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Performance of Twelve Mass Transfer Based Reference Evapotranspiration Models under Humid Climate
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作者 Koffi Djaman Komlan Koudahe +3 位作者 Mamadou Sall Isa Kabenge Daran Rudnick Suat Irmak 《Journal of Water Resource and Protection》 2017年第12期1347-1363,共17页
Reference evapotranspiration is very important parameter in the hydrological, agricultural and environmental studies and is accurately estimated by the FAO Penman-Monteith equation (FAO-PM) under different climatic co... Reference evapotranspiration is very important parameter in the hydrological, agricultural and environmental studies and is accurately estimated by the FAO Penman-Monteith equation (FAO-PM) under different climatic conditions. However, due to data requirement of the FAO-PM equation, there is a need to investigate the applicability of alternative ETo equations under limited data. The objectives of this study were to evaluate twelve mass transfer based reference evapotranspiration equations and determine the impact of ETo equation on long term water management sustainability in Tanzania and Kenya. The results showed that the Albrecht, Brockamp-Wenner, Dalto, Meyer, Rohwer and Oudin ETo equations systematically overestimated the daily ETo at all weather stations with relative errors that varied from 34% to 94% relative to the FAO-PM ETo estimates. The Penman, Mahringer, Trabert, and the Romanenko equations performed best across Tanzania and the South Western Kenya with root mean squared errors ranging from 0.98 to 1.48 mm/day, which are relatively high and mean bias error (MBE) varying from -0.33 to 0.02 mm/day and the absolute mean error (AME) from 0.79 to 1.16 mm/day. For sustainable water management, the Trabert equation could be adopted at Songea, the Mahringer equation at Tabora, the Dalton and/or the Rohwer equations at Eldoret, the Romanenko equation at Dodoma, Songea and Eldoret. However, regional calibration of the most performing equation could improve water management at regional level. 展开更多
关键词 reference EVAPOTRANSPIRATION Mass transfer EASTERN AFRICA Water
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Selection of Stable Reference Genes for Quantitative Real-Time PCR on Paeonia ostii T.Hong et J.X.Zhang Leaves Exposed to Different Drought Stress Conditions
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作者 Yuting Luan Cong Xu +2 位作者 Xiaoxiao Wang Daqiu Zhao Jun Tao 《Phyton-International Journal of Experimental Botany》 SCIE 2022年第5期1045-1059,共15页
The definition of relatively stable expressed internal reference genes is essential in both traditional blotting quantification and as a modern data quantitative strategy.Appropriate internal reference genes can accur... The definition of relatively stable expressed internal reference genes is essential in both traditional blotting quantification and as a modern data quantitative strategy.Appropriate internal reference genes can accurately standardize the expression abundance of target genes to avoid serious experimental errors.In this study,the expression profiles of ten candidate genes,ACT1,ACT2,GAPDH,eIF1,eIF2,α-TUB,β-TUB,TBP,RNA Pol II and RP II,were calculated for a suitable reference gene selection in Paeonia ostii T.Hong et J.X.Zhang leaves under various drought stress conditions.Data were processed by the four regularly used evaluation software.A comprehensive analysis revealed that RNA Pol II was the most stable gene and eIF2 was the least stable one.In addition,the geNorm program provided the optimal choice of two reference gene combination,RNA Pol II andβ-TUB,for qRT-PCR normalization in P.ostii subjected to different drought stress levels.Our research provided convenience for gene expression analysis in P.ostii under drought stress and promoted research of effective methods to alleviate P.ostii drought stress in the future. 展开更多
关键词 Paeonia ostii T.Hong et J.x.Zhang reference gene qRT-PCR drought stress
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Transfer Learning Approach to Classify the X-Ray Image that Corresponds to Corona Disease Using ResNet50 Pre-Trained by ChexNet
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作者 Mahyar Bolhassani 《Journal of Intelligent Learning Systems and Applications》 2024年第2期80-90,共11页
The COVID-19 pandemic has had a widespread negative impact globally. It shares symptoms with other respiratory illnesses such as pneumonia and influenza, making rapid and accurate diagnosis essential to treat individu... The COVID-19 pandemic has had a widespread negative impact globally. It shares symptoms with other respiratory illnesses such as pneumonia and influenza, making rapid and accurate diagnosis essential to treat individuals and halt further transmission. X-ray imaging of the lungs is one of the most reliable diagnostic tools. Utilizing deep learning, we can train models to recognize the signs of infection, thus aiding in the identification of COVID-19 cases. For our project, we developed a deep learning model utilizing the ResNet50 architecture, pre-trained with ImageNet and CheXNet datasets. We tackled the challenge of an imbalanced dataset, the CoronaHack Chest X-Ray dataset provided by Kaggle, through both binary and multi-class classification approaches. Additionally, we evaluated the performance impact of using Focal loss versus Cross-entropy loss in our model. 展开更多
关键词 x-Ray Classification Convolutional Neural Network ResNet transfer Learning Supervised Learning COVID-19 Chest x-Ray
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基于迁移学习与残差网络的快递包裹X光图像识别 被引量:1
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作者 朱磊 黄磊 +1 位作者 张媛 程诚 《印刷与数字媒体技术研究》 CAS 北大核心 2024年第2期37-45,65,共10页
针对快递包裹违禁物品识别存在种类繁多、依赖人力和X光图像获取难度大等问题,为提高快递包裹违禁物品识别的效率和准确度,本研究提出一种迁移学习与残差网络相结合的快递包裹X光图像识别方法(TL-ResNet18)。首先构建了相似度高的源领... 针对快递包裹违禁物品识别存在种类繁多、依赖人力和X光图像获取难度大等问题,为提高快递包裹违禁物品识别的效率和准确度,本研究提出一种迁移学习与残差网络相结合的快递包裹X光图像识别方法(TL-ResNet18)。首先构建了相似度高的源领域数据集和目标领域数据集;其次,选用ResNet18作为预训练模型,调整初始化参数结构,并将ResNet18学习到的内容作为初始化参数迁移到目标领域,实现快递包裹X光图像分类;最后,将相同数据集作为三种模型的输入并对结果进行对比。实验结果表明,TL-ResNet18模型的局部微调和全局微调的识别准确率分别为93.5%、95.0%,相比于ResNet18模型提高了7%、8.5%,且精确度、召回率和F1值都优于ResNet18模型,该方法性能更优,且不受小型数据集对深层网络训练的限制,有利于快递包裹X光图像识别的智能化发展。 展开更多
关键词 快递包裹 x光图像 残差网络 迁移学习
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CoP修饰Ti_(3)C_(2)T_(x)MXene纳米复合材料作为高效析氢反应电催化剂 被引量:1
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作者 孙巍 王永靖 +5 位作者 项坤 白赛帅 王海涛 邹菁 Arramel 江吉周 《物理化学学报》 SCIE CAS CSCD 北大核心 2024年第8期36-39,共4页
高效、经济和环保是电化学水分解制氢电催化剂的关键要素。二维(2D)MXene材料因其独特的物理化学性质而受到广泛关注。虽然有许多不同种类的MXene材料,但只有少数具有本征析氢反应(HER)催化活性。然而,MXene材料具有很多优点,如较大的... 高效、经济和环保是电化学水分解制氢电催化剂的关键要素。二维(2D)MXene材料因其独特的物理化学性质而受到广泛关注。虽然有许多不同种类的MXene材料,但只有少数具有本征析氢反应(HER)催化活性。然而,MXene材料具有很多优点,如较大的比表面积、高电导率和丰富的表面官能团,因此可以作为与其他物质复合的理想平台。本研究首先通过密度泛函理论(DFT)预测了CoP与Ti_(3)C_(2)T_(x)MXene(其中T_(x)=―F和―OH官能团)具有低的氢吸附自由能(ΔGH^(*))。接着,我们合成了CoP-Ti_(3)C_(2)T_(x)MXene纳米复合材料,并在0.5 mol∙L^(−1)H_(2)SO_(4)中测试了其电催化HER性能。该材料在电流密度为10 mA∙cm^(−2)时表现出了低的过电位(135 mV)和Tafel斜率为48 mV∙dec^(−1)。理论计算表明,CoP-Ti_(3)C_(2)T_(x)MXene纳米复合材料的优异电催化性能源于Ti_(3)C_(2)T_(x)的高金属导电性、良好的界面电荷转移、快速的氢吸附/解吸过程以及优化的电子结构。 展开更多
关键词 Ti_(3)C_(2)T_(x)Mxene 析氢反应 COP 密度泛函理论 界面电荷转移
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Seasonally Varying Reference Atmospheres for East Asia
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作者 Byung-Ju SOHN Geun-Hyeok RYU 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2007年第2期181-190,共10页
Vertical profiles of seasonally varying pressure, temperature, water vapor, and trace gases (O3, N2O, CO, CH4), representing atmospheric conditions up to a height of 100 km over the East Asia region (30°-50... Vertical profiles of seasonally varying pressure, temperature, water vapor, and trace gases (O3, N2O, CO, CH4), representing atmospheric conditions up to a height of 100 km over the East Asia region (30°-50°N, 110°-150°E) were constructed by using various observation data, model outputs of atmospheric thermodynamic parameters, and gaseous concentrations. Optical characteristics of the obtained East Asia reference atmospheres were compared with those from typical midlatitude summer and winter atmospheres. It was noted that, in the water vapor field, there are major differences between the two model atmospheres during the summer. The resultant impact during the summer of water vapor difference on incoming solar fluxes at the surface and emitted terrestrial fluxes at the top of the atmosphere are 14.3 W m^-2 and 6.5 W m^-2, respectively. On the other hand, the winter difference between East Asian and midlatitude atmospheres appears to be insignificant. Reference atmospheres for the spring and fall are also available. Utilizing the constructed atmospheric profiles as inputs to the radiative transfer model, it is expected that the constructed seasonally varying reference atmospheres can facilitate better descriptions of optical properties in East Asia. 展开更多
关键词 East Asian reference atmosphere radiative transfer atmospheric optical property
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50~120kV脉冲X射线参考辐射场建立及剂量率测量
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作者 郝光辉 张晓乐 +4 位作者 徐坠 李德红 黄建微 成建波 万琳健 《同位素》 CAS 2024年第1期7-16,共10页
为满足国内医疗、安检等脉冲辐射场所对剂量监测仪表准确溯源的需求,基于栅控技术建立满足规范和标准要求的50~120 kV毫秒级脉冲X射线参考辐射场,其脉冲宽度在1~6 300 ms范围内可调。通过对该辐射场的管电压稳定性、剂量线性、重复性、... 为满足国内医疗、安检等脉冲辐射场所对剂量监测仪表准确溯源的需求,基于栅控技术建立满足规范和标准要求的50~120 kV毫秒级脉冲X射线参考辐射场,其脉冲宽度在1~6 300 ms范围内可调。通过对该辐射场的管电压稳定性、剂量线性、重复性、脉冲波形等关键参数进行研究测试,建立脉冲X射线参考波形,并使用30 cm3的圆柱电离室开展脉冲剂量率测量研究。结果表明,管电压预设60 kV时,介入法、非介入法测量管电压的相对偏差均不超过±1.5%;可输出参考波形脉冲的最小脉冲宽度为20 ms,在1 m处95%均匀辐射野直径约为5.5 cm;且N系列、RQR系列辐射质条件下的剂量率范围可分别扩展至0.002~10 mGy/s和0.03~250 mGy/s,可用于防护仪表的量值溯源。 展开更多
关键词 脉冲x射线 参考辐射场 参考脉冲波形 剂量率测量 辐射剂量学
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DFT Calculations for Electron Transfer Bond-breakingReaction of CH_3-X
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作者 Yu Mei XING Zheng Yu ZHOU Ben Ni DU 《Chinese Chemical Letters》 SCIE CAS CSCD 2001年第4期347-350,共4页
DFT/6-311 + g** level calculations are performed tp study the electron transfer bond-breaking reaction of CH3-X. The calculated values are in good agreement with the experimental results or the empirical model. Throug... DFT/6-311 + g** level calculations are performed tp study the electron transfer bond-breaking reaction of CH3-X. The calculated values are in good agreement with the experimental results or the empirical model. Through analyzing the change of the energy and the charge densilty along hte reaction path, the bond-breaking in ET reaction for CH3X is investigated. 展开更多
关键词 electron transfer bond-breaking reaction density functional theory (DFT) CH_(3)x
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基于水热合成法制备的MoO_(3-x)纳米槽SERS基底的特性研究
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作者 舒敏 梁俊辉 +2 位作者 陈达 陈招 秦来顺 《人工晶体学报》 CAS 北大核心 2024年第6期1061-1068,共8页
表面增强拉曼散射(SERS)技术可以快速检测微量分子,在医药材料分析、有害物残留、食品安全等领域受到广泛关注。而SERS对被检测物质的响应极限则取决于基底性能,并直接影响最终检测效果。本文着眼于增加基底的比表面积及其与被检测物之... 表面增强拉曼散射(SERS)技术可以快速检测微量分子,在医药材料分析、有害物残留、食品安全等领域受到广泛关注。而SERS对被检测物质的响应极限则取决于基底性能,并直接影响最终检测效果。本文着眼于增加基底的比表面积及其与被检测物之间的光诱导电荷转移能力,通过简单的水热合成法成功制备出具有氧空位缺陷的MoO_(3-x)纳米槽。结合X射线光电子能谱(XPS)、紫外-可见光谱(UV-Vis)、傅里叶变换红外光谱(FT-IR)等手段,对MoO_(3-x)纳米槽的电子结构、光学性质和表面化学环境进行了分析。使用MoO_(3-x)纳米槽作为SERS基底,对罗丹明6G(R6G)、结晶紫(CV)和玫瑰红B(RhB)三种有机染料分子进行了检测,实验结果显示,其对R6G的检测极限可以达到10^(-10)mol/L,与同类型的半导体基底相比,它具有更好的拉曼增强活性。 展开更多
关键词 MoO_(3-x)纳米槽 表面增强拉曼散射 微量分子检测 氧空位缺陷 光诱导电荷转移 R6G
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汉语二语习得“X们”的偏误分析
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作者 刘杨 彭泽润 《辽东学院学报(社会科学版)》 2024年第5期55-60,共6页
运用偏误分析法对汉语中介语语料库和HSK动态作文语料库中“X们”词的偏误语料进行整理和分析,发现“X们”词的偏误率为9.0%。偏误有误加、遗漏和误代3类,其中误加偏误最多,超过偏误数量的一半;误代偏误最少。偏误产生的原因在于母语的... 运用偏误分析法对汉语中介语语料库和HSK动态作文语料库中“X们”词的偏误语料进行整理和分析,发现“X们”词的偏误率为9.0%。偏误有误加、遗漏和误代3类,其中误加偏误最多,超过偏误数量的一半;误代偏误最少。偏误产生的原因在于母语的负迁移及目的语规则的泛化,同时也跟教材对“X们”的相关知识介绍不全面有关。 展开更多
关键词 x 偏误分析 母语负迁移 目的语泛化
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Absorbed Dose to Water Rate in a Cyberknife VSI System Reference Field Using Ionization Chambers and Gafchromic Films
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作者 Guerda Massillon-JL Nestor Aragó +4 位作者 n-Martí nez Arnulfo Gó mez-Muñ oz 《International Journal of Medical Physics, Clinical Engineering and Radiation Oncology》 2017年第1期80-92,共13页
This work investigated the absorbed dose to water rate under reference conditions in a Cyberknife VSI system using radiochromic films EBT3 and MD-V3 and three ionization chambers: an Exradin A12 and two FC65P Welh&... This work investigated the absorbed dose to water rate under reference conditions in a Cyberknife VSI system using radiochromic films EBT3 and MD-V3 and three ionization chambers: an Exradin A12 and two FC65P Welh&ouml;fer Scanditronix with different serial numbers. The correction factor,, was studied using a Varian iX linac and the Cyberknife system. The measurements in the Varian iX were performed in a 10 × 10 cm2 field, 10 cm depth in liquid water at 90 cm and 70 cm SSD and in a 5.4 × 5.4 cm2 field, 10 cm depth at 70 cm SSD to simulate the Cyberknife conditions. In the Cyberknife system, measurements were performed using ionization chambers and both film types at 70 cm SSD and 10 cm depth in its 6 cm diameter reference field. The results indicate that ?is independent of the dosimeters and the evaluation methods. Maximum differences of 0.22% - 0.55% (combined uncertainties of 1.22% - 1.98%, k = 1) are obtained on ?using Varian iX, whereas discrepancies of 2.08% - 2.09% (combined uncertainties of 1.87% - 2.13%, k = 1) are observed using the Cyberknife system. Given the agreement between detectors and the combined standard uncertainties, the data from Varian iX could be considered the most accurate and consequently a weighted average factor of 0.902 ± 0.006 could be used for the Cyberknife VSI system reference field. Within measurement uncertainties, the absorbed dose rate measured in the Cyberknife VSI system reference field was found to be independent of the dosimeters used. These results suggest that the absorbed dose measured at a point within a given field size should be the same, regardless the dosimeter used, if their dosimetric characteristics are well known. This highlighted the importance of performing dosimetry by controlling all parameters that could affect the dosimeter response. One can conclude that radiochromic film dosimetry can be considered as an appropriate alternative for measuring absorbed dose to water rate. 展开更多
关键词 Small FIELD DOSIMETRY reference FIELD CYBERKNIFE Gafchromic Films Ionization CHAMBERS Dose RATE EBT3 MD-V3 6 MV x-Rays
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Luminescence and Energy Transfer of Gd_xY_(1-x)P_5O_(14):Ce, Tb──Ⅱ. Energy Transfer of Ce→Gd→Tb
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作者 郭常新 柏善岩 《Journal of Rare Earths》 SCIE EI CAS CSCD 1996年第1期12-18,共7页
The energy transfer phenomenon of Ce→Gd→Tb via Gd sublattice and its depandence has been investigated in GdxY-1-xP5O14:Ce,Tb.The fluorescent and excitation spectra of Gdp5O14,Gdp5O14:Ce,Gdp5O14:Tb and GdxY-1xP5O14:C... The energy transfer phenomenon of Ce→Gd→Tb via Gd sublattice and its depandence has been investigated in GdxY-1-xP5O14:Ce,Tb.The fluorescent and excitation spectra of Gdp5O14,Gdp5O14:Ce,Gdp5O14:Tb and GdxY-1xP5O14:Ce,Tb and absorption spectrum of Gdp5O14 have been studied.The results show that as x is larger than 0.7.the energy transfer from Ce3+ via Gd3+to Tb3+ is obvious.The main reason for the energy transfer of Ce→Gd→Tb being efficient in the region x>0.7 is that the spectral overlap between Ce3+ emission spectrum and Gd3+ absorption spectrum increases and the structure changes from monoclinic Ⅱ(C2/c) layer structure(x<0.7) to monoclinic I(P21/c) ribbon structure. 展开更多
关键词 Luminescence of Tb ̄(3+) and Ce ̄(3+) Energy transfer via Gd ̄(3+) sublattice Gd_xY_(1-x)P_5O_(14):Ce TB
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Luminescence and Energy Transfer of Gd_xY_(1-x)P_5O_(14):Ce,Tb──I.Preparation,Structure and Spectral Properties
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作者 郭常新 柏善岩 《Journal of Rare Earths》 SCIE EI CAS CSCD 1995年第4期257-261,共5页
Preparation, structure and spectral properties of rare earth pentaphosphates Gd_xY_(1-x)P_5O_(14): Ce, Tb have been investigated. When x>0. 7, the pentaphosphates belong to monoclinic crystal system Ⅰ with space g... Preparation, structure and spectral properties of rare earth pentaphosphates Gd_xY_(1-x)P_5O_(14): Ce, Tb have been investigated. When x>0. 7, the pentaphosphates belong to monoclinic crystal system Ⅰ with space group P2_1/c (C). When x≤0. 7. they belong to monoclinic crystal system Ⅱ with C2/c (C). The fluorescent and excitation spectra of Gdp_5O_(14), GdP_5O_(14): Ce. GdP_5O_(14) : Tb and Gd_xY_(1-x)P_5O_(14) : Ce, Tb have been studied and the energy transfer phenomenon from Ce(3+)→Gd(3+)→Tb(3+) by the medium of Gd(3+) sublattice has been determined. 展开更多
关键词 Luminescence of Tb ̄(3+) and Ce ̄(3+) Energy transfer via Gd ̄(3+) sublattice Gd_xY_(1-x)P_5O_(14): Ce. Tb
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45,X/46,XY混合性性腺发育不全患者采用卵母细胞捐赠获得活产1例及文献复习
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作者 郑露 马金召 +3 位作者 许娟娟 崔英霞 姚兵 陈莉 《中华男科学杂志》 CAS CSCD 2024年第5期410-418,共9页
目的:探讨45,X/46,XY混合性性腺发育不全的病因、诊断、治疗、受孕及分娩的临床特点,提高对此类患者的诊治及妊娠管理水平。方法:回顾性分析1例45,X/46,XY混合性性腺发育不全妊娠患者的临床资料并结合相关文献进行讨论。结果:通过患者... 目的:探讨45,X/46,XY混合性性腺发育不全的病因、诊断、治疗、受孕及分娩的临床特点,提高对此类患者的诊治及妊娠管理水平。方法:回顾性分析1例45,X/46,XY混合性性腺发育不全妊娠患者的临床资料并结合相关文献进行讨论。结果:通过患者第二性征发育不全、条索状性腺、染色体核型与社会性别不符等临床特征,结合性腺组织染色体畸变检测结果,确诊患者为45,X/46,XY混合性性腺发育不全,并给予“卵母细胞捐赠ICSI-ET治疗”获得活产。结合文献分析总结此类患者妊娠受孕、妊娠及分娩过程中的临床特点。结论:45,X/46,XY混合性性腺发育不全女性患者无生育能力,可通过卵母细胞捐赠获得妊娠,但此类孕妇的妊娠并发症的发病率以及异常分娩率均高于普通人群。明确诊断,加强妊娠风险评估,以改善围产结局。 展开更多
关键词 性腺发育不全 性染色体畸变 嵌合体 45 x/46 xY混合性性腺发育不全 卵母细胞捐赠 ICSI-ET 妊娠
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X射线计量实验室辐射场的测定
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作者 唐北曦 文杰 +2 位作者 王棋赟 姚正勇 林师宾 《辐射防护通讯》 2024年第5期1-5,共5页
介绍了防护水平X射线计量实验室的建立,并通过物理实验方法对辐射场的场直径、均匀性和散射辐射等性能指标进行验证。结果表明:在窄谱系列X射线参考辐射条件下,测得N-60谱射线束的距离平方反比规律与理论曲线标准偏差为0.54%,散射辐射... 介绍了防护水平X射线计量实验室的建立,并通过物理实验方法对辐射场的场直径、均匀性和散射辐射等性能指标进行验证。结果表明:在窄谱系列X射线参考辐射条件下,测得N-60谱射线束的距离平方反比规律与理论曲线标准偏差为0.54%,散射辐射的贡献小于3.4%;N-100谱10 cm光阑条件下95%场直径为9 cm。结论:本文讨论的X射线计量实验室在场直径、场均匀性及散射等关键技术指标方面,符合GB/T 12162.1—2000的要求。 展开更多
关键词 x射线 参考辐射场 场均匀性 场直径 散射
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产教融合背景下“1+X”证书制度融入高职国土测绘与规划专业实践研究
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作者 戴圣海 彭儒金 《中国科技纵横》 2024年第6期23-25,共3页
国务院于2019年印发《国家职业教育改革实施方案》,首次提出在职业院校和应用型本科启动“1+X”证书制度试点,旨在通过“三教”改革等手段,培养适应市场需求、拥有“1+X”证书的复合型技术技能人才。本文从分析“1+X”证书制度与产教融... 国务院于2019年印发《国家职业教育改革实施方案》,首次提出在职业院校和应用型本科启动“1+X”证书制度试点,旨在通过“三教”改革等手段,培养适应市场需求、拥有“1+X”证书的复合型技术技能人才。本文从分析“1+X”证书制度与产教融合契合度入手,阐述高职教育与职业资格证书制度衔接及高职国土测绘与规划专业实施“1+X”证书制度的重要意义,从评价机制、学分转换、课程体系、人培模式等方面提出该专业实施“1+X”证书制度的保障条件。 展开更多
关键词 产教融合 “1+x”证书 学分转换 人培模式
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熔融制样X射线荧光光谱法测定铜矿石中16种主次量元素 被引量:27
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作者 罗学辉 苏建芝 +2 位作者 鹿青 杨理勤 王岚 《岩矿测试》 CAS CSCD 北大核心 2014年第2期230-235,共6页
铜矿石类型繁多,矿石赋存状态各异,成分复杂.在现有的铜矿石熔融制样X射线荧光光谱(XRF)分析方法中,选取标准物质个数和矿石类型少、分析范围宽,与实际样品类型相差太大,且制备的熔融片质量不高.本文选用铜含量既有良好浓度变化范围,... 铜矿石类型繁多,矿石赋存状态各异,成分复杂.在现有的铜矿石熔融制样X射线荧光光谱(XRF)分析方法中,选取标准物质个数和矿石类型少、分析范围宽,与实际样品类型相差太大,且制备的熔融片质量不高.本文选用铜含量既有良好浓度变化范围,又符合铜矿石常见含量的包括铜金银铅锌钼铜镍等各类矿石的24个标准物质,以四硼酸锂-偏硼酸锂-氟化锂为混合熔剂,熔剂与样品质量比为30:1,以溴化锂为脱模剂,改进样品预处理方式,将通常采用样品预氧化后或熔融中加入脱模剂的方式,改进为加入脱模剂后再用混合熔剂完全覆盖的方法制备了高质量的熔融片,建立了XRF测定铜矿石中铜锌铅硅铝铁钛锰钙钾镁钼铋锑钴镍16种元素的分析方法.分析铜矿石国家标准物质GBW 07164、GBW07169,各元素的精密度(RSD)为0.1% ~5.4%.分析国家标准物质GBW07163(多金属矿石)、GBW07170(铜矿石)的测定值与标准值相符;分析实际铜矿石样品,铜锌铅钼铋锑钴镍的测试结果与电感耦合等离子体发射光谱法和其他方法的测定值相符.本文方法扩大了基体的适应性,提高了实际应用价值. 展开更多
关键词 铜矿石 x射线荧光光谱法 矿石标准物质 脱模剂
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词语族的构造理据及规范问题分析——基于“X族”“X奴”的对比分析 被引量:18
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作者 刘楚群 龚韶 《语言文字应用》 CSSCI 北大核心 2010年第2期42-48,共7页
词语模造词是当前汉语词汇发展的重要特征,"X族""X奴"即为词语模。"X族"的基本语义指具有某种新的生活形式或生活态度的人,"X奴"指为外物所奴役、所拖累之人,二者基本语义的差别决定它们在构... 词语模造词是当前汉语词汇发展的重要特征,"X族""X奴"即为词语模。"X族"的基本语义指具有某种新的生活形式或生活态度的人,"X奴"指为外物所奴役、所拖累之人,二者基本语义的差别决定它们在构造形式方面有明显的差别,"X族"的"X"常常是双音节的陈述性成分,而"X奴"中的"X"则一般是单音节的指称性成分。从语言规范的角度来看,有四类新词语应该成为规范的对象:第一类,没有增加新的意义;第二类,没有明显表现力;第三类,表意不明确或有歧义;第四类,违背构词理据。 展开更多
关键词 x族” x奴” 造词理据 陈述 指称
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X射线荧光光谱用人工标准物质的研制 被引量:13
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作者 陈永君 王亚平 +2 位作者 许春雪 郑妙子 王苏明 《岩矿测试》 CAS CSCD 北大核心 2009年第5期462-466,共5页
使用高纯物质人工合成的方法,成功研制了4个人工标准物质。该系列标准物质涵盖了钛、钒、锰、铬、钴、镍、铜、锌、砷、铅、铋、铷、锶、钇、锆、铌、钼、钨、钕、钽、铪、镱、锡、钡、铯、镓、锗、镧、铈等29个元素,不同分析元素的... 使用高纯物质人工合成的方法,成功研制了4个人工标准物质。该系列标准物质涵盖了钛、钒、锰、铬、钴、镍、铜、锌、砷、铅、铋、铷、锶、钇、锆、铌、钼、钨、钕、钽、铪、镱、锡、钡、铯、镓、锗、镧、铈等29个元素,不同分析元素的含量范围可扩大到0.00x%~8%。该系列标准物质不仅可以补充自然标准的不足,扩展校准曲线含量范围,而且能够修正干扰系数,解决了准确计算分析元素之间的干扰和仪器校正带来的实际困难。用4个人工标准物质取代单元素人工标准的配制。方法,减少标准数量,节约了资源以及标准配制的时间,避免了x射线荧光光谱分析工作者的重复劳动,提高了工作效率。研制的4个标准物质经检验均匀性和稳定性良好,量值准确可靠,已被国家质量监督检验检疫总局批准为国家一级标准物质。 展开更多
关键词 x射线荧光光谱 标准物质研制
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X射线荧光光谱法快速分析盐湖粘土矿物元素含量 被引量:12
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作者 王小欢 孟庆芬 +2 位作者 董亚萍 陈美达 李武 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2010年第3期829-833,共5页
以低压聚乙烯粉镶边垫底粉末压片法制样,用X射线荧光光谱法测定盐湖粘土矿物中主次组分含量的定量分析曲线,测量了粘土矿物中As,Mn,Co,Cu,Cr,Dy,Ga,Mo,P,Pb,Rb,S,Sr,Ba,Cs,Ta,Th,Ti,U,V,Y,Zn,Zr,MgO,K2O,Na2O,CaO,Fe2O3,Al2O3,SiO2含量... 以低压聚乙烯粉镶边垫底粉末压片法制样,用X射线荧光光谱法测定盐湖粘土矿物中主次组分含量的定量分析曲线,测量了粘土矿物中As,Mn,Co,Cu,Cr,Dy,Ga,Mo,P,Pb,Rb,S,Sr,Ba,Cs,Ta,Th,Ti,U,V,Y,Zn,Zr,MgO,K2O,Na2O,CaO,Fe2O3,Al2O3,SiO2含量。研究了各元素的谱线干扰特别是谱线的间接干扰,同时提出了元素周期表中各周期元素相互之间干扰的判别方法 使用α经验系数法及康普顿内标法校正基体效应,经对国家标准物及实际样品进行分析,测量值与标准值结果吻合。方法的检出限和准确度均满足分析要求,除了Mo,Cs,Ta 3个元素RSD较高,其他元素RSD为0.01%~5.45%。 展开更多
关键词 x射线荧光 谱线干扰 盐湖沉积 粘土矿物 标准物质
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