The study of Frequency Selective Surface(FSS)by Direct ink writing(DIW)has attracted much attention due to the convenience and effectiveness of 3D printing technology.However,the limited printing precision of DIW has ...The study of Frequency Selective Surface(FSS)by Direct ink writing(DIW)has attracted much attention due to the convenience and effectiveness of 3D printing technology.However,the limited printing precision of DIW has heavily restricted its applications as the electromagnetic performance is highly sensitive to it,especially the precision at the microscale.Herein,the ultra-high printing precision of FSS was achieved through DIW by the uniformly dispersed graphene sheets to deeply modify the rheological behavior and the steric hindrance effect.Thus,the highly precision of the printed filament width as thin as67μm with a space of only 42μm were achieved,which is difficult for conventional DIW,and no structural distortion is found after 3D printing,no matter it was 2D printed on a flat surface or the sharply skewed hook face,or even 3D printed to architectural structures.According to the highly improved precision,the electromagnetic performance matching between the designed model and the printed physical FSS device was perfectly achieved,reducing the center frequency error less than 0.3 GHz,and the transmission coefficient error less than 0.046.Our work promises an effective and easy preparation of high-quality FSS from the aid of graphene.展开更多
Assembling two-dimensional(2D)sheets into macroscopic three-dimensional(3D)forms has created a promising material family with rich functionalities.Multiscale wrinkles are intrinsic features of 2D sheets in their 3D as...Assembling two-dimensional(2D)sheets into macroscopic three-dimensional(3D)forms has created a promising material family with rich functionalities.Multiscale wrinkles are intrinsic features of 2D sheets in their 3D assembles.Therefore,the precise wrinkling modulation optimizes the transition of outstanding properties of 2D sheets to expected performances of assembled materials and dominates their fabrication process.The wrinkling evolution of 2D sheets assembling onto flat surfaces has been extensively understood,however,the wrinkling behaviors on the more generally curved surface still remain unclear.Here,we investigate the wrinkling behaviors of graphene oxide sheets assembled onto curved surfaces and reveal the selection rule of wrinkling modes that determined by the curvature mismatch between 2D sheets and target surfaces.We uncover that three wrinkling modes including isotropic cracked land,labyrinth,and anisotropic curtain phases,respectively emerge on flat,spherical,and cylindrical surfaces.A favorable description paradigm is offered to quantitatively measure the complex wrinkling patterns and assess the curvature mismatch constraint underlying the wrinkling mode selection.This research provides a general and quantitative description framework of wrinkling modulation of 2D materials such as high performance graphene fibers,and guides the precise fabrication of particles and functional coatings.展开更多
基金financially supported by the National Natural Science Foundation of China(No.51972079)the National Key Research and Development Program of China(Nos.2017YFB0310400 and 2017YFB0310402)。
文摘The study of Frequency Selective Surface(FSS)by Direct ink writing(DIW)has attracted much attention due to the convenience and effectiveness of 3D printing technology.However,the limited printing precision of DIW has heavily restricted its applications as the electromagnetic performance is highly sensitive to it,especially the precision at the microscale.Herein,the ultra-high printing precision of FSS was achieved through DIW by the uniformly dispersed graphene sheets to deeply modify the rheological behavior and the steric hindrance effect.Thus,the highly precision of the printed filament width as thin as67μm with a space of only 42μm were achieved,which is difficult for conventional DIW,and no structural distortion is found after 3D printing,no matter it was 2D printed on a flat surface or the sharply skewed hook face,or even 3D printed to architectural structures.According to the highly improved precision,the electromagnetic performance matching between the designed model and the printed physical FSS device was perfectly achieved,reducing the center frequency error less than 0.3 GHz,and the transmission coefficient error less than 0.046.Our work promises an effective and easy preparation of high-quality FSS from the aid of graphene.
基金supported by the National Natural Science Foundation of China(Nos.52122301,51973191,52090030,and 51533008)Hundred Talents Program of Zhejiang University(No.188020*194231701/113)+2 种基金Key Research and Development Plan of Zhejiang Province(No.2018C01049)Shanxi-Zheda Institute of New Materials and Chemical Engineering(No.2012SZ-FR004)the Fundamental Research Funds for the Central Universities(Nos.K20200060,2017QNA4036,and 2017XZZX001-04).
文摘Assembling two-dimensional(2D)sheets into macroscopic three-dimensional(3D)forms has created a promising material family with rich functionalities.Multiscale wrinkles are intrinsic features of 2D sheets in their 3D assembles.Therefore,the precise wrinkling modulation optimizes the transition of outstanding properties of 2D sheets to expected performances of assembled materials and dominates their fabrication process.The wrinkling evolution of 2D sheets assembling onto flat surfaces has been extensively understood,however,the wrinkling behaviors on the more generally curved surface still remain unclear.Here,we investigate the wrinkling behaviors of graphene oxide sheets assembled onto curved surfaces and reveal the selection rule of wrinkling modes that determined by the curvature mismatch between 2D sheets and target surfaces.We uncover that three wrinkling modes including isotropic cracked land,labyrinth,and anisotropic curtain phases,respectively emerge on flat,spherical,and cylindrical surfaces.A favorable description paradigm is offered to quantitatively measure the complex wrinkling patterns and assess the curvature mismatch constraint underlying the wrinkling mode selection.This research provides a general and quantitative description framework of wrinkling modulation of 2D materials such as high performance graphene fibers,and guides the precise fabrication of particles and functional coatings.