Improvement strength is beneficial to the popularization of hollow fiber nanofiltration(NF) membrane.The tri-channel hollow fiber NF membrane was prepared by interfacial polymerization(IP).The high strength tri-channe...Improvement strength is beneficial to the popularization of hollow fiber nanofiltration(NF) membrane.The tri-channel hollow fiber NF membrane was prepared by interfacial polymerization(IP).The high strength tri-channel hollow fiber ultrafiltration(UF) membrane were used as the support membrane,m-phenylenedianline(m-PDA),and polyethylenimine(PEI) were used as aqueous phase monomer,and trimesoyl chloride(TMC) was used as organic phase monomer.Fourier transform infrared spectroscopy(FTIR),scanning electron microscope(SEM),and gas sorption analyzer(GSA) were applied in structural analysis of NF membrane.Polymer FTIR illustrates the IP occurrence between aqueous phase monomer and organic phase monomer.The SEM images of NF membrane show the formation of a thin dense layer on surface of support membrane after IP.The flux(J) of optimal NF membrane is 11.2 L·m-2· h-1 at the 0.35 MPa operating pressure.Its retention(R) for NaCl,Na2SO4,MgCl2,Xylenol orange,and Neutral red is 17.4%,30.2%,16.1%,94.3%,and 51.0%,respectively.The NF membrane is on negative charge and its pore radius distributes between 0.3-2.0 nm.展开更多
Bilayer lipid membranes (BLM) formed from didodecyldimethylammonium bromide were made on the freshly exposed surface of a glassy carbon (GC) and were demonstrated by the ac impedance spectroscopy. The ion channels of ...Bilayer lipid membranes (BLM) formed from didodecyldimethylammonium bromide were made on the freshly exposed surface of a glassy carbon (GC) and were demonstrated by the ac impedance spectroscopy. The ion channels of membrane properties induced by PF -_6 were studied by the cyclic voltammetric methods. Experimental results indicated that the ion channel of BLM was open in the presence of the PF -_6 due to the interaction of PF -_6 with the BLM, while it was switched off in the absence of PF -_6. Because the ion channel behavior was affected by the concentration of PF -_6, a sensor for PF -_6 can be developed.展开更多
基金National High Technology Research and Development Program of China (863 program) (No. 2008AA06Z330)National Technician Service Enterprise Action Program,China (No. 2009GJD00048)
文摘Improvement strength is beneficial to the popularization of hollow fiber nanofiltration(NF) membrane.The tri-channel hollow fiber NF membrane was prepared by interfacial polymerization(IP).The high strength tri-channel hollow fiber ultrafiltration(UF) membrane were used as the support membrane,m-phenylenedianline(m-PDA),and polyethylenimine(PEI) were used as aqueous phase monomer,and trimesoyl chloride(TMC) was used as organic phase monomer.Fourier transform infrared spectroscopy(FTIR),scanning electron microscope(SEM),and gas sorption analyzer(GSA) were applied in structural analysis of NF membrane.Polymer FTIR illustrates the IP occurrence between aqueous phase monomer and organic phase monomer.The SEM images of NF membrane show the formation of a thin dense layer on surface of support membrane after IP.The flux(J) of optimal NF membrane is 11.2 L·m-2· h-1 at the 0.35 MPa operating pressure.Its retention(R) for NaCl,Na2SO4,MgCl2,Xylenol orange,and Neutral red is 17.4%,30.2%,16.1%,94.3%,and 51.0%,respectively.The NF membrane is on negative charge and its pore radius distributes between 0.3-2.0 nm.
基金ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 9835 12 0 )
文摘Bilayer lipid membranes (BLM) formed from didodecyldimethylammonium bromide were made on the freshly exposed surface of a glassy carbon (GC) and were demonstrated by the ac impedance spectroscopy. The ion channels of membrane properties induced by PF -_6 were studied by the cyclic voltammetric methods. Experimental results indicated that the ion channel of BLM was open in the presence of the PF -_6 due to the interaction of PF -_6 with the BLM, while it was switched off in the absence of PF -_6. Because the ion channel behavior was affected by the concentration of PF -_6, a sensor for PF -_6 can be developed.
