The Yb:YAG is an excellent high-average power and ultra-short pulse laser crystal. Transition intensity parameters A(tp)~k and Huang–Rhys factors are fitted to its emission spectrum by the full-profile fitting met...The Yb:YAG is an excellent high-average power and ultra-short pulse laser crystal. Transition intensity parameters A(tp)~k and Huang–Rhys factors are fitted to its emission spectrum by the full-profile fitting method. Calculated results indicate that the emission spectrum of Yb:YAG at cryogenic temperature consists of three pure electron state transitions and two phononassisted transitions, one vibronic transition releases one-phonon of 3 cm^(-1), and the other vibronic transition absorbs onephonon of 22 cm^(-1). At 300 K, the phonon assisted transition of 3 cm^(-1) turns into two-or more-phonon assisted transitions.The procedure absorbing phonon can reduce the thermal load of Yb:YAG and improve the laser efficiency, which may be one of the reasons why Yb:YAG has excellent performance. The emission bands of Yb:YAG are broadened thermally, and the peak values decrease by several times. The emission cross sections of Yb:YAG determined by Fuchtbauer–Ladenburg(F–L) formula are remarkably different from those calculated with A(tp)~k, which indicates that it is necessary for a laser material to determine its transition intensity parameters A(tp)~kin order to reasonably evaluate the laser performance.展开更多
Quantum aspects of the Joule-Lenz law for the transmission of energy allowed us to calculate the time rate of energy transitions between the quantum states of the hydrogen atom in a fully non-probabilistic way. The ca...Quantum aspects of the Joule-Lenz law for the transmission of energy allowed us to calculate the time rate of energy transitions between the quantum states of the hydrogen atom in a fully non-probabilistic way. The calculation has been extended to all transitions between p and s states having main quantum numbers not exceeding 6. An evident similarity between the intensity pattern obtained from the Joule-Lenz law and the corresponding quantum-mechanical transition pro-babilities has been shown.展开更多
The energy spectrum of the hydrogen atom has been applied in calculating the time rate of energy transitions between the quantum states of the atom. The formal basis of the approach has been provided by the quantum pr...The energy spectrum of the hydrogen atom has been applied in calculating the time rate of energy transitions between the quantum states of the atom. The formal basis of the approach has been provided by the quantum properties of energy and time deduced from the Joule-Lenz law. The rates of the energy transitions obtained in this way were compared with the quantum-mechanical probabilities of transitions calculated earlier by Bethe and Condon and Shortley for the same pairs of the quantum states.展开更多
The structure of the low-temperature 4f^N→4f^N-15d excitation spectra of Eu^3+ and Tb^3+ doped in crystals LiYF4, YPO4 and CaF2 measured by van Pieterson et al. in 2002 was analyzed and assigned based on the simple...The structure of the low-temperature 4f^N→4f^N-15d excitation spectra of Eu^3+ and Tb^3+ doped in crystals LiYF4, YPO4 and CaF2 measured by van Pieterson et al. in 2002 was analyzed and assigned based on the simple model proposed by Duan and co-workers in the last few years. Some complemental discussion on effects of J-mixing on the f-d transition intensities for Eu^3+ due to the f-electron crystal-field interaction Hcf(f), which was ignored in the simple mod- el, was presented. Some previously unexplained peaks for Tb^3 + were interpreted to be spin-forbidden transitions to higher 5d crystal-field levels, or assigned to be f→d excitations with the core 4f7 excited from ^8S to ^6P, ^6I and ^6D, respectively. It is shown that the main structure of 4f-Sd excitation spectra of Eu^3+ and Tb^3+ can be well interpreted with the simple model.展开更多
We apply our sky map reconstruction method for transit type interferometers to the Tianlai cylin- der array. The method is based on spherical harmonic decomposition, and can be applied to a cylindrical array as well a...We apply our sky map reconstruction method for transit type interferometers to the Tianlai cylin- der array. The method is based on spherical harmonic decomposition, and can be applied to a cylindrical array as well as dish arrays and we can compute the instrument response, synthesized beam, transfer func- tion and noise power spectrum. We consider cylinder arrays with feed spacing larger than half a wavelength and, as expected, we find that the arrays with regular spacing have grating lobes which produce spurious images in the reconstructed maps. We show that this problem can be overcome using arrays with a different feed spacing on each cylinder. We present the reconstructed maps, and study the performance in terms of noise power spectrum, transfer function and beams for both regular and irregular feed spacing configura- tions.展开更多
An accurate electric dipole moment function(EDMF) is obtained for the carbon monoxide(CO) molecule(X1+Σ)by fitting the experimental rovibrational transitional moments. Additionally, an accurate ab initio EDMF is foun...An accurate electric dipole moment function(EDMF) is obtained for the carbon monoxide(CO) molecule(X1+Σ)by fitting the experimental rovibrational transitional moments. Additionally, an accurate ab initio EDMF is found using the highly accurate, multi-reference averaged coupled-pair functional(ACPF) approach with the basis set, aug-cc-p V6 Z, and a finite-field with ±0.005 a.u.(The unit a.u. is the abbreviation of atomic unit). This ab initio EDMF is very consistent with the fitted ones. The vibrational transition matrix moments and the Herman–Wallis factors, calculated with the Rydberg–Klein–Rees(RKR) potential and the fitted and ab initio EDMFs, are compared with experimental measurements. The consistency of these line intensities with the high-resolution transmission(HITRAN) molecular database demonstrates the improved accuracy of the fitted and ab initio EDMFs derived in this work.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.61405206,51502292,and 51702322)the Knowledge Innovation Program of the Chinese Academy of Sciences(Grant Nos.CXJJ-16M251 and CXJJ-15M055)the National Key Research and Development Program of China(Grant No.2016YFB0402101)
文摘The Yb:YAG is an excellent high-average power and ultra-short pulse laser crystal. Transition intensity parameters A(tp)~k and Huang–Rhys factors are fitted to its emission spectrum by the full-profile fitting method. Calculated results indicate that the emission spectrum of Yb:YAG at cryogenic temperature consists of three pure electron state transitions and two phononassisted transitions, one vibronic transition releases one-phonon of 3 cm^(-1), and the other vibronic transition absorbs onephonon of 22 cm^(-1). At 300 K, the phonon assisted transition of 3 cm^(-1) turns into two-or more-phonon assisted transitions.The procedure absorbing phonon can reduce the thermal load of Yb:YAG and improve the laser efficiency, which may be one of the reasons why Yb:YAG has excellent performance. The emission bands of Yb:YAG are broadened thermally, and the peak values decrease by several times. The emission cross sections of Yb:YAG determined by Fuchtbauer–Ladenburg(F–L) formula are remarkably different from those calculated with A(tp)~k, which indicates that it is necessary for a laser material to determine its transition intensity parameters A(tp)~kin order to reasonably evaluate the laser performance.
文摘Quantum aspects of the Joule-Lenz law for the transmission of energy allowed us to calculate the time rate of energy transitions between the quantum states of the hydrogen atom in a fully non-probabilistic way. The calculation has been extended to all transitions between p and s states having main quantum numbers not exceeding 6. An evident similarity between the intensity pattern obtained from the Joule-Lenz law and the corresponding quantum-mechanical transition pro-babilities has been shown.
文摘The energy spectrum of the hydrogen atom has been applied in calculating the time rate of energy transitions between the quantum states of the atom. The formal basis of the approach has been provided by the quantum properties of energy and time deduced from the Joule-Lenz law. The rates of the energy transitions obtained in this way were compared with the quantum-mechanical probabilities of transitions calculated earlier by Bethe and Condon and Shortley for the same pairs of the quantum states.
文摘The structure of the low-temperature 4f^N→4f^N-15d excitation spectra of Eu^3+ and Tb^3+ doped in crystals LiYF4, YPO4 and CaF2 measured by van Pieterson et al. in 2002 was analyzed and assigned based on the simple model proposed by Duan and co-workers in the last few years. Some complemental discussion on effects of J-mixing on the f-d transition intensities for Eu^3+ due to the f-electron crystal-field interaction Hcf(f), which was ignored in the simple mod- el, was presented. Some previously unexplained peaks for Tb^3 + were interpreted to be spin-forbidden transitions to higher 5d crystal-field levels, or assigned to be f→d excitations with the core 4f7 excited from ^8S to ^6P, ^6I and ^6D, respectively. It is shown that the main structure of 4f-Sd excitation spectra of Eu^3+ and Tb^3+ can be well interpreted with the simple model.
基金supported by the MOST 863 program(Grant 2012AA121701)the CAS Repair and Procurement grant+4 种基金supported by PNCG,Observatoire de Paris,Irfu/CEA and LAL/CNRSsupported by the China Scholarship Councilsupported by the CAS Strategic Priority Research Program(XDB09020301)the National Natural Science Foundation of China(NSFC,Grant 11373030)supported by the NSFC(Grant 11473044)
文摘We apply our sky map reconstruction method for transit type interferometers to the Tianlai cylin- der array. The method is based on spherical harmonic decomposition, and can be applied to a cylindrical array as well as dish arrays and we can compute the instrument response, synthesized beam, transfer func- tion and noise power spectrum. We consider cylinder arrays with feed spacing larger than half a wavelength and, as expected, we find that the arrays with regular spacing have grating lobes which produce spurious images in the reconstructed maps. We show that this problem can be overcome using arrays with a different feed spacing on each cylinder. We present the reconstructed maps, and study the performance in terms of noise power spectrum, transfer function and beams for both regular and irregular feed spacing configura- tions.
基金supported by the National Natural Science Foundation of China(Grant Nos.11374217 and 11474207)
文摘An accurate electric dipole moment function(EDMF) is obtained for the carbon monoxide(CO) molecule(X1+Σ)by fitting the experimental rovibrational transitional moments. Additionally, an accurate ab initio EDMF is found using the highly accurate, multi-reference averaged coupled-pair functional(ACPF) approach with the basis set, aug-cc-p V6 Z, and a finite-field with ±0.005 a.u.(The unit a.u. is the abbreviation of atomic unit). This ab initio EDMF is very consistent with the fitted ones. The vibrational transition matrix moments and the Herman–Wallis factors, calculated with the Rydberg–Klein–Rees(RKR) potential and the fitted and ab initio EDMFs, are compared with experimental measurements. The consistency of these line intensities with the high-resolution transmission(HITRAN) molecular database demonstrates the improved accuracy of the fitted and ab initio EDMFs derived in this work.