Shallow velocity structure of the Luoyang basin derived from dense array observations of urban ambient noise

Determining the shallow structure of a sediment basin is important when evaluating potential seismic hazards given that such basins can significantly amplify seismic energy. The Luoyang basin is located in the western He’nan uplift and is a Meso-Cenozoic depression basin. To characterize the shallow structure of the basin, we develop a model of the shallow high-resolution three-dimensional(3D)shear-wave velocity structure of the basin by applying ambient noise tomography to a dense array of 107 portable digital seismometers deployed over the basin. More than 1,400 Rayleigh-wave dispersion curves for periods in the range 0.5–5 s are extracted. The 3D variations of shear-wave velocity in the shallow crust are inverted using a direct surface-wave tomographic method with period-dependent ray tracing, with all the surface-wave group-velocity dispersion data being inverted simultaneously. The results show that in the shallow crust of the study area, the velocity distribution corresponds to surface geology and geological features. The Luoyang basin exhibits a low shear-wave velocity feature that is consistent with the distribution of sediment in the region,while the Xiongershan and Songshan uplifts exhibit higher shear-wave velocity structures. The results provide a shallow high-resolution 3D velocity model that can be used as a basis for simulation of strong ground motion and evaluation of potential seismic hazards.

1344吡啶羧酸配体构筑的Cu(Ⅱ)-MOFs及其染料吸附降解性能

为探究不同反应条件对MOFs微观结构和宏观性能的影响,在不同反应条件下,以硫酸铜(CuSO_(4)·5H_(2)O)和6-(吡啶-3′-基)间苯二甲酸(H_(2)L)为材料,制备了2种金属有机框架材料(MOFs){[Cu_(2)(L)_(2)·C _(2) H _(3) N]}n(1)和{[Cu(HL)_(2)]}n(2),并对合成的金属有机框架材料1和2进行了结构分析、TGA和FTIR表征以及对染料的吸附性能研究。单晶衍射数据分析表明:配合物1和2都属单斜晶系,P 21/c空间群。配合物1是一种基于双核轮桨次级构筑单元[Cu_(2)(COO)_(4)]构筑的三维紧密堆积化合物,配合物2由于配体部分质子化,结构中存在氢键[O_(3)—H…O_(4)],将二维层状网络结构连接成三维结构。配合物1是rtl拓扑类型的网络结构,拓扑符号为(42.610.83);配合物2是sql拓扑类型的网络结构,拓扑符号为(4^(4).6^(2))。2种配合物在相同时间间隔下对不同染料降解性能表明配合物2对水溶液中的孔雀石绿具有一定的化学吸附降解能力。

泡沫混凝土气孔结构数学表征及其分析

为分析泡沫混凝土孔结构表征参数之间的关系和气孔结构特点,建立了紧密堆积模型和非紧密堆积模型,基于不同的理论模型推导了孔结构主要参数包括孔隙率、气孔内表面积、气孔壁厚度的计算公式,分析各参数之间的关系;通过实测泡沫混凝土的孔结构参数,验证了计算公式的可行性,并将计算公式应用于泡沫混凝土孔结构特征分析.研究结果表明:当容重等级小于1 000 kg/m3时,泡沫混凝土形成的气孔结构为紧密堆积型结构,气孔壁厚计算结果与统计结果偏差在12%以内,验证了紧密堆积型结构计算公式的可行性;当容重等级大于或等于1 000 kg/m3时,泡沫混凝土形成的气孔结构为非紧密堆积型结构,气孔壁厚计算结果与统计结果偏差在3%以内,验证了非紧密堆积型结构计算公式的可行性;在相同容重下,气孔壁厚度随气孔直径的增大而增大,随孔隙率的增大而减小;1 m3泡沫混凝土的气孔内表面积可达到3 000 m2以上,气孔壁厚可低至60μm以下,泡沫混凝土具有多孔薄壁、小体积物料与大体积的气孔空气共存于一体、小体积物料以巨大的面积暴露在气孔的气体之中的结构特征.

再生微粉颗粒级配对水泥凝胶体微观结构及强度的影响

基于Andreasen颗粒紧密堆积理论,探究再生微粉的颗粒级配对水泥凝胶体微观结构及强度的影响。将经过不同时间球磨的再生微粉以相同取代率掺入水泥砂浆中,考察水泥凝胶体中粉体材料的颗粒粒径分布变化与砂浆强度、水泥石孔隙结构及微观形貌的变化关系。结果表明:随着粉磨时间的增加,水泥凝胶体中粉体材料的颗粒级配得到改善,小于10μm的颗粒数量不断增加,这部分超细颗粒用于砂浆中可以填充到水泥浆体的孔隙中,改善水泥凝胶体的微观结构。采用球磨30 min的再生微料制备的砂浆比未经粉磨再生微粉的砂浆总孔隙率增加18.2%,而平均孔径降低51.9%,小于20 nm的无害孔的数量增加25%,孔结构得到改善,水泥石结构趋于密实,砂浆28 d后抗压强度达到43.9 MPa。