A comparison between high temperature catalytic and persulfate oxidation for the determination of total dissolved nitrogen in natural waters

Total dissolved nitrogen(TDN) is an important parameter for assessing the nutrient cycling and status of natural waters.The accurate determination of TDN in natural waters is essential for assessing its contents and distinguishing different forms of nitrogen in the water.The TDN in various systems has been largely documented,and the concentrations of TDN are usually obtained using high-temperature catalytic(HTC) or persulfate oxidation(PO).However,the accuracy of these methods and their suitability for all types of natural waters are still unclear.To explore both methods in-depth,assorted samples were tested,including eight solutions composed of nitrogen-containing compounds(3 dissolved inorganic nitrogen fractions:NO_(3)^(-),NO_(2)^(-)and NH_(4)^(+);5 organic compounds:EDTA-2Na,vitamin B1,vitamin B12,amino acids,and urea) and 105 natural waters which were collected from an open ocean(Northwest Pacific Ocean,28),a marginal sea(Yellow Sea,34),an estuary(Huanghe River mouth,31),rivers(Huanghe River,4;Licun River,4),and precipitations(4 samples).The results showed that heterocycles and molecular dimensions had certain effects on the oxidation efficiency of the PO method but had little effect on HTC.There was no significant difference between the two methods for natural waters,but HTC was more suitable for deep-sea samples with low TDN concentrations(less than 10 μmol/L) and low organic activity.Overall,HTC has a relatively simple measurement process,a high degree of automation,and low error.Therefore,HTC can be recommended to determine the TDN of samples in freshwater and seawater.

Total Maximum Allocated Loads on Stoichiometry of Nitrogen and Identification of Critical Form in Jiaozhou Bay, China

Total pollutant load control management for total dissolved nitrogen(TDN) is an urgent task required to gain a good water quality status in Jiaozhou Bay(JZB), China. In this paper, the stoichiometry of multiform TDN on land-ocean interactions associated with marine biogeochemical reaction(LOIMBR) was studied by modeling the load-response relationship based on a three-dimensional water quality model of nitrogen in JZB. The results showed that the stoichiometry on LOIMBR of dissolved organic nitrogen(DON), NO3-N and NH4-N was 3:1:1, with one-third of the contribution on the concentration of dissolved inorganic nitrogen(DIN) in JZB for the land-based DON loads to DIN loads. Based on the stoichiometric relationship of nitrogen forms, the total maximum allocated load(TMAL) of equivalent TDN(ETDN) was approximately 5300 t a^-1 in JZB, equivalent to the TMAL of 5700, 5800 and 15600 t a^-1 for NH4-N, NO3-N and DON, respectively. According to the loads of ETDN, there were four outfalls overloaded in JZB in 2015, which lie in the head of the bay. In the four overloaded outfalls, besides NO3-N, NH4-N was the critical nitrogen control form for Moshui River, while DON for Dagu River and Haibo River. The results of numerical experiments further showed that JZB will achieve good water quality after 7 years by implementation of the 'different emission reduction' based on TMAL of ETDN, which is significantly better than 'equal percent removal'.

Concentration,sources and wet deposition of dissolved nitrogen and organic carbon in the Northern Indo-Gangetic Plain during monsoon

Precipitation represents an important phenomenon for carbon and nitrogen deposition.Here,the concentrations and fluxes of dissolved organic carbon(DOC)and total dissolved nitrogen(TDN)with their potential sources were analyzed in wet precipitation during summer monsoon from the Northern Indo-Gangetic Plain(IGP),important but neglected area.The volume-weighted mean(VWM)concentration of DOC and TDN were 687.04 and 1210.23μg/L,respectively.Similarly,the VWM concentration of major ions were in a sequence of NH_(4)^(+)>Ca^(2+)>SO_(4)^(2-)>Na^(+)>K^(+)>NO_(3)~->Cl~->Mg^(2+)>F~->NO_(2)~-,suggesting NH_(4)^(+)and Ca^(2+)from agricultural activities and crustal dust played a vital role in precipitation chemistry.Moreover,the wet deposition flux of DOC and TDN were 9.95 and 17.06 kg/(ha year),respectively.The wet deposition flux of inorganic nitrogen species such as NH_(4)^(+)-N and NO_(3)^(-)-N were 14.31 and 0.47 kg/(ha year),respectively,demonstrating the strong influence of emission sources and precipitation volume.Source attribution from different analysis suggested the influence of biomass burning on DOC and anthropogenic activities(agriculture,animal husbandry)on nitrogenous species.The air-mass back trajectory analysis indicated the influence of air masses originating from the Bay of Bengal,which possibly carried marine and anthropogenic pollutants along with the biomass burning emissions to the sampling site.This study bridges the data gap in the less studied part of the northern IGP region and provides new information for policy makers to deal with pollution control.