Substituted phenoxy acetyl chloride reacted with trimethyl phosphite to form an unexpected substituted phenoxy acetic acid ester, confirmed by;HNMR, IR and MS. The mechanism suggested is different from that of Arbuzov...Substituted phenoxy acetyl chloride reacted with trimethyl phosphite to form an unexpected substituted phenoxy acetic acid ester, confirmed by;HNMR, IR and MS. The mechanism suggested is different from that of Arbuzov reaction.展开更多
A simple,efficient,and general method has been developed for the one-pot,three-component synthesis ofα-aminophosphonates from condensation reaction of trimethyl phosphite,aryl aldehydes and aryl amines in the presenc...A simple,efficient,and general method has been developed for the one-pot,three-component synthesis ofα-aminophosphonates from condensation reaction of trimethyl phosphite,aryl aldehydes and aryl amines in the presence of CoCl_2-6H_2O under solvent-free conditions.Thusα-aminophosphonates were synthesized relatively quickly in good yields at room temperature.展开更多
文摘Substituted phenoxy acetyl chloride reacted with trimethyl phosphite to form an unexpected substituted phenoxy acetic acid ester, confirmed by;HNMR, IR and MS. The mechanism suggested is different from that of Arbuzov reaction.
文摘A simple,efficient,and general method has been developed for the one-pot,three-component synthesis ofα-aminophosphonates from condensation reaction of trimethyl phosphite,aryl aldehydes and aryl amines in the presence of CoCl_2-6H_2O under solvent-free conditions.Thusα-aminophosphonates were synthesized relatively quickly in good yields at room temperature.
