We have reported previously the ultrafast energy transfer process with a time constant of 0.8 ps from a monomeric to a dimeric subunit within a perylenetetracarboxylic diimide trimer, which was derived indirectly from...We have reported previously the ultrafast energy transfer process with a time constant of 0.8 ps from a monomeric to a dimeric subunit within a perylenetetracarboxylic diimide trimer, which was derived indirectly from a model fitting into the transient absorption experimental data. Here we present a direct ultrafast fluorescence quenching measurement by employing fs time-resolved transient fluorescence spectroscopy based on noncollinear optical parametric amplification technique. The rapid decay of the monomer's emission due to energy transfer was observed directly with a time constant of about 0.82 ps, in good agreement with the previous result.展开更多
The synchronous virtual machine uses inverter power to imitate the performance of the conventional synchronous machine.It also has the same inertia,damping,frequency,voltage regulation,and other external performance a...The synchronous virtual machine uses inverter power to imitate the performance of the conventional synchronous machine.It also has the same inertia,damping,frequency,voltage regulation,and other external performance as the generator.It is the key technology to realize new energy grid connections’stable and reliable operation.This project studies a dynamic simulation model of an extensive new energy power system based on the virtual synchronous motor.A new energy storage method is proposed.The mathematical energy storage model is established by combining the fixed rotor model of a synchronous virtual machine with the charge-discharge power,state of charge,operation efficiency,dead zone,and inverter constraint.The rapid conversion of energy storage devices absorbs the excess instantaneous kinetic energy caused by interference.The branch transient of the critical cut set in the system can be confined to a limited area.Thus,the virtual synchronizer’s kinetic and potential energy can be efficiently converted into an instantaneous state.The simulation of power system analysis software package(PSASP)verifies the correctness of the theory and algorithm in this paper.This paper provides a theoretical basis for improving the transient stability of new energy-connected power grids.展开更多
Distribution networks in China and several other countries are predominantly neutral inefficiently grounding systems(NIGSs),and more than 80%of the faults in distribution networks are single-phase-to-ground(SPG)faults...Distribution networks in China and several other countries are predominantly neutral inefficiently grounding systems(NIGSs),and more than 80%of the faults in distribution networks are single-phase-to-ground(SPG)faults.Because of the weak fault current and imperfect monitoring equipment configurations,methods used to determine the faulty line secti ons with SPG faults in NIGSs are in effective.The developme nt and application of distributi on-level phasor measurement units(PMUs)provide further comprehensive fault information for fault diagnosis in a distribution network.When an SPG fault occurs,the transient energy of the faulted line section tends to be higher than the sum of the transient energies of other line sections.In this regard,transient energy-based fault location algorithms appear to be a promising resolution.In this study,a field test plan was designed and implemented for a 10 kV distribution network.The test results dem on strate the effective ness of the transient en ergy-based SPG locati on method in practical distributi on networks.展开更多
A multi-degree-of-freedom device is proposed,which can achieve efficient vibration reduction as the main objective and energy harvesting as the secondary purpose.The device comprises a multiscale nonlinear vibration a...A multi-degree-of-freedom device is proposed,which can achieve efficient vibration reduction as the main objective and energy harvesting as the secondary purpose.The device comprises a multiscale nonlinear vibration absorber(NVA)and piezoelectric components.Energy conversion and energy measurement methods are used to evaluate the device performance from multiple perspectives.Research has shown that this device can efficiently transfer transient energy from the main structure and convert a portion of transient energy into electrical energy.Main resonance and higher-order resonance are the main reasons for efficient energy transfer.The device can maintain high vibration reduction performance even when the excitation amplitude changes over a large range.Compared with the single structures with and without precompression,the multiscale NVA-piezoelectric device offers significant vibration reduction advantages.In addition,there are significant differences in the parameter settings of the two substructures for vibration reduction and energy harvesting.展开更多
For building Global Energy Interconnection(GEI), it is necessary to implement new breakthroughs on largepower system simulation. Key routes for implementing full electromagnetic transient simulation of large-power sys...For building Global Energy Interconnection(GEI), it is necessary to implement new breakthroughs on largepower system simulation. Key routes for implementing full electromagnetic transient simulation of large-power systems are described in this paper, and a top framework is designed. A combination of the new large time step algorithm and the traditional small-time step algorithm is proposed where both parts A and B are calculated independently. The method for integrating the Norton equivalence of the power electronic system to the entire power grid is proposed. A two-level gird division structure is proposed, which executes a multi-rate parallel calculation among subsystems and element parallel calculation in each subsystem. The initialization method of combining load flow derivation and automatic trial-and-error launching is introduced. The feasibility of the method is demonstrated through a practical power grid example, which lays a foundation for further research.展开更多
Deep levels in Cds/CdTe thin film solar cells have a potent influence on the electrical property of these devices. As an essential layer in the solar cell device structure, back contact is believed to induce some deep...Deep levels in Cds/CdTe thin film solar cells have a potent influence on the electrical property of these devices. As an essential layer in the solar cell device structure, back contact is believed to induce some deep defects in the CdTe thin film. With the help of deep level transient spectroscopy (DLTS), we study the deep levels in CdS/CdTe thin film solar cells with Te:Cu back contact. One hole trap and one electron trap are observed. The hole trap H1, localized at Ev+0.128~eV, originates from the vacancy of Cd (VCd. The electron trap E1, found at Ec-0.178~eV, is considered to be correlated with the interstitial Cui= in CdTe.展开更多
The present work focus on the thermal performance of a horizontal concentric heat exchanger, which is numerically investigated to evaluate the heat transfer enhancement process by adding fins with different configurat...The present work focus on the thermal performance of a horizontal concentric heat exchanger, which is numerically investigated to evaluate the heat transfer enhancement process by adding fins with different configurations. As a part of this investigation, the melting process is simulated from the onset of phase change to the offset involving physics of natural convection in PCM fluid pool. The investigation is carried out by ANSYS Fluent code, which is an efficient numerical analysis tool for investigating fluid flow and convective heat transfer phenomena during PCM melting process. The attention is mainly focused on the extension of contact area between the PCM body and cylindrical capsule to enhance heat transfer rates to PCM bodies during the melting process by employing longitudinal fins in the enclosed capsule. Two commercial PCMs: RT50 and C58, are introduced in a 2D cylindrical pipe with their thermo-physical properties as input for modelling. The selected modelling approach is validated against experimental result with respect to the total enthalpy changes that qualify our model to run in the proceeding calculation. It is ensured that an isothermal boundary condition (373 K) is applied to the inner pipe throughout the series of simulation cases and the corresponding Rayleigh number (Ra) ranges from 104 - 105 and Prandtl number (Pr) 0.05 - 0.07. Finally, parametric study is carried out to evaluate the effect of length, thickness and number of longitudinal fins on the thermal performance of PCM-LHTES (Latent Heat Thermal Energy Storage) system associated with the physics of natural convection process during PCM melting.展开更多
This letter proposes a time-domain volume integral equation based method for analyzing the transient scattering from a 2D inhomogeneous cylinder by involking the volume equivalence principle for the transverse electri...This letter proposes a time-domain volume integral equation based method for analyzing the transient scattering from a 2D inhomogeneous cylinder by involking the volume equivalence principle for the transverse electric case. This integral equation is solved by using an MOT scheme. Numerical results obtained using this method agree very well with those obtained using the FDTD method.展开更多
A modified model, a set of rate equations based on time-dependent correlation function, is used to study vibrational relaxation dynamics in transient grating spectroscopy. The dephasing, the population dynamics, and t...A modified model, a set of rate equations based on time-dependent correlation function, is used to study vibrational relaxation dynamics in transient grating spectroscopy. The dephasing, the population dynamics, and the vibrational coherence concerning two vibrational states are observed respectively in organic dye IR780 perchlorate molecules doped polyvinyl alcohol matrix. The result shows that in addition to the information concerning system-environment interaction and vibrational coherence, the vibrational energy transfer can be described by this modified model.展开更多
A novel transient rotor current control scheme is proposed in this paper for a doubly-fed induction generator(DFIG)equipped with a superconducting magnetic energy storage(SMES) device to enhance its transient volt...A novel transient rotor current control scheme is proposed in this paper for a doubly-fed induction generator(DFIG)equipped with a superconducting magnetic energy storage(SMES) device to enhance its transient voltage and frequency support capacity during grid faults. The SMES connected to the DC-link capacitor of the DFIG is controlled to regulate the transient dc-link voltage so that the whole capacity of the grid side converter(GSC) is dedicated to injecting reactive power to the grid for the transient voltage support. However, the rotor-side converter(RSC) has different control tasks for different periods of the grid fault. Firstly, for Period I, the RSC injects the demagnetizing current to ensure the controllability of the rotor voltage. Then, since the dc stator flux degenerates rapidly in Period II, the required demagnetizing current is low in Period II and the RSC uses the spare capacity to additionally generate the reactive(priority) and active current so that the transient voltage capability is corroborated and the DFIG also positively responds to the system frequency dynamic at the earliest time. Finally, a small amount of demagnetizing current is provided after the fault clearance. Most of the RSC capacity is used to inject the active current to further support the frequency recovery of the system. Simulations are carried out on a simple power system with a wind farm. Comparisons with other commonly used control methods are performed to validate the proposed control method.展开更多
The energy dissipation mechanism of energetic materials(EMs) is very important for keeping safety. We choose nitrobenzene as a model of EM and employ transient absorption(TA) spectroscopy and time-resolved coheren...The energy dissipation mechanism of energetic materials(EMs) is very important for keeping safety. We choose nitrobenzene as a model of EM and employ transient absorption(TA) spectroscopy and time-resolved coherent anti-stokes Raman scattering(CARS) to clarify its energy dissipation mechanism. The TA data confirms that the excited nitrobenzene spends about 16 ps finishing the twist intramolecular charge transfer from benzene to nitro group, and dissipates its energy through the rapid vibration relaxation in the initial excited state. And then the dynamics of vibrational modes(VMs) in the ground state of nitrobenzene, which are located at 682 cm^-1(v1), 854 cm^-1(v2), 1006 cm^-1(v3), and 1023 cm^-1(v4),is scanned by CARS. It exhibits that the excess energy of nitrobenzene on the ground state would further dissipate through intramolecular vibrational redistribution based on the vibrational cooling of vi and v2 modes, v1 and v4 modes, and v3 and v4 modes. Moreover, the vibration-vibration coupling depends not only on the energy levels of VMs, but also on the spatial position of chemical bonds relative to the VM.展开更多
Electrically active defects in the phosphor-doped single-crystal silicon, induced by helium-ion irradiation under thermal annealing, have been investigated. Isothermal charge-sensitive deep-level transient spectroscop...Electrically active defects in the phosphor-doped single-crystal silicon, induced by helium-ion irradiation under thermal annealing, have been investigated. Isothermal charge-sensitive deep-level transient spectroscopy was employed to study the activation energy and capture cross-section of helium-induced defects in silicon samples. It was shown that the activation energy levels produced by helium-ion irradiation first increased with increasing annealing temperature, with the maximum value of the activation energy occurring at 873 K, and reduced with further increase of the annealing temperature. The energy levels of defects in the samples annealed at 873 and 1073 K are found to be located near the mid-forbidden energy gap level so that they can act as thermally stable carrier recombination centres.展开更多
Eddy current pulsed thermography(ECPT) is an emerging Non-destructive testing and evaluation(NDT E) technique, which uses hybrid eddy current and thermography NDT E techniques that enhances the detectability fro...Eddy current pulsed thermography(ECPT) is an emerging Non-destructive testing and evaluation(NDT E) technique, which uses hybrid eddy current and thermography NDT E techniques that enhances the detectability from their compensation. Currently, this technique is limited by the manual selection of proper contrast frames and the issue of improving the efficiency of defect detection of complex structure samples remains a challenge. In order to select a specific frame from transient thermal image sequences to maximize the contrast of thermal variation and defect pattern from complex structure samples, an energy driven approach to compute the coefficient energy of wavelet transform is proposed which has the potential of automatically selecting both optimal transient frame and spatial scale for defect detection using ECPT. According to analysis of the variation of different frequency component and the comparison study of the detection performance of different scale and wavelets, the frame at the end of heating phase is automatically selected as an optimal transient frame for defect detection. In addition, the detection capabilities of the complex structure samples can be enhanced through proper spatial scale and wavelet selection. The proposed method has successfully been applied to low speed impact damage detection of carbon fibre reinforced polymer(CFRP) composite as well as providing the guidance to improve the detectability of ECPT technique.展开更多
Effects of the main process parameters(temperature and time) on microstructure and properties of Ti(C, N)/Ni interface bonded by (Cu+Nb) interlayer in a vacuum diffusion bonding device were investigated. The in...Effects of the main process parameters(temperature and time) on microstructure and properties of Ti(C, N)/Ni interface bonded by (Cu+Nb) interlayer in a vacuum diffusion bonding device were investigated. The interfacial microstructures consisted initially of Ni3Nb metallic compound and eutectic of Ni3Nb + CuNiss, and finally transformed to (Ti, Nb) (C, N)+Ni3Nb near Ti (C, N) and NiCuss + Ni3Nb near Ni when diffusion bonding temperature was 1 523-1 573 K. It was clear that Cu was a constituent in the transient liquid phase (TLP) into which Ni was dissolved by forming Cu-Ni transition liquid. Nb was dissolved in Cu-Ni transition liquid rapidly. Ti (C, N) conld be wetted by resultant Ni-Nb-Cu transient liquid phase which was followed by a little (Ti, Nb) (C, N) solid solution formed at interface. This increased the interface combining capability. Ultimately the interface shear strength was able to reach 140 MPa. The theoretle analysis and experimental results show that the growth of interfacial reaction layer Ni3Nb accords with parabola law, and the activation energy of diffusion reaction is 115.0±0.5 kJ/mol, while the diffusion reaction speed constant is 12.53 mm/s^1/2.展开更多
Zero-dimensional environmentally friendly carbon quantum dots(CQDs)combined with two-di-mensional materials have a wide range of applications in optoelec-tronic devices.We combined steady-state and transient absorp-ti...Zero-dimensional environmentally friendly carbon quantum dots(CQDs)combined with two-di-mensional materials have a wide range of applications in optoelec-tronic devices.We combined steady-state and transient absorp-tion spectroscopies to study the energy transfer dynamics between CQDs and molybdenum disulfide(MoS_(2)).Transient absorption plots showed photoinduced absorption and stimulated emission features,which involved the intrinsic and defect states of CQDs.Adding MoS_(2)to CQDs solution,the lowest unoccupied molecular orbital of CQDs transferred energy to MoS_(2),which quenched the intrinsic emission at 390 nm.With addition of MoS_(2),CQD-MoS_(2)composites quenched defect emission at 490 nm and upward absorption,which originated from another energy transfer from the defect state.Two energy transfer paths between CQDs and MoS_(2)were efficiently manipulated by changing the concentration of MoS_(2),which laid a foundation for improving device performance.展开更多
In this work, we investigated the energy transfer (EnT) and electron transfer (ET) processes as well as their relationship in the carbon quantum dots/rhodamine B (CQDs/RhB) including o-CQDs/Rh B and m-CQDs/RhB systems...In this work, we investigated the energy transfer (EnT) and electron transfer (ET) processes as well as their relationship in the carbon quantum dots/rhodamine B (CQDs/RhB) including o-CQDs/Rh B and m-CQDs/RhB systems by using photoluminescence spectroscopy in combination with steady-state and transient absorption spectroscopy. We found that the ET process is negligible in the o-CQDs/RhB system with an EnT efficiency as high as 73.2%,while it becomes pronounced in the m-CQDs/RhB system whose EnT efficiency is lower than 33.5%. Such an interplay of En T and ET processes revealed in the prototypical composite system consisting of carbon quantum dots and dye molecules would provide helpful insights for applications of relevance to exciton quenching.展开更多
For fixed speed wind turbines, the connection of its squirrel cage induction generator (SCIG) to the grid leads to inrush current which can reach an average of 2 p.u. up to 2.5 p.u. in higher wind speed even by using ...For fixed speed wind turbines, the connection of its squirrel cage induction generator (SCIG) to the grid leads to inrush current which can reach an average of 2 p.u. up to 2.5 p.u. in higher wind speed even by using a soft starter. We propose in this paper a new soft starting of squirrel cage induction generator based wind turbine connected to the grid. Our strategy overcomes such transient instability problems and pinpoints rapidly synchronous speed regardless the wind speed acting on pitch angle. The proposed strategy ensures at least 50% reduction of inrush current and 18% gain of WTG starting time. A state model of the system is given including the wind turbine model and the SCIG model in the synchronous reference frame. Simulation results are analysed and compared to the classic coupling procedure.展开更多
Enhancing cavern sealing is crucial for improving the efficiency of compressed air energy storage(CAES)in hard rock formations.This study introduced a novel approach using a nano-grade organosilicon polymer(NOSP)as a ...Enhancing cavern sealing is crucial for improving the efficiency of compressed air energy storage(CAES)in hard rock formations.This study introduced a novel approach using a nano-grade organosilicon polymer(NOSP)as a sealant,coupled with an air seepage evaluation model that incorporates Knudsen diffusion.Moreover,the initial coating application methods were outlined,and the advantages of using NOSP compared to other sealing materials,particularly regarding cost and construction techniques,were also examined and discussed.Experimental results indicated a significant reduction in permeability of rock specimens coated with a 7–10μm thick NOSP layer.Specifically,under a 0.5 MPa pulse pressure,the permeability decreased to less than 1 n D,and under a 4 MPa pulse pressure,it ranged between4.5×10^(-6)–5.5×10^(-6)m D,marking a 75%–80%decrease in granite permeability.The sealing efficacy of NOSP surpasses concrete and is comparable to rubber materials.The optimal viscosity for application lies between 95 and 105 KU,and the coating thickness should ideally range from 7 to 10μm,applied to substrates with less than 3%porosity.This study provides new insights into air transport and sealing mechanisms at the pore level,proposing NOSP as a cost-effective and simplified solution for CAES applications.展开更多
基金This work was supported by the National Natural Science Foundation of China (No.20925313 and No.60438020), the National Basic Research Program of China (No.2009CB929404), and the Chinese Academy of Sciences Innovation Program (KJCX2-YW-W25).
文摘We have reported previously the ultrafast energy transfer process with a time constant of 0.8 ps from a monomeric to a dimeric subunit within a perylenetetracarboxylic diimide trimer, which was derived indirectly from a model fitting into the transient absorption experimental data. Here we present a direct ultrafast fluorescence quenching measurement by employing fs time-resolved transient fluorescence spectroscopy based on noncollinear optical parametric amplification technique. The rapid decay of the monomer's emission due to energy transfer was observed directly with a time constant of about 0.82 ps, in good agreement with the previous result.
文摘The synchronous virtual machine uses inverter power to imitate the performance of the conventional synchronous machine.It also has the same inertia,damping,frequency,voltage regulation,and other external performance as the generator.It is the key technology to realize new energy grid connections’stable and reliable operation.This project studies a dynamic simulation model of an extensive new energy power system based on the virtual synchronous motor.A new energy storage method is proposed.The mathematical energy storage model is established by combining the fixed rotor model of a synchronous virtual machine with the charge-discharge power,state of charge,operation efficiency,dead zone,and inverter constraint.The rapid conversion of energy storage devices absorbs the excess instantaneous kinetic energy caused by interference.The branch transient of the critical cut set in the system can be confined to a limited area.Thus,the virtual synchronizer’s kinetic and potential energy can be efficiently converted into an instantaneous state.The simulation of power system analysis software package(PSASP)verifies the correctness of the theory and algorithm in this paper.This paper provides a theoretical basis for improving the transient stability of new energy-connected power grids.
基金National Key R&D Program of China(2017YFB0902800)Science and Technology Project of State Grid Corporation of China(52094017003D)supported this work.
文摘Distribution networks in China and several other countries are predominantly neutral inefficiently grounding systems(NIGSs),and more than 80%of the faults in distribution networks are single-phase-to-ground(SPG)faults.Because of the weak fault current and imperfect monitoring equipment configurations,methods used to determine the faulty line secti ons with SPG faults in NIGSs are in effective.The developme nt and application of distributi on-level phasor measurement units(PMUs)provide further comprehensive fault information for fault diagnosis in a distribution network.When an SPG fault occurs,the transient energy of the faulted line section tends to be higher than the sum of the transient energies of other line sections.In this regard,transient energy-based fault location algorithms appear to be a promising resolution.In this study,a field test plan was designed and implemented for a 10 kV distribution network.The test results dem on strate the effective ness of the transient en ergy-based SPG locati on method in practical distributi on networks.
基金Project supported by the National Natural Science Foundation of China(Nos.11972050 and 12332001)。
文摘A multi-degree-of-freedom device is proposed,which can achieve efficient vibration reduction as the main objective and energy harvesting as the secondary purpose.The device comprises a multiscale nonlinear vibration absorber(NVA)and piezoelectric components.Energy conversion and energy measurement methods are used to evaluate the device performance from multiple perspectives.Research has shown that this device can efficiently transfer transient energy from the main structure and convert a portion of transient energy into electrical energy.Main resonance and higher-order resonance are the main reasons for efficient energy transfer.The device can maintain high vibration reduction performance even when the excitation amplitude changes over a large range.Compared with the single structures with and without precompression,the multiscale NVA-piezoelectric device offers significant vibration reduction advantages.In addition,there are significant differences in the parameter settings of the two substructures for vibration reduction and energy harvesting.
基金supported by key project of smart grid technology and equipment of national key research and development plan of China (2016YFB0900601)
文摘For building Global Energy Interconnection(GEI), it is necessary to implement new breakthroughs on largepower system simulation. Key routes for implementing full electromagnetic transient simulation of large-power systems are described in this paper, and a top framework is designed. A combination of the new large time step algorithm and the traditional small-time step algorithm is proposed where both parts A and B are calculated independently. The method for integrating the Norton equivalence of the power electronic system to the entire power grid is proposed. A two-level gird division structure is proposed, which executes a multi-rate parallel calculation among subsystems and element parallel calculation in each subsystem. The initialization method of combining load flow derivation and automatic trial-and-error launching is introduced. The feasibility of the method is demonstrated through a practical power grid example, which lays a foundation for further research.
基金supported by the National Natural Science Foundation of China (Grant No. 60506004)the National High Technology Research and Development Program of China (Grant No. 2003AA513010)
文摘Deep levels in Cds/CdTe thin film solar cells have a potent influence on the electrical property of these devices. As an essential layer in the solar cell device structure, back contact is believed to induce some deep defects in the CdTe thin film. With the help of deep level transient spectroscopy (DLTS), we study the deep levels in CdS/CdTe thin film solar cells with Te:Cu back contact. One hole trap and one electron trap are observed. The hole trap H1, localized at Ev+0.128~eV, originates from the vacancy of Cd (VCd. The electron trap E1, found at Ec-0.178~eV, is considered to be correlated with the interstitial Cui= in CdTe.
文摘The present work focus on the thermal performance of a horizontal concentric heat exchanger, which is numerically investigated to evaluate the heat transfer enhancement process by adding fins with different configurations. As a part of this investigation, the melting process is simulated from the onset of phase change to the offset involving physics of natural convection in PCM fluid pool. The investigation is carried out by ANSYS Fluent code, which is an efficient numerical analysis tool for investigating fluid flow and convective heat transfer phenomena during PCM melting process. The attention is mainly focused on the extension of contact area between the PCM body and cylindrical capsule to enhance heat transfer rates to PCM bodies during the melting process by employing longitudinal fins in the enclosed capsule. Two commercial PCMs: RT50 and C58, are introduced in a 2D cylindrical pipe with their thermo-physical properties as input for modelling. The selected modelling approach is validated against experimental result with respect to the total enthalpy changes that qualify our model to run in the proceeding calculation. It is ensured that an isothermal boundary condition (373 K) is applied to the inner pipe throughout the series of simulation cases and the corresponding Rayleigh number (Ra) ranges from 104 - 105 and Prandtl number (Pr) 0.05 - 0.07. Finally, parametric study is carried out to evaluate the effect of length, thickness and number of longitudinal fins on the thermal performance of PCM-LHTES (Latent Heat Thermal Energy Storage) system associated with the physics of natural convection process during PCM melting.
文摘This letter proposes a time-domain volume integral equation based method for analyzing the transient scattering from a 2D inhomogeneous cylinder by involking the volume equivalence principle for the transverse electric case. This integral equation is solved by using an MOT scheme. Numerical results obtained using this method agree very well with those obtained using the FDTD method.
基金supported by the Defense Industrial Technology Development Program of China (Grant No. B1520110002)the PreResearch Foundation of PLA General Armament Department, China (Grant No. 9104C6709101106)the National Natural Science Foundation of China (Grant Nos. 20973050 and 20573028)
文摘A modified model, a set of rate equations based on time-dependent correlation function, is used to study vibrational relaxation dynamics in transient grating spectroscopy. The dephasing, the population dynamics, and the vibrational coherence concerning two vibrational states are observed respectively in organic dye IR780 perchlorate molecules doped polyvinyl alcohol matrix. The result shows that in addition to the information concerning system-environment interaction and vibrational coherence, the vibrational energy transfer can be described by this modified model.
基金supported by the National Natural Science Foundation of China(Grant No.51307124)the Major Program of the National Natural Science Foundation of China(Grant No.51190105)
文摘A novel transient rotor current control scheme is proposed in this paper for a doubly-fed induction generator(DFIG)equipped with a superconducting magnetic energy storage(SMES) device to enhance its transient voltage and frequency support capacity during grid faults. The SMES connected to the DC-link capacitor of the DFIG is controlled to regulate the transient dc-link voltage so that the whole capacity of the grid side converter(GSC) is dedicated to injecting reactive power to the grid for the transient voltage support. However, the rotor-side converter(RSC) has different control tasks for different periods of the grid fault. Firstly, for Period I, the RSC injects the demagnetizing current to ensure the controllability of the rotor voltage. Then, since the dc stator flux degenerates rapidly in Period II, the required demagnetizing current is low in Period II and the RSC uses the spare capacity to additionally generate the reactive(priority) and active current so that the transient voltage capability is corroborated and the DFIG also positively responds to the system frequency dynamic at the earliest time. Finally, a small amount of demagnetizing current is provided after the fault clearance. Most of the RSC capacity is used to inject the active current to further support the frequency recovery of the system. Simulations are carried out on a simple power system with a wind farm. Comparisons with other commonly used control methods are performed to validate the proposed control method.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.21573094,11274142,11474131,11574112,and 51502109)the National Found for Fostering Talents of Basic Science,China(Grant No.J1103202)+1 种基金the Science Challenging Program(Grant No.JCKY2016212A501)China Scholarship Council(CSC) during a visit of Ning Sui(Grant No.201706175038) to MPIA is also acknowledged
文摘The energy dissipation mechanism of energetic materials(EMs) is very important for keeping safety. We choose nitrobenzene as a model of EM and employ transient absorption(TA) spectroscopy and time-resolved coherent anti-stokes Raman scattering(CARS) to clarify its energy dissipation mechanism. The TA data confirms that the excited nitrobenzene spends about 16 ps finishing the twist intramolecular charge transfer from benzene to nitro group, and dissipates its energy through the rapid vibration relaxation in the initial excited state. And then the dynamics of vibrational modes(VMs) in the ground state of nitrobenzene, which are located at 682 cm^-1(v1), 854 cm^-1(v2), 1006 cm^-1(v3), and 1023 cm^-1(v4),is scanned by CARS. It exhibits that the excess energy of nitrobenzene on the ground state would further dissipate through intramolecular vibrational redistribution based on the vibrational cooling of vi and v2 modes, v1 and v4 modes, and v3 and v4 modes. Moreover, the vibration-vibration coupling depends not only on the energy levels of VMs, but also on the spatial position of chemical bonds relative to the VM.
基金Project supported by the National Natural Science Foundation of China (Grant No 10575124)
文摘Electrically active defects in the phosphor-doped single-crystal silicon, induced by helium-ion irradiation under thermal annealing, have been investigated. Isothermal charge-sensitive deep-level transient spectroscopy was employed to study the activation energy and capture cross-section of helium-induced defects in silicon samples. It was shown that the activation energy levels produced by helium-ion irradiation first increased with increasing annealing temperature, with the maximum value of the activation energy occurring at 873 K, and reduced with further increase of the annealing temperature. The energy levels of defects in the samples annealed at 873 and 1073 K are found to be located near the mid-forbidden energy gap level so that they can act as thermally stable carrier recombination centres.
基金Supported by National Natural Science Foundation of China(Grant No.51377015)China Post Doctor Project(Grant No.136413)Science&Technology Department of Sichuan Province,China(Grant No.2013HH0059)
文摘Eddy current pulsed thermography(ECPT) is an emerging Non-destructive testing and evaluation(NDT E) technique, which uses hybrid eddy current and thermography NDT E techniques that enhances the detectability from their compensation. Currently, this technique is limited by the manual selection of proper contrast frames and the issue of improving the efficiency of defect detection of complex structure samples remains a challenge. In order to select a specific frame from transient thermal image sequences to maximize the contrast of thermal variation and defect pattern from complex structure samples, an energy driven approach to compute the coefficient energy of wavelet transform is proposed which has the potential of automatically selecting both optimal transient frame and spatial scale for defect detection using ECPT. According to analysis of the variation of different frequency component and the comparison study of the detection performance of different scale and wavelets, the frame at the end of heating phase is automatically selected as an optimal transient frame for defect detection. In addition, the detection capabilities of the complex structure samples can be enhanced through proper spatial scale and wavelet selection. The proposed method has successfully been applied to low speed impact damage detection of carbon fibre reinforced polymer(CFRP) composite as well as providing the guidance to improve the detectability of ECPT technique.
基金Funded by the National Natural Science Foundation of China (No.50074017/E0408)
文摘Effects of the main process parameters(temperature and time) on microstructure and properties of Ti(C, N)/Ni interface bonded by (Cu+Nb) interlayer in a vacuum diffusion bonding device were investigated. The interfacial microstructures consisted initially of Ni3Nb metallic compound and eutectic of Ni3Nb + CuNiss, and finally transformed to (Ti, Nb) (C, N)+Ni3Nb near Ti (C, N) and NiCuss + Ni3Nb near Ni when diffusion bonding temperature was 1 523-1 573 K. It was clear that Cu was a constituent in the transient liquid phase (TLP) into which Ni was dissolved by forming Cu-Ni transition liquid. Nb was dissolved in Cu-Ni transition liquid rapidly. Ti (C, N) conld be wetted by resultant Ni-Nb-Cu transient liquid phase which was followed by a little (Ti, Nb) (C, N) solid solution formed at interface. This increased the interface combining capability. Ultimately the interface shear strength was able to reach 140 MPa. The theoretle analysis and experimental results show that the growth of interfacial reaction layer Ni3Nb accords with parabola law, and the activation energy of diffusion reaction is 115.0±0.5 kJ/mol, while the diffusion reaction speed constant is 12.53 mm/s^1/2.
基金supported by the National Natural Science Foundation of China(No.61805134 and No.11974229)Applied Basic Research Program in Shanxi Province,China(No.201801D221016 and No.202103021223254)+2 种基金Scientific and Technological Innovation Pro-grams of Higher Education Institutions in Shanxi(No.2020L0235 and No.2021L257)Linfen Key Re-search and Development Program(No.2028)Graduate Innovation Project in Shanxi Province(No.2022Y498).
文摘Zero-dimensional environmentally friendly carbon quantum dots(CQDs)combined with two-di-mensional materials have a wide range of applications in optoelec-tronic devices.We combined steady-state and transient absorp-tion spectroscopies to study the energy transfer dynamics between CQDs and molybdenum disulfide(MoS_(2)).Transient absorption plots showed photoinduced absorption and stimulated emission features,which involved the intrinsic and defect states of CQDs.Adding MoS_(2)to CQDs solution,the lowest unoccupied molecular orbital of CQDs transferred energy to MoS_(2),which quenched the intrinsic emission at 390 nm.With addition of MoS_(2),CQD-MoS_(2)composites quenched defect emission at 490 nm and upward absorption,which originated from another energy transfer from the defect state.Two energy transfer paths between CQDs and MoS_(2)were efficiently manipulated by changing the concentration of MoS_(2),which laid a foundation for improving device performance.
基金supported by the National Key Research and Development Program on Nano Science and Technology of MOST(No.2016YFA0200602 and No.2018YFA0208702)the National Natural Science Foundation of China(No.21573211 and No.21633007)the Anhui Initiative in Quantum Information Technologies(AHY090200)
文摘In this work, we investigated the energy transfer (EnT) and electron transfer (ET) processes as well as their relationship in the carbon quantum dots/rhodamine B (CQDs/RhB) including o-CQDs/Rh B and m-CQDs/RhB systems by using photoluminescence spectroscopy in combination with steady-state and transient absorption spectroscopy. We found that the ET process is negligible in the o-CQDs/RhB system with an EnT efficiency as high as 73.2%,while it becomes pronounced in the m-CQDs/RhB system whose EnT efficiency is lower than 33.5%. Such an interplay of En T and ET processes revealed in the prototypical composite system consisting of carbon quantum dots and dye molecules would provide helpful insights for applications of relevance to exciton quenching.
文摘For fixed speed wind turbines, the connection of its squirrel cage induction generator (SCIG) to the grid leads to inrush current which can reach an average of 2 p.u. up to 2.5 p.u. in higher wind speed even by using a soft starter. We propose in this paper a new soft starting of squirrel cage induction generator based wind turbine connected to the grid. Our strategy overcomes such transient instability problems and pinpoints rapidly synchronous speed regardless the wind speed acting on pitch angle. The proposed strategy ensures at least 50% reduction of inrush current and 18% gain of WTG starting time. A state model of the system is given including the wind turbine model and the SCIG model in the synchronous reference frame. Simulation results are analysed and compared to the classic coupling procedure.
基金supported by the National Natural Science Foundation of China(No.42272321)Hubei Provincial Key Research Projects(Nos.2022BAA093 and 2022BAD163)+1 种基金Major Scientific and Technological Special Project of Jiangxi Province(No.2023ACG01004)WSGRI Engineering&Surveying Incorporation Limited(No.6120230256)。
文摘Enhancing cavern sealing is crucial for improving the efficiency of compressed air energy storage(CAES)in hard rock formations.This study introduced a novel approach using a nano-grade organosilicon polymer(NOSP)as a sealant,coupled with an air seepage evaluation model that incorporates Knudsen diffusion.Moreover,the initial coating application methods were outlined,and the advantages of using NOSP compared to other sealing materials,particularly regarding cost and construction techniques,were also examined and discussed.Experimental results indicated a significant reduction in permeability of rock specimens coated with a 7–10μm thick NOSP layer.Specifically,under a 0.5 MPa pulse pressure,the permeability decreased to less than 1 n D,and under a 4 MPa pulse pressure,it ranged between4.5×10^(-6)–5.5×10^(-6)m D,marking a 75%–80%decrease in granite permeability.The sealing efficacy of NOSP surpasses concrete and is comparable to rubber materials.The optimal viscosity for application lies between 95 and 105 KU,and the coating thickness should ideally range from 7 to 10μm,applied to substrates with less than 3%porosity.This study provides new insights into air transport and sealing mechanisms at the pore level,proposing NOSP as a cost-effective and simplified solution for CAES applications.