Titanium dioxide films were firstly deposited on glass substrate by DBD-CVD （dielectric barrier discharge enhanced chemical vapor deposition） technique. The structure of the films was investigated by X-ray diffracti...Titanium dioxide films were firstly deposited on glass substrate by DBD-CVD （dielectric barrier discharge enhanced chemical vapor deposition） technique. The structure of the films was investigated by X-ray diffraction （XRD）, scanning electron microscopy （SEM）. TiO2 films deposited under atmosphere pressure show preferred orientation, and exhibit columnar-like structure, while TiO2 films deposited under low gas pressure show no preferred orientation. The columnar-like structure with preferred orientation exhibits higher photocatalytic efficiency, since the columnar structure has larger surface area. However, it contributes little to the improvement of hydrophilicity. DBD-CVD is an alternative method to prepare photocatalytic TiO2 for its well-controllable property.展开更多
The preparation of a new mineral composite material, calcium carbonate particles coated with titanium dioxide, was studied. The mechanism of the preparation process was proposed. The new mineral composite material was...The preparation of a new mineral composite material, calcium carbonate particles coated with titanium dioxide, was studied. The mechanism of the preparation process was proposed. The new mineral composite material was made by the mechanoehemieal method under the optimum condition that the mass ratio of calcium carbonate particles to titanium dioxide was 6.5：3.5. The mass ratios of two different types of titanium dioxide （anatase to rutile） and grinding media to grinded materials were 8：2 and 4：1 respectively, and the modified density was 60%. Under this condition, the new material was capable of forming after 120-min modification. The hiding power and oil absorption of this new material were 29.12 g/m^2 and 23.30%, respectively. The results show that the modification is based on surface hydroxylation. After coating with titanium dioxide, the hiding power of calcium carbonate can be improved greatly. The new mineral composite materials can be used as the substitute for titanium dioxide.展开更多
Titanium dioxide （TiO2） films with rod-like and sphere-like TiO2 particles were prepared on glass slides employing the sol-gel method. The shape and size of TiO2 particles were controlled using different concentrati...Titanium dioxide （TiO2） films with rod-like and sphere-like TiO2 particles were prepared on glass slides employing the sol-gel method. The shape and size of TiO2 particles were controlled using different concentrations of sodium dodecylbenzensulfonate （SDBS）. By increasing the mole ratio of SDBS, the shape of TiO2 particles transformed from rod-like to sphere-like. Also, the size of TiO2 particles became gradually smaller. Then, the size became bigger when an excess amount of SDBS was added. The films were mainly composed of anatase titania and the relative content of anatase increased with the increasing amount of SDBS. The photocatalytic activity of the TiO2 films that were added with SDBS was higher than that without SDBS. When the concentration of SDBS was 8.0 at%, the sample exhibited the best photocatalytic activity.展开更多
文摘Titanium dioxide films were firstly deposited on glass substrate by DBD-CVD （dielectric barrier discharge enhanced chemical vapor deposition） technique. The structure of the films was investigated by X-ray diffraction （XRD）, scanning electron microscopy （SEM）. TiO2 films deposited under atmosphere pressure show preferred orientation, and exhibit columnar-like structure, while TiO2 films deposited under low gas pressure show no preferred orientation. The columnar-like structure with preferred orientation exhibits higher photocatalytic efficiency, since the columnar structure has larger surface area. However, it contributes little to the improvement of hydrophilicity. DBD-CVD is an alternative method to prepare photocatalytic TiO2 for its well-controllable property.
文摘The preparation of a new mineral composite material, calcium carbonate particles coated with titanium dioxide, was studied. The mechanism of the preparation process was proposed. The new mineral composite material was made by the mechanoehemieal method under the optimum condition that the mass ratio of calcium carbonate particles to titanium dioxide was 6.5：3.5. The mass ratios of two different types of titanium dioxide （anatase to rutile） and grinding media to grinded materials were 8：2 and 4：1 respectively, and the modified density was 60%. Under this condition, the new material was capable of forming after 120-min modification. The hiding power and oil absorption of this new material were 29.12 g/m^2 and 23.30%, respectively. The results show that the modification is based on surface hydroxylation. After coating with titanium dioxide, the hiding power of calcium carbonate can be improved greatly. The new mineral composite materials can be used as the substitute for titanium dioxide.
基金supported by the Foundation of the Department of Education of Hebei Province, China (No. 2005362)the Foundation of Hebei Normal University (L2008K02)
文摘Titanium dioxide （TiO2） films with rod-like and sphere-like TiO2 particles were prepared on glass slides employing the sol-gel method. The shape and size of TiO2 particles were controlled using different concentrations of sodium dodecylbenzensulfonate （SDBS）. By increasing the mole ratio of SDBS, the shape of TiO2 particles transformed from rod-like to sphere-like. Also, the size of TiO2 particles became gradually smaller. Then, the size became bigger when an excess amount of SDBS was added. The films were mainly composed of anatase titania and the relative content of anatase increased with the increasing amount of SDBS. The photocatalytic activity of the TiO2 films that were added with SDBS was higher than that without SDBS. When the concentration of SDBS was 8.0 at%, the sample exhibited the best photocatalytic activity.
