To overcome the disadvantages of displacement ventilation( DV) and traditional mixing ventilation( MV) system,a new ventilation system known as impinging jet ventilation system( IJVS)has been developing. The warm air ...To overcome the disadvantages of displacement ventilation( DV) and traditional mixing ventilation( MV) system,a new ventilation system known as impinging jet ventilation system( IJVS)has been developing. The warm air can be supplied with impinging jet ventilation( IJV), while the DV is only used for cooling.However,the flow and temperature field of IJV under heating scenario has had few references. The paper is mainly focused on computational fluid dynamics( CFD) and developing an adequate correlation between the distance L that warm air can reach and different parameters in the warm IJVS by using response surface methodology( RSM). The results indicate that L decreases as the supply velocity υ decreases but increases as the supply temperature difference ΔT or the discharge height h decreases. In the variable air volume( VAV) system, it is necessary to determine supply parameters both under the maximum-heat-load condition and the small-heat-load condition. Unlike the VAV system,the constant air volume( CAV) system has no need to study the small-heat-load condition. Draught discomfort near the nozzle becomes the issue of concern in IJVS, thus the suitable discharge height is of great importance in design and can be calculated based on the predictive model.展开更多
It is essential to learn the temporal and spatial concentration distributions and variations of seeding agents in cloud seeding of precipitation enhancement. A three-dimensional puff trajectory model incorporating a m...It is essential to learn the temporal and spatial concentration distributions and variations of seeding agents in cloud seeding of precipitation enhancement. A three-dimensional puff trajectory model incorporating a mesoscale nonhydrostatic model has been formulated, and is applied to simulating the transporting and diffusive characteristics of multiple line sources of seeding agents within super-cooled stratus. Several important factors are taken into consideration that affect the diffusion of seeding materials such as effects of topography and vertical wind shear, temporal and spatial variation of seeding parameters and wet deposition. The particles of seeding agents are assumed to be almost inert, they have no interaction with the particles of the cloud or precipitation except that they are washed out by precipitation. The model validity is demonstrated by the analyses and comparisons of model results, and checked by the sensitivity experiments of diffusive coefficients and atmospheric stratification. The advantage of this model includes not only its exact reflection of heterogeneity and unsteadiness of background fields, but also its good simulation of transport and diffusion of multiple line sources. The horizontal diffusion rate and the horizontal transport distance have been proposed that they usually were difficult to obtain in other models. In this simulation the horizontal diffusion rate is 0.82 m s(-1) for average of one hour, and the horizontal average transport distance reaches 65 km after 1 4 which are closely related to the background Fields.展开更多
ZnO as a semiconductor photocatalyst is widely applied in the photodegradation of organic pollutants. Its photocatalytic activity is greatly decreased because of the recombination of photoexcited electrons and holes i...ZnO as a semiconductor photocatalyst is widely applied in the photodegradation of organic pollutants. Its photocatalytic activity is greatly decreased because of the recombination of photoexcited electrons and holes in the bulk. In this work, ZnO sheets are synthesized by adjusting the NaOH concentration under light irradiation at room temperature. Compared with ZnO particles, the ZnO sheets prepared with a light-assisted growth method exhibit a higher rate of photodegradation of methylene blue under UV visible light irradiation. The improved photodegradation rate is mainly attributed to the shortened transport distance of photoexcited electrons, the high surface area, and the surface atom structure modified by the light-assisted growth process. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.展开更多
This work examines the environmental and geochemical impact of recycled aggregate concrete production with properties representative for structural applications.The environmental influence of cement content,aggregate ...This work examines the environmental and geochemical impact of recycled aggregate concrete production with properties representative for structural applications.The environmental influence of cement content,aggregate production,transportation,and waste landfilling is analysed by undertaking a life cycle assessment and considering a life cycle inventory largely specific for the region.To obtain a detailed insight into the optimum life cycle parameters,a sensitivity study is carried out in which supplementary cementitious materials,different values of natural-to-recycled aggregate content ratio and case-specific transportation distances were considered.The results show that carbon emissions were between 323 and 332 kgCO_(2)e per cubic metre of cement only natural aggregate concrete.These values can be reduced by up to 17%by replacing 25%of the cement with fly ash.By contrast,carbon emissions can increase when natural coarse aggregates are replaced by recycled aggregates in proportions of 50%and 100%,and transportation is not included in analysis.However,the concrete with 50%recycled aggregate presented lower increase,only 0.3%and 3.4%for normal and high strength concrete,respectively.In some cases,the relative contribution of transportation to the total carbon emissions increased when cement was replaced by fly ash in proportions of 25%,and case-specific transportation distances were considered.In absolute values,the concrete mixes with 100%recycled aggregates and 25%fly ash had lower carbon emissions than concrete with cement and natural aggregates only.Higher environmental benefits can be obtained when the transportation distances of fly ash are relatively short(15–25 km)and the cement replacement by fly ash is equal or higher than 25%,considering that the mechanical properties are adequate for practical application.The observations from this paper show that recycled aggregate concrete with strength characteristics representative for structural members can have lower carbon emissions than conventional concrete,recommending them as an alternative to achieving global sustainability standards in construction.展开更多
The airborne ragweed pollen spectrum was investigated in the air of Ankara, Turkey for aperiod of ten years (1990-1999) using a Burkard seven-day volumetric recording trap. In our study period,long distance transporte...The airborne ragweed pollen spectrum was investigated in the air of Ankara, Turkey for aperiod of ten years (1990-1999) using a Burkard seven-day volumetric recording trap. In our study period,long distance transported Ambrosia pollen has been registered. Daily pollen levels varied from low to highin Burge抯 system. In last three years, the pollen concentration of Ambrosia showed a clear increasingtendency. Our results prove that ragweed pollen may be an important threat for ragweed sensitive patientsin Ankara city in near future.展开更多
Decomposition mass loss and pyrolysis products analyses of particles sampled at various locations along the tailpipe of a Euro-IV diesel engine were performed using a thermo gravimetry in conjunction with Fourier tran...Decomposition mass loss and pyrolysis products analyses of particles sampled at various locations along the tailpipe of a Euro-IV diesel engine were performed using a thermo gravimetry in conjunction with Fourier transformation infrared spectrometrymass spectrum.Diesel particles were collected at the same location with and without diesel oxidation catalyst(DOC)mounted on the test engine separately.The three poles in thermal gravity-differential thermal gravity images suggested that the decomposition process of diesel particles could be divided into three stages which correspond to the decompositions of lower boiling substances,higher boiling substances and soot respectively.It is noticed that no matter whether DOC was mounted or not,the further the particles were sampled away from the engine block,the lower the peak temperatures and the heavier the mass losses within the first two stages,which indicated that the soluble organic fraction in the particle samples increased and therefore lowering the activation energy of thermal decomposition.Hydroxyl,ammonia,C_xH_y fragments,benzene,toluene,and phenol were found to be the primary products of particle decomposition,which didn’t change with the location of particle sample point.The employment of DOC increased the activation energy for particle oxidation and resulted in a higher peak temperature and lower mass loss within the first-stage.Moreover,the C=O stretching bands of aldehyde and ketone at 1771 cm-1 was only detected without a DOC,while the N02 peak at 1634 cm-1 was solely noticed with the presence of DOC.Compared to the first-stage pyrolysis products,more polycyclic aromatic hydrocarbons and less C_xH_y fragments were seen in the second-stage.展开更多
In order to evaluate the secondary aerosol formation potential at a suburban site of Beijing,in situ perturbation experiments in a potential aerosol mass(PAM) reactor were carried out in the winter of 2014.The varia...In order to evaluate the secondary aerosol formation potential at a suburban site of Beijing,in situ perturbation experiments in a potential aerosol mass(PAM) reactor were carried out in the winter of 2014.The variations of secondary aerosol formation as a function of time,OH exposure,and the concentrations of gas phase pollutants and particles were reported in this study.Two periods with distinct secondary aerosol formation potentials,marked as Period Ⅰ and Period Ⅱ,were identified during the observation.In Period Ⅰ,the secondary aerosol formation potential was high,and correlated well to the air pollutants,i.e.,SO2,NO2,and CO.The maximal secondary aerosol formation was observed with an aging time equivalent to about 3 days of atmospheric oxidation.In period Ⅱ,the secondary aerosol formation potential was low,with no obvious correlation with the air pollutants.Meanwhile,the aerosol mass decreased,instead of showing a peak,with increasing aging time.Backward trajectory analysis during the two periods confirmed that the air mass in Period Ⅰwas mainly from local sources,while it was attributed mostly to long distance transport in Period Ⅱ.The air lost its reactivity during the long transport and the particles became highly aged,resulting in a low secondary aerosol formation potential.Our experimental results indicated that the in situ measurement of the secondary aerosol formation potential could provide important information for evaluating the contributions of local emission and long distance transport to the aerosol pollution.展开更多
基金National Natural Science Foundation of China(No.51278094)the Innovation Foundation of Shanghai Education Commission,China(No.13ZZ054)
文摘To overcome the disadvantages of displacement ventilation( DV) and traditional mixing ventilation( MV) system,a new ventilation system known as impinging jet ventilation system( IJVS)has been developing. The warm air can be supplied with impinging jet ventilation( IJV), while the DV is only used for cooling.However,the flow and temperature field of IJV under heating scenario has had few references. The paper is mainly focused on computational fluid dynamics( CFD) and developing an adequate correlation between the distance L that warm air can reach and different parameters in the warm IJVS by using response surface methodology( RSM). The results indicate that L decreases as the supply velocity υ decreases but increases as the supply temperature difference ΔT or the discharge height h decreases. In the variable air volume( VAV) system, it is necessary to determine supply parameters both under the maximum-heat-load condition and the small-heat-load condition. Unlike the VAV system,the constant air volume( CAV) system has no need to study the small-heat-load condition. Draught discomfort near the nozzle becomes the issue of concern in IJVS, thus the suitable discharge height is of great importance in design and can be calculated based on the predictive model.
文摘It is essential to learn the temporal and spatial concentration distributions and variations of seeding agents in cloud seeding of precipitation enhancement. A three-dimensional puff trajectory model incorporating a mesoscale nonhydrostatic model has been formulated, and is applied to simulating the transporting and diffusive characteristics of multiple line sources of seeding agents within super-cooled stratus. Several important factors are taken into consideration that affect the diffusion of seeding materials such as effects of topography and vertical wind shear, temporal and spatial variation of seeding parameters and wet deposition. The particles of seeding agents are assumed to be almost inert, they have no interaction with the particles of the cloud or precipitation except that they are washed out by precipitation. The model validity is demonstrated by the analyses and comparisons of model results, and checked by the sensitivity experiments of diffusive coefficients and atmospheric stratification. The advantage of this model includes not only its exact reflection of heterogeneity and unsteadiness of background fields, but also its good simulation of transport and diffusion of multiple line sources. The horizontal diffusion rate and the horizontal transport distance have been proposed that they usually were difficult to obtain in other models. In this simulation the horizontal diffusion rate is 0.82 m s(-1) for average of one hour, and the horizontal average transport distance reaches 65 km after 1 4 which are closely related to the background Fields.
基金support from the Institute of Metal Research,Chinese Academy of Sciencessupported by the National Science Fund of China(51202105,21366020)+1 种基金the Natural Science Foundation of Jiangxi Province(20151BAB216006)the Science and Technology Project of Education Department of Jiangxi Province(GJJ14109)
文摘ZnO as a semiconductor photocatalyst is widely applied in the photodegradation of organic pollutants. Its photocatalytic activity is greatly decreased because of the recombination of photoexcited electrons and holes in the bulk. In this work, ZnO sheets are synthesized by adjusting the NaOH concentration under light irradiation at room temperature. Compared with ZnO particles, the ZnO sheets prepared with a light-assisted growth method exhibit a higher rate of photodegradation of methylene blue under UV visible light irradiation. The improved photodegradation rate is mainly attributed to the shortened transport distance of photoexcited electrons, the high surface area, and the surface atom structure modified by the light-assisted growth process. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
文摘This work examines the environmental and geochemical impact of recycled aggregate concrete production with properties representative for structural applications.The environmental influence of cement content,aggregate production,transportation,and waste landfilling is analysed by undertaking a life cycle assessment and considering a life cycle inventory largely specific for the region.To obtain a detailed insight into the optimum life cycle parameters,a sensitivity study is carried out in which supplementary cementitious materials,different values of natural-to-recycled aggregate content ratio and case-specific transportation distances were considered.The results show that carbon emissions were between 323 and 332 kgCO_(2)e per cubic metre of cement only natural aggregate concrete.These values can be reduced by up to 17%by replacing 25%of the cement with fly ash.By contrast,carbon emissions can increase when natural coarse aggregates are replaced by recycled aggregates in proportions of 50%and 100%,and transportation is not included in analysis.However,the concrete with 50%recycled aggregate presented lower increase,only 0.3%and 3.4%for normal and high strength concrete,respectively.In some cases,the relative contribution of transportation to the total carbon emissions increased when cement was replaced by fly ash in proportions of 25%,and case-specific transportation distances were considered.In absolute values,the concrete mixes with 100%recycled aggregates and 25%fly ash had lower carbon emissions than concrete with cement and natural aggregates only.Higher environmental benefits can be obtained when the transportation distances of fly ash are relatively short(15–25 km)and the cement replacement by fly ash is equal or higher than 25%,considering that the mechanical properties are adequate for practical application.The observations from this paper show that recycled aggregate concrete with strength characteristics representative for structural members can have lower carbon emissions than conventional concrete,recommending them as an alternative to achieving global sustainability standards in construction.
基金Supported by the Research Foundation of Ankara University.
文摘The airborne ragweed pollen spectrum was investigated in the air of Ankara, Turkey for aperiod of ten years (1990-1999) using a Burkard seven-day volumetric recording trap. In our study period,long distance transported Ambrosia pollen has been registered. Daily pollen levels varied from low to highin Burge抯 system. In last three years, the pollen concentration of Ambrosia showed a clear increasingtendency. Our results prove that ragweed pollen may be an important threat for ragweed sensitive patientsin Ankara city in near future.
基金supported by the Open Research Program of State Key Laboratory of Engine Combustion(No.K2018-11)the National Nature Science Foundation of China(No.51806015)the National Engineering Laboratory for Mobile Source Emission Control Technology(No.NELMS2018A17)
文摘Decomposition mass loss and pyrolysis products analyses of particles sampled at various locations along the tailpipe of a Euro-IV diesel engine were performed using a thermo gravimetry in conjunction with Fourier transformation infrared spectrometrymass spectrum.Diesel particles were collected at the same location with and without diesel oxidation catalyst(DOC)mounted on the test engine separately.The three poles in thermal gravity-differential thermal gravity images suggested that the decomposition process of diesel particles could be divided into three stages which correspond to the decompositions of lower boiling substances,higher boiling substances and soot respectively.It is noticed that no matter whether DOC was mounted or not,the further the particles were sampled away from the engine block,the lower the peak temperatures and the heavier the mass losses within the first two stages,which indicated that the soluble organic fraction in the particle samples increased and therefore lowering the activation energy of thermal decomposition.Hydroxyl,ammonia,C_xH_y fragments,benzene,toluene,and phenol were found to be the primary products of particle decomposition,which didn’t change with the location of particle sample point.The employment of DOC increased the activation energy for particle oxidation and resulted in a higher peak temperature and lower mass loss within the first-stage.Moreover,the C=O stretching bands of aldehyde and ketone at 1771 cm-1 was only detected without a DOC,while the N02 peak at 1634 cm-1 was solely noticed with the presence of DOC.Compared to the first-stage pyrolysis products,more polycyclic aromatic hydrocarbons and less C_xH_y fragments were seen in the second-stage.
基金supported by the Key Research Program of Chinese Academy of Sciences (No. KJZD-EW-TZ-G06-01-15)the National Natural Science Foundation of China (No. 21407158)the Strategic Priority Research Program (B) of the Chinese Academy of Sciences (No. XDB05010300)
文摘In order to evaluate the secondary aerosol formation potential at a suburban site of Beijing,in situ perturbation experiments in a potential aerosol mass(PAM) reactor were carried out in the winter of 2014.The variations of secondary aerosol formation as a function of time,OH exposure,and the concentrations of gas phase pollutants and particles were reported in this study.Two periods with distinct secondary aerosol formation potentials,marked as Period Ⅰ and Period Ⅱ,were identified during the observation.In Period Ⅰ,the secondary aerosol formation potential was high,and correlated well to the air pollutants,i.e.,SO2,NO2,and CO.The maximal secondary aerosol formation was observed with an aging time equivalent to about 3 days of atmospheric oxidation.In period Ⅱ,the secondary aerosol formation potential was low,with no obvious correlation with the air pollutants.Meanwhile,the aerosol mass decreased,instead of showing a peak,with increasing aging time.Backward trajectory analysis during the two periods confirmed that the air mass in Period Ⅰwas mainly from local sources,while it was attributed mostly to long distance transport in Period Ⅱ.The air lost its reactivity during the long transport and the particles became highly aged,resulting in a low secondary aerosol formation potential.Our experimental results indicated that the in situ measurement of the secondary aerosol formation potential could provide important information for evaluating the contributions of local emission and long distance transport to the aerosol pollution.