The electro-Fenton process,with its capacity for in-situ H_(2)O_(2)formation and Fe^(2+)regeneration,is a strik-ing alternative to the traditional chemical-Fenton process.However,the frequent requirement of extra bind...The electro-Fenton process,with its capacity for in-situ H_(2)O_(2)formation and Fe^(2+)regeneration,is a strik-ing alternative to the traditional chemical-Fenton process.However,the frequent requirement of extra binders for electrode fabrication leads to low catalyst utilization,a complex fabrication process,and weak conductivity.Herein,a three-dimensional(3D)porous electrode was fabricated in-situ on a Ni foam(NF)substrate integrated with nitrogen-doped carbon nanotubes(N@C)derived from carbonization of zeolitic imidazolate framework-8(ZIF-8)without any binder.The resulting 900/N@C-NF cathode(synthesized at 900℃)was high in surface area,N content,and degree of graphitization,achieved high performance of H_(2)O_(2)production(2.58 mg L^(−1)h^(−1)H_(2)O_(2)/mg catalyst)at-0.7 V(vs.SCE),and enabled prompt regeneration of Fe^(2+).The electro-Fenton system equipped with the 900/N@C-NF cathode was effective in removing a diverse range of organic pollutants,including rhodamine B(Rh B),phenol,bisphenol A(BPA),nitroben-zene(NB),and Cu-ethylenediaminetetraacetic acid(EDTA),and significantly attenuating the concentration of chemical oxygen demand(COD)in the real acid wastewater,exhibiting superior activity and stability.This binder-free and self-supporting electro-Fenton cathode was thus shown to be an attractive candidate for application to wastewater treatment,particularly those rich in organics,acids,and Fe^(3+)/Fe^(2+).展开更多
基金financial support from the Guangdong Special Support Plan for Innovation Teams (No.2019BT02L218)the Science and Technology Planning Project of Guangdong Province,China (No.2019A050510009)+3 种基金the Guangdong Special Support Plan for Young Top-notch Talents (No.2019TQ05L179)the National Natural Science Foundation of China (No.21876052)the Science and Technology Program of Guangzhou,China (No.201904010293)the Fundamental Research Funds for the Central Universities,SCUT (No.2020ZYGXZR055)。
文摘The electro-Fenton process,with its capacity for in-situ H_(2)O_(2)formation and Fe^(2+)regeneration,is a strik-ing alternative to the traditional chemical-Fenton process.However,the frequent requirement of extra binders for electrode fabrication leads to low catalyst utilization,a complex fabrication process,and weak conductivity.Herein,a three-dimensional(3D)porous electrode was fabricated in-situ on a Ni foam(NF)substrate integrated with nitrogen-doped carbon nanotubes(N@C)derived from carbonization of zeolitic imidazolate framework-8(ZIF-8)without any binder.The resulting 900/N@C-NF cathode(synthesized at 900℃)was high in surface area,N content,and degree of graphitization,achieved high performance of H_(2)O_(2)production(2.58 mg L^(−1)h^(−1)H_(2)O_(2)/mg catalyst)at-0.7 V(vs.SCE),and enabled prompt regeneration of Fe^(2+).The electro-Fenton system equipped with the 900/N@C-NF cathode was effective in removing a diverse range of organic pollutants,including rhodamine B(Rh B),phenol,bisphenol A(BPA),nitroben-zene(NB),and Cu-ethylenediaminetetraacetic acid(EDTA),and significantly attenuating the concentration of chemical oxygen demand(COD)in the real acid wastewater,exhibiting superior activity and stability.This binder-free and self-supporting electro-Fenton cathode was thus shown to be an attractive candidate for application to wastewater treatment,particularly those rich in organics,acids,and Fe^(3+)/Fe^(2+).
