The 2D limit equilibrium method is widely used for slope stability analysis.However,with the advancement of dump engineering,composite slopes often exhibit significant 3D mechanical effects.Consequently,it is of signi...The 2D limit equilibrium method is widely used for slope stability analysis.However,with the advancement of dump engineering,composite slopes often exhibit significant 3D mechanical effects.Consequently,it is of significant importance to develop an effective 3D stability calculation method for composite slopes to enhance the design and stability control of open-pit slope engineering.Using the composite slope formed by the mining stope and inner dump in Baiyinhua No.1 and No.2 open-pit coal mine as a case study,this research investigates the failure mode of composite slopes and establishes spatial shape equations for the sliding mass.By integrating the shear resistance and sliding force of each row of microstrip columns onto the bottom surface of the strip corresponding to the main sliding surface,a novel 2D equivalent physical and mechanical parameters analysis method for the strips on the main sliding surface of 3D sliding masses is proposed.Subsequently,a comprehensive 3D stability calculation method for composite slopes is developed,and the quantitative relationship between the coordinated development distance and its 3D stability coefficients is examined.The analysis reveals that the failure mode of the composite slope is characterized by cutting-bedding sliding,with the arc serving as the side interface and the weak layer as the bottom interface,while the destabilization mechanism primarily involves shear failure.The spatial form equation of the sliding mass comprises an ellipsoid and weak plane equation.The analysis revealed that when the coordinated development distance is 1500 m,the error rate between the 3D stability calculation result and the 2D stability calculation result of the composite slope is less than 8%,thereby verifying the proposed analytical method of equivalent physical and mechanical parameters and the 3D stability calculation method for composite slopes.Furthermore,the3D stability coefficient of the composite slope exhibits an exponential correlation with the coordinated development distance,with the coefficient gradually decreasing as the coordinated development distance increases.These findings provide a theoretical guideline for designing similar slope shape parameters and conducting stability analysis.展开更多
To objectively obtain the three-dimensional coordinates of the projectile fuze proximity explosion when projectile intersects the head of missile target, we propose a dynamic seven photoelectric detection screen test ...To objectively obtain the three-dimensional coordinates of the projectile fuze proximity explosion when projectile intersects the head of missile target, we propose a dynamic seven photoelectric detection screen test method, which is made up of six plane detection screens and a flash photoelectric dynamic detection screen. The three-dimensional coordinates calculation model of the projectile proximity explosion position based on seven plane detection screens with dynamic characteristics is established.According to the relation of the dynamic seven photoelectric detection screen planes and the time values,the analytical function of the projectile proximity explosion position parameters under non-linear motion is derived. The projectile signal filtering method based on discrete wavelet transform is explored in this work. Additionally, the projectile signal recognition algorithm using an improved particle swarm is proposed. Based on the characteristics of the time duration and the signal peak error for the projectile passing through the detection screen, the signals attribution of the same projectile passing through six detection screens are analyzed for obtaining precise time values of the same projectile passing through the detection screens. On the basis of the projectile fuze proximity explosion test, the linear motion model and the proposed non-linear motion model are used to calculate and compare the same group of projectiles proximity explosion position parameters. The comparison of test results verifies that the proposed test method and calculation model in this work accurately obtain the actual projectile proximity explosion position parameters.展开更多
In this paper, the axial-flux permanent magnet driver is modeledand analyzed in a simple and novel way under three-dimensional cylindricalcoordinates. The inherent three-dimensional characteristics of the deviceare co...In this paper, the axial-flux permanent magnet driver is modeledand analyzed in a simple and novel way under three-dimensional cylindricalcoordinates. The inherent three-dimensional characteristics of the deviceare comprehensively considered, and the governing equations are solved bysimplifying the boundary conditions. The axial magnetization of the sectorshapedpermanent magnets is accurately described in an algebraic form bythe parameters, which makes the physical meaning more explicit than thepurely mathematical expression in general series forms. The parameters of theBessel function are determined simply and the magnetic field distribution ofpermanent magnets and the air-gap is solved. Furthermore, the field solutionsare completely analytical, which provides convenience and satisfactoryaccuracy for modeling a series of electromagnetic performance parameters,such as the axial electromagnetic force density, axial electromagnetic force,and electromagnetic torque. The correctness and accuracy of the analyticalmodels are fully verified by three-dimensional finite element simulations and a15 kW prototype and the results of calculations, simulations, and experimentsunder three methods are highly consistent. The influence of several designparameters on magnetic field distribution and performance is studied and discussed.The results indicate that the modeling method proposed in this papercan calculate the magnetic field distribution and performance accurately andrapidly, which affords an important reference for the design and optimizationof axial-flux permanent magnet drivers.展开更多
A three-dimensional coordination polymer [Mn2(μ1.3-N3)4(μ-PP)2]n (PP = 3-(pyrazin-2-yloxy)-pyridine) has been synthesized with 3-(pyrazin-2-yloxy)-pyridine and azide anion as mixed bridge ligand, and its c...A three-dimensional coordination polymer [Mn2(μ1.3-N3)4(μ-PP)2]n (PP = 3-(pyrazin-2-yloxy)-pyridine) has been synthesized with 3-(pyrazin-2-yloxy)-pyridine and azide anion as mixed bridge ligand, and its crystal structure was determined by X-ray crystallography. The crystal data: triclinic system, space group P1, with a = 6.794(4), b = 9.885(6), c = 9.947(6) A, α = 64.170(6), β= 84.190(8), γ= 85.319(8)°, V = 597.7(6)A^3, Z = 1, C18H14Mn2N18O2, Mr = 624.35, Dc = 1.735 g/cm^3, F(000) = 314 and μ = 1.117 mm^-1. In the crystal, the azide anion acts as a bridge ligand and makes adjacent Mn(Ⅱ) ions connect into a two-dimensional sheet on the ab plane, then 3-(pyrazin-2-yloxy)-pyridine serves as a bidentate bridge ligand to connect neighboring sheets along展开更多
The characteristics of three-dimensional (3-D) tidal current in the Oujiang Estuary are investigated according to in situ observations. The Oujiang Estuary has features of irregular coastline, complex topography, ma...The characteristics of three-dimensional (3-D) tidal current in the Oujiang Estuary are investigated according to in situ observations. The Oujiang Estuary has features of irregular coastline, complex topography, many islands, moveable boundary, and submerged dyke, therefore, σ 3-D numerical model oil an unstructured triangular grid has been degeloped. The σ coordinate transforination, the moveable boundary and submerged dyke treatment techniques were employed in the model so it is suitable for the tidal simulations in the Oujing Estuary with submerged dyke and moveable boundary problems. The model is evaluated with the in situ data, and the results show that the calculated water elevations at 19 stations and currents at 19 profiler stations are in good agreement with measured data both in magnitude and phase. This numerical model is applied to the 3-D tidal circulation simulations of experiments in stopping flow transport through the South Branch of the Oujiang Estuary, and the feasibility to cutoff the flow in the South Branch of the Oujiang Estuary is demonstrated by numerical simulation experiments. The developed numerical model simulated the 3-D tidal current circulations in complicated coastal and estuarine waters very well.展开更多
GNSS(global navigation satellite system)observations produce the geodetic position including latitude,longitude,and altitude(or ellipsoidal height)concerning the global reference datum WGS84(Word Geodetic System 1984)...GNSS(global navigation satellite system)observations produce the geodetic position including latitude,longitude,and altitude(or ellipsoidal height)concerning the global reference datum WGS84(Word Geodetic System 1984),which usually should be converted to another local datum to get the desired position meaning in a physical sense,coordinates of points in the local datum are usually calculated by the seven-parameter transformation method.This paper aims to validate the methods of position transformation between WGS84 and the Iraqi local datum Karbala 1979 using the UTM(universal transverse Mercator)projected coordinates directly.The proposed algorithm was tested for 10 ground control points in Erbil city and many selected points in other different cities over all Iraqi territory.The control points are measured by the CHCNAV i73 GNSS receiver.For the evaluation procedure,the RMSE(root mean square error)of the transformed coordinates is calculated with an average value of±10.715 m as an estimated uncertainty of the direct UTM coordinates transformation method over Erbil city territory,and more than±12 m over different places over Iraqi territory.展开更多
This paper presents a new method for extract three-dimensional (3D) discrete spherical Fourier descriptors based on surface curvature voxels for pollen particle recognition. In order to reduce the high amount of pol...This paper presents a new method for extract three-dimensional (3D) discrete spherical Fourier descriptors based on surface curvature voxels for pollen particle recognition. In order to reduce the high amount of pollen information and noise disturbance, the geometric normalized curvature voxels with the principal curvedness are first extracted to represent the intrinsic pollen volumetric data. Then the curvature voxels are decomposed into radial and angular components with spherical harmonic transform in spherical coordinates. Finally the 3D discrete Fourier transform is applied to the decomposed curvature voxels to obtain the 3D spherical Fourier descriptors for pollen recognition. Experimental results show that the presented descriptors are invariant to different pollen particle geometric transformations, such as pose change and spatial rotation, and can obtain high recognition accuracy and speed simultaneously.展开更多
To aim at the substitution of the magnitude and direction of water flow movement near bed for those of bed load transport in solid-liquid two-phase one-fluid model, and to simulate the effect of secondary flow on tran...To aim at the substitution of the magnitude and direction of water flow movement near bed for those of bed load transport in solid-liquid two-phase one-fluid model, and to simulate the effect of secondary flow on transverse bed load transport in channel bends and the effect of bed slope on bed load trans- port in a better way, a three-dimensional k-ε-kp solid-liquid two-phase two-fluid model in curvilinear coordinates is solved numerically with a finite-volume method on an adaptive grid for studying wa- ter-sediment movements and bed evolution in a 120° channel bend. Numerical results show that the trajectories of solid-phase deviate from those of liquid-phase in the channel bend, and the deviation increases with the increase of the particle diameters. The calculated bed deformation by the k-ε-kp model is in better agreement with measured bed deformation than those by one-fluid model. It is proved that the k-ε-kp model can simulate the effect of secondary flow on lateral bed load transport with the higher accuracy than the one-fluid model.展开更多
A new three-dimensional Zn(II) coordination polymer, namely [Zn4(bpydb)3(tz)2(H2O)2]n(1), has been synthesized by the self-assembly reactions of Zn(NO3)2·6H2O, bpydb H2, Htz and DMF. Single-crystal X-...A new three-dimensional Zn(II) coordination polymer, namely [Zn4(bpydb)3(tz)2(H2O)2]n(1), has been synthesized by the self-assembly reactions of Zn(NO3)2·6H2O, bpydb H2, Htz and DMF. Single-crystal X-ray structural analysis reveals that compound 1 features a three-dimensional framework structure and is the first example of Zn-containing coordination polymers based on two kinds of ligands bpydb H2 and Htz. It crystallizes in triclinic, space group P1 with a = 14.9953(12), b = 17.5335(17), c = 20.2381(11)A, α = 115.225(7), β = 92.329(5), γ = 105.606(8)o, V = 4561.9(7) A^3, Z = 2, F(000) = 1644, Dc = 1.177 Mg/m^3, Mr = 1616.76 and μ = 1.098 mm^-1. The antitumor activities of compound 1 and its corresponding organic ligands(bpydb H2 and Htz) were investigated for inhibiting human osteosarcoma cells(MG-63 and U-2 OS) growth by MTT assay. It was found that compared with the two ligands, compound 1 exerted rather potent activities against all of these cell lines.展开更多
A novel coordination polymer [Eu2(C6H8O4)3(H2O)2]n?n(4,4?-bpy) (Mr = 928.51) was synthesized by the hydrothermal reaction of EuCl3?6H2O, adipic acid and 4,4?-bpy, and determined by elemental analysis, IR spectroscop...A novel coordination polymer [Eu2(C6H8O4)3(H2O)2]n?n(4,4?-bpy) (Mr = 928.51) was synthesized by the hydrothermal reaction of EuCl3?6H2O, adipic acid and 4,4?-bpy, and determined by elemental analysis, IR spectroscopy, thermal gravimetric analysis, single-crystal diffraction and fluorescence property. X-ray analysis reveals that a three-dimensional network has been formed between Eu3+ by carboxyl of adipic acid. The crystal is of orthorhombic, space group Pbcn with a = 21.870(7), b = 7.652(2), c = 19.624(6) ?, V = 3284.1(17) ?3, Z = 4, Dc = 1.878 g/cm3, μ = 3.854 mm-1, F(000) = 1824, R = 0.0345 and wR = 0.0565. The coordination polymer exhibits intensive red light under UV excitation at room temperature, which is attributed to the 5D0→7F2 transition of Eu(Ⅲ) ions.展开更多
Compared with ground first aid, aviation medical rescue has better advantages in mountain disaster relief, remote transfer and rapid medical rescue response, which is an effective supplement to ground medical first ai...Compared with ground first aid, aviation medical rescue has better advantages in mountain disaster relief, remote transfer and rapid medical rescue response, which is an effective supplement to ground medical first aid. China’s aviation medical rescue is in its infancy, compared with the level of developed countries there is a big gap. Based on the development and characteristics of aviation medical rescue in China, this paper combs the process of air-ground cooperative rescue, analyzes the demand and current situation of air-ground cooperative rescue in aviation medical rescue in China, and puts forward some countermeasures to improve the ability of aviation medical rescue in China.展开更多
In order to get an effective solution of the in-flight wing deformation measurement for high-wing aircrafts with high-aspect-ratio,a method based on three-dimensional(3D)speckle correlation technique is proposed.First...In order to get an effective solution of the in-flight wing deformation measurement for high-wing aircrafts with high-aspect-ratio,a method based on three-dimensional(3D)speckle correlation technique is proposed.Firstly,an in-flight wing deformation measurement system with two sets of conjugate cameras is designed based on structural characteristics and test requirements of high-wing aircrafts with large-aspect-ratio.Secondly,the in-flight wing deformation measurement method based on 3D speckle correlation technique is introduced including three aspects:measuring system and wing datum calibration,speckle image matching and 3D reconstruction,and wing deformation analysis.Fi-nally,ground simulation test of dynamic deformation measurement of a scaled model wing and flight test of dynamic deformation measurement of a large transport wing are carried out.The test results show that the measuring accuracy of single point coordinate in ground simulation test is better than 0.1 mm/m,in the airborne vibration environment,the static single-point positioning accuracy is bet-ter than 5 mm,and the in-flight wing deformation measurement data is well received by the flight test engineers.This method can satisfy the requirements of stability,reliability,high precision,non-con-tact and full-field measurement for dynamic deformation measurement of aircraft wing with high-as-pect-ratio.展开更多
基金supported by the National Natural Science Foundation of China (No.52374124)National Youth Science Foundation of China (No.52204135)+3 种基金Xing Liao Talent Plan (No.XLYC2202004)Young Elite Scientists Sponsorship Program by CAST (No.2023QNRC001)Liaoning Province International Science and Technology Cooperation Plan (No.2022JH2/1070004)Liaoning Natural Science Foundation Program (No.2022-BS-327)。
文摘The 2D limit equilibrium method is widely used for slope stability analysis.However,with the advancement of dump engineering,composite slopes often exhibit significant 3D mechanical effects.Consequently,it is of significant importance to develop an effective 3D stability calculation method for composite slopes to enhance the design and stability control of open-pit slope engineering.Using the composite slope formed by the mining stope and inner dump in Baiyinhua No.1 and No.2 open-pit coal mine as a case study,this research investigates the failure mode of composite slopes and establishes spatial shape equations for the sliding mass.By integrating the shear resistance and sliding force of each row of microstrip columns onto the bottom surface of the strip corresponding to the main sliding surface,a novel 2D equivalent physical and mechanical parameters analysis method for the strips on the main sliding surface of 3D sliding masses is proposed.Subsequently,a comprehensive 3D stability calculation method for composite slopes is developed,and the quantitative relationship between the coordinated development distance and its 3D stability coefficients is examined.The analysis reveals that the failure mode of the composite slope is characterized by cutting-bedding sliding,with the arc serving as the side interface and the weak layer as the bottom interface,while the destabilization mechanism primarily involves shear failure.The spatial form equation of the sliding mass comprises an ellipsoid and weak plane equation.The analysis revealed that when the coordinated development distance is 1500 m,the error rate between the 3D stability calculation result and the 2D stability calculation result of the composite slope is less than 8%,thereby verifying the proposed analytical method of equivalent physical and mechanical parameters and the 3D stability calculation method for composite slopes.Furthermore,the3D stability coefficient of the composite slope exhibits an exponential correlation with the coordinated development distance,with the coefficient gradually decreasing as the coordinated development distance increases.These findings provide a theoretical guideline for designing similar slope shape parameters and conducting stability analysis.
基金supported by Project of the National Natural Science Foundation of China (No.62073256, 61773305)the Key Science and Technology Program of Shaanxi Province (No.2020GY-125)Xi’an Science and Technology Innovation talent service enterprise project (No.2020KJRC0041)。
文摘To objectively obtain the three-dimensional coordinates of the projectile fuze proximity explosion when projectile intersects the head of missile target, we propose a dynamic seven photoelectric detection screen test method, which is made up of six plane detection screens and a flash photoelectric dynamic detection screen. The three-dimensional coordinates calculation model of the projectile proximity explosion position based on seven plane detection screens with dynamic characteristics is established.According to the relation of the dynamic seven photoelectric detection screen planes and the time values,the analytical function of the projectile proximity explosion position parameters under non-linear motion is derived. The projectile signal filtering method based on discrete wavelet transform is explored in this work. Additionally, the projectile signal recognition algorithm using an improved particle swarm is proposed. Based on the characteristics of the time duration and the signal peak error for the projectile passing through the detection screen, the signals attribution of the same projectile passing through six detection screens are analyzed for obtaining precise time values of the same projectile passing through the detection screens. On the basis of the projectile fuze proximity explosion test, the linear motion model and the proposed non-linear motion model are used to calculate and compare the same group of projectiles proximity explosion position parameters. The comparison of test results verifies that the proposed test method and calculation model in this work accurately obtain the actual projectile proximity explosion position parameters.
基金supported by the National Natural Science Foundation of China under Grant[52077027]Liaoning Province Science and Technology Major Project[No.2020JH1/10100020].
文摘In this paper, the axial-flux permanent magnet driver is modeledand analyzed in a simple and novel way under three-dimensional cylindricalcoordinates. The inherent three-dimensional characteristics of the deviceare comprehensively considered, and the governing equations are solved bysimplifying the boundary conditions. The axial magnetization of the sectorshapedpermanent magnets is accurately described in an algebraic form bythe parameters, which makes the physical meaning more explicit than thepurely mathematical expression in general series forms. The parameters of theBessel function are determined simply and the magnetic field distribution ofpermanent magnets and the air-gap is solved. Furthermore, the field solutionsare completely analytical, which provides convenience and satisfactoryaccuracy for modeling a series of electromagnetic performance parameters,such as the axial electromagnetic force density, axial electromagnetic force,and electromagnetic torque. The correctness and accuracy of the analyticalmodels are fully verified by three-dimensional finite element simulations and a15 kW prototype and the results of calculations, simulations, and experimentsunder three methods are highly consistent. The influence of several designparameters on magnetic field distribution and performance is studied and discussed.The results indicate that the modeling method proposed in this papercan calculate the magnetic field distribution and performance accurately andrapidly, which affords an important reference for the design and optimizationof axial-flux permanent magnet drivers.
基金Supported by the National Natural Science Foundation of China (No. 20271043)Natural Science Foundation of Shandong Province (Y2007B26)
文摘A three-dimensional coordination polymer [Mn2(μ1.3-N3)4(μ-PP)2]n (PP = 3-(pyrazin-2-yloxy)-pyridine) has been synthesized with 3-(pyrazin-2-yloxy)-pyridine and azide anion as mixed bridge ligand, and its crystal structure was determined by X-ray crystallography. The crystal data: triclinic system, space group P1, with a = 6.794(4), b = 9.885(6), c = 9.947(6) A, α = 64.170(6), β= 84.190(8), γ= 85.319(8)°, V = 597.7(6)A^3, Z = 1, C18H14Mn2N18O2, Mr = 624.35, Dc = 1.735 g/cm^3, F(000) = 314 and μ = 1.117 mm^-1. In the crystal, the azide anion acts as a bridge ligand and makes adjacent Mn(Ⅱ) ions connect into a two-dimensional sheet on the ab plane, then 3-(pyrazin-2-yloxy)-pyridine serves as a bidentate bridge ligand to connect neighboring sheets along
基金The Natural Science Foundation of Tianjin, China under contract No.08JCZDZT00200
文摘The characteristics of three-dimensional (3-D) tidal current in the Oujiang Estuary are investigated according to in situ observations. The Oujiang Estuary has features of irregular coastline, complex topography, many islands, moveable boundary, and submerged dyke, therefore, σ 3-D numerical model oil an unstructured triangular grid has been degeloped. The σ coordinate transforination, the moveable boundary and submerged dyke treatment techniques were employed in the model so it is suitable for the tidal simulations in the Oujing Estuary with submerged dyke and moveable boundary problems. The model is evaluated with the in situ data, and the results show that the calculated water elevations at 19 stations and currents at 19 profiler stations are in good agreement with measured data both in magnitude and phase. This numerical model is applied to the 3-D tidal circulation simulations of experiments in stopping flow transport through the South Branch of the Oujiang Estuary, and the feasibility to cutoff the flow in the South Branch of the Oujiang Estuary is demonstrated by numerical simulation experiments. The developed numerical model simulated the 3-D tidal current circulations in complicated coastal and estuarine waters very well.
文摘GNSS(global navigation satellite system)observations produce the geodetic position including latitude,longitude,and altitude(or ellipsoidal height)concerning the global reference datum WGS84(Word Geodetic System 1984),which usually should be converted to another local datum to get the desired position meaning in a physical sense,coordinates of points in the local datum are usually calculated by the seven-parameter transformation method.This paper aims to validate the methods of position transformation between WGS84 and the Iraqi local datum Karbala 1979 using the UTM(universal transverse Mercator)projected coordinates directly.The proposed algorithm was tested for 10 ground control points in Erbil city and many selected points in other different cities over all Iraqi territory.The control points are measured by the CHCNAV i73 GNSS receiver.For the evaluation procedure,the RMSE(root mean square error)of the transformed coordinates is calculated with an average value of±10.715 m as an estimated uncertainty of the direct UTM coordinates transformation method over Erbil city territory,and more than±12 m over different places over Iraqi territory.
基金Project supported by the National Natural Science Foundation of China (Grant No. 60472061)the Natural Science Foundation of Jiangsu Province,China (Grant No. BK20090149)the Natural Science Foundation of Higher Education Institutions of Jiangsu Province,China (Grant No. 08KJD520019).
文摘This paper presents a new method for extract three-dimensional (3D) discrete spherical Fourier descriptors based on surface curvature voxels for pollen particle recognition. In order to reduce the high amount of pollen information and noise disturbance, the geometric normalized curvature voxels with the principal curvedness are first extracted to represent the intrinsic pollen volumetric data. Then the curvature voxels are decomposed into radial and angular components with spherical harmonic transform in spherical coordinates. Finally the 3D discrete Fourier transform is applied to the decomposed curvature voxels to obtain the 3D spherical Fourier descriptors for pollen recognition. Experimental results show that the presented descriptors are invariant to different pollen particle geometric transformations, such as pose change and spatial rotation, and can obtain high recognition accuracy and speed simultaneously.
基金Supported by the National Natural Science Foundation of China (Grant No. 50839001)the National Basic Research Program of China ("973") (Grant No. 2005CB724202)
文摘To aim at the substitution of the magnitude and direction of water flow movement near bed for those of bed load transport in solid-liquid two-phase one-fluid model, and to simulate the effect of secondary flow on transverse bed load transport in channel bends and the effect of bed slope on bed load trans- port in a better way, a three-dimensional k-ε-kp solid-liquid two-phase two-fluid model in curvilinear coordinates is solved numerically with a finite-volume method on an adaptive grid for studying wa- ter-sediment movements and bed evolution in a 120° channel bend. Numerical results show that the trajectories of solid-phase deviate from those of liquid-phase in the channel bend, and the deviation increases with the increase of the particle diameters. The calculated bed deformation by the k-ε-kp model is in better agreement with measured bed deformation than those by one-fluid model. It is proved that the k-ε-kp model can simulate the effect of secondary flow on lateral bed load transport with the higher accuracy than the one-fluid model.
文摘A new three-dimensional Zn(II) coordination polymer, namely [Zn4(bpydb)3(tz)2(H2O)2]n(1), has been synthesized by the self-assembly reactions of Zn(NO3)2·6H2O, bpydb H2, Htz and DMF. Single-crystal X-ray structural analysis reveals that compound 1 features a three-dimensional framework structure and is the first example of Zn-containing coordination polymers based on two kinds of ligands bpydb H2 and Htz. It crystallizes in triclinic, space group P1 with a = 14.9953(12), b = 17.5335(17), c = 20.2381(11)A, α = 115.225(7), β = 92.329(5), γ = 105.606(8)o, V = 4561.9(7) A^3, Z = 2, F(000) = 1644, Dc = 1.177 Mg/m^3, Mr = 1616.76 and μ = 1.098 mm^-1. The antitumor activities of compound 1 and its corresponding organic ligands(bpydb H2 and Htz) were investigated for inhibiting human osteosarcoma cells(MG-63 and U-2 OS) growth by MTT assay. It was found that compared with the two ligands, compound 1 exerted rather potent activities against all of these cell lines.
基金The project was supported by the Natural Science Foundation of Hebei Province (No. F2004000130)
文摘A novel coordination polymer [Eu2(C6H8O4)3(H2O)2]n?n(4,4?-bpy) (Mr = 928.51) was synthesized by the hydrothermal reaction of EuCl3?6H2O, adipic acid and 4,4?-bpy, and determined by elemental analysis, IR spectroscopy, thermal gravimetric analysis, single-crystal diffraction and fluorescence property. X-ray analysis reveals that a three-dimensional network has been formed between Eu3+ by carboxyl of adipic acid. The crystal is of orthorhombic, space group Pbcn with a = 21.870(7), b = 7.652(2), c = 19.624(6) ?, V = 3284.1(17) ?3, Z = 4, Dc = 1.878 g/cm3, μ = 3.854 mm-1, F(000) = 1824, R = 0.0345 and wR = 0.0565. The coordination polymer exhibits intensive red light under UV excitation at room temperature, which is attributed to the 5D0→7F2 transition of Eu(Ⅲ) ions.
文摘Compared with ground first aid, aviation medical rescue has better advantages in mountain disaster relief, remote transfer and rapid medical rescue response, which is an effective supplement to ground medical first aid. China’s aviation medical rescue is in its infancy, compared with the level of developed countries there is a big gap. Based on the development and characteristics of aviation medical rescue in China, this paper combs the process of air-ground cooperative rescue, analyzes the demand and current situation of air-ground cooperative rescue in aviation medical rescue in China, and puts forward some countermeasures to improve the ability of aviation medical rescue in China.
基金Supported by the National Natural Science Foundation of China(No.62271400).
文摘In order to get an effective solution of the in-flight wing deformation measurement for high-wing aircrafts with high-aspect-ratio,a method based on three-dimensional(3D)speckle correlation technique is proposed.Firstly,an in-flight wing deformation measurement system with two sets of conjugate cameras is designed based on structural characteristics and test requirements of high-wing aircrafts with large-aspect-ratio.Secondly,the in-flight wing deformation measurement method based on 3D speckle correlation technique is introduced including three aspects:measuring system and wing datum calibration,speckle image matching and 3D reconstruction,and wing deformation analysis.Fi-nally,ground simulation test of dynamic deformation measurement of a scaled model wing and flight test of dynamic deformation measurement of a large transport wing are carried out.The test results show that the measuring accuracy of single point coordinate in ground simulation test is better than 0.1 mm/m,in the airborne vibration environment,the static single-point positioning accuracy is bet-ter than 5 mm,and the in-flight wing deformation measurement data is well received by the flight test engineers.This method can satisfy the requirements of stability,reliability,high precision,non-con-tact and full-field measurement for dynamic deformation measurement of aircraft wing with high-as-pect-ratio.