Building-integrated photovoltaic(BIPV) is an important application way of solar photovoltaic power. The electric vehicle(EV) charging and parking shed of BIPV is the regeneration energy intellectual integration demons...Building-integrated photovoltaic(BIPV) is an important application way of solar photovoltaic power. The electric vehicle(EV) charging and parking shed of BIPV is the regeneration energy intellectual integration demonstration application system collection of photovoltaic(PV) grid power,PV off- grid power,EV charging and parking shed,and any part of the functions and their combination will be engaged in practical application on demand. The paper describes the PV shed system structure and design in detail with the present of its actual photos. The shed is 50 m long and 5.5 m wide and capable of parking 18 cars. Under the control of system intellectual controller,the power produced by PV from sunlight will charge the parking EV car prior to charging the storage battery,charging the storage battery prior to grid power,grid power at last,and charge the EV by utility grid when it is a cloudy or rainy day.展开更多
Time-dependent density functional theory(TDDFT) method is used to investigate the details of the excited state intramolecular proton transfer(ESIPT) process and the mechanism for temperature effect on the Enol*/K...Time-dependent density functional theory(TDDFT) method is used to investigate the details of the excited state intramolecular proton transfer(ESIPT) process and the mechanism for temperature effect on the Enol*/Keto*emission ratio for the Me2N-substited flavonoid(MNF) compound. The geometric structures of the S0 and S1 states are denoted as the Enol, Enol*, and Keto*. In addition, the absorption and fluorescence peaks are also calculated. It is noted that the calculated large Stokes shift is in good agreement with the experimental result. Furthermore, our results confirm that the ESIPT process happens upon photoexcitation, which is distinctly monitored by the formation and disappearance of the characteristic peaks of infrared(IR) spectra involved in the proton transfer and in the potential energy curves. Besides, the calculations of highest occupied molecular orbital(HOMO) and lowest unoccupied molecular orbital(LUMO) reveal that the electronegativity change of proton acceptor due to the intramolecular charge redistribution in the S1 state induces the ESIPT. Moreover, the thermodynamic calculation for the MNF shows that the Enol*/Keto*emission ratio decreasing with temperature increasing arises from the barrier lowering of ESIPT.展开更多
为了制订自动驾驶车辆(AV)停车需求管理方案,搭建多智能体停车模拟框架,提出2种空载行驶收费策略:基于行驶距离的静态收费和基于道路拥堵水平的动态收费,研究费率计算方法.建立空载行驶收费策略下停车场停车、居住地停车及持续空载巡航...为了制订自动驾驶车辆(AV)停车需求管理方案,搭建多智能体停车模拟框架,提出2种空载行驶收费策略:基于行驶距离的静态收费和基于道路拥堵水平的动态收费,研究费率计算方法.建立空载行驶收费策略下停车场停车、居住地停车及持续空载巡航3种停车模式的成本函数,使用logit模型描述不同停车模式下的选择行为.利用Simulation of urban mobility(SUMO),以南宁市主城区为例开展大规模路网下的仿真实验,研究2种策略下的AV停车行为及路网运行状态变化.仿真结果表明,静态收费策略和动态收费策略下的AV空载行驶里程分别减少了20.16%和10.85%,车辆总延误分别降低了39.80%和43.52%;动态收费策略能够灵活地根据路况变化进行实时调整,路网运行效率提升更显著.展开更多
随着电动汽车(electric vehicle,EV)普及度的不断提高,工业园区内的EV用户日益增多,其充放电行为给园区综合能源系统(park integrated energy system,PIES)的规划运行带来极大挑战。文中提出考虑EV充放电意愿的PIES双层优化调度。首先,...随着电动汽车(electric vehicle,EV)普及度的不断提高,工业园区内的EV用户日益增多,其充放电行为给园区综合能源系统(park integrated energy system,PIES)的规划运行带来极大挑战。文中提出考虑EV充放电意愿的PIES双层优化调度。首先,基于动态实时电价、电池荷电量、电池损耗补偿、额外参与激励等因素建立充放电意愿模型,在此基础上得到改进的EV充放电模型;然后,以PIES总成本最小和EV充电费用最小为目标建立双层优化调度模型,通过Karush-Kuhn-Tucker(KKT)条件将内层模型转化为外层模型的约束条件,从而快速稳定地实现单层模型的求解;最后,进行仿真求解,设置3种不同场景,对比所提模型与一般充放电意愿模型,验证了文中所提引入EV充放电意愿模型的PIES双层优化调度的有效性和可行性。展开更多
The optimization of parking charges and parking supply over the time of a day is an important problem in the design of transportation networks. This paper presents a bilevel model to determine the optimal time-varying...The optimization of parking charges and parking supply over the time of a day is an important problem in the design of transportation networks. This paper presents a bilevel model to determine the optimal time-varying parking charges and parking supply in road networks with multiple user classes and different types of parking facilities. The upper level of the model aims to maximize the network net benefit in response to the parking charges and parking supply, whereas the lower level is a time-dependent network equilibrium problem with elastic demand. A descent-gradient-based solution algorithm is adapted to solve the model. The numerical results show that the implementation of time-varying parking charges and parking supply is useful to effectively cater to the time-varying demand with different parking needs. The model provides a powerful tool for strategically designing parking locations and evaluating various parking policies.展开更多
By solving a time-dependent Schrodinger equation(TDSE), we studied the electron capture process in the He^2++ H collision system under a strong magnetic field in a wide projectile energy range. The strong enhancem...By solving a time-dependent Schrodinger equation(TDSE), we studied the electron capture process in the He^2++ H collision system under a strong magnetic field in a wide projectile energy range. The strong enhancement of the total charge transfer cross section is observed for the projectile energy below 2.0 ke V/u. With the projectile energy increasing, the cross sections will reduce a little and then increase again, compared with those in the field-free case. The cross sections to the states with different magnetic quantum numbers are presented and analyzed where the influence due to Zeeman splitting is obviously found, especially in the low projectile energy region. The comparison with other models is made and the tendency of the cross section varying with the projectile energy is found closer to that from other close coupling models.展开更多
A silver electrode was anodized in lowly concentrated potassium chloride solution almost under the steady state to generate a deposit of silver chloride on the electrode, and the deposit was cathodically stripped by l...A silver electrode was anodized in lowly concentrated potassium chloride solution almost under the steady state to generate a deposit of silver chloride on the electrode, and the deposit was cathodically stripped by linear potential scan to evaluate the reduction charge. Then the oxidation charge was larger than the reduction one. Since the equality was valid for long term chronocoulometry at the double potential step, the inequality is not due to any irreversibility of electrode reactions, but can be attributed to the process of the cathodic potential scan. A reason for the inequality is the negative charge of the capacitance involved in the electrode reaction, which has been observed in simple, dissolved redox species like a ferrocenyl derivative. The negative capacitive currents are conspicuous for high concentrations of redox species on the electrode because they result from the orientation of the dipoles of the redox species coupled with counterion, of which direction is opposite to that of the solvent dipoles. If a silver chloride film was thin enough to be regarded as a monolayer, we found that half of the cathodic stripping charge should be lost by the negative capacitance.展开更多
A quantum chemical screening of two imidazole-based chalcone ligands: 2-</span></span><span><span><span style="font-family:""> </span></span></span><sp...A quantum chemical screening of two imidazole-based chalcone ligands: 2-</span></span><span><span><span style="font-family:""> </span></span></span><span><span><span style="font-family:"">[1-(3-(1H-imidazol-1-yl)propylimino)-3-(phenylallyl)]phenol and 2-</span></span></span><span><span><span style="font-family:"">[1-(3-(1H-</span></span></span><span><span><span style="font-family:""> </span></span></span><span><span><span style="font-family:"">imidazol-1-yl)propylimino)-3-4-nitrophenylallyl]phenol (hereinafter ref</span></span></span><span><span><span style="font-family:"">erred to as HL1 and HL2 respectively) and their Pd, Pt and Zn chelates for charge transport and nonlinear optical (NLO) properties, is reported via dispersion-</span></span></span><span><span><span style="font-family:""> </span></span></span><span><span><span style="font-family:"">corrected density functional theory (DFT-D3) and time-dependent DFT (TD-</span></span></span><span><span><span style="font-family:""> </span></span></span><span><span><span style="font-family:"">DFT) methods. From our results, Pd and Pt complexes have been observed to show excellent hole-transport properties, owing to their very small reorgani<span>zation energies. The <span>light </span>extraction efficiency of the HL1-Pt complex was de</span>duced to be particularly impressive, thus suitable for the manufacture of <span>hole transport</span> layer in violet light emitting diodes (LEDs). Moreover, redox potentials and chemical stability studies have enabled us </span></span></span><span><span><span style="font-family:"">to </span></span></span><span><span><span style="font-family:"">validate the greater <span>stability in moisture (towards oxidation), of HL2 complexes compared to th</span>eir HL1 counterparts. The first and second hyperpolarizabilities of both ligands and their complexes have been found to be outstandingly higher than those of the push-pull prototypical, <span>para</span>-nitroaniline by factors of up to 12 in the case of HL2. These compounds, with the exception of the HL2-Pt complex, are thus interesting candidates having wide transparency tradeoffs for NLO efficiency in the manufacture of optoelectronic and photonic devices capable of second and third-order NLO response. Finally, metal chelation has been established to enhance the NLO response of all the chalcone-based imidazole ligands investigated as a result of metal-ligand charge transfer and ligand-</span></span></span><span><span><span style="font-family:""> </span></span></span><span><span><span style="font-family:"">metal charge transfer electronic transitions identified in the resulting complexes with the exception of the zinc complexes.展开更多
随着私家电动汽车(private electric vehicles,PREV)的普及,大规模PREV的无序充电将引起用电负荷高峰,影响配电网安全。针对商业停车场环境下的PREV充电问题,首先提出一种车辆准入机制,尽可能提高车辆准入数量,并确保准入车辆能够在预...随着私家电动汽车(private electric vehicles,PREV)的普及,大规模PREV的无序充电将引起用电负荷高峰,影响配电网安全。针对商业停车场环境下的PREV充电问题,首先提出一种车辆准入机制,尽可能提高车辆准入数量,并确保准入车辆能够在预定时间内完成充电需求;其次,采用基于熵权法确定适应度函数权重的遗传模拟退火算法(GASA),提出一种面向多目标优化的PREV充电调度策略,综合优化停车场运营商利润和车主充电满意度。实验结果表明,基于GASA的PREV充电调度策略性能良好,与极端情况(车辆数为600的无序充电)相比,该策略的运营商利润和车主充电满意度分别提高了12.3%和109.7%,综合适应度函数值增加了35.2%;另外,其能够有效平缓配电网负荷分布,在保障配电网安全前提下实现停车场运营商和PREV车主的双赢。展开更多
Smart parking lots are smart places capable of supporting both parking and charging services for electric vehicles(EVs).In order to manage EV charging,the parking lot local controller(PLLC)requires data exchange with ...Smart parking lots are smart places capable of supporting both parking and charging services for electric vehicles(EVs).In order to manage EV charging,the parking lot local controller(PLLC)requires data exchange with EV charging stations(EVCSs)through communication infrastructures.However,data losses and communication delays are unavoidable and may significantly degrade the system performance.This work aims to investigate the underlying communication networks for remote monitoring of EVCSs in a smart campus parking lot.The communication network consists of two subnetworks:parking area network(PAN)and campus area network(CAN).PAN covers communication among EVs,charging stations and PLLC,while CAN enables dedicated communication between PLLCs and a global controller of the university.As one of the major obstacles in EV system is the lack of unified communication architecture to integrate EVCS in the power grid,we develop communication models for the in-vehicle system and EVCSs based on logical node concept of IEC 61850 standard.Furthermore,we implement network models for EVCSs using OPNET modeler.Different communication technologies and configurations are considered in modeling and simulations,and end-toend delay is evaluated and discussed.展开更多
基金China Southern Power Grid New Energy Experimental Project(No.03HC0901578)
文摘Building-integrated photovoltaic(BIPV) is an important application way of solar photovoltaic power. The electric vehicle(EV) charging and parking shed of BIPV is the regeneration energy intellectual integration demonstration application system collection of photovoltaic(PV) grid power,PV off- grid power,EV charging and parking shed,and any part of the functions and their combination will be engaged in practical application on demand. The paper describes the PV shed system structure and design in detail with the present of its actual photos. The shed is 50 m long and 5.5 m wide and capable of parking 18 cars. Under the control of system intellectual controller,the power produced by PV from sunlight will charge the parking EV car prior to charging the storage battery,charging the storage battery prior to grid power,grid power at last,and charge the EV by utility grid when it is a cloudy or rainy day.
基金Project supported by the National Basic Research Program of China(Grant No.2013CB922204)the National Natural Science Foundation of China(Grant Nos.11574115 and 11704146)the Natural Science Foundation of Jilin Province,China(Grant No.20150101063JC)
文摘Time-dependent density functional theory(TDDFT) method is used to investigate the details of the excited state intramolecular proton transfer(ESIPT) process and the mechanism for temperature effect on the Enol*/Keto*emission ratio for the Me2N-substited flavonoid(MNF) compound. The geometric structures of the S0 and S1 states are denoted as the Enol, Enol*, and Keto*. In addition, the absorption and fluorescence peaks are also calculated. It is noted that the calculated large Stokes shift is in good agreement with the experimental result. Furthermore, our results confirm that the ESIPT process happens upon photoexcitation, which is distinctly monitored by the formation and disappearance of the characteristic peaks of infrared(IR) spectra involved in the proton transfer and in the potential energy curves. Besides, the calculations of highest occupied molecular orbital(HOMO) and lowest unoccupied molecular orbital(LUMO) reveal that the electronegativity change of proton acceptor due to the intramolecular charge redistribution in the S1 state induces the ESIPT. Moreover, the thermodynamic calculation for the MNF shows that the Enol*/Keto*emission ratio decreasing with temperature increasing arises from the barrier lowering of ESIPT.
文摘为了制订自动驾驶车辆(AV)停车需求管理方案,搭建多智能体停车模拟框架,提出2种空载行驶收费策略:基于行驶距离的静态收费和基于道路拥堵水平的动态收费,研究费率计算方法.建立空载行驶收费策略下停车场停车、居住地停车及持续空载巡航3种停车模式的成本函数,使用logit模型描述不同停车模式下的选择行为.利用Simulation of urban mobility(SUMO),以南宁市主城区为例开展大规模路网下的仿真实验,研究2种策略下的AV停车行为及路网运行状态变化.仿真结果表明,静态收费策略和动态收费策略下的AV空载行驶里程分别减少了20.16%和10.85%,车辆总延误分别降低了39.80%和43.52%;动态收费策略能够灵活地根据路况变化进行实时调整,路网运行效率提升更显著.
文摘随着电动汽车(electric vehicle,EV)普及度的不断提高,工业园区内的EV用户日益增多,其充放电行为给园区综合能源系统(park integrated energy system,PIES)的规划运行带来极大挑战。文中提出考虑EV充放电意愿的PIES双层优化调度。首先,基于动态实时电价、电池荷电量、电池损耗补偿、额外参与激励等因素建立充放电意愿模型,在此基础上得到改进的EV充放电模型;然后,以PIES总成本最小和EV充电费用最小为目标建立双层优化调度模型,通过Karush-Kuhn-Tucker(KKT)条件将内层模型转化为外层模型的约束条件,从而快速稳定地实现单层模型的求解;最后,进行仿真求解,设置3种不同场景,对比所提模型与一般充放电意愿模型,验证了文中所提引入EV充放电意愿模型的PIES双层优化调度的有效性和可行性。
基金Supported by the National Natural Science Foundation of China (Nos. 50578006 and 70521001)the National Basic Research Program of China (No. 2006CB705503)the Research Grants Council of the Hong Kong Special Administrative Region (Nos. PolyU 5084/05E, PolyU 5143/03E, and HKU 7134/03E)
文摘The optimization of parking charges and parking supply over the time of a day is an important problem in the design of transportation networks. This paper presents a bilevel model to determine the optimal time-varying parking charges and parking supply in road networks with multiple user classes and different types of parking facilities. The upper level of the model aims to maximize the network net benefit in response to the parking charges and parking supply, whereas the lower level is a time-dependent network equilibrium problem with elastic demand. A descent-gradient-based solution algorithm is adapted to solve the model. The numerical results show that the implementation of time-varying parking charges and parking supply is useful to effectively cater to the time-varying demand with different parking needs. The model provides a powerful tool for strategically designing parking locations and evaluating various parking policies.
基金Project supported by the National Natural Science Foundation of China(Grants Nos.11104017,11025417,11275029,and 11474032)the National Basic Research Programm of China(Grant No.2013CB922200)the Foundation for the Development of Science and Technology of the Chinese Academy of Engineering Physics(Grant Nos.2014B09036 and 2013A0102005)
文摘By solving a time-dependent Schrodinger equation(TDSE), we studied the electron capture process in the He^2++ H collision system under a strong magnetic field in a wide projectile energy range. The strong enhancement of the total charge transfer cross section is observed for the projectile energy below 2.0 ke V/u. With the projectile energy increasing, the cross sections will reduce a little and then increase again, compared with those in the field-free case. The cross sections to the states with different magnetic quantum numbers are presented and analyzed where the influence due to Zeeman splitting is obviously found, especially in the low projectile energy region. The comparison with other models is made and the tendency of the cross section varying with the projectile energy is found closer to that from other close coupling models.
文摘A silver electrode was anodized in lowly concentrated potassium chloride solution almost under the steady state to generate a deposit of silver chloride on the electrode, and the deposit was cathodically stripped by linear potential scan to evaluate the reduction charge. Then the oxidation charge was larger than the reduction one. Since the equality was valid for long term chronocoulometry at the double potential step, the inequality is not due to any irreversibility of electrode reactions, but can be attributed to the process of the cathodic potential scan. A reason for the inequality is the negative charge of the capacitance involved in the electrode reaction, which has been observed in simple, dissolved redox species like a ferrocenyl derivative. The negative capacitive currents are conspicuous for high concentrations of redox species on the electrode because they result from the orientation of the dipoles of the redox species coupled with counterion, of which direction is opposite to that of the solvent dipoles. If a silver chloride film was thin enough to be regarded as a monolayer, we found that half of the cathodic stripping charge should be lost by the negative capacitance.
文摘A quantum chemical screening of two imidazole-based chalcone ligands: 2-</span></span><span><span><span style="font-family:""> </span></span></span><span><span><span style="font-family:"">[1-(3-(1H-imidazol-1-yl)propylimino)-3-(phenylallyl)]phenol and 2-</span></span></span><span><span><span style="font-family:"">[1-(3-(1H-</span></span></span><span><span><span style="font-family:""> </span></span></span><span><span><span style="font-family:"">imidazol-1-yl)propylimino)-3-4-nitrophenylallyl]phenol (hereinafter ref</span></span></span><span><span><span style="font-family:"">erred to as HL1 and HL2 respectively) and their Pd, Pt and Zn chelates for charge transport and nonlinear optical (NLO) properties, is reported via dispersion-</span></span></span><span><span><span style="font-family:""> </span></span></span><span><span><span style="font-family:"">corrected density functional theory (DFT-D3) and time-dependent DFT (TD-</span></span></span><span><span><span style="font-family:""> </span></span></span><span><span><span style="font-family:"">DFT) methods. From our results, Pd and Pt complexes have been observed to show excellent hole-transport properties, owing to their very small reorgani<span>zation energies. The <span>light </span>extraction efficiency of the HL1-Pt complex was de</span>duced to be particularly impressive, thus suitable for the manufacture of <span>hole transport</span> layer in violet light emitting diodes (LEDs). Moreover, redox potentials and chemical stability studies have enabled us </span></span></span><span><span><span style="font-family:"">to </span></span></span><span><span><span style="font-family:"">validate the greater <span>stability in moisture (towards oxidation), of HL2 complexes compared to th</span>eir HL1 counterparts. The first and second hyperpolarizabilities of both ligands and their complexes have been found to be outstandingly higher than those of the push-pull prototypical, <span>para</span>-nitroaniline by factors of up to 12 in the case of HL2. These compounds, with the exception of the HL2-Pt complex, are thus interesting candidates having wide transparency tradeoffs for NLO efficiency in the manufacture of optoelectronic and photonic devices capable of second and third-order NLO response. Finally, metal chelation has been established to enhance the NLO response of all the chalcone-based imidazole ligands investigated as a result of metal-ligand charge transfer and ligand-</span></span></span><span><span><span style="font-family:""> </span></span></span><span><span><span style="font-family:"">metal charge transfer electronic transitions identified in the resulting complexes with the exception of the zinc complexes.
文摘随着私家电动汽车(private electric vehicles,PREV)的普及,大规模PREV的无序充电将引起用电负荷高峰,影响配电网安全。针对商业停车场环境下的PREV充电问题,首先提出一种车辆准入机制,尽可能提高车辆准入数量,并确保准入车辆能够在预定时间内完成充电需求;其次,采用基于熵权法确定适应度函数权重的遗传模拟退火算法(GASA),提出一种面向多目标优化的PREV充电调度策略,综合优化停车场运营商利润和车主充电满意度。实验结果表明,基于GASA的PREV充电调度策略性能良好,与极端情况(车辆数为600的无序充电)相比,该策略的运营商利润和车主充电满意度分别提高了12.3%和109.7%,综合适应度函数值增加了35.2%;另外,其能够有效平缓配电网负荷分布,在保障配电网安全前提下实现停车场运营商和PREV车主的双赢。
基金supported by the National Research Foundation of Korea(NRF)grant funded by Korea government(MIST)(No.2017R1A2B4004868).
文摘Smart parking lots are smart places capable of supporting both parking and charging services for electric vehicles(EVs).In order to manage EV charging,the parking lot local controller(PLLC)requires data exchange with EV charging stations(EVCSs)through communication infrastructures.However,data losses and communication delays are unavoidable and may significantly degrade the system performance.This work aims to investigate the underlying communication networks for remote monitoring of EVCSs in a smart campus parking lot.The communication network consists of two subnetworks:parking area network(PAN)and campus area network(CAN).PAN covers communication among EVs,charging stations and PLLC,while CAN enables dedicated communication between PLLCs and a global controller of the university.As one of the major obstacles in EV system is the lack of unified communication architecture to integrate EVCS in the power grid,we develop communication models for the in-vehicle system and EVCSs based on logical node concept of IEC 61850 standard.Furthermore,we implement network models for EVCSs using OPNET modeler.Different communication technologies and configurations are considered in modeling and simulations,and end-toend delay is evaluated and discussed.