A highly selective method for the asymmetric formation of trifluoromethyl-substituted α- and β-aminophos- phonates was described. The reaction proceeded with high yields and good to excellent diastereoselectivity. T...A highly selective method for the asymmetric formation of trifluoromethyl-substituted α- and β-aminophos- phonates was described. The reaction proceeded with high yields and good to excellent diastereoselectivity. The product can be easily converted into corresponding trifluoromethyl-substituted aminophosphoric acids.展开更多
基金Acknowledgement The authors gratefully acknowledge the financial support from National Basic Research Program of China （Nos. 2012CB821600, 2010CB126103）, the Key Program of the National Natural Science Foundation of China （No. 21032006）, National Natural Science Foun- dation of China （Nos. 21172244/21172245/B020304）, Agro-scientific Research in the Public Interest （No. 201103007）, the National Key Technologies R＆D Pro- gram （No. 2011BAE06B05）, and Shanghai Scientific Research Program （No. 10XD 1405200）.
文摘A highly selective method for the asymmetric formation of trifluoromethyl-substituted α- and β-aminophos- phonates was described. The reaction proceeded with high yields and good to excellent diastereoselectivity. The product can be easily converted into corresponding trifluoromethyl-substituted aminophosphoric acids.
