The Suzuki-Miyaura type coupling reaction of aryl halides with triphenylborane-pyridine was described. The reaction can be catalyzed by Pd（OAc）2 （5 mol%） in presence of Cs2CO3 at 50 ℃ or 80 ℃, and functionalized...The Suzuki-Miyaura type coupling reaction of aryl halides with triphenylborane-pyridine was described. The reaction can be catalyzed by Pd（OAc）2 （5 mol%） in presence of Cs2CO3 at 50 ℃ or 80 ℃, and functionalized biaryls were obtained in good to excellent yields. This protocol is general and can tolerate a wide range of func- tional groups.展开更多
基金This work was supported by the Natural Science Foundation of Zhejiang Province （No. Y407081） andthe Research Foundation of Education Department of Zhejiang Province （No. YZ01018492）.
文摘The Suzuki-Miyaura type coupling reaction of aryl halides with triphenylborane-pyridine was described. The reaction can be catalyzed by Pd（OAc）2 （5 mol%） in presence of Cs2CO3 at 50 ℃ or 80 ℃, and functionalized biaryls were obtained in good to excellent yields. This protocol is general and can tolerate a wide range of func- tional groups.
