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Current optimization-based control of dual three-phase PMSM for low-frequency temperature swing reduction
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作者 Linlin Lu Xueqing Wang +3 位作者 Luhan Jin Qiong Liu Yun Zhang Yao Mao 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第4期238-246,共9页
In this paper,a control scheme based on current optimization is proposed for dual three-phase permanent-magnet synchronous motor(DTP-PMSM)drive to reduce the low-frequency temperature swing.The reduction of temperatur... In this paper,a control scheme based on current optimization is proposed for dual three-phase permanent-magnet synchronous motor(DTP-PMSM)drive to reduce the low-frequency temperature swing.The reduction of temperature swing can be equivalent to reducing maximum instantaneous phase copper loss in this paper.First,a two-level optimization aiming at minimizing maximum instantaneous phase copper loss at each electrical angle is proposed.Then,the optimization is transformed to a singlelevel optimization by introducing the auxiliary variable for easy solving.Considering that singleobjective optimization trades a great total copper loss for a small reduction of maximum phase copper loss,the optimization considering both instantaneous total copper loss and maximum phase copper loss is proposed,which has the same performance of temperature swing reduction but with lower total loss.In this way,the proposed control scheme can reduce maximum junction temperature by 11%.Both simulation and experimental results are presented to prove the effectiveness and superiority of the proposed control scheme for low-frequency temperature swing reduction. 展开更多
关键词 Dual three-phase PMSM Low-frequency temperature swing Copper loss current optimization Connected neutral points
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COMPARISON AND EVALUATION OF CURRENT REFERENCE GENERATION STRATEGIES FOR ACTIVE POWER FILTERS IN THREE-PHASE FOUR-WIRE SYSTEMS
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作者 陈东华 郭涛 +1 位作者 谢少军 周波 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2005年第4期298-306,共9页
For three phase four-wire active power filters (APFs), several typical power theories and corresponding current reference generation strategies are induced, p-q, d-q, unify power factor (UPF) and instantaneous act... For three phase four-wire active power filters (APFs), several typical power theories and corresponding current reference generation strategies are induced, p-q, d-q, unify power factor (UPF) and instantaneous active current (IAC) methods are analyzed and compared with each other. The interpretation of active and reactive currents in non-sinusoidal and unbalanced three-phase four-wire systems is given based on the generalized instantaneous reactive power theory. The performance and the characteristic are evaluated, and the application conditions of current reference generation strategies are concluded. Simulation results under different source voltages and loads verify the evaluation result. 展开更多
关键词 active power filters instantaneous reactive power current reference three-phase four wire power
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Electrical characteristics of new three-phase traction power supply system for rail transit 被引量:1
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作者 Xiaohong Huang Hanlin Wang +4 位作者 Qunzhan Li Naiqi Yang Tao Ren You Peng Haoyang Li 《Railway Engineering Science》 2023年第1期75-88,共14页
A novel three-phase traction power supply system is proposed to eliminate the adverse effects caused by electric phase separation in catenary and accomplish a unifying manner of traction power supply for rail transit.... A novel three-phase traction power supply system is proposed to eliminate the adverse effects caused by electric phase separation in catenary and accomplish a unifying manner of traction power supply for rail transit.With the application of two-stage three-phase continuous power supply structure,the electrical characteristics exhibit new features differing from the existing traction system.In this work,the principle for voltage levels determining two-stage network is dissected in accordance with the requirements of traction network and electric locomotive.The equivalent model of three-phase traction system is built for deducing the formula of current distribution and voltage losses.Based on the chain network model of the traction network,a simulation model is established to analyze the electrical characteristics such as traction current distribution,voltage losses,system equivalent impedance,voltage distribution,voltage unbalance and regenerative energy utilization.In a few words,quite a lot traction current of about 99%is undertaken by long-section cable network.The proportion of system voltage losses is small attributed to the two-stage three-phase power supply structure,and the voltage unbal-ance caused by impedance asymmetry of traction network is less than 1‰.In addition,the utilization rate of regenerative energy for locomotive achieves a significant promotion of over 97%. 展开更多
关键词 three-phase AC power supply Two-stage power supply structure Electrical characteristics current distribution Voltage losses Regenerative energy
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Zero-sequence Current Suppressing Strategy for Dual Three-phase Permanent Magnet Synchronous Machines Connected with Single Neutral Point 被引量:2
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作者 Zongwang Li Yuxuan Du +2 位作者 Jinghua Ji Tao Tao Wenxiang Zhao 《CES Transactions on Electrical Machines and Systems》 CSCD 2022年第4期465-472,共8页
Dual three-phase permanent-magnet synchronous machines(DTP-PMSM)connected with a single neutral point provide a loop for zero-sequence current(ZSC).This paper proposes a novel space vector pulse width modulation(SVPWM... Dual three-phase permanent-magnet synchronous machines(DTP-PMSM)connected with a single neutral point provide a loop for zero-sequence current(ZSC).This paper proposes a novel space vector pulse width modulation(SVPWM)strategy to suppress the ZSC.Five vectors are selected as basic voltage vectors in one switching period.The fundamental and harmonic planes and the zero-sequence plane are taken into consideration to synthesis the reference voltage vector.To suppress the ZSC,a non-zero zero-sequence voltage(ZSV)is generated to compensate the third harmonic back-EMF.Rather than triangular carrier modulation,the sawtooth carrier modulation strategy is used to generate asymmetric PWM signals.The modulation range is investigated to explore the variation of modulation range caused by considering the zero-sequence plane.With the proposed method,the ZSC can be considerably reduced.The simulated and experimental results are presented to validate the effectiveness of the proposed modulation strategy. 展开更多
关键词 Zero-sequence current a single neutral point dual three-phase permanent-magnet synchronous machine third harmonic back-EMF
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Sensorless Control of Permanent Magnet Synchronous Motor Based on New Sliding Mode Observer with Single Resistor Current Reconstruction 被引量:2
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作者 Qingguo Sun Xiaolei Zhu Feng Niu 《CES Transactions on Electrical Machines and Systems》 CSCD 2022年第4期378-383,共6页
To solve the chattering problem caused by discontinuous switching function in traditional sliding mode observer,a piecewise square root switching function with continuously varying characteristics is designed,and its ... To solve the chattering problem caused by discontinuous switching function in traditional sliding mode observer,a piecewise square root switching function with continuously varying characteristics is designed,and its stability is analyzed by using Lyapunov stability criterion.Secondly,according to the relationship among bus current,switching state and phase current,a single bus resistance sampling current reconstruction scheme without current sensors is adopted,which effectively reduces the cost of motor system.Finally,the feasibility and effectiveness of the proposed scheme are verified by simulation. 展开更多
关键词 Permanent magnet synchronous motor New sliding mode observer Phase-locked loop Single resistor current reconstruction
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Three-Phase Heterojunction NiMo-Based Nano-Needle for Water Splitting at Industrial Alkaline Condition 被引量:9
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作者 Guangfu Qian Jinli Chen +3 位作者 Tianqi Yu Jiacheng Liu Lin Luo Shibin Yin 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第1期325-339,共15页
Constructing heterojunction is an effective strategy to develop high-performance non-preciousmetal-based catalysts for electrochemical water splitting(WS).Herein,we design and prepare an N-doped-carbon-encapsulated Ni... Constructing heterojunction is an effective strategy to develop high-performance non-preciousmetal-based catalysts for electrochemical water splitting(WS).Herein,we design and prepare an N-doped-carbon-encapsulated Ni/MoO_(2) nano-needle with three-phase heterojunction(Ni/MoO_(2)@CN)for accelerating the WS under industrial alkaline condition.Density functional theory calculations reveal that the electrons are redistributed at the three-phase heterojunction interface,which optimizes the adsorption energy of H-and O-containing intermediates to obtain the best ΔG_(H*) for hydrogen evolution reaction(HER)and decrease the ΔG value of ratedetermining step for oxygen evolution reaction(OER),thus enhancing the HER/OER catalytic activity.Electrochemical results confirm that Ni/MoO_(2)@CN exhibits good activity for HER(ƞ_(-10)=33 mV,ƞ_(-1000)=267 mV)and OER(ƞ_(10)=250 mV,ƞ_(1000)=420 mV).It shows a low potential of 1.86 V at 1000 mA cm^(−2) for WS in 6.0 M KOH solution at 60℃ and can steadily operate for 330 h.This good HER/OER performance can be attributed to the three-phase heterojunction with high intrinsic activity and the self-supporting nano-needle with more active sites,faster mass diffusion,and bubbles release.This work provides a unique idea for designing high efficiency catalytic materials for WS. 展开更多
关键词 three-phase heterojunction Interfacial electronic redistribution Catalyst Large current density Water splitting
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Equilibrium Reconstruction in EAST Tokamak 被引量:3
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作者 钱金平 万宝年 +8 位作者 L.L.LAO 沈飚 S.A.SABBAGH 孙有文 刘冬梅 肖炳甲 任启龙 龚先祖 李建刚 《Plasma Science and Technology》 SCIE EI CAS CSCD 2009年第2期142-145,共4页
Reconstruction of experimental axisymmetric equilibria is an important part of tokamak data analysis. Fourier expansion is applied to reconstruct the vessel current distribution in EFIT code. Benchmarking and testing ... Reconstruction of experimental axisymmetric equilibria is an important part of tokamak data analysis. Fourier expansion is applied to reconstruct the vessel current distribution in EFIT code. Benchmarking and testing calculations are performed to evaluate and validate this algorithm. Two cases for circular and non-circular plasma discharges are presented. Fourier expansion used to fit the eddy current is a robust method and the real time EFIT can be introduced to the plasma control system in the coming campaign. 展开更多
关键词 plasma equilibrium reconstruction vessel current
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Degradation Process of Coated Tinplate by Phase Space Reconstruction Theory 被引量:4
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作者 石江波 夏大海 +2 位作者 王吉会 周超 刘彦宏 《Transactions of Tianjin University》 EI CAS 2013年第2期92-97,共6页
The degradation process of organosol coated tinplate in beverage was investigated by electrochemical noise (EN) technique combined with morphology characterization.EN data were analyzed using phase space reconstructio... The degradation process of organosol coated tinplate in beverage was investigated by electrochemical noise (EN) technique combined with morphology characterization.EN data were analyzed using phase space reconstruction theory.With the correlation dimensions obtained from the phase space reconstruction,the chaotic behavior of EN was quantitatively evaluated.The results show that both electrochemical potential noise (EPN) and electrochemical current noise (ECN) have chaotic properties.The correlation dimensions of EPN increase with corrosion extent,while those of ECN seem nearly unchanged.The increased correlation dimensions of EPN during the degradation process are associated with the increased susceptibility to local corrosion. 展开更多
关键词 phase space reconstruction CHAOS electrochemical potential noise electrochemical current noise correlation dimension organic coating
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The Reconstruction of the Plasma Boundary in the Sino-United Spherical Tokamak Experiments
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作者 刘健 冯春华 +1 位作者 杨宣宗 王龙 《Plasma Science and Technology》 SCIE EI CAS CSCD 2010年第2期161-165,共5页
A method for the reconstruction of the plasma boundary in the sino-united spherical tokamak (SUNIST) based on the outer plasma magnetic diagnostics is reported. In SUNIST, the magnetic flux loop integral signals wer... A method for the reconstruction of the plasma boundary in the sino-united spherical tokamak (SUNIST) based on the outer plasma magnetic diagnostics is reported. In SUNIST, the magnetic flux loop integral signals were measured recently and the plasma boundary could be reconstructed well with a current filament (CF) model by setting 2 to 8 current filaments. There are three additional filament positional parameters in addition to the filament current to minimize the square root error in the CF model. The plasma configuration obtained with the CF method is consistent with the visible plasma image from the CCD camera. The average difference in the minor radii for the plasma boundary, by applying the CF model and EFIT code, is below 6 mm. 展开更多
关键词 boundary reconstruction spherical tokamak current filament model
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Kinetic equilibrium reconstruction for the NBI-and ICRH-heated H-mode plasma on EAST tokamak
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作者 Zhen ZHENG Nong XIANG +8 位作者 Jiale CHEN Siye DING Hongfei DU Guoqiang LI Yifeng WANG Haiqing LIU Yingying LI Bo LYU Qing ZANG 《Plasma Science and Technology》 SCIE EI CAS CSCD 2018年第6期30-38,共9页
The equilibrium reconstruction is important to study the tokamak plasma physical processes.To analyze the contribution of fast ions to the equilibrium,the kinetic equilibria at two time-slices in a typical H-mode disc... The equilibrium reconstruction is important to study the tokamak plasma physical processes.To analyze the contribution of fast ions to the equilibrium,the kinetic equilibria at two time-slices in a typical H-mode discharge with different auxiliary heatings are reconstructed by using magnetic diagnostics,kinetic diagnostics and TRANSP code.It is found that the fast-ion pressure might be up to one-third of the plasma pressure and the contribution is mainly in the core plasma due to the neutral beam injection power is primarily deposited in the core region.The fast-ion current contributes mainly in the core region while contributes little to the pedestal current.A steep pressure gradient in the pedestal is observed which gives rise to a strong edge current.It is proved that the fast ion effects cannot be ignored and should be considered in the future study of EAST. 展开更多
关键词 kinetic equilibrium reconstruction NBI ICRH pressure gradient edge current fast ions
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The improved PAC method for a three-phase PWM grid-connected inverter
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作者 李杰 马祎炜 +2 位作者 陈国呈 王得利 俞俊杰 《Journal of Shanghai University(English Edition)》 CAS 2008年第6期560-564,共5页
In this paper, a vector regulating principle of the phase and amplitude control PAC method for three-phase grid-connected inverters is presented.To solve the problem of heavy inrush current and slow dynamic response w... In this paper, a vector regulating principle of the phase and amplitude control PAC method for three-phase grid-connected inverters is presented.To solve the problem of heavy inrush current and slow dynamic response when system starts up, the starting voltage prediction control and the current feed-forward control are proposed and used, which improve the dynamic performance of the system in the PAC.The experimental results carried out on a three-phase grid-connected inverter proved the validity of the proposed method. 展开更多
关键词 three-phase pulse width modulation (PWM) grid-connected inverter phase and amplitude control (PAC) starting voltage prediction control current feed-forward control
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FCS-MPC for four-switch three-phase AC-DC converters with DC-link capacitor voltage balancing
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作者 MA Wei-jie ZHANG Bao-ge 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2019年第2期150-156,共7页
Due to the decrease in the number of switches for the four-switch three-phase alternating current-direct current(FSTP AC-DC)converter,it can easily lead to DC-link capacitor voltage imbalance and the system stability ... Due to the decrease in the number of switches for the four-switch three-phase alternating current-direct current(FSTP AC-DC)converter,it can easily lead to DC-link capacitor voltage imbalance and the system stability reduction.In order to solve these problems,a finite control set model predictive control(FCS-MPC)for FSTP AC-DC converters with DC-link capacitor voltage balancing is proposed.In this strategy,in order to facilitate calculation,theαβcoordinate system model is established and all voltage vectors are evaluated by establishing a cost function.During the whole process,phase locked loop(PLL)and complex modulation strategy are not required.In the new established cost function,the additional objective term of suppressing capacitor voltage fluctuation is to eliminate effectively the capacitor voltages oscillations and deviations and improve the system reliability.The simulation results show that the proposed strategy can keep the capacitor voltage balancing and has good dynamic and static performance. 展开更多
关键词 finite control set model predictive control(FCS-MPC) four-switch three-phase alternating current-direct current(FSTP AC-DC)converters cost function capacitor voltage balancing
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Vector Control of Three-Phase Solar Farm Converters Based on Fictive-Axis Emulation
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作者 Kai Kang Qiaoyu Wang Jiayi Meng 《Journal of Computer Science Research》 2020年第3期10-13,共4页
In this paper,a new method for adjusting the current of three-phase voltage source DC-AC converter in orthogonal(DQ)reference frame is presented.In the DQ reference system,AC variable appears in the constant form of D... In this paper,a new method for adjusting the current of three-phase voltage source DC-AC converter in orthogonal(DQ)reference frame is presented.In the DQ reference system,AC variable appears in the constant form of DC,making the controller design the same as the DC-DC converter[1].It provides controllable gain benefits at the steady-state operating point,and finally realizes zero steady-state error[2].In addition,the creative analytical model is dedicated to building up a series of virtual quantities orthogonal to the actual single-phase system.In general,orthogonal imaginary numbers get the reference signal by delaying the real quantity by a quarter period.However,the introduction of such time delay makes the dynamic response of the system worse.In this paper,orthogonal quantities are generated from a virtual axis system parallel to the real axis,which can effectively improve the dynamic performance of traditional methods without increasing the complexity of controller structure.Through PSCAD simulation,the ideal experimental results are obtained. 展开更多
关键词 current Controller Fictive-axis Emulation(FAE) three-phase voltage-source converters(VSCs) Vector controller
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基于单电流传感器的改进相电流重构技术 被引量:1
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作者 徐航 肖曦 +3 位作者 谢玉龙 王潇 曾萍 刘志刚 《电力自动化设备》 EI CSCD 北大核心 2024年第6期96-101,共6页
在电机闭环控制过程中,电流传感器故障、不同电流传感器的不一致性等因素可能导致系统失稳。为提高系统的容错能力,减小故障对控制系统稳定性的影响,提出一种基于单电流传感器的改进相电流重构技术。通过移动脉宽调制的脉冲矢量来消除... 在电机闭环控制过程中,电流传感器故障、不同电流传感器的不一致性等因素可能导致系统失稳。为提高系统的容错能力,减小故障对控制系统稳定性的影响,提出一种基于单电流传感器的改进相电流重构技术。通过移动脉宽调制的脉冲矢量来消除母线电流采样盲区,进而通过母线电流重构获得三相电流。相比于传统电流重构方法,所提改进方法重构的电流更接近真实电流值,能够减小电流总谐波,降低电磁转矩脉动,提升系统的稳态性能。通过仿真和实验对比2种重构方法,证明了所提改进方法的优势。结果表明所提改进方法能有效实现电流重构,提升系统稳态性能。 展开更多
关键词 母线电流 相电流重构 脉冲移位 单电流传感器 电流信号采样 矢量合成
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DCM升压型PFC变换器的电流重整形补偿策略
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作者 张明 罗雷明 +4 位作者 张凯 姜东升 张凡武 雷鹏 闵闰 《电机与控制学报》 EI CSCD 北大核心 2024年第6期181-188,共8页
针对不连续导通模式(DCM)下的升压型功率因数矫正(PFC)变换器,对其中的寄生参数致电流失真(PCD)效应进行研究。考虑元器件寄生参数,求解输入电压、输出电压和占空比的全微分方程,得到精确的阻尼型电感电流解析表达式。研究发现,PCD效应... 针对不连续导通模式(DCM)下的升压型功率因数矫正(PFC)变换器,对其中的寄生参数致电流失真(PCD)效应进行研究。考虑元器件寄生参数,求解输入电压、输出电压和占空比的全微分方程,得到精确的阻尼型电感电流解析表达式。研究发现,PCD效应会导致很大的电流失真,从而显著降低系统功率因数。为了减小PCD效应,通过在不同条件下推导得到的补偿增益,能将输入电流重整为正弦波。对基于无电流传感的平均电流模式(SACM)控制,提出一种能降低PCD效应的电流重整形补偿策略。该策略对阻尼型电感电流方程进行增益补偿,进而降低电流阻尼导致的PCD效应。最后仿真和实验证明,增益补偿几乎不随负载电阻变化,变换器中的PCD效应和电流重整形策略有效。 展开更多
关键词 变换器 电流失真 寄生参数效应 电流重整 增益补偿 功率因数
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基于遗传算法的三相四芯电缆相电流重构方法
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作者 朱俊宇 曾春平 +2 位作者 索春光 张文斌 黄汝金 《仪器仪表学报》 EI CAS CSCD 北大核心 2024年第4期307-316,共10页
目前多芯电缆电流重构方法受限于电缆规格或传感器阵列与线芯需按特定规则摆放导致其在实际工程应用中较为困难。本文提出基于遗传算法进行三相四芯电力电缆线芯分布相关量的求解,进而得到任意线芯分布半径、任意线芯与传感器阵列角度... 目前多芯电缆电流重构方法受限于电缆规格或传感器阵列与线芯需按特定规则摆放导致其在实际工程应用中较为困难。本文提出基于遗传算法进行三相四芯电力电缆线芯分布相关量的求解,进而得到任意线芯分布半径、任意线芯与传感器阵列角度时磁传感器阵列各单元的输出量与各线芯电流之间的耦合系数矩阵的方法,用于重构四芯电缆中各线芯电流。通过仿真验证了算法的可行性。为了能有效降低由于干扰等因素造成的误差,提出了一种先验求解模型以提高解的质量。随后进行了传感单元阵列电路拓扑的设计,使用设计的原型在搭建的实验平台进行了测试,实验结果表明,在三相平衡情况下,测量的三相电流最大误差为2.42%,最大相位误差为2.77°,在三相不平衡情况下,测量的三相电流最大误差为2.52%,最大相位误差为4.17°。实验结果验证了方法的可行性与有效性。 展开更多
关键词 四芯电缆 电流重构 遗传算法 非接触
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异质结构Ni_(2)P/CoP/FeP_(4)纳米线网络催化剂的原位表面重构实现大电流密度下全水分解
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作者 赵婷 巩兵兵 +2 位作者 许贯诚 姜佳慧 张丽 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第6期269-280,共12页
利用可再生能源发电,并通过低温电解水技术生产氢气,被认为是一种环保且可持续的制氢途径,是未来氢能发展的重要方向之一.采用该方法生产的氢气因其环保特性而被称为“绿氢”.然而,目前绿氢高昂的生产成本限制了电解水制氢技术的大规模... 利用可再生能源发电,并通过低温电解水技术生产氢气,被认为是一种环保且可持续的制氢途径,是未来氢能发展的重要方向之一.采用该方法生产的氢气因其环保特性而被称为“绿氢”.然而,目前绿氢高昂的生产成本限制了电解水制氢技术的大规模应用.因此,开发先进的非贵金属催化剂和电催化体系以降低电解水制氢成本具有重要意义.界面工程是一种提升非贵金属催化剂电解水性能的有效策略,但目前对其催化活性位点的识别及活性提升机制的研究仍然不足.本文采用简单的水热及低温磷化法制备了具有丰富异质界面的Ni_(2)P/CoP/FeP_(4)/IF催化剂,并研究了其在电解水过程中的催化活性位点及这些位点在提升催化能力方面的协同作用.采用扫描电镜(SEM)证明了Ni_(2)P/CoP/FeP_(4)/IF催化剂呈现纳米线网络结构,这种结构不仅有利于增加催化剂的电化学活性位点和加速反应动力学,而且促进了连续产生的气泡从活性位点逃逸,从而提高了催化剂的机械稳定性.电化学研究结果表明,所制备Ni_(2)P/CoP/FeP_(4)/IF催化剂在1.0 mol L^(‒1)KOH溶液中表现出较好的析氧反应(OER)和析氢反应(HER)活性,分别仅需218和127 mV的过电位,即可达到100 mA cm^(‒2)的电流密度.将Ni_(2)P/CoP/FeP_(4)/IF分别作为阴极和阳极构建双电极电解槽,该装置产生100和500 mA cm^(‒2)的电流密度分别仅需1.68和2.05 V的电压,这一性能优于大多数已报道的自支撑过渡金属磷化物催化剂.多步计时电位测试结果进一步证实了Ni_(2)P/CoP/FeP_(4)/IF作为阳极和阴极材料在水分解过程中具有较好的长期耐久性.X射线光电子能谱和差分电荷分析表明,电子从富电子的FeP_(4)向缺电子的Ni_(2)P和CoP转移,这促使Ni_(2)P和CoP上的电子积累和FeP_(4)上的空穴积累,有利于优化反应中间体的吸附和脱附自由能,提升OER和HER催化性能.结合X射线衍射、扫描电镜、透射电镜、X射线光电子能谱和原位拉曼光谱结果发现,催化剂重构后形成的特定(氧)氢氧化物结构,是OER反应真正的关键活性位点.原位拉曼光谱进一步证实了异质界面促进了OER过程中Ni_(2)P/CoP/FeP_(4)/IF的快速重构.此外,利用密度泛函理论分析了催化剂的HER反应机理.计算结果表明,H2O优先吸附在Fe位点并发生水解,随后产生的H*吸附在Ni位点上并发生解吸,从而促进了催化剂中Fe和Ni活性位点的高效利用.同时,CoP的引入提高了Ni_(2)P/CoP/FeP_(4)/IF催化剂的水吸附和解离能力,进一步提升了其HER活性.综上所述,本文通过简单的水热及低温磷化法制备了具有丰富异质界面的Ni_(2)P/CoP/FeP_(4)/IF过渡金属磷化物纳米线网络催化剂,并将其用于碱性水分解.通过多种表征技术及理论计算结果分析,识别了电解水过程中的关键催化活性位点,即催化剂重构后形成的特定(氧)氢氧化物结构,并揭示了其在OER和HER反应中的催化机制.本研究可为高性能碱性电解水催化剂的理性设计和开发提供参考. 展开更多
关键词 全水分解 多界面 磷化物 表面重构 大电流密度
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PBDB数据库在古地理重建中的重要应用进展
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作者 王晓楠 任强 +5 位作者 侯明才 董俊玲 陈安清 马超 钟瀚霆 郑栋宇 《沉积与特提斯地质》 CAS CSCD 北大核心 2024年第1期34-44,共11页
大数据时代的信息技术革命带来了科学研究的数字化变革,作为地球科学领域开展数字化科研重要里程碑的古生物数据库Paleobiology Database(PBDB),为古地理研究提供了重要的数据支撑。通过调研PBDB数据库平台内容及其在古地理重建中的应... 大数据时代的信息技术革命带来了科学研究的数字化变革,作为地球科学领域开展数字化科研重要里程碑的古生物数据库Paleobiology Database(PBDB),为古地理研究提供了重要的数据支撑。通过调研PBDB数据库平台内容及其在古地理重建中的应用实例,总结PBDB数据库目前在古地理重建中存在的问题,展望其未来的发展方向。结果表明:(1)古生物数据库包含大量的可溯源数据,是古生物领域研究的重要信息来源和成果交流平台,其中PBDB数据库具有可视化特点,能提供多种数据检索和下载方式,是古地理重建工作的首选古生物数据库;(2)PBDB数据库的分类学和采集记录数据,在约束古地理位置、修订古气候带划分方案、定量古高程古水深、校正古海岸线等古地理重建领域具有明显优势;(3)古生物数据库偏向于古生物研究领域,且古生物记录的历史可能存在偏差和不完整性,其在古地理重建中起辅助约束作用,而非绝对途径;(4)如何实现古生物数据库中数据的自动分类、筛选,如何精确约束古板块位置的相对经度,如何提升古气候、古高程、古水深等研究的精确性,是应用PBDB数据库进行古地理重建的重要发展方向。 展开更多
关键词 PBDB数据库 古生物化石 古地理重建 现存问题 应用展望
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Fe稳固的FeOOH@NiOOH电催化剂的大电流极化设计与析氧研究
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作者 吕青芸 张伟伟 +8 位作者 龙志鹏 王建涛 邹星礼 任伟 侯龙 鲁雄刚 赵玉峰 余兴 李喜 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第7期254-264,共11页
电解水技术是制取高纯度氢气的有效途径,为传统的氢气生产提供了一种可持续的替代方案.其中,开发性能优异的电催化材料是降低电解水制氢成本的关键.析氧反应(OER)由于涉及多个电子转移而导致的动力学缓慢,是克服高过电位的主要挑战.镍... 电解水技术是制取高纯度氢气的有效途径,为传统的氢气生产提供了一种可持续的替代方案.其中,开发性能优异的电催化材料是降低电解水制氢成本的关键.析氧反应(OER)由于涉及多个电子转移而导致的动力学缓慢,是克服高过电位的主要挑战.镍铁羟基/氢氧化物(NiFe(oxy)hydroxides)是近期研究的热点,其在碱性条件下具有极低的OER过电位,部分材料性能甚至超过了贵金属基催化剂,如IrO_(2)和RuO_(2).然而,NiFe(oxy)hydroxides的长期催化稳定性,尤其是在大电流下的长期催化稳定性,成为限制其实际应用的主要问题,这主要是由于铁元素的严重流失导致的.因此,如何有效控制和利用电化学溶解/沉积动力学成为稳定铁位点的关键.为克服该挑战,本文提出了一种大电流极化重构方法来固定活性铁位点.通过在大电流(1.5 A cm^(-2))下对材料进行表面快速极化重构,成功制备了FeOOH@NiOOH(eFNO_(L))电催化剂.eFNO_(L)不仅具有稳定的铁位点,还暴露出高指数晶面,因此eFNO_(L)同时展现出较好的OER催化活性和稳定性.同时,密度泛函理论计算结果表明,与具有低指数晶面的FeNiOOH相比,大电流极化工程制备的分相eFNO_(L)对铁位点表现出更高的结合能,可以有效抑制OER过程中的铁流失,且高指数晶面在改变速率决定步骤和减少吸附能垒上具有更大的优势.电化学测试结果表明,经过优化后的eFNO_(L)催化剂在产生100和500 mA cm^(-2)大电流密度仅需234和27 mV的过电位,并且具有较小的Tafel斜率(35.2 mV dec^(-1)).由于铁位点结合能的提高,eFNO_(L)催化剂在500 mA cm^(-2)的电流密度下能够稳定催化超过100 h,且仅有1.5%的性能衰减,优于近期报道的大多数镍铁基OER催化剂.综上,本文为开发高活性和高稳定性能的催化剂提供了一种有效的大电流电化学重构策略,在电解水制氢领域实现其工业化的大规模应用方面显示出巨大潜力,有望降低可持续电解水制氢成本. 展开更多
关键词 析氧反应 FeOOH@NiOOH 大电流极化重构 高指数晶面 铁位点固定
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基于ACFM单传感器的裂纹角度识别与重构
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作者 李勇 高辉 +1 位作者 周灿丰 李慧聪 《传感器与微系统》 CSCD 北大核心 2024年第7期54-58,共5页
交变电磁场测量(ACFM)技术广泛应用于海洋装备和制造业等领域中金属结构物的缺陷检测。针对单传感器检测过程中存在的角度偏转和裂纹定位等问题展开了研究。首先,通过COMSOL Multi-physics仿真结果可知B_(x)和B_(y)在多角度偏转的过程... 交变电磁场测量(ACFM)技术广泛应用于海洋装备和制造业等领域中金属结构物的缺陷检测。针对单传感器检测过程中存在的角度偏转和裂纹定位等问题展开了研究。首先,通过COMSOL Multi-physics仿真结果可知B_(x)和B_(y)在多角度偏转的过程中存在互补的规律;然后,通过建立比例因子,实现高精度的数值拟合。此外,通过多梯度偏转仿真实现了偏转裂纹的重构。最终通过搭建实验平台和信号特征提取等工作验证了拟合规律的合理性;通过优化拟合公式,提高了检测精度;通过所测角度,进而解决了非平行检测过程中裂纹重构图像的偏转问题。 展开更多
关键词 交变电磁场测量 角度偏转 重构 比例因子 数值拟合
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