期刊文献+
共找到3篇文章
< 1 >
每页显示 20 50 100
Temperature-dependent photoluminescence of lead-free cesium tin halide perovskite microplates
1
作者 谭佳雨 周译玄 +6 位作者 卢德 冯旭坤 刘玉琪 张蒙恩 卢方正一 黄媛媛 徐新龙 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第11期116-123,共8页
Tin halide perovskites recently have attracted extensive research attention due to their similar electronic and band structures but non-toxicity compared with their lead analogues. In this work, we prepare high-qualit... Tin halide perovskites recently have attracted extensive research attention due to their similar electronic and band structures but non-toxicity compared with their lead analogues. In this work, we prepare high-quality CsSnX_(3)(X=Br,I) microplates with lateral sizes of around 1–4 μm by chemical vapor deposition and investigate their low-temperature photoluminescence(PL) properties. A remarkable splitting of PL peaks of the CsSnBr_(3)microplate is observed at low temperatures. Besides the possible structural phase transition at below 70 K, the multi-peak fittings using Gauss functions and the power-dependent saturation phenomenon suggest that the PL could also be influenced by the conversion from the emission of bound excitons into free excitons. With the increase of temperature, the peak position shows a blueshift tendency for CsSnI_(3), which is governed by thermal expansion. However, the peak position of the CsSnBr3microplate exhibits a transition from redshift to blueshift at ~160 K. The full width at half maximum of CsSnX_(3)broadens with increasing temperature, and the fitting results imply that longitudinal optical phonons dominate the electron–phonon coupling and the coupling strength is much more robust in CsSnBr3than in CsSnI_(3). The PL intensity of CsSnX_(3)microplates is suppressed due to the enhanced non-radiative relaxation and exciton dissociation competing with radiative recombination. According to the Arrhenius law, the exciton binding energy of CsSnBr_(3)is ~38.4 meV, slightly smaller than that of CsSnI_(3). 展开更多
关键词 cesium tin halide perovskite temperature-dependent photoluminescence chemical vapor deposi-tion MICROPLATE
下载PDF
A New Inorganic-organic Hybrid Based on Biisoquinoline and Hexachloridostannate:Structure, Photoluminescence, Electrochemical Behavior and Theoretical Study 被引量:1
2
作者 肖光参 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2014年第11期1689-1696,共8页
A new inorganic-organic hybrid constructed from biisoquinoline dication and tin halide, [(BIQBT)(Sn Cl6)]n(1, BIQBT = 1,4-bis(isoquinoline) butane), has been synthesized and structurally determined by X-ray di... A new inorganic-organic hybrid constructed from biisoquinoline dication and tin halide, [(BIQBT)(Sn Cl6)]n(1, BIQBT = 1,4-bis(isoquinoline) butane), has been synthesized and structurally determined by X-ray diffraction method. 1 crystallizes in the monoclinic system, space group Cc with Mr = 644.82, a = 16.589(3), b = 18.388(4), c = 8.5532(17)A, β = 108.75(3)°, V = 2470.6(9) A3, Z = 4, Dc = 1.736 g/cm^3, F(000) = 1281, μ(Mo Kα) = 1.697 mm^–1, the final R = 0.0197 and wR = 0.0493 for 4614 observed reflections with I 〉 2(I). 1 consists of BIQBT^2+dications and mononuclear hexachloridostannate Sn Cl62- anion, and hydrogen bonds among them contribute to the formation of a 1-D chain. Strong fluorescence can be detected in 1, which was explained by theoretical calculation. Its electrochemical behavior was investigated, and the theoretical calculations reveal that the π···π stacking interaction is dominated for their structural stabilization. 展开更多
关键词 inorganic-organic hybrid tin halide biisoquinoline electrochemical property DFT calculation
下载PDF
Enhanced efficiency and stability in Sn-based perovskite solar cells by trimethylsilyl halide surface passivation
3
作者 Zheng Zhang Liang Wang +14 位作者 Ajay Kumar Baranwal Shahrir Razey Sahamir Gaurav Kapil Yoshitaka Sanehira Muhammad Akmal Kamarudin Kohei Nishimura Chao Ding Dong Liu Yusheng Li Hua Li Mengmeng Chen Qing Shen Teresa SRipolles Juan Bisquert Shuzi Hayase 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第8期604-611,I0016,共9页
Lead free tin perovskite solar cells(PKSCs)are the most suitable alternative candidate for conventional lead perovskite solar cells.However,the efficiency and the stability are insufficient,mainly because of the poor ... Lead free tin perovskite solar cells(PKSCs)are the most suitable alternative candidate for conventional lead perovskite solar cells.However,the efficiency and the stability are insufficient,mainly because of the poor film quality and numerous defects.Here we introduce an efficient strategy based on a simple trimethylsilyl halide surface passivation to increase the film quality and reduce the defect density.At the same time,a hydrophobic protective layer on the perovskite surface is formed,which enhanced the PKSCs’stability.The efficiency of the solar cell after the passivation was enhanced from 10.05%to 12.22%with the improved open-circuit voltage from 0.57 V to 0.70 V.In addition,after 92 days of storage in N_(2) filled glovebox,the modified T-PKSCs demonstrated high stability maintaining 80%of its initial efficiency.This work provides a simple and widely used strategy to optimize the surface/interface optoelectronic properties of perovskites for giving more efficient and stable solar cells and other optoelectronic devices. 展开更多
关键词 tin halide perovskite Trimethylsilyl halide Surface passivation STABILITY
下载PDF
上一页 1 下一页 到第
使用帮助 返回顶部