China has had 30 years experience in titanium research,development,production and appli-cation so far.It was really a rough and bumpy road for developing Ti working industry,however,since a large amount of work was do...China has had 30 years experience in titanium research,development,production and appli-cation so far.It was really a rough and bumpy road for developing Ti working industry,however,since a large amount of work was done and great many achievements were obtained by the scien-tists and engineers in this field,a firm base of Ti working industry has been established in China atlast.Especially since the beginning of 1980 s,it has been developed to a new level.On these bases,afavourable condition to speed up the development of Ti working industry arises in China.展开更多
Nowadays 80%of scandium in China is obtained from titanium pigments production waste through a complex purification process.The study mainly focused on the purification of Sc from its concentrate generated from titani...Nowadays 80%of scandium in China is obtained from titanium pigments production waste through a complex purification process.The study mainly focused on the purification of Sc from its concentrate generated from titanium pigments production waste by solvent extraction.Several extractants have been tried and 10%D_(2)EHPA-5%TBP-85%sulfonated kerosene exhibited the best extraction performance towards Sc in 7 mol/L H_(2)SO_(4)solution,so it was selected as the oil phase.0.5%of H_(2)O_(2)was added into the concentrated solution which can effectively inhibit the extraction of Ti.Both the extraction and back extraction parameters are optimized.The preferred extraction conditions were obtained,i.e.,acidity:7 mol/L H_(2)SO_(4),the phase ratio A/O:10,room temperature,mixed contact time:30 min,Sc concentrate:10 g/L,that the extraction rate of Sc in the above conditions was nearly 100%.NaOH was used for back extraction with the stripping rate 99%on the following conditions:5 mol/L NaOH stripping for 30 min at a phase ratio A/O:1 at 90℃.Finally,H_(2)C_(2)O_(4)was used to further purify the back extraction product and Sc_(2)(C_(2)O_(4))_(3)precipitant fo rmed.The final product Sc_(2)O_(3)with a purity over 99.5%was obtained by calcining Sc_(2)(C_(2)O_(4))_(3)at 1000℃for 2 h.A conceptual process for Sc purification was put forward and proved.The total recovery yield of Sc in the whole process is 95%.展开更多
文摘China has had 30 years experience in titanium research,development,production and appli-cation so far.It was really a rough and bumpy road for developing Ti working industry,however,since a large amount of work was done and great many achievements were obtained by the scien-tists and engineers in this field,a firm base of Ti working industry has been established in China atlast.Especially since the beginning of 1980 s,it has been developed to a new level.On these bases,afavourable condition to speed up the development of Ti working industry arises in China.
基金the National Natural Science Foundation of China(11705032,11675102)Natural Science Foundation of Guangxi Province(2017GXNSFBA198175)Science and Technology Major Project of Guangxi Province(AA17204100)。
文摘Nowadays 80%of scandium in China is obtained from titanium pigments production waste through a complex purification process.The study mainly focused on the purification of Sc from its concentrate generated from titanium pigments production waste by solvent extraction.Several extractants have been tried and 10%D_(2)EHPA-5%TBP-85%sulfonated kerosene exhibited the best extraction performance towards Sc in 7 mol/L H_(2)SO_(4)solution,so it was selected as the oil phase.0.5%of H_(2)O_(2)was added into the concentrated solution which can effectively inhibit the extraction of Ti.Both the extraction and back extraction parameters are optimized.The preferred extraction conditions were obtained,i.e.,acidity:7 mol/L H_(2)SO_(4),the phase ratio A/O:10,room temperature,mixed contact time:30 min,Sc concentrate:10 g/L,that the extraction rate of Sc in the above conditions was nearly 100%.NaOH was used for back extraction with the stripping rate 99%on the following conditions:5 mol/L NaOH stripping for 30 min at a phase ratio A/O:1 at 90℃.Finally,H_(2)C_(2)O_(4)was used to further purify the back extraction product and Sc_(2)(C_(2)O_(4))_(3)precipitant fo rmed.The final product Sc_(2)O_(3)with a purity over 99.5%was obtained by calcining Sc_(2)(C_(2)O_(4))_(3)at 1000℃for 2 h.A conceptual process for Sc purification was put forward and proved.The total recovery yield of Sc in the whole process is 95%.
