A fast and convenient base-free Heck reaction of acrylic acid with hypervalent iodonium salts was achieved under microwave irradiation in water, providing a simple method for the synthesis of trans-cinnanfic acids in ...A fast and convenient base-free Heck reaction of acrylic acid with hypervalent iodonium salts was achieved under microwave irradiation in water, providing a simple method for the synthesis of trans-cinnanfic acids in good yields in short time.展开更多
The present study aimed to quantify the content of trans-cinnamic acid (CA) in Cinnamomum japonicum, C. loureirii, and C. camphora and the commercial application of CA using high performance liquid chromatography (HPL...The present study aimed to quantify the content of trans-cinnamic acid (CA) in Cinnamomum japonicum, C. loureirii, and C. camphora and the commercial application of CA using high performance liquid chromatography (HPLC). A C18 column was used, with water/methanol as the mobile phase gradient. The highest content of CA was observed in the bark of C. loureirii (16.97 mg/g) and cinnamon powder A (47.60 mg/g). The lowest content of CA was observed in leaf and heartwood of C. japonicum (0.10 and 0.10 mg/g, respectively) and cinnamon powder C (22.87 mg/g). This result could be utilized as a guideline for the analysis of the commercial applications of Cinnamomum.展开更多
Objective To study the chemical constituents from the barks of Lannea coromande/ica. Methods The chemical constituents were isolated and purified by column chromatography on silica gel column. NMR spectra were used fo...Objective To study the chemical constituents from the barks of Lannea coromande/ica. Methods The chemical constituents were isolated and purified by column chromatography on silica gel column. NMR spectra were used for structural identification. Results Thirteen compounds were isolated and identified as quercetin （1）, （2S,3S,4R, lOLg-2-[（2＂R）-2＇-hydroxytetracosanoyl amino]-10-octadecene-l,3,4- triol （2）, aralia cerebroside （3）, 5,5＇-dibuthoxy-2,2＇-bifuran （4）, ^-sitosteryl- 3^-glucopyranoside-6＇-O-palmitate （5）, B-sitosterol palmitate （6）, myricadiol （7）, protocatechuic acid （8）, p-hydroxybenzoic acidethyl ester （9）, isovanillin （10）, trans- cinnamicacid （I 1）, palmiticacid （12）, and stearicacid （13）. Conclusion Compounds 2-13 are isolated from this plant for the first time.展开更多
文摘A fast and convenient base-free Heck reaction of acrylic acid with hypervalent iodonium salts was achieved under microwave irradiation in water, providing a simple method for the synthesis of trans-cinnanfic acids in good yields in short time.
文摘The present study aimed to quantify the content of trans-cinnamic acid (CA) in Cinnamomum japonicum, C. loureirii, and C. camphora and the commercial application of CA using high performance liquid chromatography (HPLC). A C18 column was used, with water/methanol as the mobile phase gradient. The highest content of CA was observed in the bark of C. loureirii (16.97 mg/g) and cinnamon powder A (47.60 mg/g). The lowest content of CA was observed in leaf and heartwood of C. japonicum (0.10 and 0.10 mg/g, respectively) and cinnamon powder C (22.87 mg/g). This result could be utilized as a guideline for the analysis of the commercial applications of Cinnamomum.
基金National Natural Science Foundation(21162009)Special Major Science and Technology R&D in Hainan(ZDZX20100007)
文摘Objective To study the chemical constituents from the barks of Lannea coromande/ica. Methods The chemical constituents were isolated and purified by column chromatography on silica gel column. NMR spectra were used for structural identification. Results Thirteen compounds were isolated and identified as quercetin （1）, （2S,3S,4R, lOLg-2-[（2＂R）-2＇-hydroxytetracosanoyl amino]-10-octadecene-l,3,4- triol （2）, aralia cerebroside （3）, 5,5＇-dibuthoxy-2,2＇-bifuran （4）, ^-sitosteryl- 3^-glucopyranoside-6＇-O-palmitate （5）, B-sitosterol palmitate （6）, myricadiol （7）, protocatechuic acid （8）, p-hydroxybenzoic acidethyl ester （9）, isovanillin （10）, trans- cinnamicacid （I 1）, palmiticacid （12）, and stearicacid （13）. Conclusion Compounds 2-13 are isolated from this plant for the first time.
