Improved controllability and energy density of ignition agents are of great significance for the devel-opment of energetic composite materials.In this study,droplet microfluidics and emulsification tech-niques were co...Improved controllability and energy density of ignition agents are of great significance for the devel-opment of energetic composite materials.In this study,droplet microfluidics and emulsification tech-niques were combined to prepare HNS/CL-20 composite microspheres with polyglycidyl azide polymer(GAP)as the binder.The influence of binder content on the morphology of microspheres was investi-gated,and the microspheres were characterized and tested for particle size,crystal structure,thermal decomposition,dispersibility,mechanical sensitivity,combustion behavior and detonation performance.The results showed that microspheres prepared with a binder content of 3%had higher sphericity and particle size uniformity.The microspheres retained the crystal structure of both HNS and CL-20(ε-type).Compared with raw HNS,the microspheres had higher apparent activation energy,better safety per-formance,and good dispersibility.The ignition experiments and detonation performance tests show that HNS/CL-20 composite microspheres have excellent ignition performance,obvious combustion flame,and significant energy release effects,which are expected to achieve high energy and high-speed response of the igniter,thus improving the ignition reliability in special environments or systems.展开更多
As the low temperature non-equilibrium plasma,microwave plasma has the same effects with the plasma produced by the traditional high voltage electrode,which has the function of widening ignition boundary and improving...As the low temperature non-equilibrium plasma,microwave plasma has the same effects with the plasma produced by the traditional high voltage electrode,which has the function of widening ignition boundary and improving combustion.Microwave has the advantages of uniformity,particle selectivity and no electrode.It can generate a large range of non-equilibrium plasma with relatively low power without electrode ablation.Therefore,how to maximize its effectiveness has become the research hotspot of ignition and combustion in engines.At present,the related research mainly focuses on microwave plasma discharge and microwave assisted spark ignition.The results show that it can broaden lean and rich burn flammability limits,improve combustion efficiency,accelerate flame propagation speed,and reduce pollutant emissions.This paper summarizes the related research at home and abroad in recent years,the main conclusion is that how the microwave plasma affects the turbulence intensity of flow field will be the promising research,and the research trend of microwave plasma ignition and assisted combustion in future will be the research of microwave assisted plasma igniter.展开更多
With the objective of producing a full-scale tiny-oil ignition burner, identical to the burner used in an 800 MWe utility boiler, numerical simulations were performed using Fluent 6.3.26 to study the progress of ignit...With the objective of producing a full-scale tiny-oil ignition burner, identical to the burner used in an 800 MWe utility boiler, numerical simulations were performed using Fluent 6.3.26 to study the progress of ignition for four coal concentration settings covering sub- operation conditions prevailing during the experiments performed with the burner. The numerical simulations conformed to the experimental results, demonstrating the suitability of the model used in the calculations. Simula- tions for a coal concentration of 0.40 kg/kg corresponding to a single burner operating at its rated output were also conducted, which indicated that gas temperatures along the burner centerline were high. As gas flowed to the burner nozzle, the high-temperature region expanded, ensuring a successful pulverized-coal ignition. With increasing coal concentration (0.08-0.40 kg/kg), the gas temperature along the burner centerline and at the first and second combustion chamber exits decreased at the equivalent radial points. At the center of the second combustion chamber exit, the O2 concentrations were almost depleted for the five coal concentrations, while the CO concentrations peaked.展开更多
The progression of ignition was numerically simulated with the aim of realizing a full-scale tiny-oil ignition burner that is identical to the burner used in an 800 MWe utility boiler. The numerical simulations were c...The progression of ignition was numerically simulated with the aim of realizing a full-scale tiny-oil ignition burner that is identical to the burner used in an 800 MWe utility boiler. The numerical simulations were conducted for four excess air ratios, 0.56, 0.75, 0.98 and 1.14 (corresponding to primary air velocities of 17, 23, 30 and 35 m/s, respectively), which were chosen because they had been used previously in practical experiments. The numerical simulations agreed well with the experimental results, which demonstrate the suitability of the model used in the calculations. The gas temperatures were high along the center line of the burner for the four excess air ratios. The flame spread to the bumer wall and the high- temperature region was enlarged in the radial direction along the primary air flow direction. The O2 concentrations for the four excess air ratios were 0.5%, 1.1%, 0.9% and 3.0% at the exit of the second combustion chamber. The CO peak concentration was very high with values of 7.9%, 9.9%, 11.3% and 10.6% for the four excess air ratios at the exit of the second combustion chamber.展开更多
基金supported by National Natural Science Foundation of China(grant No.22005275).
文摘Improved controllability and energy density of ignition agents are of great significance for the devel-opment of energetic composite materials.In this study,droplet microfluidics and emulsification tech-niques were combined to prepare HNS/CL-20 composite microspheres with polyglycidyl azide polymer(GAP)as the binder.The influence of binder content on the morphology of microspheres was investi-gated,and the microspheres were characterized and tested for particle size,crystal structure,thermal decomposition,dispersibility,mechanical sensitivity,combustion behavior and detonation performance.The results showed that microspheres prepared with a binder content of 3%had higher sphericity and particle size uniformity.The microspheres retained the crystal structure of both HNS and CL-20(ε-type).Compared with raw HNS,the microspheres had higher apparent activation energy,better safety per-formance,and good dispersibility.The ignition experiments and detonation performance tests show that HNS/CL-20 composite microspheres have excellent ignition performance,obvious combustion flame,and significant energy release effects,which are expected to achieve high energy and high-speed response of the igniter,thus improving the ignition reliability in special environments or systems.
基金supported by the National Natural Science Foundation of China(No.51436008)。
文摘As the low temperature non-equilibrium plasma,microwave plasma has the same effects with the plasma produced by the traditional high voltage electrode,which has the function of widening ignition boundary and improving combustion.Microwave has the advantages of uniformity,particle selectivity and no electrode.It can generate a large range of non-equilibrium plasma with relatively low power without electrode ablation.Therefore,how to maximize its effectiveness has become the research hotspot of ignition and combustion in engines.At present,the related research mainly focuses on microwave plasma discharge and microwave assisted spark ignition.The results show that it can broaden lean and rich burn flammability limits,improve combustion efficiency,accelerate flame propagation speed,and reduce pollutant emissions.This paper summarizes the related research at home and abroad in recent years,the main conclusion is that how the microwave plasma affects the turbulence intensity of flow field will be the promising research,and the research trend of microwave plasma ignition and assisted combustion in future will be the research of microwave assisted plasma igniter.
基金sponsored by the Hi-Tech Research and Development Program of China (863 program) (Grant No. 2006AA05Z321) and supported by the Foundation for Innovative Research Groups of the National Natural Science Foundation of China (Grant No. 51121004).
文摘With the objective of producing a full-scale tiny-oil ignition burner, identical to the burner used in an 800 MWe utility boiler, numerical simulations were performed using Fluent 6.3.26 to study the progress of ignition for four coal concentration settings covering sub- operation conditions prevailing during the experiments performed with the burner. The numerical simulations conformed to the experimental results, demonstrating the suitability of the model used in the calculations. Simula- tions for a coal concentration of 0.40 kg/kg corresponding to a single burner operating at its rated output were also conducted, which indicated that gas temperatures along the burner centerline were high. As gas flowed to the burner nozzle, the high-temperature region expanded, ensuring a successful pulverized-coal ignition. With increasing coal concentration (0.08-0.40 kg/kg), the gas temperature along the burner centerline and at the first and second combustion chamber exits decreased at the equivalent radial points. At the center of the second combustion chamber exit, the O2 concentrations were almost depleted for the five coal concentrations, while the CO concentrations peaked.
文摘The progression of ignition was numerically simulated with the aim of realizing a full-scale tiny-oil ignition burner that is identical to the burner used in an 800 MWe utility boiler. The numerical simulations were conducted for four excess air ratios, 0.56, 0.75, 0.98 and 1.14 (corresponding to primary air velocities of 17, 23, 30 and 35 m/s, respectively), which were chosen because they had been used previously in practical experiments. The numerical simulations agreed well with the experimental results, which demonstrate the suitability of the model used in the calculations. The gas temperatures were high along the center line of the burner for the four excess air ratios. The flame spread to the bumer wall and the high- temperature region was enlarged in the radial direction along the primary air flow direction. The O2 concentrations for the four excess air ratios were 0.5%, 1.1%, 0.9% and 3.0% at the exit of the second combustion chamber. The CO peak concentration was very high with values of 7.9%, 9.9%, 11.3% and 10.6% for the four excess air ratios at the exit of the second combustion chamber.