Ocean temperature is an important physical variable in marine ecosystems,and ocean temperature prediction is an important research objective in ocean-related fields.Currently,one of the commonly used methods for ocean...Ocean temperature is an important physical variable in marine ecosystems,and ocean temperature prediction is an important research objective in ocean-related fields.Currently,one of the commonly used methods for ocean temperature prediction is based on data-driven,but research on this method is mostly limited to the sea surface,with few studies on the prediction of internal ocean temperature.Existing graph neural network-based methods usually use predefined graphs or learned static graphs,which cannot capture the dynamic associations among data.In this study,we propose a novel dynamic spatiotemporal graph neural network(DSTGN)to predict threedimensional ocean temperature(3D-OT),which combines static graph learning and dynamic graph learning to automatically mine two unknown dependencies between sequences based on the original 3D-OT data without prior knowledge.Temporal and spatial dependencies in the time series were then captured using temporal and graph convolutions.We also integrated dynamic graph learning,static graph learning,graph convolution,and temporal convolution into an end-to-end framework for 3D-OT prediction using time-series grid data.In this study,we conducted prediction experiments using high-resolution 3D-OT from the Copernicus global ocean physical reanalysis,with data covering the vertical variation of temperature from the sea surface to 1000 m below the sea surface.We compared five mainstream models that are commonly used for ocean temperature prediction,and the results showed that the method achieved the best prediction results at all prediction scales.展开更多
The past decade has seen a growing interest in ocean sensor networks because of their wide applications in marine research,oceanography,ocean monitoring,offshore exploration,and defense or homeland security.Ocean sens...The past decade has seen a growing interest in ocean sensor networks because of their wide applications in marine research,oceanography,ocean monitoring,offshore exploration,and defense or homeland security.Ocean sensor networks are generally formed with various ocean sensors,autonomous underwater vehicles,surface stations,and research vessels.To make ocean sensor network applications viable,efficient communication among all devices and components is crucial.Due to the unique characteristics of underwater acoustic channels and the complex deployment environment in three dimensional(3D) ocean spaces,new efficient and reliable communication and networking protocols are needed in design of ocean sensor networks.In this paper,we aim to provide an overview of the most recent advances in network design principles for 3D ocean sensor networks,with focuses on deployment,localization,topology design,and position-based routing in 3D ocean spaces.展开更多
The space-air-ground integrated network(SAGIN)combines the superiority of the satellite,aerial,and ground communications,which is envisioned to provide high-precision positioning ability as well as seamless connectivi...The space-air-ground integrated network(SAGIN)combines the superiority of the satellite,aerial,and ground communications,which is envisioned to provide high-precision positioning ability as well as seamless connectivity in the 5G and Beyond 5G(B5G)systems.In this paper,we propose a three-dimensional SAGIN localization scheme for ground agents utilizing multi-source information from satellites,base stations and unmanned aerial vehicles(UAVs).Based on the designed scheme,we derive the positioning performance bound and establish a distributed maximum likelihood algorithm to jointly estimate the positions and clock offsets of ground agents.Simulation results demonstrate the validity of the SAGIN localization scheme and reveal the effects of the number of satellites,the number of base stations,the number of UAVs and clock noise on positioning performance.展开更多
In order to study the behavior and interconnection of network devices,graphs structures are used to formulate the properties in terms of mathematical models.Mesh network(meshnet)is a LAN topology in which devices are ...In order to study the behavior and interconnection of network devices,graphs structures are used to formulate the properties in terms of mathematical models.Mesh network(meshnet)is a LAN topology in which devices are connected either directly or through some intermediate devices.These terminating and intermediate devices are considered as vertices of graph whereas wired or wireless connections among these devices are shown as edges of graph.Topological indices are used to reflect structural property of graphs in form of one real number.This structural invariant has revolutionized the field of chemistry to identify molecular descriptors of chemical compounds.These indices are extensively used for establishing relationships between the structure of nanotubes and their physico-chemical properties.In this paper a representation of sodium chloride(NaCl)is studied,because structure of NaCl is same as the Cartesian product of three paths of length exactly like a mesh network.In this way the general formula obtained in this paper can be used in chemistry as well as for any degree-based topological polynomials of three-dimensional mesh networks.展开更多
A novel complex, (H 3O) 2[Ni(2,6-pydc) 2]·2H 2O was synthesized in an aqueous solution and characterized by means of single-crystal X-ray diffraction, elemental analyses and IR spectra. The X-ray structural a...A novel complex, (H 3O) 2[Ni(2,6-pydc) 2]·2H 2O was synthesized in an aqueous solution and characterized by means of single-crystal X-ray diffraction, elemental analyses and IR spectra. The X-ray structural analysis revealed that the novel compound forms three-dimensional(3D) networks by both π-π stacking and hydrogen-bonding interactions. The crystal data for the complex are a=13.853(3) nm, b=9.6892(19) nm, c=13.732(3) nm, α=90.00°, β=115.52(3)°, γ=90.00°, Z=3, R 1=0.0786, wR 2=0.1522.展开更多
Study on solving nonlinear least squares adjustment by parameters is one of the most important and new subjects in modern surveying and mapping field . Many researchers have done a lot of work and gained some solving ...Study on solving nonlinear least squares adjustment by parameters is one of the most important and new subjects in modern surveying and mapping field . Many researchers have done a lot of work and gained some solving methods. These methods mainly include iterative algorithms and direct algorithms mainly. The former searches some methods of rapid convergence based on which surveying adjustment is a kind of problem of nonlinear programming. Among them the iterative algorithms of the most in common use are the Gauss-Newton method, damped least quares, quasi-Newton method and some mutations etc. Although these methods improved the quantity of the observation results to a certain degree, and increased the accuracy of the adjustment results, what we want is whether the initial values of unknown parameters are close to their real values. Of course, the model of the latter has better degree in linearity, that is to say, they nearly have the meaning of deeper theories researches. This paper puts forward a kind of method of solving the problems of nonlinear least squares adjustment by parameters based on neural network theory, and studies its stability and convergency. The results of calculating of living example indicate the method acts well for solving parameters problems by nonlinear least squares adjustment without giving exact approximation of parameters.展开更多
The crystal structure of the title compound [Na2(OH2)5]2+[C6H12N4H2]2-2+ [Mo7O24]6 ?4H2O, prepared from an aqueous solution of Na2MoO4 ?2H2O in the presence of MoCl3 and hexamethylene tetramine, has been determined by...The crystal structure of the title compound [Na2(OH2)5]2+[C6H12N4H2]2-2+ [Mo7O24]6 ?4H2O, prepared from an aqueous solution of Na2MoO4 ?2H2O in the presence of MoCl3 and hexamethylene tetramine, has been determined by single-crystal X-ray diffraction. The crystal is of orthorhombic, space group Pnma with a = 14.6113(2), b = 18.6833(1), c = 15.3712(2), V = 4196.14(8)3, Z = 4, Mr = 1548.13, F(000) = 3016, = 2.157 mm-1 and Dc = 2.451 g/cm3. The final R factor is 0.0526 for 3818 unique observed reflections (I > 2(I)). The structural analysis reveals that heptamolybdate anions in the title compound consist of seven edge-sharing MoO6 octahedra, and are linked into a three-dimensional framework by sodium ions and hydrogen bonds.展开更多
One interesting coordination polymer, [Zn2(1,2,4-BTC)(OH)(H2O)2]2·2H2O 1, has been synthesized from 1,2,4-BTC (1,2,4-BTC = 1,2,4-bentricarboxylate) under hydrothermal conditions and characterized by eleme...One interesting coordination polymer, [Zn2(1,2,4-BTC)(OH)(H2O)2]2·2H2O 1, has been synthesized from 1,2,4-BTC (1,2,4-BTC = 1,2,4-bentricarboxylate) under hydrothermal conditions and characterized by elemental analyses, IR, TG and single-crystal X-ray diffraction. Complex I crystallizes in triclinic, space group P^-1, with a = 6.5200(13), b = 9,0600(18), c = 10.968(2) A^°, α = 111.55(3), β = 92.07(3),γ= 95.03(3)°, C9H10O10Zn2, Mr = 408.91, V= 598.7(2) A^°^3, Dc = 2.268 g/cm^3, F(000) = 408 and Z = 2. X-ray diffraction analysis reveals that complex 1 is a three-dimensional network built from tetranuclear Zn(Ⅱ) building unit. In this complex, the Zn4 unit is an eight-connected knot, while 1,2,4-BTC a four-connected knot. This results in a CaF2 topology. To the best of our knowledge, such Zn4 unit is the first 8-connected building block built from asymmetry ligand.展开更多
The Metropolitan Area Network (MAN) has faced serious problems after years of rapid development. The model of three-dimensional IP-based MAN, proposed by ZTE, is a next-generation MAN solution, which not only solves t...The Metropolitan Area Network (MAN) has faced serious problems after years of rapid development. The model of three-dimensional IP-based MAN, proposed by ZTE, is a next-generation MAN solution, which not only solves the existing problems but also brings new ideas for the development of next-generation MAN.展开更多
The simulation of salinity at different locations of a tidal river using physically-based hydrodynamic models is quite cumbersome because it requires many types of data, such as hydrological and hydraulic time series ...The simulation of salinity at different locations of a tidal river using physically-based hydrodynamic models is quite cumbersome because it requires many types of data, such as hydrological and hydraulic time series at boundaries, river geometry, and adjusted coefficients. Therefore, an artificial neural network (ANN) technique using a back-propagation neural network (BPNN) and a radial basis function neural network (RBFNN) is adopted as an effective alternative in salinity simulation studies. The present study focuses on comparing the performance of BPNN, RBFNN, and three-dimensional hydrodynamic models as applied to a tidal estuarine system. The observed salinity data sets collected from 18 to 22 May, 16 to 22 October, and 26 to 30 October 2002 (totaling 4320 data points) were used for BPNN and RBFNN model training and for hydrodynamic model calibration. The data sets collected from 30 May to 2 June and 11 to 15 November 2002 (totaling 2592 data points) were adopted for BPNN and RBFNN model verification and for hydrodynamic model verification. The results revealed that the ANN (BPNN and RBFNN) models were capable of predicting the nonlinear time series behavior of salinity to the multiple forcing signals of water stages at different stations and freshwater input at upstream boundaries. The salinity predicted by the ANN models was better than that predicted by the physically based hydrodynamic model. This study suggests that BPNN and RBFNN models are easy-to-use modeling tools for simulating the salinity variation in a tidal estuarine system.展开更多
Mechanical joints can have significant effects on the dynamics of assembled structures.However,the lack of efficacious predictive dynamic models tot joints hinders accurate prediction of their dynamic behavior.The goa...Mechanical joints can have significant effects on the dynamics of assembled structures.However,the lack of efficacious predictive dynamic models tot joints hinders accurate prediction of their dynamic behavior.The goal of our work is to develop physics-based,reduced-order,finite element models that are capable of replicating the effects of joints on vi- brating structures.The authors recently developed the so-called two-dimensional adjusted lwan beam element(2-D AIBE) to simulate the hysteretic behavior of bolted joints in 2-D beam structures.In this paper,2-D AIBE is extended to three-di- mensional cases by formulating a three-dimensional adjusted lwan beam element(3-D AIBE).hupulsive loading experi- ments are applied to a jointed frame structure and a beam structure containing the same joint.The frame is subjected to ex- citation out of plane so that the joint is under rotation and single axis bending.By assuming that the rotation in the joint is linear elastic,the parameters of the joint associated with bending in the flame are identified from acceleration responses of the jointed beam structure,using a multi-layer teed-torward neural network(MLFF).Numerieal simulation is then per- formed on the frame structure using the identified parameters.The good agreement between the simulated and experimental impulsive acceleration responses of the frame structure validates the efficacy of the presented 3-D AIBE,and indicates that the model can potentially be applied to more complex structural systems with joint parameters identified from a relatively simple structure.展开更多
In order to achieve dynamical optimization of mobility load balancing,we analyze the conflict between mobility load balancing and mobility robustness optimization caused by the improper operation of handover parameter...In order to achieve dynamical optimization of mobility load balancing,we analyze the conflict between mobility load balancing and mobility robustness optimization caused by the improper operation of handover parameters.To this end,a method of Handover Parameters Adjustment for Conflict Avoidance(HPACA)is proposed.Considering the movement of users,HPCAC can dynamically adjust handover range to optimize the mobility load balancing.The movement of users is an important factor of handover,which has a dramatic impact on system performance.The numerical evaluation results show the proposed approach outperforms the existing method in terms of throughput,call blocking ratio,load balancing index,radio link failure ratio,ping-pong handover ratio and call dropping ratio.展开更多
Several challenging issues,such as the poor conductivity of sulfur,shuttle effects,large volume change of cathode,and the dendritic lithium in anode,have led to the low utilization of sulfur and hampered the commercia...Several challenging issues,such as the poor conductivity of sulfur,shuttle effects,large volume change of cathode,and the dendritic lithium in anode,have led to the low utilization of sulfur and hampered the commercialization of lithium–sulfur batteries.In this study,a novel three-dimensionally interconnected network structure comprising Co9 S8 and multiwalled carbon nanotubes(MWCNTs)was synthesized by a solvothermal route and used as the sulfur host.The assembled batteries delivered a specific capacity of1154 m Ah g-1 at 0.1 C,and the retention was 64%after 400 cycles at 0.5 C.The polar and catalytic Co9 S8 nanoparticles have a strong adsorbent effect for polysulfide,which can effectively reduce the shuttling effect.Meanwhile,the three-dimensionally interconnected CNT networks improve the overall conductivity and increase the contact with the electrolyte,thus enhancing the transport of electrons and Li ions.Polysulfide adsorption is greatly increased with the synergistic effect of polar Co9 S8 and MWCNTs in the three-dimensionally interconnected composites,which contributes to their promising performance for the lithium–sulfur batteries.展开更多
Short-term prediction of traffic flow is one of the most essential elements of all proactive traffic control systems.The aim of this paper is to provide a model based on neural networks(NNs)for multi-step-ahead traffi...Short-term prediction of traffic flow is one of the most essential elements of all proactive traffic control systems.The aim of this paper is to provide a model based on neural networks(NNs)for multi-step-ahead traffic prediction.NNs'dependency on parameter setting is the major challenge in using them as a predictor.Given the fact that the best combination of NN parameters results in the minimum error of predicted output,the main problem is NN optimization.So,it is viable to set the best combination of the parameters according to a specific traffic behavior.On the other hand,an automatic method—which is applicable in general cases—is strongly desired to set appropriate parameters for neural networks.This paper defines a self-adjusted NN using the non-dominated sorting genetic algorithm II(NSGA-II)as a multi-objective optimizer for short-term prediction.NSGA-II is used to optimize the number of neurons in the first and second layers of the NN,learning ratio and slope of the activation function.This model addresses the challenge of optimizing a multi-output NN in a self-adjusted way.Performance of the developed network is evaluated by application to both univariate and multivariate traffic flow data from an urban highway.Results are analyzed based on the performance measures,showing that the genetic algorithm tunes the NN as well without any manually pre-adjustment.The achieved prediction accuracy is calculated with multiple measures such as the root mean square error(RMSE),and the RMSE value is 10 and 12 in the best configuration of the proposed model for single and multi-step-ahead traffic flow prediction,respectively.展开更多
Due to the complexity of thickness and shape synthetical adjustment system and the difficulties to build a mathematical model,a thickness and shape synthetical adjustment scheme on DC mill based on dynamic nerve-fuzzy...Due to the complexity of thickness and shape synthetical adjustment system and the difficulties to build a mathematical model,a thickness and shape synthetical adjustment scheme on DC mill based on dynamic nerve-fuzzy control was put forward,and a self-organizing fuzzy control model was established.The structure of the network can be optimized dynamically.In the course of studying,the network can automatically adjust its structure based on the specific questions and make its structure the optimal.The input and output of the network are fuzzy sets,and the trained network can complete the composite relation,the fuzzy inference.For decreasing the off-line training time of BP network,the fuzzy sets are encoded.The simulation results indicate that the self-organizing fuzzy control based on dynamic neural network is better than traditional decoupling PID control.展开更多
The title complex Mn(H2O)2(HNic)2 (C22H12MnN2O8, Mr = 367.18) crystallizes in monoclinic, space group P21/c with a = 7.5735(8), b = 12.5295(13), c = 7.6466(8)A.β = 101.2790(10)°, Z = 2, V= 711.59...The title complex Mn(H2O)2(HNic)2 (C22H12MnN2O8, Mr = 367.18) crystallizes in monoclinic, space group P21/c with a = 7.5735(8), b = 12.5295(13), c = 7.6466(8)A.β = 101.2790(10)°, Z = 2, V= 711.59(13) A^3, D, = 1.714 g/cm^3,μ(MoKa) = 0.974 mm^-1, F(000) = 374, R1 (1255 observed reflections (Ⅰ 〉 2σ(Ⅰ)) = 0.0250) and wR2 = 0.0662 (all data). In this paper, we report the complexation of Mn(Ⅱ) by the bidentate ligand 2-hydroxynicotinic acid (HNic). In the crystal the Mn(Ⅱ) ion exhibits a deformed octahedron structure. The title complex Mn(H2O)2(HNic)2 has a three-dimensional (3D) network structure extended by hydrogen bonds, which are formed by two typical eight-membered hydrogen-bonded rings.展开更多
Gravity observations adjustment is studied having in view to take full advantage of the modern technology of gravity measurement. We present here results of a test performed with the mathematical model proposed by our...Gravity observations adjustment is studied having in view to take full advantage of the modern technology of gravity measurement. We present here results of a test performed with the mathematical model proposed by our group, on the adjustment of gravity observations carried out on network design. Additionally, considering the recent improvement on instrumental technology in gravimetry, that model was modified to take into account possible nonlinear local datum scale factors, in a 1900 mGal range network, and to check its significance for microgal precision measurements. The data set of the Brazilian Fundamental Gravity Network was used as case study. With about 1900 mGal gravity range and 11 control stations the Brazilian Fundamental Gravity Network (BFGN) was used as case study. It was established mainly with the use of LaCoste & Romberg, model G, gravimeters and new additional observations with Scintrex CG-5 gravimeters. The observables involved in the model are instrumental reading, calibration functions of the gravimeters used and the absolute gravity values at the control stations. Gravity values at the gravity stations and local datum scale factors for each gravimeter were determined by least square method. The results indicate good adaptation of the tested model to network adjustments. The gravity value in the IFE-172 control station, located in Santa Maria, had the largest estimated correction of ?10.4 μGal (1 μGal = 10 nm/s2), and the largest residual for an observed reading was estimated in 0.043 reading unit. The largest correction to the calibration functions was estimated in 6.9 × 10-6mGal/reading unit.展开更多
Natural slopes usually display complicated exposed rock surfaces that are characterized by complex and substantial terrain undulation and ubiquitous undesirable phenomena such as vegetation cover and rockfalls.This st...Natural slopes usually display complicated exposed rock surfaces that are characterized by complex and substantial terrain undulation and ubiquitous undesirable phenomena such as vegetation cover and rockfalls.This study presents a systematic outcrop research of fracture pattern variations in a complicated rock slope,and the qualitative and quantitative study of the complex phenomena impact on threedimensional(3D)discrete fracture network(DFN)modeling.As the studies of the outcrop fracture pattern have been so far focused on local variations,thus,we put forward a statistical analysis of global variations.The entire outcrop is partitioned into several subzones,and the subzone-scale variability of fracture geometric properties is analyzed(including the orientation,the density,and the trace length).The results reveal significant variations in fracture characteristics(such as the concentrative degree,the average orientation,the density,and the trace length)among different subzones.Moreover,the density of fracture sets,which is approximately parallel to the slope surface,exhibits a notably higher value compared to other fracture sets across all subzones.To improve the accuracy of the DFN modeling,the effects of three common phenomena resulting from vegetation and rockfalls are qualitatively analyzed and the corresponding quantitative data processing solutions are proposed.Subsequently,the 3D fracture geometric parameters are determined for different areas of the high-steep rock slope in terms of the subzone dimensions.The results show significant variations in the same set of 3D fracture parameters across different regions with density differing by up to tenfold and mean trace length exhibiting differences of 3e4 times.The study results present precise geological structural information,improve modeling accuracy,and provide practical solutions for addressing complex outcrop issues.展开更多
The title compound, {Mn(H2O)4(VO)2(PO4)2}n 1, was synthesized by the hydro- thermal reaction of Mn(OAc)2, Na2VO3 and H3PO4 in aqueous solution and its crystal structure was determined by X-ray single-crystal analysi...The title compound, {Mn(H2O)4(VO)2(PO4)2}n 1, was synthesized by the hydro- thermal reaction of Mn(OAc)2, Na2VO3 and H3PO4 in aqueous solution and its crystal structure was determined by X-ray single-crystal analysis. Crystallographic data for 1: H4MnO14P2V2, tetragonal system, space group I4/mmm, a = 6.251(3), c = 13.410(9) ?, Mr = 446.79, V = 524.0(5) ?3, Z = 2, F(000) = 434, μ = 3.320 mm-1, Dc = 2.832 g/cm3, the final R = 0.0577 for 163 observed reflections (I > 2σ(I)). X-ray crystal structure analysis shows that the vanadium phosphorous oxide layers are further connected by MnII(H2O)4 cations to form a three-dimensional network.展开更多
基金The National Key R&D Program of China under contract No.2021YFC3101603.
文摘Ocean temperature is an important physical variable in marine ecosystems,and ocean temperature prediction is an important research objective in ocean-related fields.Currently,one of the commonly used methods for ocean temperature prediction is based on data-driven,but research on this method is mostly limited to the sea surface,with few studies on the prediction of internal ocean temperature.Existing graph neural network-based methods usually use predefined graphs or learned static graphs,which cannot capture the dynamic associations among data.In this study,we propose a novel dynamic spatiotemporal graph neural network(DSTGN)to predict threedimensional ocean temperature(3D-OT),which combines static graph learning and dynamic graph learning to automatically mine two unknown dependencies between sequences based on the original 3D-OT data without prior knowledge.Temporal and spatial dependencies in the time series were then captured using temporal and graph convolutions.We also integrated dynamic graph learning,static graph learning,graph convolution,and temporal convolution into an end-to-end framework for 3D-OT prediction using time-series grid data.In this study,we conducted prediction experiments using high-resolution 3D-OT from the Copernicus global ocean physical reanalysis,with data covering the vertical variation of temperature from the sea surface to 1000 m below the sea surface.We compared five mainstream models that are commonly used for ocean temperature prediction,and the results showed that the method achieved the best prediction results at all prediction scales.
基金Y. Wang was supported in part by the US National Science Foundation (NSF) under Grant Nos.CNS-0721666,CNS-0915331,and CNS-1050398Y. Liu was partially supported by the National Natural Science Foundation of China (NSFC) under Grant No. 61074092+1 种基金by the Shandong Provincial Natural Science Foundation,China under Grant No.Q2008E01Z. Guo was partially supported by the NSFC under Grant Nos. 61170258 and 6093301
文摘The past decade has seen a growing interest in ocean sensor networks because of their wide applications in marine research,oceanography,ocean monitoring,offshore exploration,and defense or homeland security.Ocean sensor networks are generally formed with various ocean sensors,autonomous underwater vehicles,surface stations,and research vessels.To make ocean sensor network applications viable,efficient communication among all devices and components is crucial.Due to the unique characteristics of underwater acoustic channels and the complex deployment environment in three dimensional(3D) ocean spaces,new efficient and reliable communication and networking protocols are needed in design of ocean sensor networks.In this paper,we aim to provide an overview of the most recent advances in network design principles for 3D ocean sensor networks,with focuses on deployment,localization,topology design,and position-based routing in 3D ocean spaces.
文摘The space-air-ground integrated network(SAGIN)combines the superiority of the satellite,aerial,and ground communications,which is envisioned to provide high-precision positioning ability as well as seamless connectivity in the 5G and Beyond 5G(B5G)systems.In this paper,we propose a three-dimensional SAGIN localization scheme for ground agents utilizing multi-source information from satellites,base stations and unmanned aerial vehicles(UAVs).Based on the designed scheme,we derive the positioning performance bound and establish a distributed maximum likelihood algorithm to jointly estimate the positions and clock offsets of ground agents.Simulation results demonstrate the validity of the SAGIN localization scheme and reveal the effects of the number of satellites,the number of base stations,the number of UAVs and clock noise on positioning performance.
文摘In order to study the behavior and interconnection of network devices,graphs structures are used to formulate the properties in terms of mathematical models.Mesh network(meshnet)is a LAN topology in which devices are connected either directly or through some intermediate devices.These terminating and intermediate devices are considered as vertices of graph whereas wired or wireless connections among these devices are shown as edges of graph.Topological indices are used to reflect structural property of graphs in form of one real number.This structural invariant has revolutionized the field of chemistry to identify molecular descriptors of chemical compounds.These indices are extensively used for establishing relationships between the structure of nanotubes and their physico-chemical properties.In this paper a representation of sodium chloride(NaCl)is studied,because structure of NaCl is same as the Cartesian product of three paths of length exactly like a mesh network.In this way the general formula obtained in this paper can be used in chemistry as well as for any degree-based topological polynomials of three-dimensional mesh networks.
基金Supported by the National Natural Science Foundation of China(No.2 0 1710 10)
文摘A novel complex, (H 3O) 2[Ni(2,6-pydc) 2]·2H 2O was synthesized in an aqueous solution and characterized by means of single-crystal X-ray diffraction, elemental analyses and IR spectra. The X-ray structural analysis revealed that the novel compound forms three-dimensional(3D) networks by both π-π stacking and hydrogen-bonding interactions. The crystal data for the complex are a=13.853(3) nm, b=9.6892(19) nm, c=13.732(3) nm, α=90.00°, β=115.52(3)°, γ=90.00°, Z=3, R 1=0.0786, wR 2=0.1522.
基金Project (40174003) supported by the National Natural Science Foundation of China
文摘Study on solving nonlinear least squares adjustment by parameters is one of the most important and new subjects in modern surveying and mapping field . Many researchers have done a lot of work and gained some solving methods. These methods mainly include iterative algorithms and direct algorithms mainly. The former searches some methods of rapid convergence based on which surveying adjustment is a kind of problem of nonlinear programming. Among them the iterative algorithms of the most in common use are the Gauss-Newton method, damped least quares, quasi-Newton method and some mutations etc. Although these methods improved the quantity of the observation results to a certain degree, and increased the accuracy of the adjustment results, what we want is whether the initial values of unknown parameters are close to their real values. Of course, the model of the latter has better degree in linearity, that is to say, they nearly have the meaning of deeper theories researches. This paper puts forward a kind of method of solving the problems of nonlinear least squares adjustment by parameters based on neural network theory, and studies its stability and convergency. The results of calculating of living example indicate the method acts well for solving parameters problems by nonlinear least squares adjustment without giving exact approximation of parameters.
基金This work was supported by Chinese Academy of Sciences the State Education Ministry+1 种基金 the State Personnel Ministry the NSFC (20073048)
文摘The crystal structure of the title compound [Na2(OH2)5]2+[C6H12N4H2]2-2+ [Mo7O24]6 ?4H2O, prepared from an aqueous solution of Na2MoO4 ?2H2O in the presence of MoCl3 and hexamethylene tetramine, has been determined by single-crystal X-ray diffraction. The crystal is of orthorhombic, space group Pnma with a = 14.6113(2), b = 18.6833(1), c = 15.3712(2), V = 4196.14(8)3, Z = 4, Mr = 1548.13, F(000) = 3016, = 2.157 mm-1 and Dc = 2.451 g/cm3. The final R factor is 0.0526 for 3818 unique observed reflections (I > 2(I)). The structural analysis reveals that heptamolybdate anions in the title compound consist of seven edge-sharing MoO6 octahedra, and are linked into a three-dimensional framework by sodium ions and hydrogen bonds.
基金supported by the National Natural Science Foundation of China (No. 20701005 and 20701006)
文摘One interesting coordination polymer, [Zn2(1,2,4-BTC)(OH)(H2O)2]2·2H2O 1, has been synthesized from 1,2,4-BTC (1,2,4-BTC = 1,2,4-bentricarboxylate) under hydrothermal conditions and characterized by elemental analyses, IR, TG and single-crystal X-ray diffraction. Complex I crystallizes in triclinic, space group P^-1, with a = 6.5200(13), b = 9,0600(18), c = 10.968(2) A^°, α = 111.55(3), β = 92.07(3),γ= 95.03(3)°, C9H10O10Zn2, Mr = 408.91, V= 598.7(2) A^°^3, Dc = 2.268 g/cm^3, F(000) = 408 and Z = 2. X-ray diffraction analysis reveals that complex 1 is a three-dimensional network built from tetranuclear Zn(Ⅱ) building unit. In this complex, the Zn4 unit is an eight-connected knot, while 1,2,4-BTC a four-connected knot. This results in a CaF2 topology. To the best of our knowledge, such Zn4 unit is the first 8-connected building block built from asymmetry ligand.
文摘The Metropolitan Area Network (MAN) has faced serious problems after years of rapid development. The model of three-dimensional IP-based MAN, proposed by ZTE, is a next-generation MAN solution, which not only solves the existing problems but also brings new ideas for the development of next-generation MAN.
文摘The simulation of salinity at different locations of a tidal river using physically-based hydrodynamic models is quite cumbersome because it requires many types of data, such as hydrological and hydraulic time series at boundaries, river geometry, and adjusted coefficients. Therefore, an artificial neural network (ANN) technique using a back-propagation neural network (BPNN) and a radial basis function neural network (RBFNN) is adopted as an effective alternative in salinity simulation studies. The present study focuses on comparing the performance of BPNN, RBFNN, and three-dimensional hydrodynamic models as applied to a tidal estuarine system. The observed salinity data sets collected from 18 to 22 May, 16 to 22 October, and 26 to 30 October 2002 (totaling 4320 data points) were used for BPNN and RBFNN model training and for hydrodynamic model calibration. The data sets collected from 30 May to 2 June and 11 to 15 November 2002 (totaling 2592 data points) were adopted for BPNN and RBFNN model verification and for hydrodynamic model verification. The results revealed that the ANN (BPNN and RBFNN) models were capable of predicting the nonlinear time series behavior of salinity to the multiple forcing signals of water stages at different stations and freshwater input at upstream boundaries. The salinity predicted by the ANN models was better than that predicted by the physically based hydrodynamic model. This study suggests that BPNN and RBFNN models are easy-to-use modeling tools for simulating the salinity variation in a tidal estuarine system.
文摘Mechanical joints can have significant effects on the dynamics of assembled structures.However,the lack of efficacious predictive dynamic models tot joints hinders accurate prediction of their dynamic behavior.The goal of our work is to develop physics-based,reduced-order,finite element models that are capable of replicating the effects of joints on vi- brating structures.The authors recently developed the so-called two-dimensional adjusted lwan beam element(2-D AIBE) to simulate the hysteretic behavior of bolted joints in 2-D beam structures.In this paper,2-D AIBE is extended to three-di- mensional cases by formulating a three-dimensional adjusted lwan beam element(3-D AIBE).hupulsive loading experi- ments are applied to a jointed frame structure and a beam structure containing the same joint.The frame is subjected to ex- citation out of plane so that the joint is under rotation and single axis bending.By assuming that the rotation in the joint is linear elastic,the parameters of the joint associated with bending in the flame are identified from acceleration responses of the jointed beam structure,using a multi-layer teed-torward neural network(MLFF).Numerieal simulation is then per- formed on the frame structure using the identified parameters.The good agreement between the simulated and experimental impulsive acceleration responses of the frame structure validates the efficacy of the presented 3-D AIBE,and indicates that the model can potentially be applied to more complex structural systems with joint parameters identified from a relatively simple structure.
基金supported by the National Natural Science Foundation of China under Grant No.61071118the National Basic Research Program of China(973 Program)under Grant No.2012CB316004+1 种基金Special Fund of Chongqing Key Laboratory(CSTC)Chongqing Municipal Education Commission’s Science and Technology Research Project under Grant No.KJ111506
文摘In order to achieve dynamical optimization of mobility load balancing,we analyze the conflict between mobility load balancing and mobility robustness optimization caused by the improper operation of handover parameters.To this end,a method of Handover Parameters Adjustment for Conflict Avoidance(HPACA)is proposed.Considering the movement of users,HPCAC can dynamically adjust handover range to optimize the mobility load balancing.The movement of users is an important factor of handover,which has a dramatic impact on system performance.The numerical evaluation results show the proposed approach outperforms the existing method in terms of throughput,call blocking ratio,load balancing index,radio link failure ratio,ping-pong handover ratio and call dropping ratio.
基金National Natural Science Foundation of China(No.51974209)the Natural Science Foundation of Hubei Province of China(Nos.2013CFA021,2017CFB401,2018CFA022)。
文摘Several challenging issues,such as the poor conductivity of sulfur,shuttle effects,large volume change of cathode,and the dendritic lithium in anode,have led to the low utilization of sulfur and hampered the commercialization of lithium–sulfur batteries.In this study,a novel three-dimensionally interconnected network structure comprising Co9 S8 and multiwalled carbon nanotubes(MWCNTs)was synthesized by a solvothermal route and used as the sulfur host.The assembled batteries delivered a specific capacity of1154 m Ah g-1 at 0.1 C,and the retention was 64%after 400 cycles at 0.5 C.The polar and catalytic Co9 S8 nanoparticles have a strong adsorbent effect for polysulfide,which can effectively reduce the shuttling effect.Meanwhile,the three-dimensionally interconnected CNT networks improve the overall conductivity and increase the contact with the electrolyte,thus enhancing the transport of electrons and Li ions.Polysulfide adsorption is greatly increased with the synergistic effect of polar Co9 S8 and MWCNTs in the three-dimensionally interconnected composites,which contributes to their promising performance for the lithium–sulfur batteries.
文摘Short-term prediction of traffic flow is one of the most essential elements of all proactive traffic control systems.The aim of this paper is to provide a model based on neural networks(NNs)for multi-step-ahead traffic prediction.NNs'dependency on parameter setting is the major challenge in using them as a predictor.Given the fact that the best combination of NN parameters results in the minimum error of predicted output,the main problem is NN optimization.So,it is viable to set the best combination of the parameters according to a specific traffic behavior.On the other hand,an automatic method—which is applicable in general cases—is strongly desired to set appropriate parameters for neural networks.This paper defines a self-adjusted NN using the non-dominated sorting genetic algorithm II(NSGA-II)as a multi-objective optimizer for short-term prediction.NSGA-II is used to optimize the number of neurons in the first and second layers of the NN,learning ratio and slope of the activation function.This model addresses the challenge of optimizing a multi-output NN in a self-adjusted way.Performance of the developed network is evaluated by application to both univariate and multivariate traffic flow data from an urban highway.Results are analyzed based on the performance measures,showing that the genetic algorithm tunes the NN as well without any manually pre-adjustment.The achieved prediction accuracy is calculated with multiple measures such as the root mean square error(RMSE),and the RMSE value is 10 and 12 in the best configuration of the proposed model for single and multi-step-ahead traffic flow prediction,respectively.
文摘Due to the complexity of thickness and shape synthetical adjustment system and the difficulties to build a mathematical model,a thickness and shape synthetical adjustment scheme on DC mill based on dynamic nerve-fuzzy control was put forward,and a self-organizing fuzzy control model was established.The structure of the network can be optimized dynamically.In the course of studying,the network can automatically adjust its structure based on the specific questions and make its structure the optimal.The input and output of the network are fuzzy sets,and the trained network can complete the composite relation,the fuzzy inference.For decreasing the off-line training time of BP network,the fuzzy sets are encoded.The simulation results indicate that the self-organizing fuzzy control based on dynamic neural network is better than traditional decoupling PID control.
基金This work was supported by the National Natural Science Foundation of China (No. 50572040)
文摘The title complex Mn(H2O)2(HNic)2 (C22H12MnN2O8, Mr = 367.18) crystallizes in monoclinic, space group P21/c with a = 7.5735(8), b = 12.5295(13), c = 7.6466(8)A.β = 101.2790(10)°, Z = 2, V= 711.59(13) A^3, D, = 1.714 g/cm^3,μ(MoKa) = 0.974 mm^-1, F(000) = 374, R1 (1255 observed reflections (Ⅰ 〉 2σ(Ⅰ)) = 0.0250) and wR2 = 0.0662 (all data). In this paper, we report the complexation of Mn(Ⅱ) by the bidentate ligand 2-hydroxynicotinic acid (HNic). In the crystal the Mn(Ⅱ) ion exhibits a deformed octahedron structure. The title complex Mn(H2O)2(HNic)2 has a three-dimensional (3D) network structure extended by hydrogen bonds, which are formed by two typical eight-membered hydrogen-bonded rings.
文摘Gravity observations adjustment is studied having in view to take full advantage of the modern technology of gravity measurement. We present here results of a test performed with the mathematical model proposed by our group, on the adjustment of gravity observations carried out on network design. Additionally, considering the recent improvement on instrumental technology in gravimetry, that model was modified to take into account possible nonlinear local datum scale factors, in a 1900 mGal range network, and to check its significance for microgal precision measurements. The data set of the Brazilian Fundamental Gravity Network was used as case study. With about 1900 mGal gravity range and 11 control stations the Brazilian Fundamental Gravity Network (BFGN) was used as case study. It was established mainly with the use of LaCoste & Romberg, model G, gravimeters and new additional observations with Scintrex CG-5 gravimeters. The observables involved in the model are instrumental reading, calibration functions of the gravimeters used and the absolute gravity values at the control stations. Gravity values at the gravity stations and local datum scale factors for each gravimeter were determined by least square method. The results indicate good adaptation of the tested model to network adjustments. The gravity value in the IFE-172 control station, located in Santa Maria, had the largest estimated correction of ?10.4 μGal (1 μGal = 10 nm/s2), and the largest residual for an observed reading was estimated in 0.043 reading unit. The largest correction to the calibration functions was estimated in 6.9 × 10-6mGal/reading unit.
基金supported by the National Key Research and Development Program of China(Grant No.2022YFC3080200)the National Natural Science Foundation of China(Grant No.42022053)the China Postdoctoral Science Foundation(Grant No.2023M731264).
文摘Natural slopes usually display complicated exposed rock surfaces that are characterized by complex and substantial terrain undulation and ubiquitous undesirable phenomena such as vegetation cover and rockfalls.This study presents a systematic outcrop research of fracture pattern variations in a complicated rock slope,and the qualitative and quantitative study of the complex phenomena impact on threedimensional(3D)discrete fracture network(DFN)modeling.As the studies of the outcrop fracture pattern have been so far focused on local variations,thus,we put forward a statistical analysis of global variations.The entire outcrop is partitioned into several subzones,and the subzone-scale variability of fracture geometric properties is analyzed(including the orientation,the density,and the trace length).The results reveal significant variations in fracture characteristics(such as the concentrative degree,the average orientation,the density,and the trace length)among different subzones.Moreover,the density of fracture sets,which is approximately parallel to the slope surface,exhibits a notably higher value compared to other fracture sets across all subzones.To improve the accuracy of the DFN modeling,the effects of three common phenomena resulting from vegetation and rockfalls are qualitatively analyzed and the corresponding quantitative data processing solutions are proposed.Subsequently,the 3D fracture geometric parameters are determined for different areas of the high-steep rock slope in terms of the subzone dimensions.The results show significant variations in the same set of 3D fracture parameters across different regions with density differing by up to tenfold and mean trace length exhibiting differences of 3e4 times.The study results present precise geological structural information,improve modeling accuracy,and provide practical solutions for addressing complex outcrop issues.
基金The project was supported by the 973 program of the MOST (001CB108906) the NNSFC (90206040+4 种基金 20073048) the NSF ofFujian Province 2002F015 2002J006) the State Key Lab of Structural Chemistry (030065) and the Chinese Academy of Sciences
文摘The title compound, {Mn(H2O)4(VO)2(PO4)2}n 1, was synthesized by the hydro- thermal reaction of Mn(OAc)2, Na2VO3 and H3PO4 in aqueous solution and its crystal structure was determined by X-ray single-crystal analysis. Crystallographic data for 1: H4MnO14P2V2, tetragonal system, space group I4/mmm, a = 6.251(3), c = 13.410(9) ?, Mr = 446.79, V = 524.0(5) ?3, Z = 2, F(000) = 434, μ = 3.320 mm-1, Dc = 2.832 g/cm3, the final R = 0.0577 for 163 observed reflections (I > 2σ(I)). X-ray crystal structure analysis shows that the vanadium phosphorous oxide layers are further connected by MnII(H2O)4 cations to form a three-dimensional network.