three-component non-orthogonal angles,the parameters of the non-orthogonal angles of the coils are corrected.Finally,a three-component MMR induction magnetic field sensor is designed.The volume of the sensor is controlled at 0.027 m 3.The background noise of X、Y and Z are 5.030435 nV/Hz@380 Hz and magnetic field sensitivities are 0.18995 pT/Hz@380 Hz.The three channels have good consistency,and the three-component nonorthogonal angles correction error of three components is controlled within 0.2%.

Photocatalyst-free visible-light-mediated three-component reaction ofα-diazoesters, cyclic ethers and NaSCN to access organic thiocyanates

A facile and environmentally friendly visible-light-induced three-component reaction of α-diazoesters,cyclic ethers and Na SCN to construct organic thiocyanates has been developed at room temperature. This reaction could occur under photocatalyst-and additive-free conditions to afford a number of organic thiocyanates with moderate to good yield and favorable functional group tolerance.

Efficient One-pot Synthesis of Pyrrolo[2,1-a]isoquinoline and Pyrrolo[1,2-a]quinoline Derivatives

A one-pot sequential reaction for efficient synthesis of pyrrolo[2,1-a]isoquinoline and pyrrolo[1,2-a]quinoline derivatives has been developed.The reaction included firstly the Cu-catalyzed three-component reaction of isoquinoline（quinoline）,acetylenedicarboxylate and alkynylbenzene and then Cs 2 CO 3-promoted intramolecular cyclization reaction of initially formed 1-alkenyl-2-alkynyl-1,2-dihydroisoquinoline（1,2-dihydroquinoline）.

Assessment of Water Provenances in Koxkar Glacier Region at the South Slope of Mt. Tianshan,China

Various water samples were collected for electrical conductivity (EC) and δ^18O analysis,and the proportion and contribution of atmospheric precipitation,glacier ice and shallow groundwater to discharge in the Koxkar glacier basin at the south slope of the Tianshan Mountains were studied.The results show that glacial ice-water recharge was dominant,accounting for 72.11% of the annual runoff.It also had a significant positive correlation with temperature during the warm season (from May to September).However,glacier ice ablation replenishment still existed when the temperature in the cold season was below the critical temperature of 0 ℃.This could be that the heat generated by the friction between the ice body and the ice bed during the subglacial ice sliding process led ice to melt,what's more,the stored water in the geometric passages inside and below the glacier could slowly release.Groundwater recharge accounted for 16.38% of the total runoff.The supplement was small and its variation range was relatively small in the cold season.But in the warm season,the amount of groundwater recharge increased and changed drastically.It might be that the seasonal frozen soil in the basin was widely developed and was affected by temperature changes.Atmospheric precipitation replenishment only accounted for 11.51%.The daily precipitation recharge river water had a significant response to regional precipitation,but there was hysteresis in time,and there was still precipitation recharge runoff even in the absence of precipitation.

Polarization Filtering Method for Suppressing Surface Wave in Time-Frequency Domain

In order to suppress the surface wave in three-component seismic exploration, according to the polarization characteristics of body wave and surface wave, a time-frequency domain polarization filtering method based on wavelet transform was studied. A covariance matrix was constructed in the time-frequency domain for the three-component seismic data, measured the polarization parameters of seismic waves. Combining the corresponding eigenvalues and eigenvectors of the matrix, the elliptic rate and elevation angle were used as constraints, and the polarization filter function was built to separate the surface waves. The separated surface waves were inversely transformed and then were adaptively subtracted from the original records. After the polarization filtering suppressed the surface wave, the signal-to-noise ratio of the converted wave was effectively improved. It laid a good foundation for the next seismic data processing and seismic exploration development. The actual data processing results show that the method can effectively extract surface waves from three-component seismic records and avoid the interference of surface waves on seismic signals.