Mechanical properties and grain refinement by acicular ferrite in high strength high toughness weld metal

The volume fraction and morphology of acicular ferrite evolution in a high strength high toughness weld metal were studied and the mechanical properties of weld metal under heat input of 21 kJ/cm with and without fast cooling were tested. The results show the weld metal can obtain a large proportion of acicular ferrite during a wide range of cooling rate and the sizes of acicular ferrite in length and thickness decrease with cooling rate increasing. The weld metal exhibited high tensile strength （895 MPa and 870 MPa） and good low temperature toughness （average AKv-30℃ 104 J and 79. 2 J）. The higher tensile strength and better low temperature toughness of the weld metal under fast cooling are due to the more refined grain of acicular ferrite.

Effect of Al in Ti－microalloyed Mn－Ni－Mo welding wire on microstructure and toughness of deposited metal

The effect of Al in Ti-microalloyed welding wire on microstructure and toughness of deposited metals is studied.The results show that the deposited metal toughness worsens with increasing Al in wire' The mechanism of Al is as follows:(1) Al makes oxygen content in deposited metal increase.(2)Al restrains the formation of Ti-rich oxide inclusion, which causes granular bainite microstructure in deposited metal.(3)The content of solute Ti in deposited metal increases with Al content in welding wire,as a result,a part of carbonrich constitution in deposited metal is in the form of twin martensite.

Effect of Mn and Ni on Microstructure and Impact Toughness of Submerged Arc Weld Metals

The influences of Mn and Ni contents on the impact toughness and microstructure in the weld metals of high strength low alloy steels were studied. The objective of this study was to determine the optimum composition ranges of Mn and Ni to develop welding consumables with better resistance to cold cracking. The results indicated that Mn and Ni had considerable effect on the microstructure of weld metal, and both Mn and Ni promoted acicular ferrite at the expense of proeutectoid ferrite and ferrite side plates. Varying Ni content influenced the Charpy impact energy, the extent of which depended on Mn content. Based on the properties and impact resistance, the optimum levels of Mn and Ni were suggested to be 0.6%—0.9%,, and 2.5%—3.5%, respectively. Additions beyond this limit promoted the formation of segregation structures and other microstructural features, which may be detrimental to weld metal toughness.

Dynamic fracture toughness of high strength metals under impact loading:increase or decrease

An elusive phenomenon is observed in previous investigations on dynamic fracture that the dynamic fracture toughness （DFT） of high strength metals always increases with the loading rate on the order of TPa.m1/2.s-1. For the purpose of verification, variation of DFT with the loading rate for two high strength steels commonly used in the aviation industry, 30CrMnSiA and 40Cr, is studied in this work. Results of the experiments are compared, which were conducted on the modified split Hopkinson pressure bar （SHPB） apparatus, with striker velocities ranging from 9.2 to 24.1 m/s and a constant value of 16.3 m/s for 30CrMnSiA and 40Cr, respectively. It is observed that for 30CrMnSiA, the crack tip loading rate increases with the increase of the striker velocity, while the fracture initiation time and the DFT simultaneously decrease. However, in the tests of 40Cr, there is also an increasing tendency of DFT, similar to other reports. Through an in-depth investigation on the relationship between the dynamic stress intensity factor （DSIF） and the loading rate, it is concluded that the generally increasing tendency in previous studies could be false, which is induced from a limited striker velocity domain and the errors existing in the experimental and numerical processes. To disclose the real dependency of DFT on the loading rate, experimentsneed to be performed in a comparatively large striker velocity range.

Effects of B and Ti on the Toughness of HSLA Steel Weld Metals

Effects of microalloying Ti and B on the microstructures and low temperature toughness of manual metal arc (MMA) deposits were investi- gated.Weld metals containing 200-300 ppm Ti and 29-60 ppm B deposited by manual coated elec- trodes provided an optimum low temperature toughness.The addition of B in weld metals low- ered the γ→α transformation temperature which promoted the acicular ferrite (AF) transformation. Solid solutioned B suppressed grain boundary ferrite as well as side plate ferrite formation and benefited the acicular ferrite formation.Titanium protected B from oxidizing as well as nitriding and formed Ti-Mn silicate inclusions.Ultra-high volt- age electron microscope analyses showed that TiO structure in the Ti-Mn silicate inclusions was the favorable nucleation site for acicular ferrite forma- tion.

Microstructure and toughness of local brittle zone of HSLA steel multipass weld metals

By using thermo-simulation,Auger analysis and Charpy Ⅴ impact test and with the observation of the microstructures in which cleavage crack was initiated,the morphology and toughness of the local brittle zone of C-Mn and Cr-Ni-Mo multipass weld metals have been investigated.The results indicated that the local brittle zone in C-Mn weld metals with low and high Mn％ and Cr- Ni-Mo weld metals is different.With statistical analysis,it has been revealed that the more the local brittle zone and the lower their toughness,the lower the toughness of the entire weld metals.The alloy elements have a noticeable influ- ence on the toughness of the local brittle zone,thereby changing the toughness of weld metals.

Effect of RE Oxide on Impact Toughness and Primary Structure of Surfacing Metal

The effect of rare earth(RE) oxide on impact toughness and primary structure of surfacing metal was investigated . The results show that the impact toughness of surfacing metal containing RE oxide can be increased by 50 %. The primary structure can be refined and its shape changed from columnar crystals to equiaxed ones.

Effect of microstructure on toughness of 9Cr-lMo deposited metal with varying heat inputs

The microstractures of 9Cr-lMo multipass deposited metal were observed. The effect of microstructure on impact toughness of 9Cr-lMo multipass deposited metal with varying heat inputs was investigated. Result shows that fine-grained microstructure occurs in reheated zones. The absorbed energy increases with the increase of volume fraction of fine-grained microstructure , suggesting that the volume fraction of fine-grained microstracture influences directly on impact toughness. The increasing ratio of fine-grained zone thickness to weld layer thickness is responsible for improving impact toughness after PWHT.

Effect of heat input and postweld heat treatment on microstructure and toughness of heat-resistant steel E911 deposited metal

The microstructure of E911 deposited metal was observed and the effect of heat input and postweld heat treatment on microstructure and impact toughness was investigated. The microstructure consists of tempered martensite and residual δ- ferrite. The morphology of tempered martensite is columnar and the residual δ-ferrite is polygonal. With the increase in heat input, the width of columnar martensite grain and the size of residual δ-ferrite increased, whereas the volume fraction of residual δ-ferrite varied slightly. The impact toughness decreased as heat input increased. The result reveals that coarsening columnar martensite grain and δ-ferrite have greater effect on impact toughness than volume fraction of residual δ-ferrite. As the time of postweld heat treatment is exceeded 8h, aggregation of M23 C6occurs in some grain boundaries or lath interfaces. The partial aggregation of M23 C6 results in the decrease in impact toughness.

INFLUENCE OF LOCAL BRITTLE ZONE ON THE FRACTURETOUGHNESS OF HIGH-STRENGTH LOW-ALLOYEDMULTIPASS WELD METALS

In this paper, toughness properties and microstructurc of low-alloyed multipass welds with yield strength above 700MPa have 6een studied using the weld thermal simulation and throughout thickness CTOD fracture mechanics tests. Impact testing of thermal simulated specimens showed that the primary weld metal and the fine gmmed weld metal had good toughness, while the coarse grained weld metal had the lowest toughness value as the local brittle zone (LBZ) in multipass weld metals. Cleavage fracture in CTOD testing of thick multipass weld metals was initiated from martensite-austenite (MA) phases in the LBZ. MA phases were distributed at the prior austenite grain boundaries and around ferrite grains. As the size of the local brittle zone along the fatigue crack front increases, CTOD frncture toughness of multipass weld metals decreases. The weakest link theory was used to evaluate effect of the local brittle zone on fracture toughness of thick multipass weld metals. The estimated curves agree well with the eaperimental data.

Effect of metallic phase content on mechanical properties of (85Cu-15Ni)/(10NiO-NiFe_2O_4) cermet inert anode for aluminum electrolysis

(85Cu-15Ni)/(10NiO-NiFe2O4) cermets were prepared with Cu-Ni mixed powders as toughening metallic phase and 10NiO-NiFe2O4 as ceramic matrix. The phase composition, microstructure of composite and the effect of metallic phase content on bending strength, hardness, fracture toughness and thermal shock resistance were studied. X-ray diffraction analysis indicates the coexistence of (Cu-Ni), NiO and NiFe2O4 phases in the cermets. Within the content range of metallic phase from 0% to 20% (mass fraction), the maximal bending strength (176.4 MPa) and the minimal porosity (3.9%) of composite appear at the metallic phase content of 5%. The fracture toughness increases and Vickers’ hardness decreases with increasing metal content. When the thermal shock temperature difference (△t) is below 200 ℃, the loss rate of residual strength for 10NiO-NiFe2O4 ceramic is only 8%, but about 40% for (85Cu-15Ni)/(10NiO-NiFe2O4) cermets. As △t is above 200 ℃, the residual strength sharply decreases for sample CN0 and falls slowly for samples CN5-CN20.

Simulation of Solidification Parameters during Zr Based Bulk Metallic Glass Matrix Composite’s (BMGMCs) Additive Manufacturing

After a silence of three decades, bulk metallic glasses and their composites have re-emerged as a competent engineering material owing to their excellent mechanical properties not observed in any other engineering material known till date. However, they exhibit poor ductility and little or no toughness which make them brittle and they fail catastrophically under tensile loading. Exact explanation of this behaviour is difficult, and a lot of expensive experimentation is needed before conclusive results could be drawn. In present study, a theoretical approach has been presented aimed at solving this problem. A detailed mathematical model has been developed to describe solidification phenomena in zirconium based bulk metallic glass matrix composites during additive manufacturing. It precisely models and predicts solidification parameters related to microscale solute diffusion (mass transfer) and capillary action in these rapidly solidifying sluggish slurries. Programming and simulation of model is performed in MATLAB®. Results show that the use of temperature dependent thermophysical properties yields a synergic effect for multitude improvement and refinement simulation results. Simulated values proved out to be in good agreement with prior simulated and experimental results.

Tensile and Impact Properties of Shielded Metal Arc Welded AISI 409M Ferritic Stainless Steel Joints

The present study is concerned with the effect of filler metals such as austenitic stainless steel, ferritic stainless steel and duplex stainless steel on tensile and impact properties of the ferritic stainless steel conforming to AISI 409M grade. Rolled plates of 4 mm thickness were used as the base material for preparing single pass butt welded joints. Tensile and impact properties, microhardness, microstructure and fracture surface morphology of the joints fabricated by austenitic stainless steel, ferritic stainless steel and duplex stainless steel filler metals were evaluated and the results were reported. From this investigation, it is found that the joints fabricated by duplex stainless steel filler metal showed higher tensile strength and hardness compared to the joints fabricated by austenitic and ferritic stainless steel filler metals. Joints fabricated by austenitic stainless steel filler metal exhibited higher ductility and impact toughness compared with the joints fabricated by ferritic stainless steel and duplex stainless steel filler metals.

Mo effect on the phase stability and room-temperature fracture toughness of Nb/Nb_5Si_3 in-situ composites

Nb/Nb5Si3 in-situ composites are very attractive structural materials because these materials perform a good balance in mechanical properties, including high strength at high temperature (> 1000 degrees C) and reasonably high fracture toughness at room temperature. Metastable phase Nb3Si plays an important role in the properties of Nb/Nb5Si3 composites by affecting the volume fraction of ductile phase. The addition of Mo affects on the microstructure of ductile phase and the stability of metastable phase Nb3Si. In this paper, Nb-10Si-xMo and Nb-18Si-xMo (x = 0, 5, and 15) alloys were prepared by arc melting and annealed at 1473 K for 100 h. Single edge-notched bending (SENB) test was used to study the fracture toughness of Nb-Si-Mo alloys. The room temperature fracture toughness of Nb-10Si is 10.48 MPa center dot m(1/2) and higher than that of binary Nb-18Si alloys at near-eutectic composites. The addition of 5 at.% Mo improved the fracture toughness of as-cast Nb-Si alloys from 4.1 MPa center dot m(1/2) to 9.99 MPa center dot m(1/2) at near-eutectic compositions and reduced it from 10.48 MPa center dot m(1/2) to 8.86 MPa center dot m(1/2) at hypoeutectic compositions.

Impact property analysis of weld metal and heat-affected zone for low-alloy carbon steel multi-pass welded joint

Welded joint impact performances of low-alloy carbon steel plates welded by full-automatic gas metal arc welding （GMAW） were evaluated. To clarity the effect of impact temperature on impact properties of weld metal （WM） and heat- affected zone （ HAZ）, Charpy V impact tests at different temperatures and fracture surface analysis were carried out. The Charpy V impact energy decreases with the decreasing test temperature both for the WM and HAZ, while the proportion of crystal zone on WM and HAZ impact fracture surface increases with the decreasing test temperature. Research results indicate that the welding defects （void and slag） make the impact energy of WM more scattered and lower than that of HAZ.

Effect of copper on mechanical properties of high strength SMAW weld metal

Mechanical properties of SMA W （shielded metal arc welding） weld metal （ yield strength higher than 900 MPa ） with systemazic additions of copper （ up to 1.48 wt% ） were tested, The microstructure and precipitates in different regions were analyzed by optical microscope and transmission electron microscope, The results indicate that copper improves the low temperature toughness of weld metal when the copper content is low and reaches the peak value 48 J （ at - 50℃ ） with 0. 2 wt% copper additions. When the content is high the copper precipitates as 8-Cu phase in the reheat zone of middle beads. These precipitates improve the strength of the weld metal evidently （ yield strength up to 975 MPa） without obvious effect on the low temperature toughness. The copper within 1.1 wt% content can improve the strength without toughness loss.

Toughening Mechanisms of Alumina Matrix Ceramic Composite Toughened by Rare Earth Additive

Mixed rare earth elements were incorporated into alumina ceramic materials. Hot-pressing was used to fabricate alumina matrix composites with nitrogen atmosphere protection. Microstructures and mechanical properties of the composites were tested. It is indicates that the bending strength and fracture toughness of alumina matrix ceramic composites sintered at 1550℃ and 28 MPa for 30 min are improved evidently. Based on mixed rare earth elements acting as a toughening phase, AlTiC master alloys were also added in as sintering assistant, which could prompt the formation of transient liquid phase, and thus nitrides of rare earth elements were produced. All the above are beneficial to the improvement of mechanical properties of alumina matrix ceramic composites.

钛型气保护药芯焊丝工艺质量影响因素综述

综述了涉及钛型气保护药芯焊丝工艺质量的影响因素。结果表明,合理选用药芯添加物,严格控制熔敷金属中主要强化元素C、Mn、Si的含量,可以改善焊丝熔滴过渡形态,获得焊丝熔敷金属满意的力学性能。在Ar+CO_(2)二元混合保护气体中,随着CO_(2)含量增大,熔滴过渡形态从轴向变为非轴向滴状排斥过渡,接头的抗拉强度几乎没有影响,但熔敷金属的冲击吸收能明显下降。热输入较大时,焊丝工艺性变差;热输入居中时,焊丝工艺性较好。热输入对焊丝熔敷金属韧性的影响出现了对热输入敏感和不敏感两种情况。钛型气保护药芯焊丝工艺质量的三个影响因素控制原理各具特色。

Q690D多道次GMAW接头的组织和力学性能

在无预热和焊后热处理的条件下,采用熔化极气体保护焊(GMAW)和CHW-80C1实芯焊丝对20 mm厚Q690D热机械轧制钢板进行多道次焊接试验,分析该钢焊接接头的组织转变特征和冲击性能。结果表明,采用CHW-80C1焊丝可获得成型优良的焊接接头;Q690D各道次的焊缝组织相似,均由粒状贝氏体和少量的针状铁素体、先共析铁素体组成;热影响区由粒状贝氏体、针状铁素体、先共析铁素体及M-A组元组成。焊缝与细晶热影响区的冲击吸收功相对于母材的有一定幅度的下降,焊缝与细晶热影响区的断裂类型均为韧性断裂。

焊接热输入对690 MPa级HSLA钢焊缝金属组织与力学性能的影响

采用自研直径4.0 mm的焊条对厚度为27 mm的690 MPa级HSLA钢进行不预热焊接,研究了焊接热输入对焊缝金属组织和性能的影响及强韧化机理.结果表明,焊接热输入由13 kJ/cm提高至19 kJ/cm对焊缝金属组织结构及其强韧性产生了显著影响,对接接头抗拉强度、硬度呈现降低趋势,焊缝金属−50℃冲击吸收能量呈现先升高后降低趋势.16 kJ/cm热输入条件下获得了良好的强韧性,对接接头抗拉强度为828 MPa,焊缝中心−50℃冲击吸收能量为71~90 J,均值为80 J.13 kJ/cm及19 kJ/cm热输入条件下焊缝金属强韧性较低,前者与焊缝金属中板条贝氏体及侧板条铁素体形成有关,后者与其中粗大的M-A组元形成相关.热输入16 kJ/cm条件下,充分形成了塑性良好的针状铁素体组织,针状铁素体和贝氏体呈交织分布,同时,细小弥散分布的M-A组元并未对其韧性产生显著的负面作用,焊缝金属获得了良好的强韧性配合.