Transport and transformation of nitrobenzene in Songhua River and calculation of flux and remnant based on quantification analysis

To evaluate the long-term environmental effect of the nitrobenzene precipitated into Songhua River caused by the explosion accident of CNPC Jilin Petrochemical Company, we have proved that three selected cross sections were all in a completely mixed state which was not affected by the neighborhood flow firstly. The research of the main flux of contaminants indicates that the nitrobenzene flux in all cross sections is less and less, and the attenuation trend is gradually slowing down. From the residual remnant of nitrobenzene in different segments calculated according to the related experimental data, we suppose that parts of nitrobenzene remnant are transferred by the bottom sludge adsorption and resolution. A general analysis model was set up from the one-dimensional counter-flow equation, and functions of atmosphere-water exchange process, deposit-water interaction, and river turbulent mixing and dissemination. The results of this quantification analysis are different from the real calculation, while the gross transformation trend is the same, which indicates that both analyses are based on reality and can reflect the transport and transformation of nitrobenzene actually.

Water quality model with multiform of N/P transport and transformation in the Yangtze River Estuary

As the Yangtze River Estuary and adjacent sea have been classified as a problem area with regard to eutrophication, it is important to explore the spatial and temporal variations of nitrogen and phosphorus （N/P） nutrients in this area. Based on danish hydraulic institute （DHI）＇s open platform Ecolab, a hydrodynamic and water quality model was developed for the Yangtze River Estuary, in which the transport and transformation processes of different forms of N/P nutrients were considered. Validations against measured data show that the model is overall reliable. Preliminary application of the model suggests that the model can simulate the characteristics of high phosphorus concentration area in the Yangtze River Estuary, and the high concentration area is closely related to the resuspension process of particulate phosphorus.

Driving mechanisms of nitrogen transport and transformation in lacustrine wetlands

As an essential component of proteins and genetic material for all organisms, nitrogen(N) is one of the major limiting factors that control the dynamics, biodiversity and functioning of lacustrine wetlands, in which intensified N biogeochemical activities take place. Reactive N loaded into wetland ecosystems has been doubled due to various human activities, including industrial, agricultural activities and urbanization. The main driving mechanisms of N transport and transformation in lacustrine wetlands are categorized to pushing forces and pulling forces in this study. Geomorphology, wetland age, N concentrations, and temperature are the main pushing forces(passive forces); whereas water table variation, oxygen concentration, other elements availability, oxidation-reduction potential(Eh) and p H, and microorganisms are the predominant pulling forces(active forces). The direction and kinetic energy of reactions are determined by pulling forces and then are stimulated by pushing forces. These two types of forces are analyzed and discussed separately. Based on the analysis of driving mechanisms, possible solutions to wetland N pollutions are proposed at individual, regional and global scales, respectively. Additional research needs are addressed to obtain a thorough understanding of N transport and transformations in wetlands and to reduce detrimental impacts of excessive N on such fragile ecosystems.